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Title: High Order Oxygen Local Vibrational Modes in ZnS1-xOx

Abstract

Substitution of O in the ZnS lattice is observed to result in a doublet consisting of two local vibrational modes (LVMs) and a second order harmonic of the LVMs. The first order doublet is attributed to vibrational modes of a defect with trigonal (C3v) symmetry. The results of temperature dependent resonant Raman scattering and anti-Stokes scattering support this assignment. The substitution of O in the lattice also leads to the presence of LVM + nLO combination modes, which are interpreted in terms of the cascade model and resonance effects.

Authors:
ORCiD logo [1];  [2];  [3];  [2]
  1. Washington State Univ., Pullman, WA (United States); Univ. of Idaho, Moscow, ID (United States)
  2. Washington State Univ., Pullman, WA (United States)
  3. Univ. of Idaho, Moscow, ID (United States)
Publication Date:
Research Org.:
Washington State Univ., Pullman, WA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division
OSTI Identifier:
1601475
Grant/Contract Number:  
FG02-07ER46386
Resource Type:
Accepted Manuscript
Journal Name:
Physica Status Solidi B. Basic Solid State Physics
Additional Journal Information:
Journal Volume: 256; Journal Issue: 8; Journal ID: ISSN 0370-1972
Publisher:
Wiley-Blackwell
Country of Publication:
United States
Language:
English
Subject:
74 ATOMIC AND MOLECULAR PHYSICS; raman; cascade; local modes; resonance; semiconductors

Citation Formats

Huso, Jesse, Ritter, Jacob R., Bergman, Leah, and McCluskey, Matthew D. High Order Oxygen Local Vibrational Modes in ZnS1-xOx. United States: N. p., 2019. Web. doi:10.1002/pssb.201800607.
Huso, Jesse, Ritter, Jacob R., Bergman, Leah, & McCluskey, Matthew D. High Order Oxygen Local Vibrational Modes in ZnS1-xOx. United States. https://doi.org/10.1002/pssb.201800607
Huso, Jesse, Ritter, Jacob R., Bergman, Leah, and McCluskey, Matthew D. Fri . "High Order Oxygen Local Vibrational Modes in ZnS1-xOx". United States. https://doi.org/10.1002/pssb.201800607. https://www.osti.gov/servlets/purl/1601475.
@article{osti_1601475,
title = {High Order Oxygen Local Vibrational Modes in ZnS1-xOx},
author = {Huso, Jesse and Ritter, Jacob R. and Bergman, Leah and McCluskey, Matthew D.},
abstractNote = {Substitution of O in the ZnS lattice is observed to result in a doublet consisting of two local vibrational modes (LVMs) and a second order harmonic of the LVMs. The first order doublet is attributed to vibrational modes of a defect with trigonal (C3v) symmetry. The results of temperature dependent resonant Raman scattering and anti-Stokes scattering support this assignment. The substitution of O in the lattice also leads to the presence of LVM + nLO combination modes, which are interpreted in terms of the cascade model and resonance effects.},
doi = {10.1002/pssb.201800607},
journal = {Physica Status Solidi B. Basic Solid State Physics},
number = 8,
volume = 256,
place = {United States},
year = {Fri Mar 08 00:00:00 EST 2019},
month = {Fri Mar 08 00:00:00 EST 2019}
}

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