skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on February 23, 2021

Title: Unconventional crystal-field splitting in noncentrosymmetric BaTiO 3 thin films

Authors:
ORCiD logo; ; ORCiD logo; ; ; ORCiD logo; ; ; ; ; ; ;
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1601703
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Physical Review Materials
Additional Journal Information:
Journal Name: Physical Review Materials Journal Volume: 4 Journal Issue: 2; Journal ID: ISSN 2475-9953
Publisher:
American Physical Society
Country of Publication:
United States
Language:
English

Citation Formats

Song, Yang, Liu, Xiaoran, Wen, Fangdi, Kareev, M., Zhang, Ruyi, Pei, Yujuan, Bi, Jiachang, Shafer, Padraic, N'Diaye, Alpha T., Arenholz, Elke, Park, Se Young, Cao, Yanwei, and Chakhalian, J. Unconventional crystal-field splitting in noncentrosymmetric BaTiO 3 thin films. United States: N. p., 2020. Web. doi:10.1103/PhysRevMaterials.4.024413.
Song, Yang, Liu, Xiaoran, Wen, Fangdi, Kareev, M., Zhang, Ruyi, Pei, Yujuan, Bi, Jiachang, Shafer, Padraic, N'Diaye, Alpha T., Arenholz, Elke, Park, Se Young, Cao, Yanwei, & Chakhalian, J. Unconventional crystal-field splitting in noncentrosymmetric BaTiO 3 thin films. United States. doi:10.1103/PhysRevMaterials.4.024413.
Song, Yang, Liu, Xiaoran, Wen, Fangdi, Kareev, M., Zhang, Ruyi, Pei, Yujuan, Bi, Jiachang, Shafer, Padraic, N'Diaye, Alpha T., Arenholz, Elke, Park, Se Young, Cao, Yanwei, and Chakhalian, J. Mon . "Unconventional crystal-field splitting in noncentrosymmetric BaTiO 3 thin films". United States. doi:10.1103/PhysRevMaterials.4.024413.
@article{osti_1601703,
title = {Unconventional crystal-field splitting in noncentrosymmetric BaTiO 3 thin films},
author = {Song, Yang and Liu, Xiaoran and Wen, Fangdi and Kareev, M. and Zhang, Ruyi and Pei, Yujuan and Bi, Jiachang and Shafer, Padraic and N'Diaye, Alpha T. and Arenholz, Elke and Park, Se Young and Cao, Yanwei and Chakhalian, J.},
abstractNote = {},
doi = {10.1103/PhysRevMaterials.4.024413},
journal = {Physical Review Materials},
number = 2,
volume = 4,
place = {United States},
year = {2020},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on February 23, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Anomalous orbital structure in a spinel–perovskite interface
journal, August 2016


Evolution of element-specific electronic structures in alkaline titanates
journal, June 2019

  • Fan, Wei; Song, Yang; Bi, Jiachang
  • AIP Advances, Vol. 9, Issue 6
  • DOI: 10.1063/1.5109588

Projector augmented-wave method
journal, December 1994


Magnetism and electronic structure of YTiO3 thin films
journal, September 2015

  • Cao, Yanwei; Shafer, P.; Liu, Xiaoran
  • Applied Physics Letters, Vol. 107, Issue 11
  • DOI: 10.1063/1.4931039

An updated version of wannier90: A tool for obtaining maximally-localised Wannier functions
journal, August 2014

  • Mostofi, Arash A.; Yates, Jonathan R.; Pizzi, Giovanni
  • Computer Physics Communications, Vol. 185, Issue 8
  • DOI: 10.1016/j.cpc.2014.05.003

Two-Dimensional Electron Gases at LaAlO 3 / SrTiO 3 Interfaces: Orbital Symmetry and Hierarchy Engineered by Crystal Orientation
journal, October 2014


