Technetium immobilization by materials through sorption and redox-driven processes: A literature review

Pearce, Carolyn I.; Moore, Robert C.; Morad, Joseph W.; Asmussen, R. Matthew; Chatterjee, Sayandev; Lawter, Amanda R.; Levitskaia, Tatiana G.; Neeway, James J.; Qafoku, Nikolla P.; Rigali, Mark J.; Saslow, Sarah A.; Szecsody, Jim E.; Thallapally, Praveen K.; Wang, Guohui; Freedman, Vicky L.

doi:10.1016/j.scitotenv.2019.06.195

Title: Technetium immobilization by materials through sorption and redox-driven processes: A literature review

Journal Article · 14 June 2019 · Science of the Total Environment

DOI: https://doi.org/10.1016/j.scitotenv.2019.06.195 · OSTI ID:1601144

^[1]; Moore, Robert C. ^[1]; Morad, Joseph W. ^[1];

^[1];

^[1]; Lawter, Amanda R. ^[1];

^[1];

^[1]; Rigali, Mark J. ^[2];

^[1]; Szecsody, Jim E. ^[1];

^[1]; Wang, Guohui ^[1]; Freedman, Vicky L. ^[1]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

The purpose of this review is to evaluate materials for use as a barrier or other deployed technology to treat technetium-99 (Tc) in the subsurface. To achieve this, Tc interactions with different materials are considered within the context of remediation strategies. Several naturally occurring materials are considered for Tc immobilization, including iron oxides and low solubility sulfide phases. Synthetic materials are also considered, and include tin-based materials, sorbents (resins, activated carbon, modified clays), layered double hydroxides, metal organic frameworks, cationic polymeric networks and aerogels. All of the materials were evaluated for their potential in-situ and ex-situ performance with respect to long-term Tc uptake and immobilization, environmental impacts and deployability. Other factors such as the technology maturity, cost and availability were also considered. Given the difficulty of evaluating materials under different experimental conditions (e.g., solution chemistry, redox conditions, solution to solid ratio, Tc concentration etc.), a subset of these materials will be selected, on the basis of this review, for subsequent standardized batch loading tests.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1601144

Alternate ID(s):: OSTI ID: 1638577

Report Number(s):: PNNL-SA-138464

Journal Information:: Science of the Total Environment, Vol. 716, Issue 10; ISSN 0048-9697

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (90)

