Harvesting 48V at the National Superconducting Cyclotron Laboratory

Loveless, C. Shaun; Marois, Boone E.; Ferran, Samuel J.; Wilkinson, John T.; Sutherlin, Logan; Severin, Gregory; Shusterman, Jennifer A.; Scielzo, Nicholas D.; Stoyer, Mark A.; Morrissey, David J.; Robertson, J. David; Peaslee, Graham F.; Lapi, Suzanne E.

doi:10.1016/j.apradiso.2019.109023

Title: Harvesting 48V at the National Superconducting Cyclotron Laboratory

Abstract

As part of a project to develop aqueous isotope harvesting techniques at radioactive beam facilities, ⁴⁸V and a cocktail of primary- and secondary-beam ions created by the fragmentation reaction of a 160 MeV/nucleon ⁵⁸Ni beam were stopped in an aqueous target cell. After collection, ⁴⁸V was separated from the mixture of beam ions using cation-exchange chromatography. The extraction efficiency from the aqueous solution was (47.0 ± 2.5)%, and the isolated ⁴⁸V had a radiochemical purity of 95.8%. This proof-of-concept work shows that aqueous isotope harvesting could provide significant quantities of rare isotopes which are currently unavailable at conventional facilities.

Authors:

Loveless, C. Shaun ^[1]; Marois, Boone E. ^[2]; Ferran, Samuel J. ^[3]; Wilkinson, John T. ^[4]; Sutherlin, Logan ^[5]; Severin, Gregory ^[6]; Shusterman, Jennifer A. ^[7]; Scielzo, Nicholas D. ^[8]; Stoyer, Mark A. ^[8]; Morrissey, David J. ^[6]; Robertson, J. David ^[5]; Peaslee, Graham F. ^[4]; Lapi, Suzanne E. ^[3]

Univ. of Alabama, Birmingham, AL (United States); Washington Univ., St. Louis, MO (United States)
Hope College, Holland, MI (United States). Dept. of Chemistry
Univ. of Alabama, Birmingham, AL (United States)
Univ. of Notre Dame, IN (United States)
Univ. of Missouri, Columbia, MO (United States). Dept. of Chemistry
Michigan State Univ., East Lansing, MI (United States)
City Univ. of New York (CUNY), NY (United States)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

Publication Date:: Wed Dec 11 00:00:00 EST 2019

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1599563

Alternate Identifier(s):: OSTI ID: 1596160

Report Number(s):: LLNL-JRNL-756931
Journal ID: ISSN 0969-8043; 891574; TRN: US2103478

Grant/Contract Number:: AC52-07NA27344; 16-ERD-022

Resource Type:: Accepted Manuscript

Journal Name:: Applied Radiation and Isotopes

Additional Journal Information:: Journal Volume: 157; Journal Issue: C; Journal ID: ISSN 0969-8043

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 07 ISOTOPE AND RADIATION SOURCES; Physics; Nuclear science and engineering; Nuclear physics and radiation physics; ⁴⁸VI; sotope harvesting; Heavy-ion fragmentation; National superconducting cyclotron laboratory

Citation Formats


                    Loveless, C. Shaun, Marois, Boone E., Ferran, Samuel J., Wilkinson, John T., Sutherlin, Logan, Severin, Gregory, Shusterman, Jennifer A., Scielzo, Nicholas D., Stoyer, Mark A., Morrissey, David J., Robertson, J. David, Peaslee, Graham F., and Lapi, Suzanne E. Harvesting 48V at the National Superconducting Cyclotron Laboratory.  United States: N. p., 2019. 
Web.  doi:10.1016/j.apradiso.2019.109023.

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                    Loveless, C. Shaun, Marois, Boone E., Ferran, Samuel J., Wilkinson, John T., Sutherlin, Logan, Severin, Gregory, Shusterman, Jennifer A., Scielzo, Nicholas D., Stoyer, Mark A., Morrissey, David J., Robertson, J. David, Peaslee, Graham F., & Lapi, Suzanne E. Harvesting 48V at the National Superconducting Cyclotron Laboratory.  United States.  https://doi.org/10.1016/j.apradiso.2019.109023

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                    Loveless, C. Shaun, Marois, Boone E., Ferran, Samuel J., Wilkinson, John T., Sutherlin, Logan, Severin, Gregory, Shusterman, Jennifer A., Scielzo, Nicholas D., Stoyer, Mark A., Morrissey, David J., Robertson, J. David, Peaslee, Graham F., and Lapi, Suzanne E. Wed .  
"Harvesting 48V at the National Superconducting Cyclotron Laboratory".  United States.  https://doi.org/10.1016/j.apradiso.2019.109023.  https://www.osti.gov/servlets/purl/1599563.

