Thermochemistry of cation disordered Li ion battery cathode materials, (M′ = Nb and Ta, M′′ = Mn and Fe)
Abstract
Enthalpies of formation from oxides (Δ H f,ox ) of novel disordered Li 1+x Ta x Fe 1−2x O 2 and reported (M′′ = Mn 3+ and Fe 3+ ).
- Authors:
-
- Peter A. Rock Thermochemistry Laboratory, NEAT ORU, University of California, Davis, USA
- Publication Date:
- Research Org.:
- Univ. of California, Davis, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1599253
- Alternate Identifier(s):
- OSTI ID: 1800119
- Grant/Contract Number:
- FG02-03ER46053
- Resource Type:
- Published Article
- Journal Name:
- RSC Advances
- Additional Journal Information:
- Journal Name: RSC Advances Journal Volume: 10 Journal Issue: 11; Journal ID: ISSN 2046-2069
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Chemistry
Citation Formats
Subramani, Tamilarasan, and Navrotsky, Alexandra. Thermochemistry of cation disordered Li ion battery cathode materials, (M′ = Nb and Ta, M′′ = Mn and Fe). United Kingdom: N. p., 2020.
Web. doi:10.1039/C9RA09759G.
Subramani, Tamilarasan, & Navrotsky, Alexandra. Thermochemistry of cation disordered Li ion battery cathode materials, (M′ = Nb and Ta, M′′ = Mn and Fe). United Kingdom. https://doi.org/10.1039/C9RA09759G
Subramani, Tamilarasan, and Navrotsky, Alexandra. Wed .
"Thermochemistry of cation disordered Li ion battery cathode materials, (M′ = Nb and Ta, M′′ = Mn and Fe)". United Kingdom. https://doi.org/10.1039/C9RA09759G.
@article{osti_1599253,
title = {Thermochemistry of cation disordered Li ion battery cathode materials, (M′ = Nb and Ta, M′′ = Mn and Fe)},
author = {Subramani, Tamilarasan and Navrotsky, Alexandra},
abstractNote = {Enthalpies of formation from oxides (Δ H f,ox ) of novel disordered Li 1+x Ta x Fe 1−2x O 2 and reported (M′′ = Mn 3+ and Fe 3+ ).},
doi = {10.1039/C9RA09759G},
journal = {RSC Advances},
number = 11,
volume = 10,
place = {United Kingdom},
year = {2020},
month = {2}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1039/C9RA09759G
https://doi.org/10.1039/C9RA09759G
Other availability
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Stabilizing Effect of Mg on the Energetics of the Li(Ni,Co,Al)O 2 Cathode Material for Lithium Ion Batteries
journal, December 2012
- Tavakoli, Amir H.; Kondo, Hiroki; Ukyo, Yoshio
- Journal of The Electrochemical Society, Vol. 160, Issue 2
Double-slit photoelectron interference in strong-field ionization of the neon dimer
journal, January 2019
- Kunitski, Maksim; Eicke, Nicolas; Huber, Pia
- Nature Communications, Vol. 10, Issue 1
Die Kristallstruktur von Li2SnO3
journal, January 1971
- Kreuzburg, G.; Stewner, F.; Hoppe, R.
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 379, Issue 3
Challenges for Rechargeable Li Batteries
journal, February 2010
- Goodenough, John B.; Kim, Youngsik
- Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
Lithium Batteries and Cathode Materials
journal, October 2004
- Whittingham, M. Stanley
- Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
Characterization of Disordered Li (1+ x ) Ti 2 x Fe (1–3 x ) O 2 as Positive Electrode Materials in Li-Ion Batteries Using Percolation Theory
journal, November 2015
- Glazier, Stephen L.; Li, Jing; Zhou, Jigang
- Chemistry of Materials, Vol. 27, Issue 22
Mitigating oxygen loss to improve the cycling performance of high capacity cation-disordered cathode materials
journal, October 2017
- Lee, Jinhyuk; Papp, Joseph K.; Clément, Raphaële J.
