Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Cadiau, Amandine; Xie, Lilia S.; Kolobov, Nikita; Shkurenko, Aleksander; Qureshi, Muhammad; Tchalala, Mohamed R.; Park, Sarah S.; Bavykina, Anastasiya; Eddaoudi, Mohamed; Dincă, Mircea; Hendon, Christopher H.; Gascon, Jorge

doi:10.1021/acs.chemmater.9b02462

Title: Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Journal Article · 17 December 2019 · Chemistry of Materials

DOI: https://doi.org/10.1021/acs.chemmater.9b02462 · OSTI ID:1601980

Cadiau, Amandine ^[1]; Xie, Lilia S. ^[2]; Kolobov, Nikita ^[3];

^[3]; Qureshi, Muhammad ^[4]; Tchalala, Mohamed R. ^[3]; Park, Sarah S. ^[2]; Bavykina, Anastasiya ^[3];

^[3];

^[2];

^[5];

^[3]

King Abdullah Univ. of Science and Technology (KAUST), Thuwal, Jeddah (Saudi Arabia); MIT
Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
King Abdullah Univ. of Science and Technology (KAUST), Thuwal, Jeddah (Saudi Arabia)
Univ. of Montpellier (France); French National Centre for Scientific Research (CNRS), Montpellier (France); Ecole Nationale Supérieure de Chimie de Montpellier (ENSCM) (France)
Univ. of Oregon, Eugene, OR (United States)

Nowadays, zirconium metal–organic frameworks attract more attention because of their robustness and their easier predictability in terms of topology. In this work, we have been able to control synthetic parameters in order to construct two new 2D MOFs with the same sql topology. Both materials, ACM-10 and ACM-11, have been characterized by single-crystal X-ray diffraction, thermogravimetric analysis, and UV–vis spectroscopy. Here, their textural, electrochemical, and conductivity properties are presented along with the opportunities that these new topologically interesting scaffolds offer for the design of new structures.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: KAUST Office of Sponsored Research; National Science Foundation (NSF); P.I.A “MOPGA”; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0018235

OSTI ID:: 1601980

Journal Information:: Chemistry of Materials, Journal Name: Chemistry of Materials Journal Issue: 1 Vol. 32; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (56)

