Lessons from intramolecular singlet fission with covalently bound chromophores

Korovina, Nadezhda; Pompetti, Nicholas; Johnson, Justin C.

doi:10.1063/1.5135307

Title: Lessons from intramolecular singlet fission with covalently bound chromophores

Journal Article · 27 January 2020 · Journal of Chemical Physics

DOI: https://doi.org/10.1063/1.5135307 · OSTI ID:1600904

Korovina, Nadezhda ^[1]; Pompetti, Nicholas ^[1];

^[1]

National Renewable Energy Lab. (NREL), Golden, CO (United States)

Molecular dimers, oligomers, and polymers are versatile components in photophysical and optoelectronic architectures that could impact a large variety of applications. We present a perspective on such systems in the field of singlet fission, which effectively multiplies excitons and produces a unique excited state species, the triplet pair. The choice of chromophore and the nature of the attachment between units, both geometrical and chemical, play a defining role in the dynamical scheme that evolves upon photoexcitation. Specific final outcomes (e.g., separated and uncorrelated triplet pairs) are being sought through rational design of covalently bound chromophore architectures built with guidance from recent fundamental studies that correlate structure with excited state population flow kinetics.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC36-08GO28308

OSTI ID:: 1600904

Report Number(s):: NREL/JA-5900-75360

Journal Information:: Journal of Chemical Physics, Journal Name: Journal of Chemical Physics Journal Issue: 4 Vol. 152; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
75 CONDENSED MATTER PHYSICS
SUPERCONDUCTIVITY AND SUPERFLUIDITY
chemical bonding
chemical compounds
delocalization
electronic coupling
excitons
isomerism
molecular dynamics
photochemistry
photoexcitations
ultrafast molecular spectra

Title: Lessons from intramolecular singlet fission with covalently bound chromophores

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