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Title: Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride

Abstract

We report that a small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found to retain the encapsulated fluoride anion within its cavity even after one or two pyrrolic NH protons were subject to deprotonation.

Authors:
 [1];  [1]; ORCiD logo [2];  [1]
  1. Gyeongsang National Univ., Jinju (Korea)
  2. Univ. of Texas, Austin, TX (United States)
Publication Date:
Research Org.:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Research Foundation of Korea (NRF); Robert A. Welch Foundation
OSTI Identifier:
1598888
Alternate Identifier(s):
OSTI ID: 1558130
Grant/Contract Number:  
FG02-01ER15186; NRF-2019R1F1A1061780; 2017R1A4A1014595; F-0018
Resource Type:
Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 55; Journal Issue: 73; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Han, Hye Jin, Oh, Ju Hyun, Sessler, Jonathan L., and Kim, Sung Kuk. Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride. United States: N. p., 2019. Web. https://doi.org/10.1039/C9CC05613K.
Han, Hye Jin, Oh, Ju Hyun, Sessler, Jonathan L., & Kim, Sung Kuk. Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride. United States. https://doi.org/10.1039/C9CC05613K
Han, Hye Jin, Oh, Ju Hyun, Sessler, Jonathan L., and Kim, Sung Kuk. Mon . "Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride". United States. https://doi.org/10.1039/C9CC05613K. https://www.osti.gov/servlets/purl/1598888.
@article{osti_1598888,
title = {Small triiminopyrrolic molecular cage with high affinity and selectivity for fluoride},
author = {Han, Hye Jin and Oh, Ju Hyun and Sessler, Jonathan L. and Kim, Sung Kuk},
abstractNote = {We report that a small molecular cage (4) with high affinity and complete selectivity for fluoride to the limit of detection over other competing small anions was synthesized. Cage 4 was also found to retain the encapsulated fluoride anion within its cavity even after one or two pyrrolic NH protons were subject to deprotonation.},
doi = {10.1039/C9CC05613K},
journal = {ChemComm},
number = 73,
volume = 55,
place = {United States},
year = {2019},
month = {8}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 6 works
Citation information provided by
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Figures / Tables:

Figure 1 Figure 1: Partial 1H NMR spectra recorded during the titration of cage 4 (3 mM) with TBAF (tetrabutylammonium fluoride) in the presence of TBACl, TBABr, TBAI, and (TBA)2SO4 (>10 equiv. each) in CDCl3.

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