High catalytic performance of Fe-Ni/Palygorskite in the steam reforming of toluene for hydrogen production
Abstract
The inexpensive and abundant material, palygorskite, was used as a promising catalyst support to prepare Fe-Ni/Pal catalysts. Catalytic steam reforming of toluene as a biomass tar model compound over these catalysts was investigated in a fixed-bed reactor under different parameters, including reaction temperatures and S/C molar ratios. The stability and lifetime of Fe3Ni8/Palygorskite catalyst was evaluated under optimal conditions and its kinetic parameters were determined as well. The fresh and used catalysts were characterized using X-ray diffraction (XRD), H2 temperature-programmed reduction (H2-TPR), transmission electron microscopy (TEM), and Raman spectra. The results showed that the Fe3Ni8/Palygorskite catalyst with high dispersion was successfully prepared and exhibited superior catalytic performance compared with those of the monometallic catalysts (Fe3/Palygorskite and Ni8/Palygorskite) and the bare Palygorskite. Increasing the reaction temperature from 500 °C to 700 °C was beneficial for the toluene conversion and gaseous yields. The catalytic activity of Fe3Ni8/Palygorskite varied distinctly with the increase of S/C molar ratio and reached maximum at the the S/C molar ratio of 1.0. The apparent activation energy of 41.55 kJ mol-1 and the pre-exponential factor of 1.35 × 103 m3 kg-1 h-1 were obtained for Fe3Ni8/Palygorskite in kinetic studies under optimal reaction conditions, respectively. Here, the carbon depositionmore »
- Authors:
-
- Hefei Univ. of Technology (China); Univ. of Connecticut, Storrs, CT (United States)
- Hefei Univ. of Technology (China)
- Chinese Academy of Science, Guangzhou (China)
- Univ. of Connecticut, Storrs, CT (United States)
- Publication Date:
- Research Org.:
- Univ. of Connecticut, Storrs, CT (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; National Science Foundation of China
- OSTI Identifier:
- 1598168
- Grant/Contract Number:
- FG02-86ER13622; 41372045; 41572028; 41772038
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Energy
- Additional Journal Information:
- Journal Volume: 226; Journal Issue: C; Journal ID: ISSN 0306-2619
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Fe-Ni/palygorskite catalyst; awaruite (Ni-Fe alloy); steam reforming; toluene; biomass tar; kinetic study
Citation Formats
Zou, Xuehua, Chen, Tianhu, Zhang, Ping, Chen, Dong, He, Junkai, Dang, Yanliu, Ma, Zhiyuan, Chen, Ye, Toloueinia, Panteha, Zhu, Chengzhu, Xie, Jingjing, Liu, Haibo, and Suib, Steven L. High catalytic performance of Fe-Ni/Palygorskite in the steam reforming of toluene for hydrogen production. United States: N. p., 2018.
Web. doi:10.1016/j.apenergy.2018.06.005.
Zou, Xuehua, Chen, Tianhu, Zhang, Ping, Chen, Dong, He, Junkai, Dang, Yanliu, Ma, Zhiyuan, Chen, Ye, Toloueinia, Panteha, Zhu, Chengzhu, Xie, Jingjing, Liu, Haibo, & Suib, Steven L. High catalytic performance of Fe-Ni/Palygorskite in the steam reforming of toluene for hydrogen production. United States. https://doi.org/10.1016/j.apenergy.2018.06.005
Zou, Xuehua, Chen, Tianhu, Zhang, Ping, Chen, Dong, He, Junkai, Dang, Yanliu, Ma, Zhiyuan, Chen, Ye, Toloueinia, Panteha, Zhu, Chengzhu, Xie, Jingjing, Liu, Haibo, and Suib, Steven L. Fri .
"High catalytic performance of Fe-Ni/Palygorskite in the steam reforming of toluene for hydrogen production". United States. https://doi.org/10.1016/j.apenergy.2018.06.005. https://www.osti.gov/servlets/purl/1598168.
