Enhancement of Ni–(Y 2 O 3 ) 0.08 (ZrO 2 ) 0.92 fuel electrode performance by infiltration of Ce 0.8 Gd 0.2 O 2−δ nanoparticles

Park, Beom-Kyeong; Scipioni, Roberto; Cox, Dalton; Barnett, Scott A.

doi:10.1039/C9TA12316D

Title: Enhancement of Ni–(Y ₂ O ₃ ) _0.08 (ZrO ₂ ) _0.92 fuel electrode performance by infiltration of Ce _0.8 Gd _0.2 O _2−δ nanoparticles

Abstract

GDC nanoparticles reduce the reaction resistance associated with three-phase boundaries and improve oxygen transport in the Ni–YSZ electrode, as measured by electrochemical impedance spectroscopy under actual solid oxide cell operating conditions.

Authors:

^[1];

^[1]

Department of Materials Science and Engineering, Northwestern University, Evanston, USA

Publication Date:: 2020-02-18

Sponsoring Org.:: USDOE

OSTI Identifier:: 1598393

Grant/Contract Number:: 0008079; FE0027584

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Journal of Materials Chemistry. A

Additional Journal Information:: Journal Name: Journal of Materials Chemistry. A Journal Volume: 8 Journal Issue: 7; Journal ID: ISSN 2050-7488

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Park, Beom-Kyeong, Scipioni, Roberto, Cox, Dalton, and Barnett, Scott A. Enhancement of Ni–(Y 2 O 3 ) 0.08 (ZrO 2 ) 0.92 fuel electrode performance by infiltration of Ce 0.8 Gd 0.2 O 2−δ nanoparticles.  United Kingdom: N. p., 2020. 
Web.  doi:10.1039/C9TA12316D.

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                    Park, Beom-Kyeong, Scipioni, Roberto, Cox, Dalton, & Barnett, Scott A. Enhancement of Ni–(Y 2 O 3 ) 0.08 (ZrO 2 ) 0.92 fuel electrode performance by infiltration of Ce 0.8 Gd 0.2 O 2−δ nanoparticles.  United Kingdom.  https://doi.org/10.1039/C9TA12316D

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                    Park, Beom-Kyeong, Scipioni, Roberto, Cox, Dalton, and Barnett, Scott A. Tue .  
"Enhancement of Ni–(Y 2 O 3 ) 0.08 (ZrO 2 ) 0.92 fuel electrode performance by infiltration of Ce 0.8 Gd 0.2 O 2−δ nanoparticles".  United Kingdom.  https://doi.org/10.1039/C9TA12316D.

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@article{osti_1598393,

  title        = {Enhancement of Ni–(Y 2 O 3 ) 0.08 (ZrO 2 ) 0.92 fuel electrode performance by infiltration of Ce 0.8 Gd 0.2 O 2−δ nanoparticles},

  author       = {Park, Beom-Kyeong and Scipioni, Roberto and Cox, Dalton and Barnett, Scott A.},

  abstractNote = {GDC nanoparticles reduce the reaction resistance associated with three-phase boundaries and improve oxygen transport in the Ni–YSZ electrode, as measured by electrochemical impedance spectroscopy under actual solid oxide cell operating conditions.},

  doi          = {10.1039/C9TA12316D},

  journal      = {Journal of Materials Chemistry. A},

  number       = 7,

  volume       = 8,

  place        = {United Kingdom},

  year         = {2020},

  month        = {2}

}

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https://doi.org/10.1039/C9TA12316D

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Works referenced in this record:

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Title: Enhancement of Ni–(Y 2 O 3 ) 0.08 (ZrO 2 ) 0.92 fuel electrode performance by infiltration of Ce 0.8 Gd 0.2 O 2−δ nanoparticles

Abstract

Citation Formats

Ceria Nanocoating for Sulfur Tolerant Ni-Based Anodes of Solid Oxide Fuel Cells journal, January 2007

Electrochemical Characterization of Ni/ScYSZ Electrodes as SOFC Anodes journal, January 2014

Atomic Layer Deposition Functionalized Composite SOFC Cathode La 0.6 Sr 0.4 Fe 0.8 Co 0.2 O 3-δ -Gd 0.2 Ce 0.8 O 1.9 : Enhanced Long-Term Stability journal, October 2013

Boosting the performance and durability of Ni/YSZ cathode for hydrogen production at high current densities via decoration with nano-sized electrocatalysts journal, January 2019

Improving intermediate temperature performance of Ni-YSZ cermet anodes for solid oxide fuel cells by liquid infiltration of nickel nanoparticles journal, August 2018

Towards Understanding the Impedance Response of Ni/YSZ Anodes conference, January 2007

On porous electrodes in electrolyte solutions—IV journal, September 1964

Cobalt-substituted SrTi 0.3 Fe 0.7 O 3−δ : a stable high-performance oxygen electrode material for intermediate-temperature solid oxide electrochemical cells journal, January 2018

Gas Diffusion Impedance in Characterization of Solid Oxide Fuel Cell Anodes journal, January 1999

Electrochemical characterization of Ni–yttria stabilized zirconia electrode for hydrogen production in solid oxide electrolysis cells journal, October 2013

