An unprecedented 2D covalent organic framework with an htb net topology

Cai, Song-Liang; He, Zi-Hao; Li, Xin-Le; Zhang, Kai; Zheng, Sheng-Run; Fan, Jun; Liu, Yi; Zhang, Wei-Guang

doi:10.1039/c9cc06780a

Title: An unprecedented 2D covalent organic framework with an htb net topology

Abstract

A 2D imine-linked COF with a hitherto unreported htb type topology was synthesized from a linear diamine linker and a judiciously designed tetra-aldehyde building block. Finally, this work opens the door to the development of COFs with unprecedented topologies and may broaden the scope of COF functional materials by pore size and pore surface engineering.

Authors:

^[1]; He, Zi-Hao ^[2]; Li, Xin-Le ^[3]; Zhang, Kai ^[2];

^[2];

^[3]; Zhang, Wei-Guang ^[2]

South China Normal Univ. Guangzhou (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
South China Normal Univ. Guangzhou (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry

Publication Date:: Mon Oct 14 00:00:00 EDT 2019

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division (SC-22.3); National Natural Science Foundation of China (NSFC); Natural Science Foundation of Guangdong Province; USDOE

OSTI Identifier:: 1599817

Alternate Identifier(s):: OSTI ID: 1571689

Grant/Contract Number:: AC02-05CH11231; 21603076; 21571070; 216A030310437; 2018A030313093

Resource Type:: Accepted Manuscript

Journal Name:: ChemComm

Additional Journal Information:: Journal Volume: 55; Journal Issue: 89; Journal ID: ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Cai, Song-Liang, He, Zi-Hao, Li, Xin-Le, Zhang, Kai, Zheng, Sheng-Run, Fan, Jun, Liu, Yi, and Zhang, Wei-Guang. An unprecedented 2D covalent organic framework with an htb net topology.  United States: N. p., 2019. 
Web.  doi:10.1039/c9cc06780a.

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                    Cai, Song-Liang, He, Zi-Hao, Li, Xin-Le, Zhang, Kai, Zheng, Sheng-Run, Fan, Jun, Liu, Yi, & Zhang, Wei-Guang. An unprecedented 2D covalent organic framework with an htb net topology.  United States.  https://doi.org/10.1039/c9cc06780a

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                    Cai, Song-Liang, He, Zi-Hao, Li, Xin-Le, Zhang, Kai, Zheng, Sheng-Run, Fan, Jun, Liu, Yi, and Zhang, Wei-Guang. Mon .  
"An unprecedented 2D covalent organic framework with an htb net topology".  United States.  https://doi.org/10.1039/c9cc06780a.  https://www.osti.gov/servlets/purl/1599817.

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@article{osti_1599817,

  title        = {An unprecedented 2D covalent organic framework with an htb net topology},

  author       = {Cai, Song-Liang and He, Zi-Hao and Li, Xin-Le and Zhang, Kai and Zheng, Sheng-Run and Fan, Jun and Liu, Yi and Zhang, Wei-Guang},

  abstractNote = {A 2D imine-linked COF with a hitherto unreported htb type topology was synthesized from a linear diamine linker and a judiciously designed tetra-aldehyde building block. Finally, this work opens the door to the development of COFs with unprecedented topologies and may broaden the scope of COF functional materials by pore size and pore surface engineering.},

  doi          = {10.1039/c9cc06780a},

  journal      = {ChemComm},

  number       = 89,

  volume       = 55,

  place        = {United States},

  year         = {Mon Oct 14 00:00:00 EDT 2019},

  month        = {Mon Oct 14 00:00:00 EDT 2019}

}

Copy to clipboard

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Works referenced in this record:

Constructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks
journal, September 2016

Xu, Hai-Sen; Ding, San-Yuan; An, Wan-Kai
Journal of the American Chemical Society, Vol. 138, Issue 36
DOI: 10.1021/jacs.6b07516

Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II)
journal, February 2016

Ding, San-Yuan; Dong, Ming; Wang, Ya-Wen
Journal of the American Chemical Society, Vol. 138, Issue 9
DOI: 10.1021/jacs.5b10754

Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene
journal, April 2011

Colson, J. W.; Woll, A. R.; Mukherjee, A.
Science, Vol. 332, Issue 6026
DOI: 10.1126/science.1202747

Desymmetrized Vertex Design for the Synthesis of Covalent Organic Frameworks with Periodically Heterogeneous Pore Structures
journal, October 2015

Zhu, Youlong; Wan, Shun; Jin, Yinghua
Journal of the American Chemical Society, Vol. 137, Issue 43
DOI: 10.1021/jacs.5b09487

Luminescent metal–organic frameworks for chemical sensing and explosive detection
journal, January 2014

Hu, Zhichao; Deibert, Benjamin J.; Li, Jing
Chem. Soc. Rev., Vol. 43, Issue 16
DOI: 10.1039/C4CS00010B

The atom, the molecule, and the covalent organic framework
journal, March 2017

Diercks, Christian S.; Yaghi, Omar M.
Science, Vol. 355, Issue 6328
DOI: 10.1126/science.aal1585

3D Anionic Silicate Covalent Organic Framework with srs Topology
journal, April 2018

Yahiaoui, Oussama; Fitch, Andrew N.; Hoffmann, Frank
Journal of the American Chemical Society, Vol. 140, Issue 16
DOI: 10.1021/jacs.8b01774

Tessellated multiporous two-dimensional covalent organic frameworks
journal, July 2017

Jin, Yinghua; Hu, Yiming; Zhang, Wei
Nature Reviews Chemistry, Vol. 1, Issue 7
DOI: 10.1038/s41570-017-0056

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework
journal, April 2009

Uribe-Romo, Fernando J.; Hunt, Joseph R.; Furukawa, Hiroyasu
Journal of the American Chemical Society, Vol. 131, Issue 13, p. 4570-4571
DOI: 10.1021/ja8096256

Covalent organic frameworks: a materials platform for structural and functional designs
journal, September 2016

Huang, Ning; Wang, Ping; Jiang, Donglin
Nature Reviews Materials, Vol. 1, Issue 10
DOI: 10.1038/natrevmats.2016.68

Construction of a hydrazone-linked chiral covalent organic framework–silica composite as the stationary phase for high performance liquid chromatography
journal, October 2017

Zhang, Kai; Cai, Song-Liang; Yan, Yi-Lun
Journal of Chromatography A, Vol. 1519
DOI: 10.1016/j.chroma.2017.09.007

Designed Synthesis of 3D Covalent Organic Frameworks
journal, April 2007

El-Kaderi, Hani M.; Hunt, Joseph R.; Mendoza-Cortes, Jose L.
Science, Vol. 316, Issue 5822, p. 268-272
DOI: 10.1126/science.1139915

Precision Construction of 2D Heteropore Covalent Organic Frameworks by a Multiple-Linking-Site Strategy
journal, October 2016

Qian, Cheng; Xu, Shun-Qi; Jiang, Guo-Fang
Chemistry - A European Journal, Vol. 22, Issue 49
DOI: 10.1002/chem.201603043

An Azine-Linked Covalent Organic Framework
journal, November 2013

Dalapati, Sasanka; Jin, Shangbin; Gao, Jia
Journal of the American Chemical Society, Vol. 135, Issue 46
DOI: 10.1021/ja4103293

Construction of 2D covalent organic frameworks by taking advantage of the variable orientation of imine bonds
journal, January 2017

Xu, Shun-Qi; Liang, Rong-Ran; Zhan, Tian-Guang
Chemical Communications, Vol. 53, Issue 16
DOI: 10.1039/C6CC09906H

Construction of Covalent Organic Frameworks Bearing Three Different Kinds of Pores through the Heterostructural Mixed Linker Strategy
journal, March 2016

Pang, Zhong-Fu; Xu, Shun-Qi; Zhou, Tian-You
Journal of the American Chemical Society, Vol. 138, Issue 14
DOI: 10.1021/jacs.6b01244