@article{osti_1598168,
title = {High catalytic performance of Fe-Ni/Palygorskite in the steam reforming of toluene for hydrogen production},
author = {Zou, Xuehua and Chen, Tianhu and Zhang, Ping and Chen, Dong and He, Junkai and Dang, Yanliu and Ma, Zhiyuan and Chen, Ye and Toloueinia, Panteha and Zhu, Chengzhu and Xie, Jingjing and Liu, Haibo and Suib, Steven L.},
abstractNote = {The inexpensive and abundant material, palygorskite, was used as a promising catalyst support to prepare Fe-Ni/Pal catalysts. Catalytic steam reforming of toluene as a biomass tar model compound over these catalysts was investigated in a fixed-bed reactor under different parameters, including reaction temperatures and S/C molar ratios. The stability and lifetime of Fe3Ni8/Palygorskite catalyst was evaluated under optimal conditions and its kinetic parameters were determined as well. The fresh and used catalysts were characterized using X-ray diffraction (XRD), H2 temperature-programmed reduction (H2-TPR), transmission electron microscopy (TEM), and Raman spectra. The results showed that the Fe3Ni8/Palygorskite catalyst with high dispersion was successfully prepared and exhibited superior catalytic performance compared with those of the monometallic catalysts (Fe3/Palygorskite and Ni8/Palygorskite) and the bare Palygorskite. Increasing the reaction temperature from 500 °C to 700 °C was beneficial for the toluene conversion and gaseous yields. The catalytic activity of Fe3Ni8/Palygorskite varied distinctly with the increase of S/C molar ratio and reached maximum at the the S/C molar ratio of 1.0. The apparent activation energy of 41.55 kJ mol-1 and the pre-exponential factor of 1.35 × 103 m3 kg-1 h-1 were obtained for Fe3Ni8/Palygorskite in kinetic studies under optimal reaction conditions, respectively. Here, the carbon deposition analysis of the used catalysts revealed that the formation of graphitic carbon rather than amorphous carbon was the main reason for the deactivation of Fe3Ni8/Palygorskite catalysts. When ceased the injection of steam into the reaction system, the graphitic carbon would be accelerating formed on the surface of the Fe3Ni8/Palygorskite and decreased its catalytic activity for toluene conversion. But owing to the water gas shift reaction, the catalytic activity of Fe3Ni8/Palygorskite seemed to recover gradually to its optimum.},
doi = {10.1016/j.apenergy.2018.06.005},
journal = {Applied Energy},
number = C,
volume = 226,
place = {United States},
year = {Fri Jun 15 00:00:00 EDT 2018},
month = {Fri Jun 15 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Evolution of syngas from cardboard gasification
journal, September 2009
- Ahmed, I.; Gupta, A. K.
- Applied Energy, Vol. 86, Issue 9
Characteristics of syngas from co-gasification of polyethylene and woodchips
journal, January 2011
- Ahmed, I. I.; Nipattummakul, N.; Gupta, A. K.
- Applied Energy, Vol. 88, Issue 1
Char and char-supported nickel catalysts for secondary syngas cleanup and conditioning
journal, May 2011
- Wang, Duo; Yuan, Wenqiao; Ji, Wei
- Applied Energy, Vol. 88, Issue 5
Tar removal from biomass pyrolysis gas in two-step function of decomposition and adsorption
journal, July 2010
- Phuphuakrat, Thana; Namioka, Tomoaki; Yoshikawa, Kunio
- Applied Energy, Vol. 87, Issue 7
Steam–air fluidized bed gasification of distillers grains: Effects of steam to biomass ratio, equivalence ratio and gasification temperature
journal, March 2009
- Kumar, Ajay; Eskridge, Kent; Jones, David D.