Cu ₃ (hexaiminotriphenylene) ₂ : An Electrically Conductive 2D Metal-Organic Framework for Chemiresistive Sensing Campbell, Michael G.; Sheberla, Dennis; Liu, Sophie F. Angewandte Chemie International Edition, Vol. 54, Issue 14 https://doi.org/10.1002/anie.201411854	journal	February 2015
Electrically Conductive Porous Metal-Organic Frameworks Sun, Lei; Campbell, Michael G.; Dincă, Mircea Angewandte Chemie International Edition, Vol. 55, Issue 11 https://doi.org/10.1002/anie.201506219	journal	January 2016
Photo- and Electronically Switchable Spin-Crossover Iron(II) Metal-Organic Frameworks Based on a Tetrathiafulvalene Ligand Wang, Hai-Ying; Ge, Jing-Yuan; Hua, Carol Angewandte Chemie International Edition, Vol. 56, Issue 20 https://doi.org/10.1002/anie.201611824	journal	April 2017
Novel Topology in Semiconducting Tetrathiafulvalene Lanthanide Metal-Organic Frameworks Xie, Lilia S.; Dincă, Mircea Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800068	journal	August 2018
Recent Development and Application of Conductive MOFs Li, Pengfei; Wang, Bo Israel Journal of Chemistry, Vol. 58, Issue 9-10 https://doi.org/10.1002/ijch.201800078	journal	August 2018
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set Kresse, G.; Furthmüller, J. Computational Materials Science, Vol. 6, Issue 1, p. 15-50 https://doi.org/10.1016/0927-0256(96)00008-0	journal	July 1996
Tetrathiafulvalene-based group XV ligands: Synthesis, coordination chemistry and radical cation salts Lorcy, Dominique; Bellec, Nathalie; Fourmigué, Marc Coordination Chemistry Reviews, Vol. 253, Issue 9-10 https://doi.org/10.1016/j.ccr.2008.09.012	journal	May 2009
Functional coordination polymers based on redox-active tetrathiafulvalene and its derivatives Wang, Hai-Ying; Cui, Long; Xie, Jia-Ze Coordination Chemistry Reviews, Vol. 345 https://doi.org/10.1016/j.ccr.2016.10.011	journal	August 2017
Metal–organic frameworks for electrocatalysis Liao, Pei-Qin; Shen, Jian-Qiang; Zhang, Jie-Peng Coordination Chemistry Reviews, Vol. 373 https://doi.org/10.1016/j.ccr.2017.09.001	journal	October 2018
Metal-organic frameworks for direct electrochemical applications Xu, Yuxia; Li, Qing; Xue, Huaiguo Coordination Chemistry Reviews, Vol. 376 https://doi.org/10.1016/j.ccr.2018.08.010	journal	December 2018
Catalytic applications of enzymes encapsulated in metal–organic frameworks Drout, Riki J.; Robison, Lee; Farha, Omar K. Coordination Chemistry Reviews, Vol. 381 https://doi.org/10.1016/j.ccr.2018.11.009	journal	February 2019
Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs Chen, Zhijie; Hanna, Sylvia L.; Redfern, Louis R. Coordination Chemistry Reviews, Vol. 386 https://doi.org/10.1016/j.ccr.2019.01.017	journal	May 2019
Functional metal–organic frameworks for catalytic applications Xu, Chunping; Fang, Ruiqi; Luque, Rafael Coordination Chemistry Reviews, Vol. 388 https://doi.org/10.1016/j.ccr.2019.03.005	journal	June 2019
Recent advances in gas storage and separation using metal–organic frameworks Li, Hao; Wang, Kecheng; Sun, Yujia Materials Today, Vol. 21, Issue 2 https://doi.org/10.1016/j.mattod.2017.07.006	journal	March 2018
Hydrogen Storage in the Expanded Pore Metal–Organic Frameworks M ₂ (dobpdc) (M = Mg, Mn, Fe, Co, Ni, Zn) Gygi, David; Bloch, Eric D.; Mason, Jarad A. Chemistry of Materials, Vol. 28, Issue 4 https://doi.org/10.1021/acs.chemmater.5b04538	journal	February 2016
Revisiting the Incorporation of Ti(IV) in UiO-type Metal–Organic Frameworks: Metal Exchange versus Grafting and Their Implications on Photocatalysis Santaclara, Jara G.; Olivos-Suarez, Alma I.; Gonzalez-Nelson, Adrian Chemistry of Materials, Vol. 29, Issue 21 https://doi.org/10.1021/acs.chemmater.7b03320	journal	October 2017
Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks Rimoldi, Martino; Howarth, Ashlee J.; DeStefano, Matthew R. ACS Catalysis, Vol. 7, Issue 2 https://doi.org/10.1021/acscatal.6b02923	journal	December 2016
Synthesis and Stability of Tagged UiO-66 Zr-MOFs Kandiah, Mathivathani; Nilsen, Merete Hellner; Usseglio, Sandro Chemistry of Materials, Vol. 22, Issue 24 https://doi.org/10.1021/cm102601v	journal	December 2010
Tetrathiafulvalene−Tetracarboxylate: An Intriguing Building Block with Versatility in Coordination Structures and Redox Properties Qin, Yu-Rong; Zhu, Qin-Yu; Huo, Li-Bin Inorganic Chemistry, Vol. 49, Issue 16 https://doi.org/10.1021/ic100546r	journal	August 2010
Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47 Bourrelly, Sandrine; Llewellyn, Philip L.; Serre, Christian Journal of the American Chemical Society, Vol. 127, Issue 39 https://doi.org/10.1021/ja054668v	journal	October 2005
High Charge Mobility in a Tetrathiafulvalene-Based Microporous Metal–Organic Framework Narayan, Tarun C.; Miyakai, Tomoyo; Seki, Shu Journal of the American Chemical Society, Vol. 134, Issue 31 https://doi.org/10.1021/ja3059827	journal	July 2012
Electronic Chemical Potentials of Porous Metal–Organic Frameworks Butler, Keith T.; Hendon, Christopher H.; Walsh, Aron Journal of the American Chemical Society, Vol. 136, Issue 7 https://doi.org/10.1021/ja4110073	journal	February 2014
A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology Feng, Dawei; Gu, Zhi-Yuan; Chen, Ying-Pin Journal of the American Chemical Society, Vol. 136, Issue 51 https://doi.org/10.1021/ja510525s	journal	December 2014
Cation-Dependent Intrinsic Electrical Conductivity in Isostructural Tetrathiafulvalene-Based Microporous Metal–Organic Frameworks Park, Sarah S.; Hontz, Eric R.; Sun, Lei Journal of the American Chemical Society, Vol. 137, Issue 5 https://doi.org/10.1021/ja512437u	journal	January 2015
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
Metal–Organic Framework Nodes as Nearly Ideal Supports for Molecular Catalysts: NU-1000- and UiO-66-Supported Iridium Complexes Yang, Dong; Odoh, Samuel O.; Wang, Timothy C. Journal of the American Chemical Society, Vol. 137, Issue 23, p. 7391-7396 https://doi.org/10.1021/jacs.5b02956	journal	June 2015
Chemiresistive Sensor Arrays from Conductive 2D Metal–Organic Frameworks Campbell, Michael G.; Liu, Sophie F.; Swager, Timothy M. Journal of the American Chemical Society, Vol. 137, Issue 43 https://doi.org/10.1021/jacs.5b09600	journal	October 2015
High Methane Storage Working Capacity in Metal–Organic Frameworks with Acrylate Links Jiang, Juncong; Furukawa, Hiroyasu; Zhang, Yue-Biao Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b05261	journal	August 2016
