Control of quantum dot emission by colloidal plasmonic pyramids in a liquid crystal
Abstract
We study the plasmon-enhanced fluorescence of a single semiconducting quantum dot near the apex of a colloidal gold pyramid spatially localized by the elastic forces of the liquid crystal host. The gold pyramid particles were manipulated within the liquid crystal medium by laser tweezers, enabling the self-assembly of a semiconducting quantum dot dispersed in the medium near the apex of the gold pyramid, allowing us to probe the plasmon-exciton interactions. We demonstrate the effect of plasmon coupling on the fluorescence lifetime and the blinking properties of the quantum dot. Our results demonstrate that topological defects around colloidal particles in liquid crystal combined with laser tweezers provide a platform for plasmon exciton interaction studies and potentially could be extended to the scale of composite materials for nanophotonic applications.
- Authors:
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1599261
- Alternate Identifier(s):
- OSTI ID: 1600905
- Report Number(s):
- NREL/JA-5900-75469
Journal ID: ISSN 1094-4087; OPEXFF
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Published Article
- Journal Name:
- Optics Express
- Additional Journal Information:
- Journal Name: Optics Express Journal Volume: 28 Journal Issue: 4; Journal ID: ISSN 1094-4087
- Publisher:
- Optical Society of America (OSA)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; plasmonics; quantum dots; light emission; blinking
Citation Formats
Mundoor, Haridas, Cruz-Colón, Enid M., Park, Sungoh, Liu, Qingkun, Smalyukh, Ivan I., and van de Lagemaat, Jao. Control of quantum dot emission by colloidal plasmonic pyramids in a liquid crystal. United States: N. p., 2020.
Web. doi:10.1364/OE.383672.
Mundoor, Haridas, Cruz-Colón, Enid M., Park, Sungoh, Liu, Qingkun, Smalyukh, Ivan I., & van de Lagemaat, Jao. Control of quantum dot emission by colloidal plasmonic pyramids in a liquid crystal. United States. doi:10.1364/OE.383672.
Mundoor, Haridas, Cruz-Colón, Enid M., Park, Sungoh, Liu, Qingkun, Smalyukh, Ivan I., and van de Lagemaat, Jao. Wed .
"Control of quantum dot emission by colloidal plasmonic pyramids in a liquid crystal". United States. doi:10.1364/OE.383672.
@article{osti_1599261,
title = {Control of quantum dot emission by colloidal plasmonic pyramids in a liquid crystal},
author = {Mundoor, Haridas and Cruz-Colón, Enid M. and Park, Sungoh and Liu, Qingkun and Smalyukh, Ivan I. and van de Lagemaat, Jao},
abstractNote = {We study the plasmon-enhanced fluorescence of a single semiconducting quantum dot near the apex of a colloidal gold pyramid spatially localized by the elastic forces of the liquid crystal host. The gold pyramid particles were manipulated within the liquid crystal medium by laser tweezers, enabling the self-assembly of a semiconducting quantum dot dispersed in the medium near the apex of the gold pyramid, allowing us to probe the plasmon-exciton interactions. We demonstrate the effect of plasmon coupling on the fluorescence lifetime and the blinking properties of the quantum dot. Our results demonstrate that topological defects around colloidal particles in liquid crystal combined with laser tweezers provide a platform for plasmon exciton interaction studies and potentially could be extended to the scale of composite materials for nanophotonic applications.},
doi = {10.1364/OE.383672},
journal = {Optics Express},
number = 4,
volume = 28,
place = {United States},
year = {2020},
month = {2}
}
DOI: 10.1364/OE.383672
Works referenced in this record:
Physics of colloidal dispersions in nematic liquid crystals
journal, October 2001
- Stark, Holger
- Physics Reports, Vol. 351, Issue 6
Triclinic nematic colloidal crystals from competing elastic and electrostatic interactions
journal, March 2016
- Mundoor, H.; Senyuk, B.; Smalyukh, I. I.
- Science, Vol. 352, Issue 6281
Plasmon–Exciton Interactions Probed Using Spatial Coentrapment of Nanoparticles by Topological Singularities
journal, October 2015
- Ackerman, Paul J.; Mundoor, Haridas; Smalyukh, Ivan I.
- ACS Nano, Vol. 9, Issue 12
Topological defects in liquid crystals as templates for molecular self-assembly
journal, September 2015
- Wang, Xiaoguang; Miller, Daniel S.; Bukusoglu, Emre
- Nature Materials, Vol. 15, Issue 1
Nematic liquid crystal boojums with handles on colloidal handlebodies
journal, May 2013
- Liu, Qingkun; Senyuk, Bohdan; Tasinkevych, Mykola
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 23
Plasmonics for improved photovoltaic devices
journal, February 2010
- Atwater, Harry A.; Polman, Albert
- Nature Materials, Vol. 9, Issue 3, p. 205-213
Plasmon-Enhanced Energy Transfer for Improved Upconversion of Infrared Radiation in Doped-Lanthanide Nanocrystals
journal, December 2013
- Sun, Qi-C.; Mundoor, Haridas; Ribot, Josep C.
- Nano Letters, Vol. 14, Issue 1
Shape-Dependent Oriented Trapping and Scaffolding of Plasmonic Nanoparticles by Topological Defects for Self-Assembly of Colloidal Dimers in Liquid Crystals
journal, January 2012
- Senyuk, Bohdan; Evans, Julian S.; Ackerman, Paul J.
