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Title: Cationic and anionic redox in lithium-ion based batteries

Journal Article · · Chemical Society Reviews
DOI: https://doi.org/10.1039/C8CS00426A · OSTI ID:1601688
ORCiD logo [1];  [2];  [2]; ORCiD logo [3]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [2]
  1. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, USA, Department of Chemical Engineering
  2. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, USA
  3. Department of Chemical Engineering, Waterloo Institute of Nanotechnology, University of Waterloo, Waterloo, Canada
  4. Chemical Sciences and Engineering Division, Argonne National Laboratory, Lemont, USA, Department of Material Science and Engineering
  5. School of Materials Science and Engineering, Tianjin University, Tianjin, China

This review will present the current understanding, experimental evidence and future direction of anionic and cationic redox for Li-ion batteries.

Sponsoring Organization:
USDOE
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1601688
Journal Information:
Chemical Society Reviews, Journal Name: Chemical Society Reviews Vol. 49 Journal Issue: 6; ISSN 0306-0012
Publisher:
Royal Society of Chemistry (RSC)Copyright Statement
Country of Publication:
United Kingdom
Language:
English
Citation Metrics:
Cited by: 128 works
Citation information provided by
Web of Science

References (120)

Crystal and electronic structure analysis and thermodynamic stabilities for electrochemically or chemically delithiated Li1.2−xMn0.54Ni0.13Co0.13O2 journal July 2016
Improved capacity retention in rechargeable 4 V lithium/lithium-manganese oxide (spinel) cells journal April 1994
A Lithium-Sulfur Battery using a 2D Current Collector Architecture with a Large-Sized Sulfur Host Operated under High Areal Loading and Low E/S Ratio journal October 2018
Evidence for anionic redox activity in a tridimensional-ordered Li-rich positive electrode β-Li2IrO3 journal February 2017
Review on anionic redox for high-capacity lithium- and sodium-ion batteries journal April 2017
Unified picture of anionic redox in Li/Na-ion batteries journal March 2019
The structural and chemical origin of the oxygen redox activity in layered and cation-disordered Li-excess cathode materials journal May 2016
The effects of Na doping on performance of layered Li1.1−xNax[Ni0.2Co0.3Mn0.4]O2 materials for lithium secondary batteries journal February 2006
Calibrating transition-metal energy levels and oxygen bands in first-principles calculations: Accurate prediction of redox potentials and charge transfer in lithium transition-metal oxides journal September 2015
Thermodynamic Activation of Charge Transfer in Anionic Redox Process for Li-Ion Batteries journal November 2017
Anion Redox Chemistry in the Cobalt Free 3d Transition Metal Oxide Intercalation Electrode Li[Li 0.2 Ni 0.2 Mn 0.6 ]O 2 journal August 2016
Aprotic and Aqueous Li–O2 Batteries journal April 2014
Why LiFePO 4 is a safe battery electrode: Coulomb repulsion induced electron-state reshuffling upon lithiation journal January 2015
Disordered Lithium-Rich Oxyfluoride as a Stable Host for Enhanced Li + Intercalation Storage journal February 2015
Enhanced cycling stability of Li[Li0.2Mn0.54Ni0.13Co0.13]O2 by surface modification of MgO with melting impregnation method journal January 2013
A New Sealed Lithium-Peroxide Battery with a Co-Doped Li2O Cathode in a Superconcentrated Lithium Bis(fluorosulfonyl)amide Electrolyte journal July 2014
Revealing reaction mechanisms of nanoconfined Li 2 S: implications for lithium–sulfur batteries journal January 2018
High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure journal June 2015
Hidden structural and chemical order controls lithium transport in cation-disordered oxides for rechargeable batteries journal February 2019
Vapor-Phase Atomic-Controllable Growth of Amorphous Li 2 S for High-Performance Lithium–Sulfur Batteries journal October 2014
