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Title: Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes

Abstract

Structural, spectroscopic and theoretical analyses of mer-MBr3(OPcy3)3 (M = Am, Nd, Pr, Ce, La) reveal significant amounts of metal based p-orbital contribution.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1599242
Grant/Contract Number:  
FG02-13ER16414; SC0010677
Resource Type:
Published Article
Journal Name:
Chemical Science
Additional Journal Information:
Journal Name: Chemical Science; Journal ID: ISSN 2041-6520
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Windorff, Cory J., Celis-Barros, Cristian, Sperling, Joseph M., McKinnon, Noah C., and Albrecht-Schmitt, Thomas E. Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes. United Kingdom: N. p., 2020. Web. doi:10.1039/C9SC05268B.
Windorff, Cory J., Celis-Barros, Cristian, Sperling, Joseph M., McKinnon, Noah C., & Albrecht-Schmitt, Thomas E. Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes. United Kingdom. doi:10.1039/C9SC05268B.
Windorff, Cory J., Celis-Barros, Cristian, Sperling, Joseph M., McKinnon, Noah C., and Albrecht-Schmitt, Thomas E. Wed . "Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes". United Kingdom. doi:10.1039/C9SC05268B.
@article{osti_1599242,
title = {Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes},
author = {Windorff, Cory J. and Celis-Barros, Cristian and Sperling, Joseph M. and McKinnon, Noah C. and Albrecht-Schmitt, Thomas E.},
abstractNote = {Structural, spectroscopic and theoretical analyses of mer-MBr3(OPcy3)3 (M = Am, Nd, Pr, Ce, La) reveal significant amounts of metal based p-orbital contribution.},
doi = {10.1039/C9SC05268B},
journal = {Chemical Science},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
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DOI: 10.1039/C9SC05268B

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