Harvesting 48V at the National Superconducting Cyclotron Laboratory

Loveless, C. Shaun; Marois, Boone E.; Ferran, Samuel J.; Wilkinson, John T.; Sutherlin, Logan; Severin, Gregory; Shusterman, Jennifer A.; Scielzo, Nicholas D.; Stoyer, Mark A.; Morrissey, David J.; Robertson, J. David; Peaslee, Graham F.; Lapi, Suzanne E.

doi:10.1016/j.apradiso.2019.109023

Title: Harvesting 48V at the National Superconducting Cyclotron Laboratory

Journal Article · 11 December 2019 · Applied Radiation and Isotopes

DOI: https://doi.org/10.1016/j.apradiso.2019.109023 · OSTI ID:1599563

Loveless, C. Shaun ^[1]; Marois, Boone E. ^[2]; Ferran, Samuel J. ^[3]; Wilkinson, John T. ^[4]; Sutherlin, Logan ^[5]; Severin, Gregory ^[6]; Shusterman, Jennifer A. ^[7]; Scielzo, Nicholas D. ^[8]; Stoyer, Mark A. ^[8]; Morrissey, David J. ^[6]; Robertson, J. David ^[5]; Peaslee, Graham F. ^[4]; Lapi, Suzanne E. ^[3]

Univ. of Alabama, Birmingham, AL (United States); Washington Univ., St. Louis, MO (United States)
Hope College, Holland, MI (United States). Dept. of Chemistry
Univ. of Alabama, Birmingham, AL (United States)
Univ. of Notre Dame, IN (United States)
Univ. of Missouri, Columbia, MO (United States). Dept. of Chemistry
Michigan State Univ., East Lansing, MI (United States)
City Univ. of New York (CUNY), NY (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

As part of a project to develop aqueous isotope harvesting techniques at radioactive beam facilities, ⁴⁸V and a cocktail of primary- and secondary-beam ions created by the fragmentation reaction of a 160 MeV/nucleon ⁵⁸Ni beam were stopped in an aqueous target cell. After collection, ⁴⁸V was separated from the mixture of beam ions using cation-exchange chromatography. The extraction efficiency from the aqueous solution was (47.0 ± 2.5)%, and the isolated ⁴⁸V had a radiochemical purity of 95.8%. This proof-of-concept work shows that aqueous isotope harvesting could provide significant quantities of rare isotopes which are currently unavailable at conventional facilities.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1599563

Report Number(s):: LLNL-JRNL--756931; 891574

Journal Information:: Applied Radiation and Isotopes, Journal Name: Applied Radiation and Isotopes Journal Issue: C Vol. 157; ISSN 0969-8043

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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