DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Printing 2D Conjugated Polymer Monolayers and Their Distinct Electronic Properties

 [1];  [1];  [2];  [1];  [2]; ORCiD logo [1]
  1. Department of Chemical and Biomolecular Engineering University of Illinois at Urbana‐Champaign 600 South Mathews Avenue Urbana IL 61801 USA
  2. Department of Chemistry University of Illinois at Urbana‐Champaign 505 S Mathews Avenue Urbana IL 61801 USA
Publication Date:
Sponsoring Org.:
OSTI Identifier:
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Functional Materials
Additional Journal Information:
Journal Name: Advanced Functional Materials Journal Volume: 30 Journal Issue: 12; Journal ID: ISSN 1616-301X
Wiley Blackwell (John Wiley & Sons)
Country of Publication:

Citation Formats

Kafle, Prapti, Zhang, Fengjiao, Schorr, Noah B., Huang, Kai‐Yu, Rodríguez‐López, Joaquín, and Diao, Ying. Printing 2D Conjugated Polymer Monolayers and Their Distinct Electronic Properties. Germany: N. p., 2020. Web. doi:10.1002/adfm.201909787.
Kafle, Prapti, Zhang, Fengjiao, Schorr, Noah B., Huang, Kai‐Yu, Rodríguez‐López, Joaquín, & Diao, Ying. Printing 2D Conjugated Polymer Monolayers and Their Distinct Electronic Properties. Germany.
Kafle, Prapti, Zhang, Fengjiao, Schorr, Noah B., Huang, Kai‐Yu, Rodríguez‐López, Joaquín, and Diao, Ying. Thu . "Printing 2D Conjugated Polymer Monolayers and Their Distinct Electronic Properties". Germany.
title = {Printing 2D Conjugated Polymer Monolayers and Their Distinct Electronic Properties},
author = {Kafle, Prapti and Zhang, Fengjiao and Schorr, Noah B. and Huang, Kai‐Yu and Rodríguez‐López, Joaquín and Diao, Ying},
abstractNote = {},
doi = {10.1002/adfm.201909787},
journal = {Advanced Functional Materials},
number = 12,
volume = 30,
place = {Germany},
year = {2020},
month = {2}

Works referenced in this record:

Integrated circuits based on conjugated polymer monolayer
journal, January 2018

Sensors for Breath Testing: From Nanomaterials to Comprehensive Disease Detection
journal, August 2013

  • Konvalina, Gady; Haick, Hossam
  • Accounts of Chemical Research, Vol. 47, Issue 1
  • DOI: 10.1021/ar400070m

Semiconductive Single Molecular Bilayers Realized Using Geometrical Frustration
journal, April 2018

  • Arai, Shunto; Inoue, Satoru; Hamai, Takamasa
  • Advanced Materials, Vol. 30, Issue 23
  • DOI: 10.1002/adma.201707256

Dynamic-template-directed multiscale assembly for large-area coating of highly-aligned conjugated polymer thin films
journal, July 2017

  • Mohammadi, Erfan; Zhao, Chuankai; Meng, Yifei
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms16070

Microstructure-Dependent Charge Carrier Transport of Poly(3-hexylthiophene) Ultrathin Films with Different Thicknesses
journal, April 2017

Influence of Alkyl Chain Branching Positions on the Hole Mobilities of Polymer Thin-Film Transistors
journal, September 2012

2D materials: to graphene and beyond
journal, January 2011

  • Mas-Ballesté, Rubén; Gómez-Navarro, Cristina; Gómez-Herrero, Julio
  • Nanoscale, Vol. 3, Issue 1
  • DOI: 10.1039/C0NR00323A

Tuning conformation, assembly, and charge transport properties of conjugated polymers by printing flow
journal, August 2019

  • Park, Kyung Sun; Kwok, Justin J.; Dilmurat, Rishat
  • Science Advances, Vol. 5, Issue 8
  • DOI: 10.1126/sciadv.aaw7757

Macroscopic and high-throughput printing of aligned nanostructured polymer semiconductors for MHz large-area electronics
journal, September 2015

  • Bucella, Sadir G.; Luzio, Alessandro; Gann, Eliot
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9394

Effect of the Phase States of Self-Assembled Monolayers on Pentacene Growth and Thin-Film Transistor Characteristics
journal, August 2008

  • Lee, Hwa Sung; Kim, Do Hwan; Cho, Jeong Ho
  • Journal of the American Chemical Society, Vol. 130, Issue 32
  • DOI: 10.1021/ja800142t

Understanding Film-To-Stripe Transition of Conjugated Polymers Driven by Meniscus Instability
journal, October 2018

  • Qu, Ge; Kwok, Justin J.; Mohammadi, Erfan
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 47
  • DOI: 10.1021/acsami.8b13790

Solution-printed organic semiconductor blends exhibiting transport properties on par with single crystals
journal, November 2015

  • Niazi, Muhammad R.; Li, Ruipeng; Qiang Li, Er
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9598

2D materials and van der Waals heterostructures
journal, July 2016

The dedicated high-resolution grazing-incidence X-ray scattering beamline 8-ID-E at the Advanced Photon Source
journal, June 2012

