skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Crystallization of TiO 2 polymorphs from RF-sputtered, amorphous thin-film precursors

Authors:
 [1]; ORCiD logo [1];  [1]; ORCiD logo [1];  [1];  [1];  [1];  [2]; ORCiD logo [2];  [3];  [4]; ORCiD logo [4]; ORCiD logo [1]
  1. Department of Physics, Oregon State University, Corvallis, Oregon 97331, USA
  2. Department of Metallurgical and Materials Engineering, Colorado School of Mines, Golden, Colorado 80401, USA
  3. National Renewable Energy Laboratory, Golden, Colorado 80401, USA
  4. SLAC National Accelerator Laboratory, Menlo Park, California 94025, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1598071
Grant/Contract Number:  
AC3608GO28308
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Name: AIP Advances Journal Volume: 10 Journal Issue: 2; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Agirseven, O., Rivella, Jr., D. T., Haggerty, J. E. S., Berry, P. O., Diffendaffer, K., Patterson, A., Kreb, J., Mangum, J. S., Gorman, B. P., Perkins, J. D., Chen, B. R., Schelhas, L. T., and Tate, J. Crystallization of TiO 2 polymorphs from RF-sputtered, amorphous thin-film precursors. United States: N. p., 2020. Web. doi:10.1063/1.5140368.
Agirseven, O., Rivella, Jr., D. T., Haggerty, J. E. S., Berry, P. O., Diffendaffer, K., Patterson, A., Kreb, J., Mangum, J. S., Gorman, B. P., Perkins, J. D., Chen, B. R., Schelhas, L. T., & Tate, J. Crystallization of TiO 2 polymorphs from RF-sputtered, amorphous thin-film precursors. United States. doi:10.1063/1.5140368.
Agirseven, O., Rivella, Jr., D. T., Haggerty, J. E. S., Berry, P. O., Diffendaffer, K., Patterson, A., Kreb, J., Mangum, J. S., Gorman, B. P., Perkins, J. D., Chen, B. R., Schelhas, L. T., and Tate, J. Sat . "Crystallization of TiO 2 polymorphs from RF-sputtered, amorphous thin-film precursors". United States. doi:10.1063/1.5140368.
@article{osti_1598071,
title = {Crystallization of TiO 2 polymorphs from RF-sputtered, amorphous thin-film precursors},
author = {Agirseven, O. and Rivella, Jr., D. T. and Haggerty, J. E. S. and Berry, P. O. and Diffendaffer, K. and Patterson, A. and Kreb, J. and Mangum, J. S. and Gorman, B. P. and Perkins, J. D. and Chen, B. R. and Schelhas, L. T. and Tate, J.},
abstractNote = {},
doi = {10.1063/1.5140368},
journal = {AIP Advances},
number = 2,
volume = 10,
place = {United States},
year = {2020},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1063/1.5140368

Save / Share:

Works referenced in this record:

Absorption spectra of anatase TiO 2 single crystals heat-treated under oxygen atmosphere
journal, August 2000


Controlled formation of anatase and rutile TiO 2 thin films by reactive magnetron sputtering
journal, September 2015

  • Rafieian, Damon; Ogieglo, Wojciech; Savenije, Tom
  • AIP Advances, Vol. 5, Issue 9
  • DOI: 10.1063/1.4931925

Selective brookite polymorph formation related to the amorphous precursor state in TiO2 thin films
journal, February 2019


An Unusual Strong Visible-Light Absorption Band in Red Anatase TiO 2 Photocatalyst Induced by Atomic Hydrogen-Occupied Oxygen Vacancies
journal, January 2018


New understanding of the difference of photocatalytic activity among anatase, rutile and brookite TiO 2
journal, January 2014

  • Zhang, Jinfeng; Zhou, Peng; Liu, Jianjun
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 38
  • DOI: 10.1039/c4cp02201g

Intrinsic n-type Defect Formation in TiO 2 : A Comparison of Rutile and Anatase from GGA+ U Calculations
journal, January 2010

  • Morgan, Benjamin J.; Watson, Graeme W.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 5
  • DOI: 10.1021/jp9088047

Anatase, Brookite, and Rutile Nanocrystals via Redox Reactions under Mild Hydrothermal Conditions:  Phase-Selective Synthesis and Physicochemical Properties
journal, April 2007

  • Li, Ji-Guang; Ishigaki, Takamasa; Sun, Xudong
  • The Journal of Physical Chemistry C, Vol. 111, Issue 13
  • DOI: 10.1021/jp0673258

Tailoring of TiO2 film microstructure by pulsed-DC and RF magnetron co-sputtering
journal, November 2019


Anatase phase TiO2 thin films obtained by pulsed laser deposition for gas sensing applications
journal, July 2005


Brookite, the Least Known TiO2 Photocatalyst
journal, January 2013

  • Di Paola, Agatino; Bellardita, Marianna; Palmisano, Leonardo
  • Catalysts, Vol. 3, Issue 1
  • DOI: 10.3390/catal3010036

Enhancement of optical absorption by modulation of the oxygen flow of TiO 2 films deposited by reactive sputtering
journal, June 2012

  • Pereira, André L. J.; Lisboa Filho, Paulo N.; Acuña, Javier
  • Journal of Applied Physics, Vol. 111, Issue 11
  • DOI: 10.1063/1.4724334

High-fraction brookite films from amorphous precursors
journal, November 2017

  • Haggerty, James E. S.; Schelhas, Laura T.; Kitchaev, Daniil A.
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/s41598-017-15364-y

Utilizing TiO 2 amorphous precursors for polymorph selection: An in situ TEM study of phase formation and kinetics
journal, December 2019

  • Mangum, John S.; Garten, Lauren M.; Ginley, David S.
  • Journal of the American Ceramic Society, Vol. 103, Issue 4
  • DOI: 10.1111/jace.16965

Brookite TiO 2 Thin Film Epitaxially Grown on (110) YSZ Substrate by Atomic Layer Deposition
journal, July 2014

  • Kim, Dai-Hong; Kim, Won-Sik; Kim, Sungtae
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 15
  • DOI: 10.1021/am501656r