Decreasing the polarisation resistance of a Ni-YSZ solid oxide fuel cell anode by infiltration of a ceria-based solution journal, November 2016

Fabrication and modification of solid oxide fuel cell anodes via wet impregnation/infiltration technique journal, September 2013

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Model anodes and anode models for understanding the mechanism of hydrogen oxidation in solid oxide fuel cells journal, January 2010

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The NumPy Array: A Structure for Efficient Numerical Computation journal, March 2011

Detailed impedance characterization of a well performing and durable Ni:CGO infiltrated cermet anode for metal-supported solid oxide fuel cells journal, December 2012

Eliminating degradation in solid oxide electrochemical cells by reversible operation journal, December 2014

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Solid oxide cells with zirconia/ceria Bi-Layer electrolytes fabricated by reduced temperature firing journal, January 2015

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Long-term tests of a Jülich planar short stack with reversible solid oxide cells in both fuel cell and electrolysis modes journal, April 2013

Enhancing SOFC cathode performance by surface modification through infiltration journal, January 2014

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Title: Enhancement of Ni–(Y ₂ O ₃ ) _0.08 (ZrO ₂ ) _0.92 fuel electrode performance by infiltration of Ce _0.8 Gd _0.2 O _2−δ nanoparticles

Ceria Nanocoating for Sulfur Tolerant Ni-Based Anodes of Solid Oxide Fuel Cells
journal, January 2007

Electrochemical Characterization of Ni/ScYSZ Electrodes as SOFC Anodes
journal, January 2014

Atomic Layer Deposition Functionalized Composite SOFC Cathode La _0.6 Sr _0.4 Fe _0.8 Co _0.2 O _3-δ -Gd _0.2 Ce _0.8 O _1.9 : Enhanced Long-Term Stability
journal, October 2013

Boosting the performance and durability of Ni/YSZ cathode for hydrogen production at high current densities via decoration with nano-sized electrocatalysts
journal, January 2019

Improving intermediate temperature performance of Ni-YSZ cermet anodes for solid oxide fuel cells by liquid infiltration of nickel nanoparticles
journal, August 2018

Towards Understanding the Impedance Response of Ni/YSZ Anodes
conference, January 2007

On porous electrodes in electrolyte solutions—IV
journal, September 1964

Cobalt-substituted SrTi _0.3 Fe _0.7 O _3−δ : a stable high-performance oxygen electrode material for intermediate-temperature solid oxide electrochemical cells
journal, January 2018

Gas Diffusion Impedance in Characterization of Solid Oxide Fuel Cell Anodes
journal, January 1999

Electrochemical characterization of Ni–yttria stabilized zirconia electrode for hydrogen production in solid oxide electrolysis cells
journal, October 2013

Decreasing the polarisation resistance of a Ni-YSZ solid oxide fuel cell anode by infiltration of a ceria-based solution
journal, November 2016

Fabrication and modification of solid oxide fuel cell anodes via wet impregnation/infiltration technique
journal, September 2013

Performance enhancement of Ni-YSZ electrode by impregnation of Mo_0.1Ce_0.9O_2+δ
journal, April 2012

Model anodes and anode models for understanding the mechanism of hydrogen oxidation in solid oxide fuel cells
journal, January 2010

Characteristics of low-carbon data centres
journal, June 2013

High‐Performance Solid Oxide Fuel Cell with an Electrochemically Surface‐Tailored Oxygen Electrode
journal, July 2018

Conditions for stable operation of solid oxide electrolysis cells: oxygen electrode effects
journal, January 2019

Climate Sensitivity Uncertainty and the Need for Energy Without CO2 Emission
journal, March 2003

Enhancing Sulfur Tolerance of a Ni-YSZ Anode through BaZr _0.1 Ce _0.7 Y _0.1 Yb _0.1 O _{3− δ} Infiltration
journal, January 2014

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journal, January 2011

A novel solid oxide redox flow battery for grid energy storage
journal, January 2011

Comparing in Situ Carbon Tolerances of Sn-Infiltrated and BaO-Infiltrated Ni-YSZ Cermet Anodes in Solid Oxide Fuel Cells Exposed to Methane
journal, March 2015

Matplotlib: A 2D Graphics Environment
journal, January 2007

100% Clean and Renewable Wind, Water, and Sunlight All-Sector Energy Roadmaps for 139 Countries of the World
journal, September 2017

Progress in metal-supported solid oxide fuel cells: A review
journal, August 2010

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journal, November 2015

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journal, March 2011

Detailed impedance characterization of a well performing and durable Ni:CGO infiltrated cermet anode for metal-supported solid oxide fuel cells
journal, December 2012

Eliminating degradation in solid oxide electrochemical cells by reversible operation
journal, December 2014

Reactivating the Ni-YSZ electrode in solid oxide cells and stacks by infiltration
journal, February 2018

Solid oxide cells with zirconia/ceria Bi-Layer electrolytes fabricated by reduced temperature firing
journal, January 2015

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journal, January 2008

Long-term tests of a Jülich planar short stack with reversible solid oxide cells in both fuel cell and electrolysis modes
journal, April 2013

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journal, January 2014

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journal, January 2013