- Nature Communications, Vol. 8, Issue 1
Short-range ordering in a battery electrode, the ‘cation-disordered’ rocksalt Li 1.25 Nb 0.25 Mn 0.5 O 2
journal, January 2019
- Jones, Michael A.; Reeves, Philip J.; Seymour, Ieuan D.
- Chemical Communications, Vol. 55, Issue 61
Enthalpy of formation of Li1+xMn2−xO4 (0<x<0.1) spinel phases
journal, January 2015
- Cupid, Damian M.; Reif, Alexandra; Seifert, Hans J.
- Thermochimica Acta, Vol. 599
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976
- Shannon, R. D.
- Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767
Lithium manganese oxyfluoride as a new cathode material exhibiting oxygen redox
journal, January 2018
- House, Robert A.; Jin, Liyu; Maitra, Urmimala
- Energy & Environmental Science, Vol. 11, Issue 4
The thermodynamics of cation distributions in simple spinels
journal, November 1967
- Navrotsky, A.; Kleppa, O. J.
- Journal of Inorganic and Nuclear Chemistry, Vol. 29, Issue 11
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006
- Kang, Kisuk; Shirley Meng, Ying; Breger, Julien
- Science, Vol. 311, Issue 5763, p. 977-980
Unravelling Solid-State Redox Chemistry in Li 1.3 Nb 0.3 Mn 0.4 O 2 Single-Crystal Cathode Material
journal, February 2018
- Kan, Wang Hay; Chen, Dongchang; Papp, Joseph K.
- Chemistry of Materials, Vol. 30, Issue 5
Magnetic Properties of Metastable Lithium Iron Oxides Obtained by Solvothermal/Hydrothermal Reaction
journal, December 1998
- Tabuchi, Mitsuharu; Ado, Kazuaki; Kobayashi, Hironori
- Journal of Solid State Chemistry, Vol. 141, Issue 2
Enthalpy of formation of LiNiO2, LiCoO2 and their solid solution, LiNi1−xCoxO2
journal, January 2004
- Wang, M.
- Solid State Ionics, Vol. 166, Issue 1-2
Mineralogy, materials science, energy, and environment: A 2015 perspective
journal, April 2015
- Navrotsky, A.
- American Mineralogist, Vol. 100, Issue 4
Enthalpy of Formation of Li[sub x]CoO[sub 2] (0.5 ≤ x ≤ 1.0)
journal, January 2005
- Wang, Miaojun; Navrotsky, Alexandra; Venkatraman, Sivaramakrishnan
- Journal of The Electrochemical Society, Vol. 152, Issue 7
Improvement of Cathode Properties by Lithium Excess in Disordered Rocksalt Li<sub>2+2</sub><i><sub>x</sub></i>Mn<sub>1−</sub><i><sub>x</sub></i>Ti<sub>1−</sub><i><sub>x</sub></i>O<sub>4</sub>
journal, January 2016
- Kitajou, Ayuko; Tanaka, Kosuke; Miki, Hidenori
- Electrochemistry, Vol. 84, Issue 8
GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013
- Toby, Brian H.; Von Dreele, Robert B.
- Journal of Applied Crystallography, Vol. 46, Issue 2
Structure and bonding in lithium ruthenate, Li2RuO3
journal, June 1988
- James, A. C. W. P.; Goodenough, J. B.
- Journal of Solid State Chemistry, Vol. 74, Issue 2
Understanding the Effect of Local Short-Range Ordering on Lithium Diffusion in Li1.3Nb0.3Mn0.4O2 Single-Crystal Cathode
journal, September 2018
- Kan, Wang Hay; Deng, Biao; Xu, Yahong
- Chem, Vol. 4, Issue 9
Unlocking the Potential of Cation-Disordered Oxides for Rechargeable Lithium Batteries
journal, January 2014
- Lee, J.; Urban, A.; Li, X.
