Solid state characterization of oxidized actinides co-crystallized with uranyl nitrate hexahydrate

Einkauf, Jeffrey D.; Burns, Jonathan D.

doi:10.1039/C9DT04000E

Title: Solid state characterization of oxidized actinides co-crystallized with uranyl nitrate hexahydrate

Journal Article · 16 December 2019 · Dalton Transactions

DOI: https://doi.org/10.1039/C9DT04000E · OSTI ID:1600514

^[1];

^[1]

Texas A & M Univ., College Station, TX (United States)

Characterization of the penta- and hexavalent dioxo cations of NpO₂⁺, NpO₂²⁺, PuO₂²⁺, and AmO₂²⁺ has been carried out by diffuse reflectance UV-Vis-NIR spectroscopy, with the first observations of NpO₂⁺, NpO₂²⁺, and AmO₂²⁺ in the solid state. Absorbance measurements confirmed the presence of the higher actinides of Np, Pu, and Am, with shifts in their absorbance bands indicating the formation of the dinitrate species in the crystalline phase. The oxidized actinides were prepared in the solid state by co-crystallization with UO₂(NO₃)₂·6H₂O by a simple reduction in temperature. The hexavalent species were all co-crystallized in near proportion to UO₂²⁺ and the pentavalent species was co-crystallized in a slightly less efficient manner, roughly 83% of that of UO₂²⁺.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: NE0008653

OSTI ID:: 1600514

Alternate ID(s):: OSTI ID: 1580765

Journal Information:: Dalton Transactions, Vol. 49, Issue 3; ISSN 1477-9226

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 3 works

Citation information provided by
Web of Science

References (14)

Synthetic Influences on Neptunium Incorporation in Naturally Occurring Copper Uranyl Phosphates Meredith, Nathan A.; Polinski, Matthew J.; Cross, Justin N. Crystal Growth & Design, Vol. 13, Issue 1 https://doi.org/10.1021/cg3015755	journal	December 2012
Structural and Spectroscopic Characterization of Plutonyl(VI) Nitrate under Acidic Conditions Gaunt, Andrew J.; May, Iain; Neu, Mary P. Inorganic Chemistry, Vol. 50, Issue 10 https://doi.org/10.1021/ic200525u	journal	May 2011
Uranyl nitrate hexahydrate solubility in nitric acid and its crystallization selectivity in the presence of nitrate salts Burns, Jonathan D.; Moyer, Bruce A. Journal of Cleaner Production, Vol. 172 https://doi.org/10.1016/j.jclepro.2017.10.258	journal	January 2018
Prevented Mortality and Greenhouse Gas Emissions from Historical and Projected Nuclear Power Kharecha, Pushker A.; Hansen, James E. Environmental Science & Technology, Vol. 47, Issue 9, p. 4889-4895 https://doi.org/10.1021/es3051197	journal	April 2013
Generating the Option of a Two-Stage Nuclear Renaissance Grimes, R. W.; Nuttall, W. J. Science, Vol. 329, Issue 5993 https://doi.org/10.1126/science.1188928	journal	August 2010
Radioactive waste partitioning and transmutation within advanced fuel cycles: Achievements and challenges Salvatores, M.; Palmiotti, G. Progress in Particle and Nuclear Physics, Vol. 66, Issue 1 https://doi.org/10.1016/j.ppnp.2010.10.001	journal	January 2011
A TBP/BTBP-based GANEX Separation Process. Part 1: Feasibility Aneheim, Emma; Ekberg, Christian; Fermvik, Anna Solvent Extraction and Ion Exchange, Vol. 28, Issue 4 https://doi.org/10.1080/07366299.2010.480930	journal	June 2010
Aqueous Partitioning of Minor Actinides by Different Processes Ansari, Seraj A.; Pathak, Priyanath; Mohapatra, Prashanta K. Separation & Purification Reviews, Vol. 40, Issue 1 https://doi.org/10.1080/15422119.2010.545466	journal	February 2011
Group Hexavalent Actinide Separations: A New Approach to Used Nuclear Fuel Recycling Burns, Jonathan D.; Moyer, Bruce A. Inorganic Chemistry, Vol. 55, Issue 17 https://doi.org/10.1021/acs.inorgchem.6b01430	journal	August 2016
NUCLEAR POWER:A Nuclear Solution to Climate Change? Sailor, W. C. Science, Vol. 288, Issue 5469 https://doi.org/10.1126/science.288.5469.1177	journal	May 2000
Electrochemical oxidation of 243Am(III) in nitric acid by a terpyridyl-derivatized electrode Dares, C. J.; Lapides, A. M.; Mincher, B. J. Science, Vol. 350, Issue 6261 https://doi.org/10.1126/science.aac9217	journal	November 2015
Higher Oxidation States of Americium: Preparation, Characterization and Use for Separations Runde, Wolfgang H.; Mincher, Bruce J. Chemical Reviews, Vol. 111, Issue 9 https://doi.org/10.1021/cr100181f	journal	September 2011
Structure and spectroscopy of hydrated neptunyl(vi) nitrate complexes Lindqvist-Reis, Patric; Apostolidis, Christos; Walter, Olaf Dalton Transactions, Vol. 42, Issue 43 https://doi.org/10.1039/c3dt51650d	journal	January 2013
Separations and Transmutation Criteria to Improve Utilization of a Geologic Repository Wigeland, Roald A.; Bauer, Theodore H.; Fanning, Thomas H. Nuclear Technology, Vol. 154, Issue 1 https://doi.org/10.13182/NT06-3	journal	April 2006

Similar Records

Spectroscopic characterization of neptunium(VI), plutonium(VI), americium(VI) and neptunium(V) encapsulated in uranyl nitrate hexahydrate

Journal Article · 2021 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1782692

Yu, Xiaojuan; Einkauf, Jeffrey D.; Bryantsev, Vyacheslav S.; +4 more

Spectroscopic characterization of neptunium(VI), plutonium(VI), americium(VI) and neptunium(V) encapsulated in uranyl nitrate hexahydrate

Journal Article · 2021 · Physical Chemistry Chemical Physics. PCCP · OSTI ID:1798329

Yu, Xiaojuan; Einkauf, Jeffrey; Bryantsev, Vyacheslav S.; +4 more

Pentavalent neptunyl ([OΞNpΞO]⁺) cation–cation interactions in aqueous/polar organic mixed-solvent media

Journal Article · 2017 · Journal of Solution Chemistry · OSTI ID:1366418

Burn, Adam G.; Martin, Leigh R.; Nash, Kenneth L.

Related Subjects

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS

Title: Solid state characterization of oxidized actinides co-crystallized with uranyl nitrate hexahydrate

Citation Formats

References (14)

Similar Records

Related Subjects