Synthesis and characterization of MgO-B2O3 mixed oxides prepared by coprecipitation; selective dehydrogenation of propan-2-ol Aramendía, M. A.; Boráu, V.; Jiménez, C. Journal of Materials Chemistry, Vol. 9, Issue 3 https://doi.org/10.1039/a807536k	journal	January 1999
Synthesis and characterization of a novel Mg/In layered double hydroxide Ángeles Aramendía, María; Borau, Victoriano; Jiménez, César Journal of Materials Chemistry, Vol. 9, Issue 10 https://doi.org/10.1039/a906148g	journal	January 1999
The function of Sn(II)-apatite as a Tc immobilizing agent Asmussen, R. Matthew; Neeway, James J.; Lawter, Amanda R. Journal of Nuclear Materials, Vol. 480 https://doi.org/10.1016/j.jnucmat.2016.09.002	journal	November 2016
Removal of Pertechnetate-Related Oxyanions from Solution Using Functionalized Hierarchical Porous Frameworks Banerjee, Debasis; Elsaidi, Sameh K.; Aguila, Briana Chemistry - A European Journal, Vol. 22, Issue 49 https://doi.org/10.1002/chem.201603908	journal	October 2016
Removal of TcO ₄ ⁻ ions from solution: materials and future outlook Banerjee, Debasis; Kim, Dongsang; Schweiger, Michael J. Chemical Society Reviews, Vol. 45, Issue 10 https://doi.org/10.1039/C5CS00330J	journal	January 2016
New hydrotalcite-type anionic clays containing noble metals Basile, F.; Basini, L.; Fornasari, G. Chem. Commun., Issue 21 https://doi.org/10.1039/CC9960002435	journal	January 1996
Development of Bifunctional Anion-Exchange Resins with Improved Selectivity and Sorptive Kinetics for Pertechnetate: Batch-Equilibrium Experiments Bonnesen, Peter V.; Brown, Gilbert M.; Alexandratos, Spiro D. Environmental Science & Technology, Vol. 34, Issue 17 https://doi.org/10.1021/es990858s	journal	September 2000
The identification of FeS2 as a sorption sink for Tc(IV) Bruggeman, C.; Maes, A.; Vancluysen, J. Physics and Chemistry of the Earth, Parts A/B/C, Vol. 32, Issue 8-14 https://doi.org/10.1016/j.pce.2005.12.006	journal	January 2007
Catalysts for low-temperature methanol synthesis. Preparation of Cu$z.dbnd;Zn$z.dbnd;Al mixed oxides via hydrotalcite-like precursors Busetto, C. Journal of Catalysis, Vol. 85, Issue 1 https://doi.org/10.1016/0021-9517(84)90130-1	journal	January 1984
Layered double hydroxides (LDHs) Carrado, K. Solid State Ionics, Vol. 26, Issue 2 https://doi.org/10.1016/0167-2738(88)90018-5	journal	March 1988
Hydrotalcite-type anionic clays: Preparation, properties and applications. Cavani, F.; Trifirò, F.; Vaccari, A. Catalysis Today, Vol. 11, Issue 2 https://doi.org/10.1016/0920-5861(91)80068-K	journal	December 1991
Low-Temperature Synthesis of Mg _x Co ₁ _- _x Co ₂ O ₄ Spinel Catalysts for N ₂ O Decomposition Chellam, U.; Xu, Z. P.; Zeng, H. C. Chemistry of Materials, Vol. 12, Issue 3 https://doi.org/10.1021/cm990355l	journal	March 2000
Adsorption of phosphate by layered double hydroxides in aqueous solutions Das, J.; Patra, B. S.; Baliarsingh, N. Applied Clay Science, Vol. 32, Issue 3-4 https://doi.org/10.1016/j.clay.2006.02.005	journal	May 2006
Technetium-99 Removal from Process Solutions and Contaminated Groundwater del Cul, G. D.; Bostick, W. D.; Trotter, D. R. Separation Science and Technology, Vol. 28, Issue 1-3 https://doi.org/10.1080/01496399308019506	journal	January 1993
Behaviour of 99Tc in aqueous solutions in the presence of iron oxides and microorganisms Druteikienė, Rūta; Lukšienė, Benedikta; Pečiulytė, Dalia Applied Radiation and Isotopes, Vol. 89 https://doi.org/10.1016/j.apradiso.2014.02.020	journal	July 2014
Ion exchange behaviour of hydrous tin oxide: Kinetics of anion exchange El-Naggar, I. Talanta, Vol. 39, Issue 6 https://doi.org/10.1016/0039-9140(92)80076-P	journal	June 1992