Measuring and Reporting Electrical Conductivity in Metal–Organic Frameworks: Cd ₂ (TTFTB) as a Case Study Sun, Lei; Park, Sarah S.; Sheberla, Dennis Journal of the American Chemical Society, Vol. 138, Issue 44 https://doi.org/10.1021/jacs.6b09345	journal	October 2016
The Organic Secondary Building Unit: Strong Intermolecular π Interactions Define Topology in MIT-25, a Mesoporous MOF with Proton-Replete Channels Park, Sarah S.; Hendon, Christopher H.; Fielding, Alistair J. Journal of the American Chemical Society, Vol. 139, Issue 10 https://doi.org/10.1021/jacs.6b13176	journal	March 2017
Maximizing the Photocatalytic Activity of Metal–Organic Frameworks with Aminated-Functionalized Linkers: Substoichiometric Effects in MIL-125-NH ₂ Chambers, Matthew B.; Wang, Xia; Ellezam, Laura Journal of the American Chemical Society, Vol. 139, Issue 24 https://doi.org/10.1021/jacs.7b02186	journal	June 2017
Increased Electrical Conductivity in a Mesoporous Metal–Organic Framework Featuring Metallacarboranes Guests Kung, Chung-Wei; Otake, Kenichi; Buru, Cassandra T. Journal of the American Chemical Society, Vol. 140, Issue 11 https://doi.org/10.1021/jacs.8b00605	journal	February 2018
Breathing-Dependent Redox Activity in a Tetrathiafulvalene-Based Metal–Organic Framework Souto, Manuel; Romero, Jorge; Calbo, Joaquín Journal of the American Chemical Society, Vol. 140, Issue 33 https://doi.org/10.1021/jacs.8b05890	journal	July 2018
Bulk-to-Surface Proton-Coupled Electron Transfer Reactivity of the Metal–Organic Framework MIL-125 Saouma, Caroline T.; Richard, Sarah; Smolders, Simon Journal of the American Chemical Society, Vol. 140, Issue 47 https://doi.org/10.1021/jacs.8b09120	journal	October 2018
Redox-switchable breathing behavior in tetrathiafulvalene-based metal–organic frameworks Su, Jian; Yuan, Shuai; Wang, Hai-Ying Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-02256-y	journal	December 2017
Topologically guided tuning of Zr-MOF pore structures for highly selective separation of C6 alkane isomers Wang, Hao; Dong, Xinglong; Lin, Junzhong Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04152-5	journal	May 2018
Electronic origins of photocatalytic activity in d0 metal organic frameworks Nasalevich, Maxim A.; Hendon, Christopher H.; Santaclara, Jara G. Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep23676	journal	March 2016
Diverse π–π stacking motifs modulate electrical conductivity in tetrathiafulvalene-based metal–organic frameworks Xie, Lilia S.; Alexandrov, Eugeny V.; Skorupskii, Grigorii Chemical Science, Vol. 10, Issue 37 https://doi.org/10.1039/C9SC03348C	journal	January 2019
Tetrathiafulvalene (TTF) derivatives: key building-blocks for switchable processes Canevet, David; Sallé, Marc; Zhang, Guanxin Chemical Communications, Issue 17 https://doi.org/10.1039/b818607n	journal	January 2009
Zr-based metal–organic frameworks: design, synthesis, structure, and applications Bai, Yan; Dou, Yibo; Xie, Lin-Hua Chemical Society Reviews, Vol. 45, Issue 8 https://doi.org/10.1039/c5cs00837a	journal	January 2016
Exploiting redox activity in metal–organic frameworks: concepts, trends and perspectives D'Alessandro, D. M. Chemical Communications, Vol. 52, Issue 58 https://doi.org/10.1039/c6cc00805d	journal	January 2016
Metal–organic and covalent organic frameworks as single-site catalysts Rogge, S. M. J.; Bavykina, A.; Hajek, J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00033b	journal	January 2017
An updated roadmap for the integration of metal–organic frameworks with electronic devices and chemical sensors Stassen, Ivo; Burtch, Nicholas; Talin, Alec Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00122c	journal	January 2017
Gas/vapour separation using ultra-microporous metal–organic frameworks: insights into the structure/separation relationship Adil, Karim; Belmabkhout, Youssef; Pillai, Renjith S. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/c7cs00153c	journal	January 2017
A highly stable and hierarchical tetrathiafulvalene-based metal–organic framework with improved performance as a solid catalyst Souto, Manuel; Santiago-Portillo, Andrea; Palomino, Miguel Chemical Science, Vol. 9, Issue 9 https://doi.org/10.1039/c7sc04829g	journal	January 2018
Conductive two-dimensional metal–organic frameworks as multifunctional materials Ko, Michael; Mendecki, Lukasz; Mirica, Katherine A. Chemical Communications, Vol. 54, Issue 57 https://doi.org/10.1039/c8cc02871k	journal	January 2018
Revisiting the structural homogeneity of NU-1000, a Zr-based metal–organic framework Islamoglu, Timur; Otake, Ken-ichi; Li, Peng CrystEngComm, Vol. 20, Issue 39 https://doi.org/10.1039/c8ce00455b	journal	January 2018
A porous, electrically conductive hexa-zirconium( iv ) metal–organic framework Goswami, Subhadip; Ray, Debmalya; Otake, Ken-ichi Chemical Science, Vol. 9, Issue 19 https://doi.org/10.1039/c8sc00961a	journal	January 2018
Sodium-coupled electron transfer reactivity of metal–organic frameworks containing titanium clusters: the importance of cations in redox chemistry Saouma, Caroline T.; Tsou, Chih-Chin; Richard, Sarah Chemical Science, Vol. 10, Issue 5 https://doi.org/10.1039/c8sc04138e	journal	January 2019
Topology and porosity control of metal–organic frameworks through linker functionalization Lyu, Jiafei; Zhang, Xuan; Otake, Ken-ichi Chemical Science, Vol. 10, Issue 4 https://doi.org/10.1039/c8sc04220a	journal	January 2019
Influence of the exchange screening parameter on the performance of screened hybrid functionals Krukau, Aliaksandr V.; Vydrov, Oleg A.; Izmaylov, Artur F. The Journal of Chemical Physics, Vol. 125, Issue 22 https://doi.org/10.1063/1.2404663	journal	December 2006
Restoring the Density-Gradient Expansion for Exchange in Solids and Surfaces Perdew, John P.; Ruzsinszky, Adrienn; Csonka, Gábor I. Physical Review Letters, Vol. 100, Issue 13 https://doi.org/10.1103/physrevlett.100.136406	journal	April 2008
WinGX and ORTEP for Windows : an update Farrugia, Louis J. Journal of Applied Crystallography, Vol. 45, Issue 4 https://doi.org/10.1107/s0021889812029111	journal	July 2012
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/s2053229614024218	journal	January 2015
A metal-organic framework-based splitter for separating propylene from propane Cadiau, A.; Adil, K.; Bhatt, P. M. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf6323	journal	July 2016
Hydrolytically stable fluorinated metal-organic frameworks for energy-efficient dehydration Cadiau, Amandine; Belmabkhout, Youssef; Adil, Karim Science, Vol. 356, Issue 6339 https://doi.org/10.1126/science.aam8310	journal	May 2017

