DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Crystallization of TiO2 polymorphs from RF-sputtered, amorphous thin-film precursors

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [2]; ORCiD logo [2];  [3];  [4]; ORCiD logo [4]; ORCiD logo [1]
  1. Oregon State Univ., Corvallis, OR (United States)
  2. Colorado School of Mines, Golden, CO (United States)
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  4. SLAC National Accelerator Lab., Menlo Park, CA (United States)
Publication Date:
Research Org.:
National Renewable Energy Lab. (NREL), Golden, CO (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1602697
Alternate Identifier(s):
OSTI ID: 1598071; OSTI ID: 1633974
Report Number(s):
NREL-JA-5K00-76206
Journal ID: ISSN 2158-3226; TRN: US2104674
Grant/Contract Number:  
AC36-08GO28308; AC3608GO28308; AC02-76SF00515; SURE Science Award
Resource Type:
Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 10; Journal Issue: 2; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY; 36 MATERIALS SCIENCE; optical imaging; pulsed laser deposition; x-ray diffraction; raman spectroscopy; sputter deposition; optical absorption; magnetron sputtering; polymorphism; thin films; crystallization

Citation Formats

Agirseven, O., Rivella, D. T., Haggerty, J. E. S., Berry, P. O., Diffendaffer, K., Patterson, A., Kreb, J., Mangum, J. S., Gorman, B. P., Perkins, J. D., Chen, B. R., Schelhas, L. T., and Tate, J. Crystallization of TiO2 polymorphs from RF-sputtered, amorphous thin-film precursors. United States: N. p., 2020. Web. doi:10.1063/1.5140368.
Agirseven, O., Rivella, D. T., Haggerty, J. E. S., Berry, P. O., Diffendaffer, K., Patterson, A., Kreb, J., Mangum, J. S., Gorman, B. P., Perkins, J. D., Chen, B. R., Schelhas, L. T., & Tate, J. Crystallization of TiO2 polymorphs from RF-sputtered, amorphous thin-film precursors. United States. https://doi.org/10.1063/1.5140368
Agirseven, O., Rivella, D. T., Haggerty, J. E. S., Berry, P. O., Diffendaffer, K., Patterson, A., Kreb, J., Mangum, J. S., Gorman, B. P., Perkins, J. D., Chen, B. R., Schelhas, L. T., and Tate, J. Thu . "Crystallization of TiO2 polymorphs from RF-sputtered, amorphous thin-film precursors". United States. https://doi.org/10.1063/1.5140368. https://www.osti.gov/servlets/purl/1602697.
@article{osti_1602697,
title = {Crystallization of TiO2 polymorphs from RF-sputtered, amorphous thin-film precursors},
author = {Agirseven, O. and Rivella, D. T. and Haggerty, J. E. S. and Berry, P. O. and Diffendaffer, K. and Patterson, A. and Kreb, J. and Mangum, J. S. and Gorman, B. P. and Perkins, J. D. and Chen, B. R. and Schelhas, L. T. and Tate, J.},
abstractNote = {},
doi = {10.1063/1.5140368},
journal = {AIP Advances},
number = 2,
volume = 10,
place = {United States},
year = {Thu Feb 06 00:00:00 EST 2020},
month = {Thu Feb 06 00:00:00 EST 2020}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 5 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Absorption spectra of anatase TiO 2 single crystals heat-treated under oxygen atmosphere
journal, August 2000


Controlled formation of anatase and rutile TiO 2 thin films by reactive magnetron sputtering
journal, September 2015

  • Rafieian, Damon; Ogieglo, Wojciech; Savenije, Tom
  • AIP Advances, Vol. 5, Issue 9
  • DOI: 10.1063/1.4931925

Selective brookite polymorph formation related to the amorphous precursor state in TiO2 thin films
journal, February 2019


An Unusual Strong Visible-Light Absorption Band in Red Anatase TiO 2 Photocatalyst Induced by Atomic Hydrogen-Occupied Oxygen Vacancies
journal, January 2018


New understanding of the difference of photocatalytic activity among anatase, rutile and brookite TiO 2
journal, January 2014

  • Zhang, Jinfeng; Zhou, Peng; Liu, Jianjun
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 38
  • DOI: 10.1039/c4cp02201g

Interference-Free Determination of the Optical Absorption Coefficient and the Optical Gap of Amorphous Silicon Thin Films
journal, May 1991

  • Hishikawa, Yoshihiro; Nakamura, Noboru; Tsuda, Shinya
  • Japanese Journal of Applied Physics, Vol. 30, Issue Part 1, No. 5
  • DOI: 10.1143/jjap.30.1008

Intrinsic n-type Defect Formation in TiO 2 : A Comparison of Rutile and Anatase from GGA+ U Calculations
journal, January 2010

  • Morgan, Benjamin J.; Watson, Graeme W.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 5
  • DOI: 10.1021/jp9088047

Anatase, Brookite, and Rutile Nanocrystals via Redox Reactions under Mild Hydrothermal Conditions:  Phase-Selective Synthesis and Physicochemical Properties
journal, April 2007

  • Li, Ji-Guang; Ishigaki, Takamasa; Sun, Xudong
  • The Journal of Physical Chemistry C, Vol. 111, Issue 13
  • DOI: 10.1021/jp0673258

Tailoring of TiO2 film microstructure by pulsed-DC and RF magnetron co-sputtering
journal, November 2019


Anatase phase TiO2 thin films obtained by pulsed laser deposition for gas sensing applications
journal, July 2005


Brookite, the Least Known TiO2 Photocatalyst
journal, January 2013

  • Di Paola, Agatino; Bellardita, Marianna; Palmisano, Leonardo
  • Catalysts, Vol. 3, Issue 1
  • DOI: 10.3390/catal3010036

Enhancement of optical absorption by modulation of the oxygen flow of TiO 2 films deposited by reactive sputtering
journal, June 2012

  • Pereira, André L. J.; Lisboa Filho, Paulo N.; Acuña, Javier
  • Journal of Applied Physics, Vol. 111, Issue 11
  • DOI: 10.1063/1.4724334

High-fraction brookite films from amorphous precursors
journal, November 2017

  • Haggerty, James E. S.; Schelhas, Laura T.; Kitchaev, Daniil A.
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/s41598-017-15364-y

Utilizing TiO 2 amorphous precursors for polymorph selection: An in situ TEM study of phase formation and kinetics
journal, December 2019

  • Mangum, John S.; Garten, Lauren M.; Ginley, David S.
  • Journal of the American Ceramic Society, Vol. 103, Issue 4
  • DOI: 10.1111/jace.16965

Brookite TiO 2 Thin Film Epitaxially Grown on (110) YSZ Substrate by Atomic Layer Deposition
journal, July 2014

  • Kim, Dai-Hong; Kim, Won-Sik; Kim, Sungtae
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 15
  • DOI: 10.1021/am501656r