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@article{osti_1599563,

  title        = {Harvesting 48V at the National Superconducting Cyclotron Laboratory},

  author       = {Loveless, C. Shaun and Marois, Boone E. and Ferran, Samuel J. and Wilkinson, John T. and Sutherlin, Logan and Severin, Gregory and Shusterman, Jennifer A. and Scielzo, Nicholas D. and Stoyer, Mark A. and Morrissey, David J. and Robertson, J. David and Peaslee, Graham F. and Lapi, Suzanne E.},

  abstractNote = {As part of a project to develop aqueous isotope harvesting techniques at radioactive beam facilities, 48V and a cocktail of primary- and secondary-beam ions created by the fragmentation reaction of a 160 MeV/nucleon 58Ni beam were stopped in an aqueous target cell. After collection, 48V was separated from the mixture of beam ions using cation-exchange chromatography. The extraction efficiency from the aqueous solution was (47.0 ± 2.5)%, and the isolated 48V had a radiochemical purity of 95.8%. This proof-of-concept work shows that aqueous isotope harvesting could provide significant quantities of rare isotopes which are currently unavailable at conventional facilities.},

  doi          = {10.1016/j.apradiso.2019.109023},

  journal      = {Applied Radiation and Isotopes},

  number       = C,

  volume       = 157,

  place        = {United States},

  year         = {Wed Dec 11 00:00:00 EST 2019},

  month        = {Wed Dec 11 00:00:00 EST 2019}

}

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Title: Harvesting 48V at the National Superconducting Cyclotron Laboratory

Abstract

Citation Formats

Isotope harvesting at FRIB: additional opportunities for scientific discovery journal, August 2019

Revised pourbaix diagrams for chromium at 25–300 °C journal, January 1997

Vanadium Peroxide Complexes journal, May 1994

Radiometals for Combined Imaging and Therapy journal, October 2012

Fishing for Isotopes: Capturing Beryllium-7 from Brookhaven LINAC Isotope Producer’s 300 gallons of Cooling Water journal, March 2018

Cation Exchange Separation of Vanadium from Metal Ions. journal, August 1962

Identification and separation of radioactive isotope beams by the BigRIPS separator at the RIKEN RI Beam Factory journal, December 2013

Plan of LLFP Neutron Cross Section Measurements for Nuclear Transmutation journal, August 2002

Hydrous oxides and their cation-exchange properties journal, October 1965

Ni 62 ( n , γ ) and Ni 63 ( n , γ ) cross sections measured at the n_TOF facility at CERN journal, February 2014

Feasibility of Isotope Harvesting at a Projectile Fragmentation Facility: 67Cu journal, October 2014

Harvesting 67 Cu from the Collection of a Secondary Beam Cocktail at the National Superconducting Cyclotron Laboratory journal, October 2015

Commissioning the A1900 projectile fragment separator journal, May 2003

The Role of the Nuclear Reaction Data Centres in Experimental Nuclear Data Knowledge Sharing journal, August 2011

Design and construction of a water target system for harvesting radioisotopes at the National Superconducting Cyclotron Laboratory journal, May 2014

Peroxo complexes of titanium journal, November 1970

Paving the Way to Personalized Medicine: Production of Some Promising Theragnostic Radionuclides at Brookhaven National Laboratory journal, May 2012

Improved empirical parametrization of fragmentation cross sections journal, July 2012

Discovery of new isotopes Mo 81 , 82 and Ru 85 , 86 and a determination of the particle instability of 103 Sb journal, September 2017

LISE++: Radioactive beam production with in-flight separators journal, October 2008

Cross-sections for (p,x) reactions on natural chromium for the production of 52,52m,54Mn radioisotopes journal, February 2015

Isotope harvesting at FRIB: additional opportunities for scientific discovery
journal, August 2019

Revised pourbaix diagrams for chromium at 25–300 °C
journal, January 1997

Vanadium Peroxide Complexes
journal, May 1994

Radiometals for Combined Imaging and Therapy
journal, October 2012

Fishing for Isotopes: Capturing Beryllium-7 from Brookhaven LINAC Isotope Producer’s 300 gallons of Cooling Water
journal, March 2018

Cation Exchange Separation of Vanadium from Metal Ions.
journal, August 1962

Identification and separation of radioactive isotope beams by the BigRIPS separator at the RIKEN RI Beam Factory
journal, December 2013

Plan of LLFP Neutron Cross Section Measurements for Nuclear Transmutation
journal, August 2002

Hydrous oxides and their cation-exchange properties
journal, October 1965

${}^{62}{Ni}$ ( $n, γ$ ) and ${}^{63}{Ni}$ ( $n, γ$ ) cross sections measured at the n_TOF facility at CERN
journal, February 2014

Feasibility of Isotope Harvesting at a Projectile Fragmentation Facility: 67Cu
journal, October 2014

Harvesting ⁶⁷ Cu from the Collection of a Secondary Beam Cocktail at the National Superconducting Cyclotron Laboratory
journal, October 2015

Commissioning the A1900 projectile fragment separator
journal, May 2003

The Role of the Nuclear Reaction Data Centres in Experimental Nuclear Data Knowledge Sharing
journal, August 2011

Design and construction of a water target system for harvesting radioisotopes at the National Superconducting Cyclotron Laboratory
journal, May 2014

Peroxo complexes of titanium
journal, November 1970

Paving the Way to Personalized Medicine: Production of Some Promising Theragnostic Radionuclides at Brookhaven National Laboratory
journal, May 2012

Improved empirical parametrization of fragmentation cross sections
journal, July 2012

Discovery of new isotopes ${}^{81, 82}{Mo}$ and ${}^{85, 86}{Ru}$ and a determination of the particle instability of $^{103} Sb$
journal, September 2017

LISE++: Radioactive beam production with in-flight separators
journal, October 2008

Cross-sections for (p,x) reactions on natural chromium for the production of 52,52m,54Mn radioisotopes
journal, February 2015