Local structure of Sr2CuO3.3, a 95 K cuprate superconductor without CuO2 planes

Conradson, Steven D.; Geballe, Theodore H.; Jin, Changqing; Cao, Lipeng; Baldinozzi, Gianguido; Jiang, Jack M.; Latimer, Matthew J.; Mueller, Oliver

doi:10.1073/pnas.1918890117

Title: Local structure of Sr₂CuO_3.3, a 95 K cuprate superconductor without CuO₂ planes

Journal Article · 14 February 2020 · Proceedings of the National Academy of Sciences of the United States of America

DOI: https://doi.org/10.1073/pnas.1918890117 · OSTI ID:1599910

Conradson, Steven D. ^[1]; Geballe, Theodore H. ^[2]; Jin, Changqing ^[3]; Cao, Lipeng ^[4];

^[5]; Jiang, Jack M. ^[2]; Latimer, Matthew J. ^[6]; Mueller, Oliver ^[6]

Jozef Stefan Inst., Ljubljana (Slovenia); Washington State Univ., Pullman, WA (United States)
Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Chinese Academy of Sciences (CAS), Beijing (China); Materials Research Lab. at Songshan Lake, Dongguan (China)
Chinese Academy of Sciences (CAS), Beijing (China)
CNRS CentraleSupélec Univ. Paris-Saclay, Gif-sur-Yvette (France)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

The local structure of the highly “overdoped” 95 K superconductor Sr₂CuO_3.3 determined by Cu K X-ray absorption fine structure (XAFS) at 62 K in magnetically oriented samples shows that 1) the magnetization is perpendicular to the c axis; 2) at these levels of precision the Cu sublattice is tetragonal in agreement with the crystal structure; the O sublattice has 3) continuous -Cu-O- chains that orient perpendicular to an applied magnetic field; 4) approximately half-filled -Cu-O- chains that orient parallel to this field; 5) a substantial number of apical O vacancies; 6) O ions at some apical positions with expanded Cu-O distances; and 7) interstitial positions that imply highly displaced Sr ions. These results contradict the universally accepted features of cuprates that require intact CuO₂ planes, magnetization along thecaxis, and a termination of the superconductivity when the excess charge on the CuO₂Cu ions exceeds 0.27. Here, these radical differences in charge and structure demonstrate that this compound constitutes a separate class of Cu-O–based superconductors in which the superconductivity originates in a different, more complicated structural unit than CuO₂ planes while retaining exceptionally high transition temperatures.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF); Ministry of Science and Technology (MOST); National Natural Science Foundation (NSF) of China

Grant/Contract Number:: 1928874; P1-0040; 2018YFA03057001; 2017YFA0302901; 11820101003; 2016YFA0300301; 2015CB921000; 112111KYS820150017; AC02-76SF00515

OSTI ID:: 1599910

Alternate ID(s):: OSTI ID: 1608342

Journal Information:: Proceedings of the National Academy of Sciences of the United States of America, Vol. 117, Issue 9; ISSN 0027-8424

Publisher:: National Academy of SciencesCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 6 works

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Title: Local structure of Sr2CuO3.3, a 95 K cuprate superconductor without CuO2 planes

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Title: Local structure of Sr₂CuO_3.3, a 95 K cuprate superconductor without CuO₂ planes