skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on February 24, 2021

Title: Direct Nano‐Synthesis Methods Notably Benefit Mg‐Battery Cathode Performance

Authors:
 [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Joint Center for Energy Storage ResearchDepartment of Chemistry and the Waterloo Institute for NanotechnologyUniversity of Waterloo Waterloo Ontario N2L 3G1 Canada
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1601678
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Small Methods
Additional Journal Information:
[Journal Name: Small Methods]; Journal ID: ISSN 2366-9608
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Blanc, Lauren E., Sun, Xiaoqi, Shyamsunder, Abhinandan, Duffort, Victor, and Nazar, Linda F. Direct Nano‐Synthesis Methods Notably Benefit Mg‐Battery Cathode Performance. United States: N. p., 2020. Web. doi:10.1002/smtd.202000029.
Blanc, Lauren E., Sun, Xiaoqi, Shyamsunder, Abhinandan, Duffort, Victor, & Nazar, Linda F. Direct Nano‐Synthesis Methods Notably Benefit Mg‐Battery Cathode Performance. United States. doi:10.1002/smtd.202000029.
Blanc, Lauren E., Sun, Xiaoqi, Shyamsunder, Abhinandan, Duffort, Victor, and Nazar, Linda F. Tue . "Direct Nano‐Synthesis Methods Notably Benefit Mg‐Battery Cathode Performance". United States. doi:10.1002/smtd.202000029.
@article{osti_1601678,
title = {Direct Nano‐Synthesis Methods Notably Benefit Mg‐Battery Cathode Performance},
author = {Blanc, Lauren E. and Sun, Xiaoqi and Shyamsunder, Abhinandan and Duffort, Victor and Nazar, Linda F.},
abstractNote = {},
doi = {10.1002/smtd.202000029},
journal = {Small Methods},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on February 24, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Nanostructured binary and ternary metal sulfides: synthesis methods and their application in energy conversion and storage devices
journal, January 2017

  • Kulkarni, Pranav; Nataraj, S. K.; Balakrishna, R. Geetha
  • J. Mater. Chem. A, Vol. 5, Issue 42
  • DOI: 10.1039/C7TA07329A

On the Reliability of Half-Cell Tests for Monovalent (Li + , Na + ) and Divalent (Mg 2+ , Ca 2+ ) Cation Based Batteries
journal, January 2017

  • Tchitchekova, D. S.; Monti, D.; Johansson, P.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.0411707jes

Can Multielectron Intercalation Reactions Be the Basis of Next Generation Batteries?
journal, January 2018


Toward Understanding of Electrical Limitations (Electronic, Ionic) in LiMPO[sub 4] (M=Fe, Mn) Electrode Materials
journal, January 2005

  • Delacourt, C.; Laffont, L.; Bouchet, R.
  • Journal of The Electrochemical Society, Vol. 152, Issue 5
  • DOI: 10.1149/1.1884787

How General is the Conversion Reaction in Mg Battery Cathode: A Case Study of the Magnesiation of α-MnO 2
journal, August 2015


Rapid microwave-assisted preparation of binary and ternary transition metal sulfide compounds
journal, December 2017


One-Step Low-Temperature Route for the Preparation of Electrochemically Active LiMnPO 4 Powders
journal, January 2004

  • Delacourt, C.; Poizot, P.; Morcrette, M.
  • Chemistry of Materials, Vol. 16, Issue 1
  • DOI: 10.1021/cm030347b

Particle Size Effects on the Electrochemical Performance of Copper Oxides toward Lithium
journal, January 2001

  • Grugeon, S.; Laruelle, S.; Herrera-Urbina, R.
  • Journal of The Electrochemical Society, Vol. 148, Issue 4
  • DOI: 10.1149/1.1353566

Control of Size and Composition of Colloidal Nanocrystals of Manganese Oxide
journal, October 2018


Hetero-layered MoS2/C composites enabling ultrafast and durable Na storage
journal, September 2019


