Interfacial charge transfer enhancement via formation of binary molecular assemblies on electronically corrugated boron nitride

Tan, A.; Zhang, P. P.

doi:10.1039/c9cp04853g

Title: Interfacial charge transfer enhancement via formation of binary molecular assemblies on electronically corrugated boron nitride

Journal Article · 15 November 2019 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/c9cp04853g · OSTI ID:1602044

Tan, A. ^[1];

^[1]

Michigan State Univ., East Lansing, MI (United States). Dept. of Physics and Astronomy

Using scanning tunneling microscopy/spectroscopy (STM/STS) in conjunction with finite element simulation, we investigate the interfacial behaviors in single-component zinc phthalocyanine (ZnPc) and hexadecafluorinated zinc phthalocyanine (F₁₆ZnPc) molecular overlayers as well as their 1 : 1 mixedphase superstructures on h-BN/Cu(111). We show herein that the formation of the binary molecular superstructure drastically increases the charge transfer between F₁₆ZnPc molecules and the substrate, which is attributed to the greater electrostatic stability of the binary assembly compared to that of the pure phase. This study highlights the significant complication in the design of donor–acceptor molecular thin films as the presence of the substrate, even a weakly interacting one, such as h-BN/metal, can still perturb the intermolecular charge transfer and thereby the physical behaviors of the hybrid system via interfacial processes.

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Research Organization:: Michigan State Univ., East Lansing, MI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division

Grant/Contract Number:: SC0019120

OSTI ID:: 1602044

Alternate ID(s):: OSTI ID: 1575098

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Vol. 21, Issue 47; ISSN 1463-9076

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 4 works

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