Electrosorption and Reduction of Pertechnetate by Anodically Polarized Magnetite Farrell, James; Bostick, William D.; Jarabek, Robert J. Environmental Science & Technology, Vol. 33, Issue 8 https://doi.org/10.1021/es980086k	journal	April 1999
Preparation and thermal stability of manganese-containing hydrotalcite, [Mg _0.75 Mn ^II _0.04 Mn ^III _0.21 (OH) ₂ ](CO ₃ ) _0.11 ·nH ₂ O Fernandez, José M.; Barriga, Cristobalina; Ulibarri, Maria-Angeles J. Mater. Chem., Vol. 4, Issue 7 https://doi.org/10.1039/JM9940401117	journal	January 1994
Application of layered double hydroxides for removal of oxyanions: A review Goh, Kok-Hui; Lim, Teik-Thye; Dong, Zhili Water Research, Vol. 42, Issue 6-7 https://doi.org/10.1016/j.watres.2007.10.043	journal	March 2008
Efficient separation and recovery of technetium-99 from contaminated groundwater Gu, Baohua; Dowlen, Kathryn E.; Liang, Liyuan Separations Technology, Vol. 6, Issue 2 https://doi.org/10.1016/0956-9618(96)00147-6	journal	April 1996
Direct Extraction of Ag ⁺ and Hg ²⁺ from Cyanide Complexes and Mode of Binding by the Layered K ₂ MgSn ₂ S ₆ (KMS-2) Hassanzadeh Fard, Zohreh; Malliakas, Christos D.; Mertz, Joshua L. Chemistry of Materials, Vol. 27, Issue 6 https://doi.org/10.1021/acs.chemmater.5b00374	journal	March 2015
XAFS Study of the Chemical and Structural States of Technetium in Fe(III) Oxide Co-Precipitates Heald, Steve M.; Zachara, John M.; Jeon, Byong-Hun X-RAY ABSORPTION FINE STRUCTURE - XAFS13: 13th International Conference, AIP Conference Proceedings https://doi.org/10.1063/1.2644465	conference	January 2007
Incorporation of pertechnetate and perrhenate into corroded steel surfaces studied by X-ray absorption fine structure spectroscopy Heald, S. M.; Krupka, K. M.; Brown, C. F. Radiochimica Acta, Vol. 100, Issue 4 https://doi.org/10.1524/ract.2012.1912	journal	April 2012
The biogeochemistry of technetium: A review of the behavior of an artificial element in the natural environment Icenhower, J. P.; Qafoku, N. P.; Zachara, J. M. American Journal of Science, Vol. 310, Issue 8 https://doi.org/10.2475/08.2010.02	journal	October 2010
Sorption of MO4- (M = Tc, Re) on Mg/Al Layered Double Hydroxide by Anion Exchange Kang, M. J.; Rhee, S. W.; Moon, H. Radiochimica Acta, Vol. 75, Issue 3 https://doi.org/10.1524/ract.1996.75.3.169	journal	January 1996
Functional Monolithic Polymeric Organic Framework Aerogel as Reducing and Hosting Media for Ag nanoparticles and Application in Capturing of Iodine Vapors Katsoulidis, Alexandros P.; He, Jiaqing; Kanatzidis, Mercouri G. Chemistry of Materials, Vol. 24, Issue 10 https://doi.org/10.1021/cm300696g	journal	May 2012
Sorption of Tungsten(Vi) and Rhenium(Vii) on Various Ion-Exchange Materials Khalid, M.; Mushtaq, A.; Iqbal, M. Z. Separation Science and Technology, Vol. 36, Issue 2 https://doi.org/10.1081/SS-100001079	journal	December 2001
Selective Sorption of Technetium on Antimony-Doped Tin Dioxide Koivula, Risto; Harjula, Risto Separation Science and Technology, Vol. 46, Issue 2 https://doi.org/10.1080/01496395.2010.506902	journal	December 2010
Synthesis and Characterization of Hydrotalcite-like Compounds Containing V ³⁺ in the Layers and of Their Calcination Products Labajos, F. M.; Rives, V.; Malet, P. Inorganic Chemistry, Vol. 35, Issue 5 https://doi.org/10.1021/ic950835o	journal	January 1996
The crystal structure of some rhenium and technetium dichalcogenides Lamfers, H. -J.; Meetsma, A.; Wiegers, G. A. Journal of Alloys and Compounds, Vol. 241, Issue 1-2 https://doi.org/10.1016/0925-8388(96)02313-4	journal	August 1996