- Bioresource Technology, Vol. 100, Issue 6
Steam reforming of tar from pyrolysis of biomass over Ni/Mg/Al catalysts prepared from hydrotalcite-like precursors
journal, February 2011
- Li, Dalin; Wang, Lei; Koike, Mitsuru
- Applied Catalysis B: Environmental, Vol. 102, Issue 3-4
In situ catalytic conversion of tar using rice husk char/ash supported nickel–iron catalysts for biomass pyrolytic gasification combined with the mixing-simulation in fluidized-bed gasifier
journal, December 2015
- Shen, Yafei; Zhao, Peitao; Shao, Qinfu
- Applied Energy, Vol. 160
Catalytic performance and characterization of Co/Mg/Al catalysts prepared from hydrotalcite-like precursors for the steam gasification of biomass
journal, May 2014
- Wang, Lei; Li, Dalin; Watanabe, Hideo
- Applied Catalysis B: Environmental, Vol. 150-151
Comparison of Co/MgO and Ni/MgO catalysts for the steam reforming of naphthalene as a model compound of tar derived from biomass gasification
journal, January 2005
- Furusawa, Takeshi; Tsutsumi, Atsushi
- Applied Catalysis A: General, Vol. 278, Issue 2
Characterization and reactivity in toluene reforming of a Fe/olivine catalyst designed for gas cleanup in biomass gasification
journal, November 2010
- Virginie, Mirella; Courson, Claire; Niznansky, Daniel
- Applied Catalysis B: Environmental, Vol. 101, Issue 1-2
Hydrogen from the high temperature water gas shift reaction with an industrial Fe/Cr catalyst using biomass gasification tar rich synthesis gas
journal, April 2015
- Chianese, Simeone; Loipersböck, Jurgen; Malits, Markus
- Fuel Processing Technology, Vol. 132
Chemical looping reforming of methane using magnetite as oxygen carrier: Structure evolution and reduction kinetics
journal, February 2018
- Lu, Chunqiang; Li, Kongzhai; Wang, Hua
- Applied Energy, Vol. 211
A comparison of Rh/CeO2/SiO2 catalysts with steam reforming catalysts, dolomite and inert materials as bed materials in low throughput fluidized bed gasification systems
journal, March 2004
- Asadullah, Mohammad; Miyazawa, Tomohisa; Ito, Shin-ichi
- Biomass and Bioenergy, Vol. 26, Issue 3
Influence of sulfur on the carbon deposition in steam reforming of liquid hydrocarbons over CeO2–Al2O3 supported Ni and Rh catalysts
journal, February 2011
- Xie, Chao; Chen, Yongsheng; Li, Yan
- Applied Catalysis A: General, Vol. 394, Issue 1-2
Equilibrium composition of ethanol steam reforming reaction to produce H 2 applied to Ni, Co and Pt/hydrotalcite–WO x catalysts
journal, October 2014
- Contreras, J. L.; Tapia, C.; Fuentes, G. A.
- International Journal of Hydrogen Energy, Vol. 39, Issue 29
Steam reforming of naphthalene/benzene with various types of Pt- and Ni-based catalysts for hydrogen production
journal, January 2013
- Furusawa, Takeshi; Saito, Katsuhiko; Kori, Yoshihiko
- Fuel, Vol. 103
Decomposition of hydrocarbons to hydrogen and carbon
journal, May 2009
- Ahmed, Shakeel; Aitani, Abdullah; Rahman, Faizur
- Applied Catalysis A: General, Vol. 359, Issue 1-2, p. 1-24
Catalytic performance and characterization of Ni–Co catalysts for the steam reforming of biomass tar to synthesis gas
journal, October 2013
- Wang, Lei; Li, Dalin; Koike, Mitsuru
- Fuel, Vol. 112
Catalytic performance and characterization of Ni-Fe catalysts for the steam reforming of tar from biomass pyrolysis to synthesis gas
journal, January 2011
- Wang, Lei; Li, Dalin; Koike, Mitsuru
- Applied Catalysis A: General, Vol. 392, Issue 1-2
Promoting effect of trace Pd on hydrotalcite-derived Ni/Mg/Al catalyst in oxidative steam reforming of biomass tar
journal, December 2015
- Chen, Jinhai; Tamura, Masazumi; Nakagawa, Yoshinao
- Applied Catalysis B: Environmental, Vol. 179
Promoting effect of Pt addition to Ni/CeO2/Al2O3 catalyst for steam gasification of biomass
journal, February 2008
- Nishikawa, Jin; Miyazawa, Tomohisa; Nakamura, Kazuya
- Catalysis Communications, Vol. 9, Issue 2
Catalytic steam reforming of biomass tar over iron- or nickel-based catalyst supported on calcined scallop shell
journal, April 2012
- Guan, Guoqing; Chen, Gang; Kasai, Yutaka
- Applied Catalysis B: Environmental, Vol. 115-116
Regenerability of Hydrotalcite-Derived Nickel-Iron Alloy Nanoparticles for Syngas Production from Biomass Tar
journal, December 2013
- Li, Dalin; Koike, Mitsuru; Wang, Lei
- ChemSusChem, Vol. 7, Issue 2, p. 510-522
Steam reforming of tar from a biomass gasification process over Ni/olivine catalyst using toluene as a model compound
journal, July 2007
- Świerczyński, D.; Libs, S.; Courson, C.