Aerosol-Spray Pyrolysis toward Preparation of Nanostructured Materials for Batteries and Supercapacitors
journal, December 2017


Screening for positive electrodes for magnesium batteries: a protocol for studies at elevated temperatures
journal, January 2016

  • Duffort, Victor; Sun, Xiaoqi; Nazar, Linda F.
  • Chemical Communications, Vol. 52, Issue 84
  • DOI: 10.1039/C6CC05363G

High surface area nanocrystalline hausmannite synthesized by a solvent-free route
journal, September 2012


Monocyclopentadienyl titanium(IV) alkyl xanthate complexes
journal, January 1984


Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges
journal, February 2017

  • Canepa, Pieremanuele; Sai Gautam, Gopalakrishnan; Hannah, Daniel C.
  • Chemical Reviews, Vol. 117, Issue 5
  • DOI: 10.1021/acs.chemrev.6b00614

A high capacity thiospinel cathode for Mg batteries
journal, January 2016

  • Sun, Xiaoqi; Bonnick, Patrick; Duffort, Victor
  • Energy & Environmental Science, Vol. 9, Issue 7
  • DOI: 10.1039/C6EE00724D

Tailoring the electrochemical activity of magnesium chromium oxide towards Mg batteries through control of size and crystal structure
journal, January 2019

  • Hu, Linhua; Johnson, Ian D.; Kim, Soojeong
  • Nanoscale, Vol. 11, Issue 2
  • DOI: 10.1039/C8NR08347A

Ultrathin MoO2 nanosheets for superior lithium storage
journal, January 2015


Layered TiS 2 Positive Electrode for Mg Batteries
journal, June 2016


On the Way to Rechargeable Mg Batteries: The Challenge of New Cathode Materials
journal, February 2010

  • Levi, E.; Gofer, Y.; Aurbach, D.
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm9016497

Inorganic nanomaterials for batteries
journal, January 2008


Performance study of magnesium–sulfur battery using a graphene based sulfur composite cathode electrode and a non-nucleophilic Mg electrolyte
journal, January 2016

  • Vinayan, B. P.; Zhao-Karger, Zhirong; Diemant, Thomas
  • Nanoscale, Vol. 8, Issue 6
  • DOI: 10.1039/C5NR04383B

Prototype systems for rechargeable magnesium batteries
journal, October 2000

  • Aurbach, D.; Lu, Z.; Schechter, A.
  • Nature, Vol. 407, Issue 6805, p. 724-727
  • DOI: 10.1038/35037553

Well-Defined Colloidal 2-D Layered Transition-Metal Chalcogenide Nanocrystals via Generalized Synthetic Protocols
journal, October 2012

  • Jeong, Sohee; Yoo, Dongwon; Jang, Jung-tak
  • Journal of the American Chemical Society, Vol. 134, Issue 44
  • DOI: 10.1021/ja3089845

Copper sulfide nanoparticles as high-performance cathode materials for magnesium secondary batteries
journal, January 2018


Alkali ions pre-intercalated layered vanadium oxide nanowires for stable magnesium ions storage
journal, April 2019


Mg rechargeable batteries: an on-going challenge
journal, January 2013

  • Yoo, Hyun Deog; Shterenberg, Ivgeni; Gofer, Yosef
  • Energy & Environmental Science, Vol. 6, Issue 8, p. 2265-2279
  • DOI: 10.1039/c3ee40871j

Understanding the Electrochemical Mechanism of K-αMnO 2 for Magnesium Battery Cathodes
journal, May 2014

  • Arthur, Timothy S.; Zhang, Ruigang; Ling, Chen
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 10
  • DOI: 10.1021/am5015327

Smart Materials and Design toward Safe and Durable Lithium Ion Batteries
journal, May 2019


Elucidating Zn and Mg Electrodeposition Mechanisms in Nonaqueous Electrolytes for Next-Generation Metal Batteries
journal, December 2017