  • Jiang, Zhang; Li, Xuefa; Strzalka, Joseph
  • Journal of Synchrotron Radiation, Vol. 19, Issue 4
  • DOI: 10.1107/S0909049512022017

Tailoring Structure and Field-Effect Characteristics of Ultrathin Conjugated Polymer Films via Phase Separation
journal, February 2018

  • Ge, Feng; Wei, Shiyu; Liu, Zhen
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 11
  • DOI: 10.1021/acsami.7b19171

Dimensionality of charge transport in organic field-effect transistors
journal, June 2012

2D Organic Materials for Optoelectronic Applications
journal, October 2017

  • Yang, Fangxu; Cheng, Shanshan; Zhang, Xiaotao
  • Advanced Materials, Vol. 30, Issue 2
  • DOI: 10.1002/adma.201702415

Mechanism of Crystallization and Implications for Charge Transport in Poly(3-ethylhexylthiophene) Thin Films
journal, April 2014

  • Duong, Duc T.; Ho, Victor; Shang, Zhengrong
  • Advanced Functional Materials, Vol. 24, Issue 28
  • DOI: 10.1002/adfm.201304247

Calculating the trap density of states in organic field-effect transistors from experiment: A comparison of different methods
journal, January 2010

Charge transport in monolayer poly(3-hexylthiophene) thin-film transistors
journal, April 2014

Monolayer Transistor Using a Highly Ordered Conjugated Polymer as the Channel
journal, December 2006

  • Scott, J. Campbell; Samuel, J. D. Jeyaprakash; Hou, Jennifer H.
  • Nano Letters, Vol. 6, Issue 12
  • DOI: 10.1021/nl0622449

Human exhaled air analytics: biomarkers of diseases
journal, January 2007

  • Buszewski, Bogusław; Kęsy, Martyna; Ligor, Tomasz
  • Biomedical Chromatography, Vol. 21, Issue 6
  • DOI: 10.1002/bmc.835

High‐Performance Organic Thin‐Film Transistors through Solution‐Sheared Deposition of Small‐Molecule Organic Semiconductors
journal, July 2008

  • Becerril, Héctor A.; Roberts, Mark E.; Liu, Zihong
  • Advanced Materials, Vol. 20, Issue 13, p. 2588-2594
  • DOI: 10.1002/adma.200703120

Exploring the origin of high optical absorption in conjugated polymers
journal, May 2016

  • Vezie, Michelle S.; Few, Sheridan; Meager, Iain
  • Nature Materials, Vol. 15, Issue 7
  • DOI: 10.1038/nmat4645

Electrical Contact Properties between the Accumulation Layer and Metal Electrodes in Ultrathin Poly(3-hexylthiophene)(P3HT) Field Effect Transistors
journal, May 2011

  • Park, Byoungnam; Aiyar, Avishek; Hong, Jung-il
  • ACS Applied Materials & Interfaces, Vol. 3, Issue 5
  • DOI: 10.1021/am200143g

Molecular field‐effect transistors using conducting polymer Langmuir–Blodgett films
journal, March 1990

  • Paloheimo, J.; Kuivalainen, P.; Stubb, H.
  • Applied Physics Letters, Vol. 56, Issue 12
  • DOI: 10.1063/1.103182

Poly(3-hexylthiophene) monolayer nanowhiskers
journal, January 2013

  • Guo, Yan; Jiang, Lang; Ma, Xiaojing
  • Polymer Chemistry, Vol. 4, Issue 16
  • DOI: 10.1039/c3py00728f

Morphology control strategies for solution-processed organic semiconductor thin films
journal, January 2014

  • Diao, Ying; Shaw, Leo; Bao, Zhenan
  • Energy Environ. Sci., Vol. 7, Issue 7
  • DOI: 10.1039/C4EE00688G

Recent Advances in Ultrathin Two-Dimensional Nanomaterials
journal, March 2017

Ultrathin Regioregular Poly(3-hexyl thiophene) Field-Effect Transistors
journal, December 2002

  • Sandberg, Henrik G. O.; Frey, Gitti L.; Shkunov, Maxim N.
  • Langmuir, Vol. 18, Issue 26
  • DOI: 10.1021/la0261444

Enabling high-mobility, ambipolar charge-transport in a DPP-benzotriazole copolymer by side-chain engineering
journal, January 2015

  • Gruber, Mathias; Jung, Seok-Heon; Schott, Sam
  • Chemical Science, Vol. 6, Issue 12
  • DOI: 10.1039/C5SC01326G

H- and J-Aggregate Behavior in Polymeric Semiconductors
journal, April 2014

Field-Effect Carrier Transport in Poly(3-alkylthiophene) Nanofiber Networks and Isolated Nanofibers
journal, October 2010

  • Samitsu, Sadaki; Shimomura, Takeshi; Heike, Seiji
  • Macromolecules, Vol. 43, Issue 19, p. 7891-7894
  • DOI: 10.1021/ma101655s

