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Title: Single‐Site, Single‐Metal‐Atom, Heterogeneous Electrocatalyst: Metal–Organic‐Framework Supported Molybdenum Sulfide for Redox Mediator‐Assisted Hydrogen Evolution Reaction

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [2];  [3];  [4];  [1]
  1. Department of ChemistryNorthwestern University 2145 Sheridan Rd. Evanston IL 60208 USA
  2. Department of ChemistryNorthwestern University 2145 Sheridan Rd. Evanston IL 60208 USA, College of Mechanics and MaterialsHohai University Nanjing 210098 China
  3. Department of Chemical and Biological EngineeringNorthwestern University 2145 Sheridan Rd. Evanston IL 60208 USA
  4. Department of ChemistryNorthwestern University 2145 Sheridan Rd. Evanston IL 60208 USA, Department of Chemical and Biological EngineeringNorthwestern University 2145 Sheridan Rd. Evanston IL 60208 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1598745
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
ChemElectroChem
Additional Journal Information:
Journal Name: ChemElectroChem Journal Volume: 7 Journal Issue: 2; Journal ID: ISSN 2196-0216
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Noh, Hyunho, Yang, Ying, Zhang, Xuan, Goetjen, Timothy A., Syed, Zoha H., Lu, Zhiyong, Ahn, Sol, Farha, Omar K., and Hupp, Joseph T. Single‐Site, Single‐Metal‐Atom, Heterogeneous Electrocatalyst: Metal–Organic‐Framework Supported Molybdenum Sulfide for Redox Mediator‐Assisted Hydrogen Evolution Reaction. Germany: N. p., 2020. Web. doi:10.1002/celc.201901650.
Noh, Hyunho, Yang, Ying, Zhang, Xuan, Goetjen, Timothy A., Syed, Zoha H., Lu, Zhiyong, Ahn, Sol, Farha, Omar K., & Hupp, Joseph T. Single‐Site, Single‐Metal‐Atom, Heterogeneous Electrocatalyst: Metal–Organic‐Framework Supported Molybdenum Sulfide for Redox Mediator‐Assisted Hydrogen Evolution Reaction. Germany. doi:10.1002/celc.201901650.
Noh, Hyunho, Yang, Ying, Zhang, Xuan, Goetjen, Timothy A., Syed, Zoha H., Lu, Zhiyong, Ahn, Sol, Farha, Omar K., and Hupp, Joseph T. Mon . "Single‐Site, Single‐Metal‐Atom, Heterogeneous Electrocatalyst: Metal–Organic‐Framework Supported Molybdenum Sulfide for Redox Mediator‐Assisted Hydrogen Evolution Reaction". Germany. doi:10.1002/celc.201901650.
@article{osti_1598745,
title = {Single‐Site, Single‐Metal‐Atom, Heterogeneous Electrocatalyst: Metal–Organic‐Framework Supported Molybdenum Sulfide for Redox Mediator‐Assisted Hydrogen Evolution Reaction},
author = {Noh, Hyunho and Yang, Ying and Zhang, Xuan and Goetjen, Timothy A. and Syed, Zoha H. and Lu, Zhiyong and Ahn, Sol and Farha, Omar K. and Hupp, Joseph T.},
abstractNote = {},
doi = {10.1002/celc.201901650},
journal = {ChemElectroChem},
number = 2,
volume = 7,
place = {Germany},
year = {2020},
month = {2}
}

Journal Article:
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Works referenced in this record:

The Fischer–Tropsch process: 1950–2000
journal, January 2002


Postsynthetic Tuning of Metal–Organic Frameworks for Targeted Applications
journal, February 2017


Coordination polymer structure and revisited hydrogen evolution catalytic mechanism for amorphous molybdenum sulfide
journal, March 2016

  • Tran, Phong D.; Tran, Thu V.; Orio, Maylis
  • Nature Materials, Vol. 15, Issue 6
  • DOI: 10.1038/nmat4588

Octahedral vs. trigonal-prismatic coordination and clustering in transition-metal dichalcogenides
journal, June 1984

  • Kertesz, Miklos; Hoffmann, Roald
  • Journal of the American Chemical Society, Vol. 106, Issue 12
  • DOI: 10.1021/ja00324a012

Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Molybdenum Speciation and its Impact on Catalytic Activity during Methane Dehydroaromatization in Zeolite ZSM-5 as Revealed by Operando X-Ray Methods
journal, March 2016

  • Lezcano-González, Inés; Oord, Ramon; Rovezzi, Mauro
  • Angewandte Chemie International Edition, Vol. 55, Issue 17
  • DOI: 10.1002/anie.201601357

Sub-5 nm Ultra-Fine FeP Nanodots as Efficient Co-Catalysts Modified Porous g-C 3 N 4 for Precious-Metal-Free Photocatalytic Hydrogen Evolution under Visible Light
journal, January 2019

  • Zeng, Deqian; Zhou, Ting; Ong, Wee-Jun
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 6
  • DOI: 10.1021/acsami.8b20958