- Applied Catalysis B: Environmental, Vol. 74, Issue 3-4
Catalytic cracking of toluene over hematite derived from thermally treated natural limonite
journal, August 2016
- Zou, Xuehua; Chen, Tianhu; Liu, Haibo
- Fuel, Vol. 177
Olivine as tar removal catalyst in biomass gasification: Catalyst dynamics under model conditions
journal, February 2013
- Fredriksson, Hans O. A.; Lancee, Remco J.; Thüne, Peter C.
- Applied Catalysis B: Environmental, Vol. 130-131
Textual properties and catalytic performances of halloysite hybrid CeO2-ZrO2 nanoparticles
journal, November 2017
- Ouyang, Jing; Zhao, Zai; Zhang, Yi
- Journal of Colloid and Interface Science, Vol. 505
Catalytic cracking of tars derived from rice hull gasification over goethite and palygorskite
journal, December 2012
- Liu, Haibo; Chen, Tianhu; Chang, Dongyin
- Applied Clay Science, Vol. 70
Characterization and catalytic performance of Fe3Ni8/palygorskite for catalytic cracking of benzene
journal, April 2013
- Liu, Haibo; Chen, Tianhu; Chang, Dongyin
- Applied Clay Science, Vol. 74
Effect of Additives on Catalytic Cracking of Biomass Gasification Tar over a Nickel-Based Catalyst
journal, January 2010
- Liu, Haibo; Chen, Tianhu; Zhang, Xianlong
- Chinese Journal of Catalysis, Vol. 31, Issue 4
Effect of preparation method of palygorskite-supported Fe and Ni catalysts on catalytic cracking of biomass tar
journal, April 2012
- Liu, Haibo; Chen, Tianhu; Chang, Dongyin
- Chemical Engineering Journal, Vol. 188
An insight into the effect of calcination conditions on catalytic cracking of toluene over 3Fe8Ni/palygorskite: Catalysts characterization and performance
journal, February 2017
- Zou, Xuehua; Chen, Tianhu; Liu, Haibo
- Fuel, Vol. 190
CO 2 reforming of toluene as model compound of biomass tar on Ni/Palygorskite
journal, May 2013
- Chen, Tianhu; Liu, Haibo; Shi, Peichao
- Fuel, Vol. 107
Modelling of tar formation and evolution for biomass gasification: A review
journal, November 2013
- Font Palma, Carolina
- Applied Energy, Vol. 111
Experimental study of Ni/MgO catalyst in carbon dioxide reforming of toluene, a model compound of tar from biomass gasification
journal, September 2012
- Kong, Meng; Yang, Qi; Fei, Jinhua
- International Journal of Hydrogen Energy, Vol. 37, Issue 18
Steam treatment on Ni/γ-Al2O3 for enhanced carbon resistance in combined steam and carbon dioxide reforming of methane
journal, May 2013
- Son, In Hyuk; Lee, Seung Jae; Soon, Aloysius
- Applied Catalysis B: Environmental, Vol. 134-135
Steam reforming of biomass tar for hydrogen production over NiO/ceramic foam catalyst
journal, July 2015
- Gao, Ningbo; Liu, Shuang; Han, Ying
- International Journal of Hydrogen Energy, Vol. 40, Issue 25
Hydrogen production from catalytic steam reforming of benzene as tar model compound of biomass gasification
journal, July 2016
- Gao, Ningbo; Wang, Xiao; Li, Aimin
- Fuel Processing Technology, Vol. 148
Ca2Fe2O5: A promising oxygen carrier for CO/CH4 conversion and almost-pure H2 production with inherent CO2 capture over a two-step chemical looping hydrogen generation process
journal, February 2018
- Sun, Zhao; Chen, Shiyi; Hu, Jun
- Applied Energy, Vol. 211
Mechanism and kinetic modeling for steam reforming of toluene on La 0.8 Sr 0.2 Ni 0.8 Fe 0.2 O 3 catalyst
journal, August 2014
- Oemar, Usman; Ming Li, Ang; Hidajat, Kus
- AIChE Journal, Vol. 60, Issue 12
A crucial role of O2− and O22− on mayenite structure for biomass tar steam reforming over Ni/Ca12Al14O33
journal, May 2009
- Li, Chunshan; Hirabayashi, Daisuke; Suzuki, Kenzi
- Applied Catalysis B: Environmental, Vol. 88, Issue 3-4
Improving the Modeling of the Kinetics of the Catalytic Tar Elimination in Biomass Gasification
journal, July 2002
