Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

Windorff, Cory J.; Celis-Barros, Cristian; Sperling, Joseph M.; McKinnon, Noah C.; Albrecht-Schmitt, Thomas E.

doi:10.1039/C9SC05268B

Title: Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

Journal Article · 10 March 2020 · Chemical Science

DOI: https://doi.org/10.1039/C9SC05268B · OSTI ID:1599242

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^[1]; McKinnon, Noah C. ^[1];

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Department of Chemistry and Biochemistry, Florida State University, Tallahassee, USA

Structural, spectroscopic and theoretical analyses of mer-MBr3(OPcy3)3 (M = Am, Nd, Pr, Ce, La) reveal significant amounts of metal based p-orbital contribution.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Florida State Univ., Tallahassee, FL (United States); Florida State University, Tallahassee, FL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0010677; SC0016568

OSTI ID:: 1599242

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 10 Vol. 11; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

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