  • Ta, Kim; See, Kimberly A.; Gewirth, Andrew A.
  • The Journal of Physical Chemistry C, Vol. 122, Issue 25
  • DOI: 10.1021/acs.jpcc.8b00835

Mg Desolvation and Intercalation Mechanism at the Mo 6 S 8 Chevrel Phase Surface
journal, August 2015


Controlled Synthesis and Catalytic Activity of Copper Sulfide Nanostructured Assemblies with Different Morphologies
journal, January 2014

  • Kundu, Joyjit; Pradhan, Debabrata
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 3
  • DOI: 10.1021/am404829g

Unveil the Chemistry of Olivine FePO 4 as Magnesium Battery Cathode
journal, July 2016


Morphology, composition and electrochemistry of a nano-porous silicon versus bulk silicon anode for lithium-ion batteries
journal, November 2016


Post-Li batteries: promises and challenges
journal, July 2019

  • Ponrouch, Alexandre; Palacín, M. Rosa
  • Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, Vol. 377, Issue 2152
  • DOI: 10.1098/rsta.2018.0297

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

  • Poizot, P.; Laruelle, S.; Grugeon, S.
  • Nature, Vol. 407, Issue 6803, p. 496-499
  • DOI: 10.1038/35035045

Exploits, advances and challenges benefiting beyond Li-ion battery technologies
journal, March 2020


A flexible copper sulfide @ multi-walled carbon nanotubes cathode for advanced magnesium-lithium-ion batteries
journal, October 2019


Synthesis of chalcopyrite-type and thiospinel minerals/materials by low temperature melts of xanthates
journal, January 2018

  • Khan, Malik Dilshad; Murtaza, Ghulam; Revaprasadu, Neerish
  • Dalton Transactions, Vol. 47, Issue 27
  • DOI: 10.1039/C8DT00953H

Rechargeable Magnesium Batteries using Conversion-Type Cathodes: A Perspective and Minireview
journal, July 2018


A review on the problems of the solid state ions diffusion in cathodes for rechargeable Mg batteries
journal, December 2007


Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010

  • Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
  • Advanced Materials, Vol. 22, Issue 35
  • DOI: 10.1002/adma.201000717

Facile Synthesis of Chevrel Phase Nanocubes and Their Applications for Multivalent Energy Storage
journal, August 2014

  • Cheng, Yingwen; Parent, Lucas R.; Shao, Yuyan
  • Chemistry of Materials, Vol. 26, Issue 17
  • DOI: 10.1021/cm502306c

Methods for the Stabilization of Nanostructured Electrode Materials for Advanced Rechargeable Batteries
journal, May 2017


Recent advances in rechargeable battery materials: a chemist’s perspective
journal, January 2009

  • Palacín, M. Rosa
  • Chemical Society Reviews, Vol. 38, Issue 9
  • DOI: 10.1039/b820555h

Electrochemical Energy Storage for Green Grid
journal, May 2011

  • Yang, Zhenguo; Zhang, Jianlu; Kintner-Meyer, Michael C. W.
  • Chemical Reviews, Vol. 111, Issue 5, p. 3577-3613
  • DOI: 10.1021/cr100290v

Chimie douce with solid precursors, past and present
journal, April 1996


Fervent Hype behind Magnesium Batteries: An Open Call to Synthetic Chemists-Electrolytes and Cathodes Needed
journal, August 2017

  • Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas
  • Angewandte Chemie International Edition, Vol. 56, Issue 40
  • DOI: 10.1002/anie.201700673

Microwave-Assisted Synthesis of CuS Hierarchical Nanosheets as the Cathode Material for High-Capacity Rechargeable Magnesium Batteries
journal, January 2019

  • Wang, Zhitao; Rafai, Souleymen; Qiao, Chen
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 7
  • DOI: 10.1021/acsami.8b20533

The effect of milling on the performance of a Mo6S8 Chevrel phase as a cathode material for rechargeable Mg batteries
journal, February 2005