- Corella, José; Toledo, José M.; Aznar, Maria-Pilar
- Industrial & Engineering Chemistry Research, Vol. 41, Issue 14
Study of steam reforming of toluene used as model compound of tar produced by biomass gasification
journal, March 2008
- Swierczynski, Dariusz; Courson, Claire; Kiennemann, Alain
- Chemical Engineering and Processing: Process Intensification, Vol. 47, Issue 3
Commercial Steam Reforming Catalysts To Improve Biomass Gasification with Steam−Oxygen Mixtures. 2. Catalytic Tar Removal
journal, July 1998
- Aznar, María P.; Caballero, Miguel A.; Gil, Javier
- Industrial & Engineering Chemistry Research, Vol. 37, Issue 7
Development of new nickel based catalyst for biomass tar steam reforming producing H2-rich syngas
journal, June 2009
- Li, Chunshan; Hirabayashi, Daisuke; Suzuki, Kenzi
- Fuel Processing Technology, Vol. 90, Issue 6
Catalytic decomposition of toluene using a biomass derived catalyst
journal, October 2013
- Mani, Sudhagar; Kastner, James R.; Juneja, Ankita
- Fuel Processing Technology, Vol. 114
Catalytic decomposition of tar using iron supported biochar
journal, February 2015
- Kastner, James R.; Mani, Sudhagar; Juneja, Ankita
- Fuel Processing Technology, Vol. 130
Kinetic modelling of VOC catalytic steam pyrolysis for tar abatement phenomena in gasification/pyrolysis technologies
journal, June 2004
- Taralas, Georgios; Kontominas, Michael G.
- Fuel, Vol. 83, Issue 9
Two Advanced Models for the Kinetics of the Variation of the Tar Composition in Its Catalytic Elimination in Biomass Gasification
journal, June 2003
- Corella, José; Caballero, Miguel A.; Aznar, María-Pilar
- Industrial & Engineering Chemistry Research, Vol. 42, Issue 13
Catalytic Effect of Ni and Fe Addition to Gasifier Bed Material in the Steam Reforming of Producer Gas
journal, August 2014
- Bambal, Ashish S.; Vecchio, Kenneth S.; Cattolica, Robert J.
- Industrial & Engineering Chemistry Research, Vol. 53, Issue 35
Nickel-iron catalysts prepared by homogeneous deposition-precipitation of cyanide complexes on a titania support
journal, March 1995
- van de Loosdrecht, J.; van Dillen, A. J.; van der Horst, A. A.
- Topics in Catalysis, Vol. 2, Issue 1-4
Hydrogen production by steam gasification of polypropylene with various nickel catalysts
journal, April 2009
- Wu, Chunfei; Williams, Paul T.
- Applied Catalysis B: Environmental, Vol. 87, Issue 3-4
Effect of calcium addition on catalytic ethanol steam reforming of Ni/Al2O3: I. Catalytic stability, electronic properties and coking mechanism
journal, November 2011
- Choong, Catherine K. S.; Zhong, Ziyi; Huang, Lin
- Applied Catalysis A: General, Vol. 407, Issue 1-2
Green synthesis of Ni supported hematite catalysts for syngas production from catalytic cracking of toluene as a model compound of biomass tar
journal, April 2018
- Zou, Xuehua; Ma, Zhiyuan; Liu, Haibo
- Fuel, Vol. 217
XPS, XAES, and TG/DTA characterization of deposited carbon in methane dehydroaromatization over Ga–Mo/ZSM-5 catalyst
journal, March 2007
- Liu, B. S.; Jiang, L.; Sun, H.
- Applied Surface Science, Vol. 253, Issue 11
High-rate and long-life of Li-ion batteries using reduced graphene oxide/Co 3 O 4 as anode materials
journal, January 2016
- He, Junkai; Liu, Ying; Meng, Yongtao
- RSC Advances, Vol. 6, Issue 29
Works referencing / citing this record:
Plasma-Aided Reforming of Toluene and Isopropanol with Analysis of Decomposition Mechanism
journal, March 2019
- Pang, Yin; Bosch, Hannah; Hammer, Thomas
- Waste and Biomass Valorization, Vol. 11, Issue 2
Microstructural evolution and sintering properties of palygorskite nanofibers
journal, February 2020
- Wang, Kailei; Wang, Lijuan; Zhang, Yu
- International Journal of Applied Ceramic Technology, Vol. 17, Issue 4