Systematic Tuning and Multifunctionalization of Covalent Organic Polymers for Enhanced Carbon Capture
journal, October 2015

Xiang, Zhonghua; Mercado, Rocio; Huck, Johanna M.
Journal of the American Chemical Society, Vol. 137, Issue 41
DOI: 10.1021/jacs.5b06266

A Pyrene-Based, Fluorescent Three-Dimensional Covalent Organic Framework
journal, March 2016

Lin, Guiqing; Ding, Huimin; Yuan, Daqiang
Journal of the American Chemical Society, Vol. 138, Issue 10
DOI: 10.1021/jacs.6b00652

Rational design of crystalline supermicroporous covalent organic frameworks with triangular topologies
journal, July 2015

Dalapati, Sasanka; Addicoat, Matthew; Jin, Shangbin
Nature Communications, Vol. 6, Issue 1
DOI: 10.1038/ncomms8786

A microporous lanthanum metal–organic framework as a bi-functional chemosensor for the detection of picric acid and Fe ³⁺ ions
journal, January 2015

Zhang, Chuanqi; Yan, Yan; Pan, Qinhe
Dalton Transactions, Vol. 44, Issue 29
DOI: 10.1039/C5DT01065A

Covalent Organic Frameworks as Exceptional Hydrogen Storage Materials
journal, September 2008

Han, Sang Soo; Furukawa, Hiroyasu; Yaghi, Omar M.
Journal of the American Chemical Society, Vol. 130, Issue 35, p. 11580-11581
DOI: 10.1021/ja803247y

Visible-light-induced photoelectrochemical behaviors of Fe-modified TiO2 nanotube arrays
journal, January 2011

Xu, Zhihua; Yu, Jiaguo
Nanoscale, Vol. 3, Issue 8
DOI: 10.1039/c1nr10282f

Chiral Covalent Organic Frameworks with High Chemical Stability for Heterogeneous Asymmetric Catalysis
journal, June 2017

Han, Xing; Xia, Qingchun; Huang, Jinjing
Journal of the American Chemical Society, Vol. 139, Issue 25
DOI: 10.1021/jacs.7b04008

Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005

Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
Science, Vol. 310, Issue 5751, p. 1166-1170
DOI: 10.1126/science.1120411

Toward Covalent Organic Frameworks Bearing Three Different Kinds of Pores: The Strategy for Construction and COF-to-COF Transformation via Heterogeneous Linker Exchange
journal, May 2017

Qian, Cheng; Qi, Qiao-Yan; Jiang, Guo-Fang
Journal of the American Chemical Society, Vol. 139, Issue 19
DOI: 10.1021/jacs.7b02303

Synthesis of Metallophthalocyanine Covalent Organic Frameworks That Exhibit High Carrier Mobility and Photoconductivity
journal, December 2010

Ding, Xuesong; Guo, Jia; Feng, Xiao
Angewandte Chemie International Edition, Vol. 50, Issue 6
DOI: 10.1002/anie.201005919

Rationally Designed 2D Covalent Organic Framework with a Brick-Wall Topology
journal, November 2016

Cai, Song-Liang; Zhang, Kai; Tan, Jing-Bo
ACS Macro Letters, Vol. 5, Issue 12
DOI: 10.1021/acsmacrolett.6b00805

Bottom-up synthesis of chiral covalent organic frameworks and their bound capillaries for chiral separation
journal, July 2016

Qian, Hai-Long; Yang, Cheng-Xiong; Yan, Xiu-Ping
Nature Communications, Vol. 7, Issue 1
DOI: 10.1038/ncomms12104

Chiral 3D Covalent Organic Frameworks for High Performance Liquid Chromatographic Enantioseparation
journal, January 2018

Han, Xing; Huang, Jinjing; Yuan, Chen
Journal of the American Chemical Society, Vol. 140, Issue 3
DOI: 10.1021/jacs.7b12110

One-Step Construction of Two Different Kinds of Pores in a 2D Covalent Organic Framework
journal, October 2014