Inorganic tin aluminophosphate nanocomposite for reductive separation of pertechnetate Levitskaia, Tatiana G.; Chatterjee, Sayandev; Pence, Natasha K. Environmental Science: Nano, Vol. 3, Issue 5 https://doi.org/10.1039/C6EN00130K	journal	January 2016
Sorption coefficients and molecular mechanisms of Pu, U, Np, Am and Tc to Fe (hydr)oxides: A review Li, Dien; Kaplan, Daniel I. Journal of Hazardous Materials, Vol. 243 https://doi.org/10.1016/j.jhazmat.2012.09.011	journal	December 2012
Aqueous 99Tc, 129I and 137Cs removal from contaminated groundwater and sediments using highly effective low-cost sorbents Li, Dien; Kaplan, Daniel I.; Knox, Anna S. Journal of Environmental Radioactivity, Vol. 136 https://doi.org/10.1016/j.jenvrad.2014.05.010	journal	October 2014
99TcO4− remediation by a cationic polymeric network Li, Jie; Dai, Xing; Zhu, Lin Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-05380-5	journal	August 2018
Technetium in the Hydrosphere and in the Geosphere Lieser, K. H.; Bauscher, Ch. Radiochimica Acta, Vol. 42, Issue 4 https://doi.org/10.1524/ract.1987.42.4.205	journal	January 1987
Pertechnetate immobilization with amorphous iron sulfide Liu, Yongjian; Terry, Jeff; Jurisson, Silvia S. Radiochimica Acta, Vol. 96, Issue 12 https://doi.org/10.1524/ract.2008.1528	journal	January 2008
Tc(VII) reduction kinetics by titanomagnetite (Fe3−xTixO4) nanoparticles Liu, J.; Pearce, C. I.; Qafoku, O. Geochimica et Cosmochimica Acta, Vol. 92 https://doi.org/10.1016/j.gca.2012.06.004	journal	September 2012
X-ray absorption spectroscopy studies of reactions of technetium, uranium and neptunium with mackinawite Livens, Francis R.; Jones, Mark J.; Hynes, Amanda J. Journal of Environmental Radioactivity, Vol. 74, Issue 1-3 https://doi.org/10.1016/j.jenvrad.2004.01.012	journal	January 2004
Incorporation of Technetium into Spinel Ferrites Lukens, Wayne W.; Magnani, Nicola; Tyliszczak, Tolek Environmental Science & Technology, Vol. 50, Issue 23 https://doi.org/10.1021/acs.est.6b04209	journal	November 2016
Incorporating technetium in minerals and other solids: A review Luksic, Steven A.; Riley, Brian J.; Schweiger, Michael Journal of Nuclear Materials, Vol. 466 https://doi.org/10.1016/j.jnucmat.2015.08.052	journal	November 2015
Layered Metal Sulfides Capture Uranium from Seawater Manos, Manolis. J.; Kanatzidis, Mercouri G. Journal of the American Chemical Society, Vol. 134, Issue 39 https://doi.org/10.1021/ja308028n	journal	September 2012
Incorporation and Retention of 99-Tc(IV) in Magnetite under High pH Conditions Marshall, Timothy A.; Morris, Katherine; Law, Gareth T. W. Environmental Science & Technology, Vol. 48, Issue 20 https://doi.org/10.1021/es503438e	journal	October 2014
Functionalized Silica Aerogels: Advanced Materials to Capture and Immobilize Radioactive Iodine Matyáš, J.; Fryxell, G. E.; Busche, B. J. Ceramic Materials for Energy Applications: Ceramic Engineering and Science Proceedings, Vol. 32 https://doi.org/10.1002/9781118095386.ch3	book	September 2011
Silica-based waste form for immobilization of iodine from reprocessing plant off-gas streams Matyáš, Josef; Canfield, Nathan; Sulaiman, Sannoh Journal of Nuclear Materials, Vol. 476 https://doi.org/10.1016/j.jnucmat.2016.04.047	journal	August 2016
Selective Removal of Cs ⁺ , Sr ²⁺ , and Ni ²⁺ by K _{2 x} Mg _x Sn _{3– x} S ₆ ( x = 0.5–1) (KMS-2) Relevant to Nuclear Waste Remediation Mertz, Joshua L.; Fard, Zohreh Hassanzadeh; Malliakas, Christos D. Chemistry of Materials, Vol. 25, Issue 10 https://doi.org/10.1021/cm400699r	journal	May 2013
Anion-exchange reactions of layered double hydroxides Meyn, Martina; Beneke, Klaus; Lagaly, Gerhard Inorganic Chemistry, Vol. 29, Issue 26 https://doi.org/10.1021/ic00351a013	journal	December 1990