Artificial two-dimensional polar metal at room temperature
journal, April 2018


Why Are There so Few Magnetic Ferroelectrics?
journal, July 2000

  • Hill, Nicola A.
  • The Journal of Physical Chemistry B, Vol. 104, Issue 29
  • DOI: 10.1021/jp000114x

Electric field control of magnetic anisotropies and magnetic coercivity in Fe/BaTiO3(001) heterostructures
journal, February 2011

  • Brivio, S.; Petti, D.; Bertacco, R.
  • Applied Physics Letters, Vol. 98, Issue 9
  • DOI: 10.1063/1.3554432

Thin-film ferroelectric materials and their applications
journal, November 2016


Two-dimensional electron systems in A TiO 3 perovskites ( A = Ca , Ba, Sr): Control of orbital hybridization and energy order
journal, July 2017


Ferroelectricity woos pairing
journal, April 2017

  • Gabay, Marc; Triscone, Jean-Marc
  • Nature Physics, Vol. 13, Issue 7
  • DOI: 10.1038/nphys4124

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999


Ferroelectric Schottky Diode
journal, October 1994


A ferroelectric quantum phase transition inside the superconducting dome of Sr1−xCaxTiO3−δ
journal, April 2017

  • Rischau, Carl Willem; Lin, Xiao; Grams, Christoph P.
  • Nature Physics, Vol. 13, Issue 7
  • DOI: 10.1038/nphys4085

The pressure temperature phase diagram of BaTiO 3 : a macroscopic description of the low-temperature behaviour
journal, August 2002


Origin of ferroelectricity in perovskite oxides
journal, July 1992


Fatigue of piezoelectric properties in Pb(Zr,Ti)O 3 films
journal, April 1996

  • Kholkin, A. L.; Colla, E. L.; Tagantsev, A. K.
  • Applied Physics Letters, Vol. 68, Issue 18
  • DOI: 10.1063/1.116189

Manipulation of Electric Field Effect by Orbital Switch
journal, December 2015

  • Cui, Bin; Song, Cheng; Mao, Haijun
  • Advanced Functional Materials, Vol. 26, Issue 5
  • DOI: 10.1002/adfm.201504036

Enhancement of Ferroelectricity in Strained BaTiO3 Thin Films
journal, November 2004


Theory of polarization of crystalline solids
journal, January 1993


Probing ferroelectricity in PbZr 0.2 Ti 0.8 O 3 with polarized soft x rays
journal, October 2010


Magnetic Interactions at the Nanoscale in Trilayer Titanates
journal, February 2016


Macroscopic polarization in crystalline dielectrics: the geometric phase approach
journal, July 1994


Orbital Reconstruction and the Two-Dimensional Electron Gas at the LaAlO3/SrTiO3 Interface
journal, April 2009


Strong polarization enhancement in asymmetric three-component ferroelectric superlattices
journal, January 2005

  • Lee, Ho Nyung; Christen, Hans M.; Chisholm, Matthew F.
  • Nature, Vol. 433, Issue 7024
  • DOI: 10.1038/nature03261

Structures of the ferroelectric phases of barium titanate
journal, March 1993

  • Kwei, G. H.; Lawson, A. C.; Billinge, S. J. L.
  • The Journal of Physical Chemistry, Vol. 97, Issue 10
  • DOI: 10.1021/j100112a043

MATERIALS SCIENCE: The Renaissance of Magnetoelectric Multiferroics
journal, July 2005


Local Jahn-Teller distortion in La 1 x Sr x MnO 3 observed by pulsed neutron diffraction
journal, October 1997


Titanium dx y ferromagnetism at the LaAlO3/SrTiO3 interface
journal, June 2013

  • Lee, J. -S.; Xie, Y. W.; Sato, H. K.
  • Nature Materials, Vol. 12, Issue 8
  • DOI: 10.1038/nmat3674

Pseudo Jahn–Teller origin of ferroelectric instability in BaTiO3 type perovskites: The Green's function approach and beyond
journal, January 2015