Zhou, Tian-You; Xu, Shun-Qi; Wen, Qiang
Journal of the American Chemical Society, Vol. 136, Issue 45
DOI: 10.1021/ja5092936

Multiple-component covalent organic frameworks
journal, July 2016

Huang, Ning; Zhai, Lipeng; Coupry, Damien E.
Nature Communications, Vol. 7, Issue 1
DOI: 10.1038/ncomms12325

Stable Hydrazone-Linked Covalent Organic Frameworks Containing O,N,O′-Chelating Sites for Fe(III) Detection in Water
journal, March 2019

Chen, Gui; Lan, Hai-Hang; Cai, Song-Liang
ACS Applied Materials & Interfaces, Vol. 11, Issue 13
DOI: 10.1021/acsami.9b02640

A Photoconductive Thienothiophene-Based Covalent Organic Framework Showing Charge Transfer Towards Included Fullerene
journal, February 2013

Dogru, Mirjam; Handloser, Matthias; Auras, Florian
Angewandte Chemie International Edition, Vol. 52, Issue 10
DOI: 10.1002/anie.201208514

Reticular Synthesis of Multinary Covalent Organic Frameworks
journal, June 2019

Zhang, Bing; Mao, Haiyan; Matheu, Roc
Journal of the American Chemical Society, Vol. 141, Issue 29
DOI: 10.1021/jacs.9b05626

Tunable electrical conductivity in oriented thin films of tetrathiafulvalene-based covalent organic framework
journal, January 2014

Cai, Song-Liang; Zhang, Yue-Biao; Pun, Andrew B.
Chem. Sci., Vol. 5, Issue 12
DOI: 10.1039/C4SC02593H

Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets
journal, September 2011

O’Keeffe, Michael; Yaghi, Omar M.
Chemical Reviews, Vol. 112, Issue 2, p. 675-702
DOI: 10.1021/cr200205j

Synthesis of Metallophthalocyanine Covalent Organic Frameworks That Exhibit High Carrier Mobility and Photoconductivity
journal, December 2010

Ding, Xuesong; Guo, Jia; Feng, Xiao
Angewandte Chemie, Vol. 123, Issue 6
DOI: 10.1002/ange.201005919

A Photoconductive Thienothiophene-Based Covalent Organic Framework Showing Charge Transfer Towards Included Fullerene
journal, February 2013

Dogru, Mirjam; Handloser, Matthias; Auras, Florian
Angewandte Chemie, Vol. 125, Issue 10
DOI: 10.1002/ange.201208514

Works referencing / citing this record:

Ultrahigh Responsivity Photodetectors of 2D Covalent Organic Frameworks Integrated on Graphene
journal, January 2020

Xiong, Yifeng; Liao, Qiaobo; Huang, Zhengping
Advanced Materials, Vol. 32, Issue 9
DOI: 10.1002/adma.201907242

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Title: An unprecedented 2D covalent organic framework with an htb net topology

Abstract

Citation Formats

Constructing Crystalline Covalent Organic Frameworks from Chiral Building Blocks journal, September 2016

Thioether-Based Fluorescent Covalent Organic Framework for Selective Detection and Facile Removal of Mercury(II) journal, February 2016

Oriented 2D Covalent Organic Framework Thin Films on Single-Layer Graphene journal, April 2011

Desymmetrized Vertex Design for the Synthesis of Covalent Organic Frameworks with Periodically Heterogeneous Pore Structures journal, October 2015

Luminescent metal–organic frameworks for chemical sensing and explosive detection journal, January 2014

The atom, the molecule, and the covalent organic framework journal, March 2017

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Tessellated multiporous two-dimensional covalent organic frameworks journal, July 2017

A Crystalline Imine-Linked 3-D Porous Covalent Organic Framework journal, April 2009

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Deconstructing the Crystal Structures of Metal–Organic Frameworks and Related Materials into Their Underlying Nets journal, September 2011

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journal, October 2015

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journal, January 2015

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