Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy
Abstract
A novel mathematical algorithm was developed to calculate refractive index (n + ik) from specular reflectance infrared (SR-IR) spectra in the strongly-absorbing glass network vibration region. The method is named as two-angle SR-IR (TASR-IR), since it is based on the Fresnel equations of specular reflectance at two incidence angles (10° and 45°). The results obtained from TASR-IR are comparable with the values obtained from spectroscopic ellipsometry. The TASR-IR method allows one to obtain the peak positions and intensities of fundamental network vibration modes of glass from the imaginary component (k) of complex refractive index without convolutions from the dispersion effect due to chains in the real component (n) of refractive index. The TASR-IR method is applied to silica, silicate, borosilicate, and boroaluminosilicate glasses; tentative peak assignments of glass network vibrations are proposed. The origin and concept of peaks in the vibrational spectra of glasses is discussed.
- Authors:
-
- Pennsylvania State Univ., University Park, PA (United States)
- Corning Inc., Corning, NY (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD); Pennsylvania State Univ., University Park, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1600990
- Alternate Identifier(s):
- OSTI ID: 1582895
- Grant/Contract Number:
- SC0016584
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Non-Crystalline Solids
- Additional Journal Information:
- Journal Volume: 494; Journal Issue: C; Journal ID: ISSN 0022-3093
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Vibrational spectroscopy; Complex refractive index
Citation Formats
Luo, Jiawei, Smith, Nicholas J., Pantano, Carlo G., and Kim, Seong H. Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy. United States: N. p., 2018.
Web. doi:10.1016/j.jnoncrysol.2018.04.050.
Luo, Jiawei, Smith, Nicholas J., Pantano, Carlo G., & Kim, Seong H. Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy. United States. https://doi.org/10.1016/j.jnoncrysol.2018.04.050
Luo, Jiawei, Smith, Nicholas J., Pantano, Carlo G., and Kim, Seong H. Mon .
"Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy". United States. https://doi.org/10.1016/j.jnoncrysol.2018.04.050. https://www.osti.gov/servlets/purl/1600990.
@article{osti_1600990,
title = {Complex refractive index of silica, silicate, borosilicate, and boroaluminosilicate glasses – Analysis of glass network vibration modes with specular-reflection IR spectroscopy},
author = {Luo, Jiawei and Smith, Nicholas J. and Pantano, Carlo G. and Kim, Seong H.},
abstractNote = {A novel mathematical algorithm was developed to calculate refractive index (n + ik) from specular reflectance infrared (SR-IR) spectra in the strongly-absorbing glass network vibration region. The method is named as two-angle SR-IR (TASR-IR), since it is based on the Fresnel equations of specular reflectance at two incidence angles (10° and 45°). The results obtained from TASR-IR are comparable with the values obtained from spectroscopic ellipsometry. The TASR-IR method allows one to obtain the peak positions and intensities of fundamental network vibration modes of glass from the imaginary component (k) of complex refractive index without convolutions from the dispersion effect due to chains in the real component (n) of refractive index. The TASR-IR method is applied to silica, silicate, borosilicate, and boroaluminosilicate glasses; tentative peak assignments of glass network vibrations are proposed. The origin and concept of peaks in the vibrational spectra of glasses is discussed.},
doi = {10.1016/j.jnoncrysol.2018.04.050},
journal = {Journal of Non-Crystalline Solids},
number = C,
volume = 494,
place = {United States},
year = {Mon May 07 00:00:00 EDT 2018},
month = {Mon May 07 00:00:00 EDT 2018}
}
Web of Science
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