Control of Physical and Chemical Processes with Nonlocal Metal–Dielectric Environments

Peters, Vanessa N.; Prayakarao, Srujana; Koutsares, Samantha R.; Bonner, Carl E.; Noginov, Mikhail A.

doi:10.1021/acsphotonics.9b00734

Title: Control of Physical and Chemical Processes with Nonlocal Metal–Dielectric Environments

Journal Article · 02 December 2019 · ACS Photonics

DOI: https://doi.org/10.1021/acsphotonics.9b00734 · OSTI ID:1598957

Peters, Vanessa N. ^[1]; Prayakarao, Srujana ^[1]; Koutsares, Samantha R. ^[1]; Bonner, Carl E. ^[1]; Noginov, Mikhail A. ^[1]

Norfolk State Univ., Norfolk, VA (United States)

In this report, we make the case that (meta) material platforms that were originally designed to control the propagation of light can affect scores of physical and chemical phenomena, which are often thought to lie outside of the traditional electrodynamics domain. We show that nonlocal metal-dielectric environments, which can be as simple as metal–dielectric interfaces, can control spontaneous and stimulated emission, Förster energy transfer, wetting contact angle, and rates of chemical reactions. The affected phenomena can occur in both strong and weak coupling regimes and the large coupling strength seems to enhance the effects of nonlocal environments. This intriguing field of study has experienced a rapid growth over the past decade and many exciting discoveries and applications are expected in the years to come.

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Research Organization:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC52-07NA27344

OSTI ID:: 1598957

Report Number(s):: LLNL-JRNL-772309; 964093

Journal Information:: ACS Photonics, Vol. 6, Issue 12; ISSN 2330-4022

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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