Ternary Self-Assembly of Ordered Metal Oxide−Graphene Nanocomposites for Electrochemical Energy Storage
journal, March 2010

  • Wang, Donghai; Kou, Rong; Choi, Daiwon
  • ACS Nano, Vol. 4, Issue 3, p. 1587-1595
  • DOI: 10.1021/nn901819n

Aqueous vs. nonaqueous Zn-ion batteries: consequences of the desolvation penalty at the interface
journal, January 2018

  • Kundu, Dipan; Hosseini Vajargah, Shahrzad; Wan, Liwen
  • Energy & Environmental Science, Vol. 11, Issue 4
  • DOI: 10.1039/C8EE00378E

Spinel/Lithium‐Rich Manganese Oxide Hybrid Nanofibers as Cathode Materials for Rechargeable Lithium‐Ion Batteries
journal, August 2019


Electrolyte Solutions with a Wide Electrochemical Window for Rechargeable Magnesium Batteries
journal, January 2008

  • Mizrahi, Oren; Amir, Nir; Pollak, Elad
  • Journal of The Electrochemical Society, Vol. 155, Issue 2, p. A103-A109
  • DOI: 10.1149/1.2806175

Quantitatively Predict the Potential of MnO 2 Polymorphs as Magnesium Battery Cathodes
journal, February 2016

  • Ling, Chen; Zhang, Ruigang; Mizuno, Fuminori
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 7
  • DOI: 10.1021/acsami.5b11460

The Interplay of Al and Mg Speciation in Advanced Mg Battery Electrolyte Solutions
journal, December 2015

  • See, Kimberly A.; Chapman, Karena W.; Zhu, Lingyang
  • Journal of the American Chemical Society, Vol. 138, Issue 1
  • DOI: 10.1021/jacs.5b10987

A new class of non-corrosive, highly efficient electrolytes for rechargeable magnesium batteries
journal, January 2017

  • Zhao-Karger, Zhirong; Gil Bardaji, Maria Elisa; Fuhr, Olaf
  • Journal of Materials Chemistry A, Vol. 5, Issue 22
  • DOI: 10.1039/C7TA02237A

Investigation of the Mechanism of Mg Insertion in Birnessite in Nonaqueous and Aqueous Rechargeable Mg-Ion Batteries
journal, January 2016


Nanoparticulate TiO2(B): An Anode for Lithium-Ion Batteries
journal, January 2012

  • Ren, Yu; Liu, Zheng; Pourpoint, Frédérique
  • Angewandte Chemie International Edition, Vol. 51, Issue 9
  • DOI: 10.1002/anie.201108300

Materials Science and Materials Chemistry for Large Scale Electrochemical Energy Storage: From Transportation to Electrical Grid
journal, June 2012

  • Liu, Jun; Zhang, Ji-Guang; Yang, Zhenguo
  • Advanced Functional Materials, Vol. 23, Issue 8
  • DOI: 10.1002/adfm.201200690

Practical Stability Limits of Magnesium Electrolytes
journal, January 2016

  • Lipson, Albert L.; Han, Sang-Don; Pan, Baofei
  • Journal of The Electrochemical Society, Vol. 163, Issue 10
  • DOI: 10.1149/2.0451610jes

Quest for Nonaqueous Multivalent Secondary Batteries: Magnesium and Beyond
journal, October 2014

  • Muldoon, John; Bucur, Claudiu B.; Gregory, Thomas
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500049y

Copper sulfide nanoparticles as high-performance cathode materials for Mg-ion batteries
journal, May 2019


Microwaves as a synthetic route for preparing electrochemically active TiO 2 nanoparticles
journal, September 2012

  • Monti, Damien; Ponrouch, Alexandre; Estruga, Marc
  • Journal of Materials Research, Vol. 28, Issue 3
  • DOI: 10.1557/jmr.2012.289

Multivalent Electrochemistry of Spinel Mg x Mn 3– x O 4 Nanocrystals
journal, February 2018