Toward Inexpensive Photocatalytic Hydrogen Evolution: A Nickel Sulfide Catalyst Supported on a High-Stability Metal–Organic Framework
journal, August 2016

  • Peters, Aaron W.; Li, Zhanyong; Farha, Omar K.
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 32
  • DOI: 10.1021/acsami.6b04729

Modeling the Electrochemical Hydrogen Oxidation and Evolution Reactions on the Basis of Density Functional Theory Calculations
journal, October 2010

  • Skúlason, Egill; Tripkovic, Vladimir; Björketun, Mårten E.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 42
  • DOI: 10.1021/jp1048887

Molybdenum Speciation and its Impact on Catalytic Activity during Methane Dehydroaromatization in Zeolite ZSM-5 as Revealed by Operando X-Ray Methods
journal, March 2016

  • Lezcano-González, Inés; Oord, Ramon; Rovezzi, Mauro
  • Angewandte Chemie, Vol. 128, Issue 17
  • DOI: 10.1002/ange.201601357

Room Temperature Synthesis of an 8-Connected Zr-Based Metal–Organic Framework for Top-Down Nanoparticle Encapsulation
journal, March 2018


Recent advances in heterogeneous electrocatalysts for the hydrogen evolution reaction
journal, January 2015

  • Zeng, Min; Li, Yanguang
  • Journal of Materials Chemistry A, Vol. 3, Issue 29
  • DOI: 10.1039/C5TA02974K

Advances in the Development of Novel Cobalt Fischer−Tropsch Catalysts for Synthesis of Long-Chain Hydrocarbons and Clean Fuels
journal, May 2007

  • Khodakov, Andrei Y.; Chu, Wei; Fongarland, Pascal
  • Chemical Reviews, Vol. 107, Issue 5
  • DOI: 10.1021/cr050972v

Single-Atom-Based Vanadium Oxide Catalysts Supported on Metal–Organic Frameworks: Selective Alcohol Oxidation and Structure–Activity Relationship
journal, June 2018

  • Otake, Ken-ichi; Cui, Yuexing; Buru, Cassandra T.
  • Journal of the American Chemical Society, Vol. 140, Issue 28
  • DOI: 10.1021/jacs.8b05107

Fine-Tuning the Activity of Metal–Organic Framework-Supported Cobalt Catalysts for the Oxidative Dehydrogenation of Propane
journal, October 2017

  • Li, Zhanyong; Peters, Aaron W.; Platero-Prats, Ana E.
  • Journal of the American Chemical Society, Vol. 139, Issue 42
  • DOI: 10.1021/jacs.7b09365

Redox-Mediator-Assisted Electrocatalytic Hydrogen Evolution from Water by a Molybdenum Sulfide-Functionalized Metal–Organic Framework
journal, September 2018


Site-Directed Synthesis of Cobalt Oxide Clusters in a Metal–Organic Framework
journal, March 2018

  • Peters, Aaron W.; Otake, Kenichi; Platero-Prats, Ana E.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 17
  • DOI: 10.1021/acsami.8b02825

Über die Realstruktur von “Ammoniakeisen” und ihre Stabilität während des Haber-Bosch-Verfahrens
journal, October 2013

  • Kandemir, Timur; Schuster, Manfred E.; Senyshyn, Anatoliy
  • Angewandte Chemie, Vol. 125, Issue 48
  • DOI: 10.1002/ange.201305812

Enhanced Activity of Heterogeneous Pd(II) Catalysts on Acid-Functionalized Metal–Organic Frameworks
journal, April 2019


Single-Site Cobalt Catalysts at New Zr 82 -O) 82 -OH) 4 Metal-Organic Framework Nodes for Highly Active Hydrogenation of Alkenes, Imines, Carbonyls, and Heterocycles
journal, September 2016

  • Ji, Pengfei; Manna, Kuntal; Lin, Zekai
  • Journal of the American Chemical Society, Vol. 138, Issue 37
  • DOI: 10.1021/jacs.6b06759

An Exceptionally Stable Metal–Organic Framework Supported Molybdenum(VI) Oxide Catalyst for Cyclohexene Epoxidation
journal, October 2016

  • Noh, Hyunho; Cui, Yuexing; Peters, Aaron W.
  • Journal of the American Chemical Society, Vol. 138, Issue 44
  • DOI: 10.1021/jacs.6b08898

Facile Dimerization of Viologen Radical Cations Covalently Bonded to β-Cyclodextrin and Suppression of the Dimerization by β-Cyclodextrin and Amphiphiles
journal, January 1996

  • Park, Joon Woo; Choi, Nak Hee; Kim, Jung Ha
  • The Journal of Physical Chemistry, Vol. 100, Issue 2
  • DOI: 10.1021/jp9520308

Pushing the Limits on Metal–Organic Frameworks as a Catalyst Support: NU-1000 Supported Tungsten Catalysts for o -Xylene Isomerization and Disproportionation
journal, June 2018

  • Ahn, Sol; Nauert, Scott L.; Buru, Cassandra T.
  • Journal of the American Chemical Society, Vol. 140, Issue 27
  • DOI: 10.1021/jacs.8b04059