- Nano Letters, Vol. 12, Issue 2
Enhancement and Quenching of Single-Molecule Fluorescence
journal, March 2006
- Anger, Pascal; Bharadwaj, Palash; Novotny, Lukas
- Physical Review Letters, Vol. 96, Issue 11, Article No. 113002
Novel Colloidal Interactions in Anisotropic Fluids
journal, March 1997
- Poulin, P.
- Science, Vol. 275, Issue 5307
Colloidal plasmonic DNA-origami with photo-switchable chirality in liquid crystals
journal, January 2019
- Liu, Qingkun; Kuzyk, Anton; Endo, Masayuki
- Optics Letters, Vol. 44, Issue 11
Intrinsically ultrastrong plasmon–exciton interactions in crystallized films of carbon nanotubes
journal, November 2018
- Ho, Po-Hsun; Farmer, Damon B.; Tulevski, George S.
- Proceedings of the National Academy of Sciences, Vol. 115, Issue 50
Observation of Selective Plasmon-Exciton Coupling in Nonradiative Energy Transfer: Donor-Selective versus Acceptor-Selective Plexcitons
journal, June 2013
- Ozel, Tuncay; Hernandez-Martinez, Pedro Ludwig; Mutlugun, Evren
- Nano Letters, Vol. 13, Issue 7
Polymer and biopolymer mediated self-assembly of gold nanoparticles
journal, January 2008
- Ofir, Yuval; Samanta, Bappaditya; Rotello, Vincent M.
- Chemical Society Reviews, Vol. 37, Issue 9
Enhancement of Multiphoton Emission from Single CdSe Quantum Dots Coupled to Gold Films
journal, March 2013
- LeBlanc, Sharonda J.; McClanahan, Mason R.; Jones, Marcus
- Nano Letters, Vol. 13, Issue 4
Modified Power Law Behavior in Quantum Dot Blinking: A Novel Role for Biexcitons and Auger Ionization
journal, January 2009
- Peterson, Jeffrey J.; Nesbitt, David J.
- Nano Letters, Vol. 9, Issue 1
Amplified Spontaneous Emission in Semiconductor-Nanocrystal/Synthetic-Opal Composites: Optical-Gain Enhancement via a Photonic Crystal Pseudogap
journal, February 2006
- Maskaly, G. R.; Petruska, M. A.; Nanda, J.
- Advanced Materials, Vol. 18, Issue 3
Unidirectional Emission of a Quantum Dot Coupled to a Nanoantenna
journal, August 2010
- Curto, A. G.; Volpe, G.; Taminiau, T. H.
- Science, Vol. 329, Issue 5994
Imaging of Resonant Quenching of Surface Plasmons by Quantum Dots
journal, December 2006
- Romero, Manuel J.; van de Lagemaat, Jao; Mora-Sero, Ivan
- Nano Letters, Vol. 6, Issue 12
Plasmonic coupling in noble metal nanostructures
journal, March 2010
- Jain, Prashant K.; El-Sayed, Mostafa A.
- Chemical Physics Letters, Vol. 487, Issue 4-6
Radiative and Nonradiative Lifetime Engineering of Quantum Dots in Multiple Solvents by Surface Atom Stoichiometry and Ligands
journal, January 2013
- Omogo, Benard; Aldana, Jose F.; Heyes, Colin D.
- The Journal of Physical Chemistry C, Vol. 117, Issue 5
Colloidal Surfaces with Boundaries, Apex Boojums, and Nested Elastic Self-Assembly of Nematic Colloids
journal, December 2016
- Park, Sungoh; Liu, Qingkun; Smalyukh, Ivan I.
- Physical Review Letters, Vol. 117, Issue 27
Photoluminescence spectroscopy and lifetime measurements from self-assembled semiconductor-metal nanoparticle hybrid arrays
journal, August 2010
- Haridas, M.; Basu, J. K.; Gosztola, D. J.
- Applied Physics Letters, Vol. 97, Issue 8
Tuning and Switching a Plasmonic Quantum Dot “Sandwich” in a Nematic Line Defect
journal, February 2018
- Mundoor, Haridas; Sheetah, Ghadah H.; Park, Sungoh
- ACS Nano, Vol. 12, Issue 3
Plasmon Enhanced Solar-to-Fuel Energy Conversion
journal, August 2011
- Thomann, Isabell; Pinaud, Blaise A.; Chen, Zhebo
- Nano Letters, Vol. 11, Issue 8
Exciton−Plasmon Interaction and Hybrid Excitons in Semiconductor−Metal Nanoparticle Assemblies
journal, May 2006
- Govorov, Alexander O.; Bryant, Garnett W.; Zhang, Wei
- Nano Letters, Vol. 6, Issue 5
Fabrication of Free-Standing Metallic Pyramidal Shells
journal, December 2004
- Xu, Qiaobing; Tonks, Ian; Fuerstman, Michael J.
- Nano Letters, Vol. 4, Issue 12, p. 2509-2511
Liquid Crystal Colloids
journal, March 2018
- Smalyukh, Ivan I.
- Annual Review of Condensed Matter Physics, Vol. 9, Issue 1
Two-Dimensional DNA-Programmable Assembly of Nanoparticles at Liquid Interfaces
journal, May 2014
- Srivastava, Sunita; Nykypanchuk, Dmytro; Fukuto, Masafumi
- Journal of the American Chemical Society, Vol. 136, Issue 23
Plasmon Coupling of Gold Nanorods at Short Distances and in Different Geometries
journal, April 2009
- Funston, Alison M.; Novo, Carolina; Davis, Tim J.
- Nano Letters, Vol. 9, Issue 4