Co-intercalation of Mg 2+ and Na + in Na 0.69 Fe 2 (CN) 6 as a High-Voltage Cathode for Magnesium Batteries journal March 2016
Transition-metal dichalcogenides from disintercalation processes. Crystal structure determination and Mossbauer study of Li 2 FeS 2 and its disintercalates Li x FeS 2 (0.2⩽x⩽2) journal September 1987
High Voltage Magnesium-ion Battery Enabled by Nanocluster Mg 3 Bi 2 Alloy Anode in Noncorrosive Electrolyte journal April 2018
Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries journal March 2015
Revealing the Electrochemical Charging Mechanism of Nanosized Li 2 S by in Situ and Operando X-ray Absorption Spectroscopy journal July 2017
Spectroscopic Signature of Oxidized Oxygen States in Peroxides journal October 2018
Understanding the Anomalous Capacity of Li / Li [ NixLi ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ]  O2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies journal January 2002
Anionic Redox in Rechargeable Lithium Batteries journal June 2017
Evolution of redox couples in Li- and Mn-rich cathode materials and mitigation of voltage fade by reducing oxygen release journal July 2018
Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and Challenges journal January 2015
Metal–oxygen decoordination stabilizes anion redox in Li-rich oxides journal February 2019
Li-rich layered composite Li[Li0.2Ni0.2Mn0.6]O2 synthesized by a novel approach as cathode material for lithium ion battery journal May 2013
Improved Cycling Performance of Li-Excess Cation-Disordered Cathode Materials upon Fluorine Substitution journal November 2018
An artificial interphase enables reversible magnesium chemistry in carbonate electrolytes journal April 2018
Functioning Mechanism of AlF 3 Coating on the Li- and Mn-Rich Cathode Materials journal November 2014
Identification of cathode materials for lithium batteries guided by first-principles calculations journal April 1998
Investigating phase transformation in the Li1.2Co0.1Mn0.55Ni0.15O2 lithium-ion battery cathode during high-voltage hold (4.5 V) via magnetic, X-ray diffraction and electron microscopy studies journal January 2013
Elucidating anionic oxygen activity in lithium-rich layered oxides journal March 2018
High-Capacity Micrometer-Sized Li2 S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries journal September 2012
Direct Experimental Probe of the Ni(II)/Ni(III)/Ni(IV) Redox Evolution in LiNi 0.5 Mn 1.5 O 4 Electrodes journal November 2015
Origin of stabilization and destabilization in solid-state redox reaction of oxide ions for lithium-ion batteries journal December 2016
Aqueous lithium-air batteries with a lithium-ion conducting solid electrolyte Li1.3Al0.5Nb0.2Ti1.3(PO4)3 journal April 2018
Anion-redox nanolithia cathodes for Li-ion batteries journal July 2016
Electrochemical performance of cobalt free, Li1.2(Mn0.32Ni0.32Fe0.16)O2 cathodes for lithium batteries journal April 2012
High Performance Li 2 Ru 1– y Mn y O 3 (0.2 ≤ y ≤ 0.8) Cathode Materials for Rechargeable Lithium-Ion Batteries: Their Understanding journal March 2013
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes journal July 2013
Burning lithium in CS2 for high-performing compact Li2S–graphene nanocapsules for Li–S batteries journal June 2017
Layered Cathode Materials Li[Ni[sub x]Li[sub (1/3−2x/3)]Mn[sub (2/3−x/3)]]O[sub 2] for Lithium-Ion Batteries journal January 2001
Surface Modification of Over-Lithiated Layered Oxides with PEDOT:PSS Conducting Polymer in Lithium-Ion Batteries journal January 2015
Surface Modification of Li 1.2 Ni 0.13 Mn 0.54 Co 0.13 O 2 by Hydrazine Vapor as Cathode Material for Lithium-Ion Batteries journal July 2015
A lithium–oxygen battery based on lithium superoxide journal January 2016
Band gaps and electronic structure of transition-metal compounds journal July 1985
State-of-the-art characterization techniques for advanced lithium-ion batteries journal March 2017
Reversible Mn2+/Mn4+ double redox in lithium-excess cathode materials journal April 2018
Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries journal March 2014
Al Doping for Mitigating the Capacity Fading and Voltage Decay of Layered Li and Mn-Rich Cathodes for Li-Ion Batteries journal February 2016
Anionic and cationic redox and interfaces in batteries: Advances from soft X-ray absorption spectroscopy to resonant inelastic scattering journal June 2018
Resonant X-Ray Emission Spectroscopy of Molecular Oxygen journal April 1996
Requirements for reversible extra-capacity in Li-rich layered oxides for Li-ion batteries journal January 2017
Electron-energy-loss near-edge structures in the oxygen K -edge spectra of transition-metal oxides journal May 1993
Anionic redox processes for electrochemical devices journal January 2016
Role of Oxygen Holes in Li x CoO 2 Revealed by Soft X-Ray Spectroscopy journal August 2013
Correlation Between Oxygen Vacancy, Microstrain, and Cation Distribution in Lithium-Excess Layered Oxides During the First Electrochemical Cycle journal April 2013
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries journal January 2014
The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteries journal January 2016
Understanding the Roles of Anionic Redox and Oxygen Release during Electrochemical Cycling of Lithium-Rich Layered Li 4 FeSbO 6 journal April 2015
A lithium–oxygen battery with a long cycle life in an air-like atmosphere journal March 2018
Fundamental interplay between anionic/cationic redox governing the kinetics and thermodynamics of lithium-rich cathodes journal December 2017
Enhanced oxygen reduction with single-atomic-site iron catalysts for a zinc-air battery and hydrogen-air fuel cell journal December 2018
In Situ Structural and Electrochemical Study of Ni1−xCoxO2 Metastable Oxides Prepared by Soft Chemistry journal October 1999
Origin of voltage decay in high-capacity layered oxide electrodes journal December 2014
Li 2 S- or S-Based Lithium-Ion Batteries journal July 2018
Understanding the Charging Mechanism of Lithium-Sulfur Batteries Using Spatially Resolved Operando X-Ray Absorption Spectroscopy journal January 2016
A disordered rock-salt Li-excess cathode material with high capacity and substantial oxygen redox activity: Li 1.25 Nb 0.25 Mn 0.5 O 2 journal November 2015
Multifunctional AlPO 4 Coating for Improving Electrochemical Properties of Low-Cost Li[Li 0.2 Fe 0.1 Ni 0.15 Mn 0.55 ]O 2 Cathode Materials for Lithium-Ion Batteries journal February 2015
Material Design Concept of Lithium‐Excess Electrode Materials with Rocksalt‐Related Structures for Rechargeable Non‐Aqueous Batteries journal October 2018
Electrochemical Behavior of Layered Solid Solution Li2MnO3−LiMO2 (M = Ni, Mn, Co) Li-Ion Cathodes with and without Alumina Coatings journal January 2011
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteries journal December 2015
Confession of a Magnesium Battery journal August 2015
Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in LixCoO2 journal January 1992
Oxygen 1 s x-ray-absorption edges of transition-metal oxides journal September 1989
Commercialization of Lithium Battery Technologies for Electric Vehicles journal June 2019
Structure and electrochemistry of LiMO2 (M=Ti, Mn, Fe, Co, Ni) prepared by mechanochemical synthesis journal September 1998
Lithium metal rechargeable cells using Li2MnO3 as the positive electrode journal July 1999
Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl 6 x ( x = 3, 2) journal February 2015
Electrochemically primed functional redox mediator generator from the decomposition of solid state electrolyte journal April 2019
Review on Challenges and Recent Advances in the Electrochemical Performance of High Capacity Li- and Mn-Rich Cathode Materials for Li-Ion Batteries journal December 2017
A nanostructured cathode architecture for low charge overpotential in lithium-oxygen batteries journal August 2013
A high-energy-density and long-life lithium-ion battery via reversible oxide–peroxide conversion journal October 2019