Synthesis of new Hydrotalcite-Like Compounds and Their Physico-Chemical Properties Miyata, Shigeo; Kumura, Teruhiko Chemistry Letters, Vol. 2, Issue 8 https://doi.org/10.1246/cl.1973.843	journal	August 1973
Size-Driven Structural and Thermodynamic Complexity in Iron Oxides Navrotsky, A.; Mazeina, L.; Majzlan, J. Science, Vol. 319, Issue 5870 https://doi.org/10.1126/science.1148614	journal	March 2008
Removal of TcO ₄ ^– from Representative Nuclear Waste Streams with Layered Potassium Metal Sulfide Materials Neeway, James J.; Asmussen, R. Matthew; Lawter, Amanda R. Chemistry of Materials, Vol. 28, Issue 11 https://doi.org/10.1021/acs.chemmater.6b01296	journal	May 2016
Zn, Al, Rh-mixed oxides derived from hydrotalcite-like compound and their catalytic properties for N2O decomposition Oi, J.; Obuchi, A.; Ogata, A. Applied Catalysis B: Environmental, Vol. 13, Issue 3-4 https://doi.org/10.1016/S0926-3373(96)00105-1	journal	November 1997
Synthesis and properties of titanomagnetite (Fe3−xTixO4) nanoparticles: A tunable solid-state Fe(II/III) redox system Pearce, C. I.; Qafoku, O.; Liu, J. Journal of Colloid and Interface Science, Vol. 387, Issue 1 https://doi.org/10.1016/j.jcis.2012.06.092	journal	December 2012
Technetium Stabilization in Low-Solubility Sulfide Phases: A Review Pearce, Carolyn I.; Icenhower, Jonathan P.; Asmussen, R. Matthew ACS Earth and Space Chemistry, Vol. 2, Issue 6 https://doi.org/10.1021/acsearthspacechem.8b00015	journal	April 2018
Treatment of radioactive wastes: An X-ray absorption spectroscopy study of the reaction of technetium with green rust Pepper, Sarah E.; Bunker, Debbie J.; Bryan, Nicholas D. Journal of Colloid and Interface Science, Vol. 268, Issue 2 https://doi.org/10.1016/j.jcis.2003.08.024	journal	December 2003
Heterogeneous reduction of Tc(VII) by Fe(II) at the solid–water interface Peretyazhko, T.; Zachara, J. M.; Heald, S. M. Geochimica et Cosmochimica Acta, Vol. 72, Issue 6 https://doi.org/10.1016/j.gca.2008.01.004	journal	March 2008
Reduction of Tc(VII) by Fe(II) Sorbed on Al (hydr)oxides Peretyazhko, T.; Zachara, J. M.; Heald, S. M. Environmental Science & Technology, Vol. 42, Issue 15 https://doi.org/10.1021/es8003156	journal	August 2008
Structural promotion and stabilizing effect of Mg in the catalytic decomposition of nitrous oxide over calcined hydrotalcite-like compounds Pérez-Ramı́rez, Javier; Overeijnder, Joost; Kapteijn, Freek Applied Catalysis B: Environmental, Vol. 23, Issue 1 https://doi.org/10.1016/S0926-3373(99)00066-1	journal	October 1999
Chalcogen-Based Aerogels As Sorbents for Radionuclide Remediation Riley, Brian J.; Chun, Jaehun; Um, Wooyong Environmental Science & Technology, Vol. 47, Issue 13 https://doi.org/10.1021/es400595z	journal	June 2013
A new hydrotalcite-like compound containing vanadium(3+) ions in the layers Rives, Vicente; Labajos, Francisco M.; Ulibarri, Maria A. Inorganic Chemistry, Vol. 32, Issue 23 https://doi.org/10.1021/ic00075a008	journal	November 1993
The effect of interlayer anion on the reactivity of Mg–Al layered double hydroxides: Improving and extending the customization capacity of anionic clays Rojas, Ricardo; Bruna, Felipe; de Pauli, Carlos P. Journal of Colloid and Interface Science, Vol. 359, Issue 1 https://doi.org/10.1016/j.jcis.2011.03.056	journal	July 2011
Insights on the Structural Chemistry of Hydrocalumite and Hydrotalcite-like Materials: Investigation of the Series Ca2M3+(OH)6Cl·2H2O (M3+: Al3+, Ga3+, Fe3+, and Sc3+) by X-Ray Powder Diffraction Rousselot, Isabelle; Taviot-Guého, Christine; Leroux, Fabrice Journal of Solid State Chemistry, Vol. 167, Issue 1 https://doi.org/10.1006/jssc.2002.9635	journal	August 2002