Switching between H- and J-type electronic coupling in single conjugated polymer aggregates
journal, November 2017

High-Performance Ambipolar Diketopyrrolopyrrole-Thieno[3,2- b ]thiophene Copolymer Field-Effect Transistors with Balanced Hole and Electron Mobilities
journal, October 2011

  • Chen, Zhuoying; Lee, Mi Jung; Shahid Ashraf, Raja
  • Advanced Materials, Vol. 24, Issue 5
  • DOI: 10.1002/adma.201102786

Critical Role of Surface Energy in Guiding Crystallization of Solution-Coated Conjugated Polymer Thin Films
journal, October 2017

Efficient two layer leds on a polymer blend basis
journal, June 1995

From Convective Assembly to Landau−Levich Deposition of Multilayered Phospholipid Films of Controlled Thickness
journal, March 2009

  • Le Berre, Maël; Chen, Yong; Baigl, Damien
  • Langmuir, Vol. 25, Issue 5
  • DOI: 10.1021/la803646e

Drying of a Solution in a Meniscus: A Model Coupling the Liquid and the Gas Phases
journal, September 2010

Solution-Processed Nanoporous Organic Semiconductor Thin Films: Toward Health and Environmental Monitoring of Volatile Markers
journal, May 2017

  • Zhang, Fengjiao; Qu, Ge; Mohammadi, Erfan
  • Advanced Functional Materials, Vol. 27, Issue 23
  • DOI: 10.1002/adfm.201701117

Controlling Rigidity and Planarity in Conjugated Polymers: Poly(3,4-ethylenedithioselenophene)
journal, July 2009

  • Wijsboom, Yair H.; Patra, Asit; Zade, Sanjio S.
  • Angewandte Chemie International Edition, Vol. 48, Issue 30
  • DOI: 10.1002/anie.200901231

The meniscus-guided deposition of semiconducting polymers
journal, February 2018

Tuning charge transport in solution-sheared organic semiconductors using lattice strain
journal, December 2011

  • Giri, Gaurav; Verploegen, Eric; Mannsfeld, Stefan C. B.
  • Nature, Vol. 480, Issue 7378, p. 504-508
  • DOI: 10.1038/nature10683

A few-layer molecular film on polymer substrates to enhance the performance of organic devices
journal, December 2017

Mercury : visualization and analysis of crystal structures
journal, May 2006

  • Macrae, Clare F.; Edgington, Paul R.; McCabe, Patrick
  • Journal of Applied Crystallography, Vol. 39, Issue 3
  • DOI: 10.1107/S002188980600731X

From Monolayer to Multilayer N-Channel Polymeric Field-Effect Transistors with Precise Conformational Order
journal, January 2012

  • Fabiano, Simone; Musumeci, Chiara; Chen, Zhihua
  • Advanced Materials, Vol. 24, Issue 7
  • DOI: 10.1002/adma.201103800

Molecular Packing of High-Mobility Diketo Pyrrolo-Pyrrole Polymer Semiconductors with Branched Alkyl Side Chains
journal, September 2011

  • Zhang, Xinran; Richter, Lee J.; DeLongchamp, Dean M.
  • Journal of the American Chemical Society, Vol. 133, Issue 38
  • DOI: 10.1021/ja204515s

Theory of optical transitions in conjugated polymers. II. Real systems
journal, October 2014

  • Marcus, Max; Tozer, Oliver Robert; Barford, William
  • The Journal of Chemical Physics, Vol. 141, Issue 16
  • DOI: 10.1063/1.4897985

Microstructure Evolution and Device Performance in Solution-Processed Polymeric Field-Effect Transistors: The Key Role of the First Monolayer
journal, February 2012

  • Wang, Suhao; Kiersnowski, Adam; Pisula, Wojciech
  • Journal of the American Chemical Society, Vol. 134, Issue 9
  • DOI: 10.1021/ja211630w

Langmuir−Blodgett Films of Regioregular Poly(3-hexylthiophene) as Field-Effect Transistors
journal, February 2000

  • Xu, Guofeng; Bao, Zhenan; Groves, John T.
  • Langmuir, Vol. 16, Issue 4
  • DOI: 10.1021/la9904455

Quantitative Image Analysis of Fractal‐Like Thin Films of Organic Semiconductors
journal, August 2019

  • Zhu, Weikun; Mohammadi, Erfan; Diao, Ying
  • Journal of Polymer Science Part B: Polymer Physics, Vol. 57, Issue 23
  • DOI: 10.1002/polb.24875

Ultrathin Film Organic Transistors: Precise Control of Semiconductor Thickness via Spin-Coating
journal, November 2012

  • Zhang, Fengjiao; Di, Chong-an; Berdunov, Nikolai
  • Advanced Materials, Vol. 25, Issue 10
  • DOI: 10.1002/adma.201204075

Mitigating Meniscus Instabilities in Solution-Sheared Polymer Films for Organic Field-Effect Transistors
journal, July 2019

  • Teixeira da Rocha, Cecilia; Qu, Ge; Yang, Xuegeng
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 33
  • DOI: 10.1021/acsami.9b07832