Enhancing the Kinetics of Li-Rich Cathode Materials through the Pinning Effects of Gradient Surface Na + Doping journal December 2015
Charge-compensation in 3d-transition-metal-oxide intercalation cathodes through the generation of localized electron holes on oxygen journal March 2016
Structure, and magnetic and electrochemical properties of layered oxides, Li2IrO3 journal February 2003
30 Years of Lithium-Ion Batteries journal June 2018
Recent advances in zinc–air batteries journal January 2014
Compact high volumetric and areal capacity lithium sulfur batteries through rock salt induced nano-architectured sulfur hosts journal January 2017
Corrosion/Fragmentation of Layered Composite Cathode and Related Capacity/Voltage Fading during Cycling Process journal July 2013
Understanding materials challenges for rechargeable ion batteries with in situ transmission electron microscopy journal August 2017
Ligand K-edge X-ray absorption spectroscopy: covalency of ligand–metal bonds journal January 2005
Oxygen Contribution on Li-Ion Intercalation−Deintercalation in LiCoO 2 Investigated by O K-Edge and Co L-Edge X-ray Absorption Spectroscopy journal March 2002
Combined NMR and XAS Study on Local Environments and Electronic Structures of Electrochemically Li-Ion Deintercalated Li[sub 1−x]Co[sub 1/3]Ni[sub 1/3]Mn[sub 1/3]O[sub 2] Electrode System journal January 2004
High Reversibility of Lattice Oxygen Redox Quantified by Direct Bulk Probes of Both Anionic and Cationic Redox Reactions journal February 2019
Mechanism of Exact Transition between Cationic and Anionic Redox Activities in Cathode Material Li 2 FeSiO 4 journal October 2018
Structural and Electrochemical Study of Al 2 O 3 and TiO 2 Coated Li 1.2 Ni 0.13 Mn 0.54 Co 0.13 O 2 Cathode Material Using ALD journal June 2013
Neutron Diffraction and Magnetic Susceptibility Studies on a High-Voltage Li 1.2 Mn 0.55 Ni 0.15 Co 0.10 O 2 Lithium Ion Battery Cathode: Insight into the Crystal Structure journal September 2013
A new active Li–Mn–O compound for high energy density Li-ion batteries journal November 2015
Chemical versus Electrochemical Electrolyte Oxidation on NMC111, NMC622, NMC811, LNMO, and Conductive Carbon journal September 2017
Functional surface modifications of a high capacity layered Li[Li0.2Mn0.54Ni0.13Co0.13]O2 cathode journal January 2010
Thick Electrodes for High Energy Lithium Ion Batteries journal January 2015
The Configurational Space of Rocksalt-Type Oxides for High-Capacity Lithium Battery Electrodes journal May 2014
Anion–Cation Redox Competition and the Formation of New Compounds in Highly Covalent Systems journal September 1996
Coupling between oxygen redox and cation migration explains unusual electrochemistry in lithium-rich layered oxides journal December 2017
Distinct charge dynamics in battery electrodes revealed by in situ and operando soft X-ray spectroscopy journal October 2013
Understanding the Role of Ni in Stabilizing the Lithium-Rich High-Capacity Cathode Material Li[Ni x Li (1–2 x )/3 Mn (2– x )/3 ]O 2 (0 ≤ x ≤ 0.5) journal December 2014
Oxygen Release and Its Effect on the Cycling Stability of LiNi x Mn y Co z O 2 (NMC) Cathode Materials for Li-Ion Batteries journal January 2017
A highly ordered nanostructured carbon–sulphur cathode for lithium–sulphur batteries journal May 2009
Lithium manganese oxides from Li2MnO3 for rechargeable lithium battery applications journal June 1991
Enabling the high capacity of lithium-rich anti-fluorite lithium iron oxide by simultaneous anionic and cationic redox journal December 2017
LixCoO2 (0<-1): A new cathode material for batteries of high energy density journal June 1980
Interplay of cation and anion redox in Li 4 Mn 2 O 5 cathode material and prediction of improved Li 4 (Mn,M) 2 O 5 electrodes for Li-ion batteries journal May 2018
Minimization of the cation mixing in Li1+x(NMC)1−xO2 as cathode material journal March 2010

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