Reduction and Simultaneous Removal of ⁹⁹ Tc and Cr by Fe(OH) ₂ (s) Mineral Transformation Saslow, Sarah A.; Um, Wooyong; Pearce, Carolyn I. Environmental Science & Technology, Vol. 51, Issue 15 https://doi.org/10.1021/acs.est.7b02278	journal	July 2017
Extraction and Reductive Stripping of Pertechnetate from Spent Nuclear Fuel Waste Streams Shkrob, Ilya A.; Marin, Timothy W.; Stepinski, Dominique C. Separation Science and Technology, Vol. 46, Issue 3 https://doi.org/10.1080/01496395.2010.527893	journal	February 2011
Technetium Incorporation into Hematite (α-Fe ₂ O ₃ ) Skomurski, Frances N.; Rosso, Kevin M.; Krupka, Kenneth M. Environmental Science & Technology, Vol. 44, Issue 15 https://doi.org/10.1021/es100069x	journal	August 2010
Technetium Incorporation into Goethite (α-FeOOH): An Atomic-Scale Investigation Smith, Frances N.; Taylor, Christopher D.; Um, Wooyong Environmental Science & Technology, Vol. 49, Issue 22 https://doi.org/10.1021/acs.est.5b03354	journal	October 2015
Computational Investigation of Technetium(IV) Incorporation into Inverse Spinels: Magnetite (Fe ₃ O ₄ ) and Trevorite (NiFe ₂ O ₄ ) Smith, Frances N.; Um, Wooyong; Taylor, Christopher D. Environmental Science & Technology, Vol. 50, Issue 10 https://doi.org/10.1021/acs.est.6b00200	journal	April 2016
Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities Soelberg, Nick R.; Garn, Troy G.; Greenhalgh, Mitchell R. Science and Technology of Nuclear Installations, Vol. 2013 https://doi.org/10.1155/2013/702496	journal	January 2013
The Sorption of Technetium and Iodine Radioisotopes by Various Minerals Strickert, R.; Friedman, A. M.; Fried, S. Nuclear Technology, Vol. 49, Issue 2 https://doi.org/10.13182/NT80-A32488	journal	July 1980
The rapid formation of crystalline double hydroxy salts and other compounds by controlled hydrolysis Taylor, R. M. Clay Minerals, Vol. 19, Issue 4 https://doi.org/10.1180/claymin.1984.019.4.06	journal	September 1984
Tc removal from the waste treatment and immobilization plant low-activity waste vitrification off-gas recycle Taylor-Pashow, Kathryn M. L.; McCabe, Daniel J.; Nash, Charles A. Separation Science and Technology, Vol. 53, Issue 12 https://doi.org/10.1080/01496395.2017.1302952	journal	May 2017
Immobilization of 99-Technetium (VII) by Fe(II)-Goethite and Limited Reoxidation Um, Wooyong; Chang, Hyun-Shik; Icenhower, Jonathan P. Environmental Science & Technology, Vol. 45, Issue 11 https://doi.org/10.1021/es104343p	journal	June 2011
Iron oxide waste form for stabilizing 99Tc Um, Wooyong; Chang, Hyunshik; Icenhower, Jonathan P. Journal of Nuclear Materials, Vol. 429, Issue 1-3 https://doi.org/10.1016/j.jnucmat.2012.06.004	journal	October 2012
Uranium and technetium interactions with wüstite [Fe _1–x O] and portlandite [Ca(OH) ₂ ] surfaces under geological disposal facility conditions Van Veelen, A.; Preedy, O.; Qi, J. Mineralogical Magazine, Vol. 78, Issue 5 https://doi.org/10.1180/minmag.2014.078.5.02	journal	October 2014
New hydrotalcite-like anionic clays containing Zr4+ in the layers Velu, S.; Ramaswamy, Veda; Sivasanker, S. Chemical Communications, Issue 21 https://doi.org/10.1039/a704752e	journal	January 1997
New Hydrotalcite-like Anionic Clays Containing Zr ⁴⁺ in the Layers: Synthesis and Physicochemical Properties Velu, S.; Sabde, D. P.; Shah, Neepa Chemistry of Materials, Vol. 10, Issue 11 https://doi.org/10.1021/cm980185x	journal	November 1998
Synthesis of New Sn-Incorporated Layered Double Hydroxides and Their Thermal Evolution to Mixed Oxides Velu, S.; Suzuki, K.; Okazaki, M. Chemistry of Materials, Vol. 11, Issue 8 https://doi.org/10.1021/cm990067p	journal	August 1999