Linked Research (2)

Similar Records

Recent progress in the synthesis of metal–organic frameworks

Journal Article · 2015 · Science and Technology of Advanced Materials · OSTI ID:1239842

Sun, Yujia; Zhou, Hong -Cai

A versatile synthetic route for the preparation of titanium metal–organic frameworks

Journal Article · 2015 · Chemical Science · OSTI ID:1236869

Zou, Lanfang; Feng, Dawei; Liu, Tian-Fu; +6 more

Catalytic Zirconium/Hafnium-Based Metal–Organic Frameworks

Journal Article · 2016 · ACS Catalysis · OSTI ID:1871000

Rimoldi, Martino; Howarth, Ashlee J.; DeStefano, Matthew R.; +5 more

Related Subjects

36 MATERIALS SCIENCE
Cluster chemistry
Electrical conductivity
Ligands
Materials
Metal organic frameworks

CCDC 1910185: Experimental Crystal Structure Determination Amandine, Cadiau,; S., Xie, Lilia; Nikita, Kolobov, https://doi.org/10.5517/ccdc.csd.cc223pws The current record is supplemented by this dataset	dataset	January 2020
CCDC 1910226: Experimental Crystal Structure Determination Amandine, Cadiau,; S., Xie, Lilia; Nikita, Kolobov, https://doi.org/10.5517/ccdc.csd.cc223r65 The current record is supplemented by this dataset	dataset	January 2020

Title: Toward New 2D Zirconium-Based Metal–Organic Frameworks: Synthesis, Structures, and Electronic Properties

Citation Formats

References (56)

Linked Research (2)

Similar Records

Related Subjects