Ferroelectrically tunable magnetic skyrmions in ultrathin oxide heterostructures
journal, November 2018


Origin of Interface Magnetism in BiMnO 3 / SrTiO 3 and LaAlO 3 / SrTiO 3 Heterostructures
journal, August 2013


Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996


Polar metal phase stabilized in strained La-doped BaTiO3films
journal, July 2017


The CTM4XAS program for EELS and XAS spectral shape analysis of transition metal L edges
journal, October 2010


On the origin of ferroelectricity in perovskite-type crystals
journal, April 1966


Ab initio study of the phase diagram of epitaxial BaTiO 3
journal, June 2004


Electric in-plane polarization in multiferroic CoFe2O4/BaTiO3 nanocomposite tuned by magnetic fields
journal, June 2013

  • Schmitz-Antoniak, Carolin; Schmitz, Detlef; Borisov, Pavel
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3051

Ferroelectric thin films: Review of materials, properties, and applications
journal, September 2006

  • Setter, N.; Damjanovic, D.; Eng, L.
  • Journal of Applied Physics, Vol. 100, Issue 5
  • DOI: 10.1063/1.2336999

Ferroelectric Properties of Individual Barium Titanate Nanowires Investigated by Scanned Probe Microscopy
journal, May 2002

  • Yun, Wan Soo; Urban, Jeffrey J.; Gu, Qian
  • Nano Letters, Vol. 2, Issue 5, p. 447-450
  • DOI: 10.1021/nl015702g

Phase Diagram of BaTi O 3
journal, March 1997


Ground State of the Electron Gas by a Stochastic Method
journal, August 1980


Physics of thin-film ferroelectric oxides
journal, October 2005


Multiferroics progress and prospects in thin films
journal, January 2007

  • Ramesh, R.; Spaldin, Nicola A.
  • Nature Materials, Vol. 6, Issue 1, p. 21-29
  • DOI: 10.1038/nmat1805

Strain modification of epitaxial perovskite oxide thin films using structural transitions of ferroelectric BaTiO3 substrate
journal, November 2000

  • Lee, M. K.; Nath, T. K.; Eom, C. B.
  • Applied Physics Letters, Vol. 77, Issue 22
  • DOI: 10.1063/1.1328762

Crystal Structure and the Paraelectric-to-Ferroelectric Phase Transition of Nanoscale BaTiO 3
journal, June 2008

  • Smith, Millicent B.; Page, Katharine; Siegrist, Theo
  • Journal of the American Chemical Society, Vol. 130, Issue 22
  • DOI: 10.1021/ja0758436

Orbital configuration in CaTiO3 films on NdGaO3
journal, October 2016

  • Cao, Yanwei; Park, Se Young; Liu, Xiaoran
  • Applied Physics Letters, Vol. 109, Issue 15
  • DOI: 10.1063/1.4964828

Structural and Electronic Reconstructions at the LaAlO 3 /SrTiO 3 Interface
journal, February 2013


Interface-induced multiferroism by design in complex oxide superlattices
journal, June 2017

  • Guo, Hangwen; Wang, Zhen; Dong, Shuai
  • Proceedings of the National Academy of Sciences
  • DOI: 10.1073/pnas.1706814114

L 2 , 3 x-ray-absorption edges of d 0 compounds: K + , Ca 2 + , Sc 3 + , and Ti 4 + in O h (octahedral) symmetry
journal, January 1990


Polar instability under electrostatic doping in tetragonal SnTi O 3
journal, July 2017


Strain-engineering stabilization of BaTi O 3 -based polar metals
journal, March 2018


Multiferroic and magnetoelectric materials
journal, August 2006

  • Eerenstein, W.; Mathur, N. D.; Scott, J. F.
  • Nature, Vol. 442, Issue 7104
  • DOI: 10.1038/nature05023

Strain Tuning of Ferroelectric Thin Films
journal, August 2007