- Science, Vol. 343, Issue 6170
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011
- Momma, Koichi; Izumi, Fujio
- Journal of Applied Crystallography, Vol. 44, Issue 6
Identifying the redox activity of cation-disordered Li–Fe–V–Ti oxide cathodes for Li-ion batteries
journal, January 2016
- Chen, Ruiyong; Witte, Ralf; Heinzmann, Ralf
- Physical Chemistry Chemical Physics, Vol. 18, Issue 11
Fine Li(4 ? x)/3Ti(2 ? 2x)/3FexO2 (0.18 ? x ? 0.67) powder with cubic rock-salt structure as a positive electrode material for rechargeable lithium batteries
journal, January 2003
- Tabuchi, Mitsuharu; Nakashima, Akiko; Shigemura, Hikari
- Journal of Materials Chemistry, Vol. 13, Issue 7
Synthesis and electrochemical properties of Li 1.3 Nb 0.3 V 0.4 O 2 as a positive electrode material for rechargeable lithium batteries
journal, January 2016
- Yabuuchi, Naoaki; Takeuchi, Mitsue; Komaba, Shinichi
- Chemical Communications, Vol. 52, Issue 10
Progress and new directions in high temperature calorimetry
journal, January 1977
- Navrotsky, Alexandra
- Physics and Chemistry of Minerals, Vol. 2, Issue 1-2
Design principles for high transition metal capacity in disordered rocksalt Li-ion cathodes
journal, January 2018
- Kitchaev, Daniil A.; Lun, Zhengyan; Richards, William D.
- Energy & Environmental Science, Vol. 11, Issue 8
Progress and New Directions in Calorimetry: A 2014 Perspective
journal, October 2014
- Navrotsky, Alexandra
- Journal of the American Ceramic Society, Vol. 97, Issue 11
Crystal growth and structure refinement of monoclinic Li2TiO3
journal, January 2009
- Kataoka, Kunimitsu; Takahashi, Yasuhiko; Kijima, Norihito
- Materials Research Bulletin, Vol. 44, Issue 1
The Configurational Space of Rocksalt-Type Oxides for High-Capacity Lithium Battery Electrodes
journal, May 2014
- Urban, Alexander; Lee, Jinhyuk; Ceder, Gerbrand
- Advanced Energy Materials, Vol. 4, Issue 13
LiMO2 (M=Mn, Fe, and Co): Energetics, polymorphism and phase transformation
journal, April 2005
- Wang, Miaojun; Navrotsky, Alexandra
- Journal of Solid State Chemistry, Vol. 178, Issue 4, p. 1230-1240
Progress and new directions in high temperature calorimetry revisited
journal, April 1997
- Navrotsky, Alexandra
- Physics and Chemistry of Minerals, Vol. 24, Issue 3
High-capacity electrode materials for rechargeable lithium batteries: Li 3 NbO 4 -based system with cation-disordered rocksalt structure
journal, June 2015
- Yabuuchi, Naoaki; Takeuchi, Mitsue; Nakayama, Masanobu
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 25
Thermochemistry of Li1+xMn2−xO4 (0⩽x⩽1/3) spinel
journal, April 2005
- Wang, Miaojun; Navrotsky, Alexandra
- Journal of Solid State Chemistry, Vol. 178, Issue 4
A new class of high capacity cation-disordered oxides for rechargeable lithium batteries: Li–Ni–Ti–Mo oxides
journal, January 2015
- Lee, Jinhyuk; Seo, Dong-Hwa; Balasubramanian, Mahalingam
- Energy & Environmental Science, Vol. 8, Issue 11
Evolution of Local Structural Ordering and Chemical Distribution upon Delithiation of a Rock Salt–Structured Li 1.3 Ta 0.3 Mn 0.4 O 2 Cathode
journal, February 2019
- Kan, Wang Hay; Wei, Chenxi; Chen, Dongchang
- Advanced Functional Materials, Vol. 29, Issue 17
Lithium Extraction and Insertion Behavior of Nanocrystalline Li[sub 2]TiO[sub 3]-LiFeO[sub 2] Solid Solution with Cubic Rock Salt Structure
journal, January 2003
- Shigemura, Hikari; Tabuchi, Mitsuharu; Sakaebe, Hikari
- Journal of The Electrochemical Society, Vol. 150, Issue 5