An Injectable Apatite Permeable Reactive Barrier for In Situ ⁹⁰ Sr Immobilization Vermeul, Vince R.; Szecsody, Jim E.; Fritz, Brad G. Groundwater Monitoring & Remediation, Vol. 34, Issue 2 https://doi.org/10.1111/gwmr.12055	journal	April 2014
Preparation of Cd/Al layered double hydroxides and their intercalation reactions with phosphonic acids Vichi, Flávio Maron; Alves, Oswaldo Luiz Journal of Materials Chemistry, Vol. 7, Issue 8 https://doi.org/10.1039/a606866i	journal	January 1997
Compositional and structural control on anion sorption capability of layered double hydroxides (LDHs) Wang, Yifeng; Gao, Huizhen Journal of Colloid and Interface Science, Vol. 301, Issue 1 https://doi.org/10.1016/j.jcis.2006.04.061	journal	September 2006
NDTB-1: A Supertetrahedral Cationic Framework That Removes TcO ₄ ⁻ from Solution Wang, Shuao; Alekseev, Evgeny V.; Diwu, Juan Angewandte Chemie International Edition, Vol. 49, Issue 6 https://doi.org/10.1002/anie.200906397	journal	February 2010
Selectivity, Kinetics, and Efficiency of Reversible Anion Exchange with TcO4− in a Supertetrahedral Cationic Framework Wang, Shuao; Yu, Ping; Purse, Bryant A. Advanced Functional Materials, Vol. 22, Issue 11 https://doi.org/10.1002/adfm.201103081	journal	March 2012
Synthesis of Organically Templated Nanoporous Tin(II/IV) Phosphate for Radionuclide and Metal Sequestration Wellman, Dawn M.; Mattigod, Shas V.; Parker, Kent E. Inorganic Chemistry, Vol. 45, Issue 6 https://doi.org/10.1021/ic051949v	journal	March 2006
An X-ray absorption spectroscopy study of the coprecipitation of Tc and Re with mackinawite (FeS) Wharton, M. J.; Atkins, B.; Charnockab, J. M. Applied Geochemistry, Vol. 15, Issue 3 https://doi.org/10.1016/S0883-2927(99)00045-1	journal	March 2000
The sorption of anionic species on hydrous tin dioxide White, D. A.; Rãutiu, R. Chemical Engineering Journal, Vol. 66, Issue 2 https://doi.org/10.1016/S1385-8947(96)03163-4	journal	February 1997
Control of Surface Area and Porosity of Co ₃ O ₄ via Intercalation of Oxidative or Nonoxidative Anions in Hydrotalcite-like Precursors Xu, Z. P.; Zeng, H. C. Chemistry of Materials, Vol. 12, Issue 11 https://doi.org/10.1021/cm000371e	journal	November 2000
In-Situ Generation of Maximum Trivalent Cobalt in Synthesis of Hydrotalcite-like Compounds Mg _x Co ^II ₁ _- _x _- _y Co ^III _y (OH) ₂ (NO ₃ ) _y · n H ₂ O Xu, Z. P.; Zeng, H. C. Chemistry of Materials, Vol. 12, Issue 9 https://doi.org/10.1021/cm000053f	journal	August 2000
A new approach for design and synthesis of CoII and CoII,III hydroxide materials Xu, Z. P.; Zeng, H. C. International Journal of Inorganic Materials, Vol. 2, Issue 2-3 https://doi.org/10.1016/S1466-6049(00)00020-9	journal	June 2000
Systematic XAS study on the reduction and uptake of Tc by magnetite and mackinawite Yalçıntaş, Ezgi; Scheinost, Andreas C.; Gaona, Xavier Dalton Transactions, Vol. 45, Issue 44 https://doi.org/10.1039/C6DT02872A	journal	January 2016
Geomaterials: their application to environmental remediation Yamada, Hirohisa; Tamura, Kenji; Watanabe, Yujiro Science and Technology of Advanced Materials, Vol. 12, Issue 6 https://doi.org/10.1088/1468-6996/12/6/064705	journal	December 2011
Identifying the Recognition Site for Selective Trapping of ⁹⁹ TcO ₄ ^– in a Hydrolytically Stable and Radiation Resistant Cationic Metal–Organic Framework Zhu, Lin; Sheng, Daopeng; Xu, Chao Journal of the American Chemical Society, Vol. 139, Issue 42 https://doi.org/10.1021/jacs.7b08632	journal	October 2017
Retardation of Technetium and Iodine by Antimony- and Mercury-Containing Minerals Zhuang, Η. E.; Zheng, J. S.; Xia, D. Y. Radiochimica Acta, Vol. 68, Issue 4 https://doi.org/10.1524/ract.1995.68.4.245	journal	January 1995

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