Topology and porosity control of metal–organic frameworks through linker functionalization
journal, January 2019

  • Lyu, Jiafei; Zhang, Xuan; Otake, Ken-ichi
  • Chemical Science, Vol. 10, Issue 4
  • DOI: 10.1039/C8SC04220A

Structure of intrazeolite molybdenum oxide clusters and their catalysis of the oxidation of ethyl alcohol
journal, May 2002

  • Okamoto, Yasuaki; Oshima, Nobuyuki; Kobayashi, Yasuhiro
  • Physical Chemistry Chemical Physics, Vol. 4, Issue 12
  • DOI: 10.1039/b108639c

How a century of ammonia synthesis changed the world
journal, September 2008

  • Erisman, Jan Willem; Sutton, Mark A.; Galloway, James
  • Nature Geoscience, Vol. 1, Issue 10
  • DOI: 10.1038/ngeo325

P ROSPECTS FOR B UILDING A H YDROGEN E NERGY I NFRASTRUCTURE
journal, November 1999


Catalyzing the Hydrogen Evolution Reaction (HER) with Molybdenum Sulfide Nanomaterials
journal, October 2014

  • Benck, Jesse D.; Hellstern, Thomas R.; Kibsgaard, Jakob
  • ACS Catalysis, Vol. 4, Issue 11
  • DOI: 10.1021/cs500923c

Defining the Proton Topology of the Zr6-Based Metal–Organic Framework NU-1000
journal, October 2014

  • Planas, Nora; Mondloch, Joseph E.; Tussupbayev, Samat
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 21, p. 3716-3723
  • DOI: 10.1021/jz501899j

Molybdenum Sulfide within a Metal–Organic Framework for Photocatalytic Hydrogen Evolution from Water
journal, January 2019

  • Noh, Hyunho; Yang, Ying; Ahn, Sol
  • Journal of The Electrochemical Society, Vol. 166, Issue 5
  • DOI: 10.1149/2.0261905jes

Noble metal-free hydrogen evolution catalysts for water splitting
journal, January 2015

  • Zou, Xiaoxin; Zhang, Yu
  • Chemical Society Reviews, Vol. 44, Issue 15
  • DOI: 10.1039/C4CS00448E

A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production
journal, April 2007

  • Ni, Meng; Leung, Michael K. H.; Leung, Dennis Y. C.
  • Renewable and Sustainable Energy Reviews, Vol. 11, Issue 3
  • DOI: 10.1016/j.rser.2005.01.009

A review of advanced catalyst development for Fischer–Tropsch synthesis of hydrocarbons from biomass derived syn-gas
journal, January 2014

  • Jahangiri, Hessam; Bennett, James; Mahjoubi, Parvin
  • Catal. Sci. Technol., Vol. 4, Issue 8
  • DOI: 10.1039/C4CY00327F

Turnover Numbers, Turnover Frequencies, and Overpotential in Molecular Catalysis of Electrochemical Reactions. Cyclic Voltammetry and Preparative-Scale Electrolysis
journal, June 2012

  • Costentin, Cyrille; Drouet, Samuel; Robert, Marc
  • Journal of the American Chemical Society, Vol. 134, Issue 27, p. 11235-11242
  • DOI: 10.1021/ja303560c

Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts
journal, July 2007

  • Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.
  • Science, Vol. 317, Issue 5834, p. 100-102
  • DOI: 10.1126/science.1141483

Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
journal, May 2013

  • Mondloch, Joseph E.; Bury, Wojciech; Fairen-Jimenez, David
  • Journal of the American Chemical Society, Vol. 135, Issue 28, p. 10294-10297
  • DOI: 10.1021/ja4050828

Amorphous Molybdenum Sulfide Catalysts for Electrochemical Hydrogen Production: Insights into the Origin of their Catalytic Activity
journal, August 2012

  • Benck, Jesse D.; Chen, Zhebo; Kuritzky, Leah Y.
  • ACS Catalysis, Vol. 2, Issue 9, p. 1916-1923
  • DOI: 10.1021/cs300451q

Interrogating Kinetic versus Thermodynamic Topologies of Metal–Organic Frameworks via Combined Transmission Electron Microscopy and X-ray Diffraction Analysis
journal, March 2019

  • Gong, Xinyi; Noh, Hyunho; Gianneschi, Nathan C.
  • Journal of the American Chemical Society, Vol. 141, Issue 15
  • DOI: 10.1021/jacs.9b01789

The Haber-Bosch Process Revisited: On the Real Structure and Stability of “Ammonia Iron” under Working Conditions
journal, October 2013

  • Kandemir, Timur; Schuster, Manfred E.; Senyshyn, Anatoliy
  • Angewandte Chemie International Edition, Vol. 52, Issue 48
  • DOI: 10.1002/anie.201305812

Active edge sites in MoSe 2 and WSe 2 catalysts for the hydrogen evolution reaction: a density functional study
journal, January 2014

  • Tsai, Charlie; Chan, Karen; Abild-Pedersen, Frank
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 26
  • DOI: 10.1039/C4CP01237B