This content will become publicly available on January 28, 2021
Electrochemically induced crystallization of amorphous materials in molten MgCl 2 : boron nitride and hard carbon
Abstract
A novel and versatile strategy toward the amorphous-to-crystalline transformation of boron nitride was developed through an electrochemical pathway using molten MgCl 2 at low temperature (750 °C) and can be extended for transformation of amorphous carbon to graphite.
- Authors:
-
[3];
[2]
- Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, USA
- Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, USA, Department of Chemistry
- Department of Chemistry, University of Tennessee, Knoxville, USA
- Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, USA
- Energy and Transportation Science Division, Oak Ridge National Laboratory, Oak Ridge, USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1598053
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Name: ChemComm; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry (RSC)
- Country of Publication:
- United Kingdom
- Language:
- English
Citation Formats
Bagri, Prashant, P. Thapaliya, Bishnu, Yang, Zhenzhen, Jiang, Wei, Sulejmanovic, Dino, Luo, Huimin, and Dai, Sheng. Electrochemically induced crystallization of amorphous materials in molten MgCl 2 : boron nitride and hard carbon. United Kingdom: N. p., 2020.
Web. doi:10.1039/C9CC08717F.
Bagri, Prashant, P. Thapaliya, Bishnu, Yang, Zhenzhen, Jiang, Wei, Sulejmanovic, Dino, Luo, Huimin, & Dai, Sheng. Electrochemically induced crystallization of amorphous materials in molten MgCl 2 : boron nitride and hard carbon. United Kingdom. doi:10.1039/C9CC08717F.
Bagri, Prashant, P. Thapaliya, Bishnu, Yang, Zhenzhen, Jiang, Wei, Sulejmanovic, Dino, Luo, Huimin, and Dai, Sheng. Wed .
"Electrochemically induced crystallization of amorphous materials in molten MgCl 2 : boron nitride and hard carbon". United Kingdom. doi:10.1039/C9CC08717F.
@article{osti_1598053,
title = {Electrochemically induced crystallization of amorphous materials in molten MgCl 2 : boron nitride and hard carbon},
author = {Bagri, Prashant and P. Thapaliya, Bishnu and Yang, Zhenzhen and Jiang, Wei and Sulejmanovic, Dino and Luo, Huimin and Dai, Sheng},
abstractNote = {A novel and versatile strategy toward the amorphous-to-crystalline transformation of boron nitride was developed through an electrochemical pathway using molten MgCl 2 at low temperature (750 °C) and can be extended for transformation of amorphous carbon to graphite.},
doi = {10.1039/C9CC08717F},
journal = {ChemComm},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}
Free Publicly Available Full Text
This content will become publicly available on January 28, 2021
Publisher's Version of Record
DOI: 10.1039/C9CC08717F
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Nano boron nitride flatland
journal, January 2014
- Pakdel, Amir; Bando, Yoshio; Golberg, Dmitri
- Chem. Soc. Rev., Vol. 43, Issue 3
Enhanced performance of graphite anode materials by AlF3 coating for lithium-ion batteries
journal, January 2012
- Ding, Fei; Xu, Wu; Choi, Daiwon
- Journal of Materials Chemistry, Vol. 22, Issue 25
Synthesis of Mo2N nanolayer coated MoO2 hollow nanostructures as high-performance anode materials for lithium-ion batteries
journal, January 2013
- Liu, Jun; Tang, Shasha; Lu, Yakun
- Energy & Environmental Science, Vol. 6, Issue 9
Controlled Gas Exfoliation of Boron Nitride into Few-Layered Nanosheets
journal, July 2016
- Zhu, Wenshuai; Gao, Xiang; Li, Qian
- Angewandte Chemie International Edition, Vol. 55, Issue 36
Electrochemical Reduction of (U, Pu)O 2 in Molten LiCl and CaCl 2 Electrolytes
journal, May 2007
- Iizuka, Masatoshi; Inoue, Tadashi; Ougier, Michel
- Journal of Nuclear Science and Technology, Vol. 44, Issue 5
Boron Nitride Nanostructures: Fabrication, Functionalization and Applications
journal, April 2016
- Yin, Jun; Li, Jidong; Hang, Yang
- Small, Vol. 12, Issue 22
Recent Advances in Ultrathin Two-Dimensional Nanomaterials
journal, March 2017
- Tan, Chaoliang; Cao, Xiehong; Wu, Xue-Jun
- Chemical Reviews, Vol. 117, Issue 9
The formation and stability of the solid electrolyte interface on the graphite anode
journal, December 2014
- Agubra, Victor A.; Fergus, Jeffrey W.
- Journal of Power Sources, Vol. 268
Functionalized hexagonal boron nitride nanomaterials: emerging properties and applications
journal, January 2016
- Weng, Qunhong; Wang, Xuebin; Wang, Xi
- Chemical Society Reviews, Vol. 45, Issue 14
Electrochemically Alternating Voltage Induced Mn3O4/Graphite Powder Composite with Enhanced Electrochemical Performances for Lithium-ion Batteries
journal, February 2015
- Jing, Mingjun; Hou, Hongshuai; Yang, Yingchang
- Electrochimica Acta, Vol. 155
Deep Ultraviolet Light-Emitting Hexagonal Boron Nitride Synthesized at Atmospheric Pressure
journal, August 2007
- Kubota, Y.; Watanabe, K.; Tsuda, O.
- Science, Vol. 317, Issue 5840
Electrochemically Driven Transformation of Amorphous Carbons to Crystalline Graphite Nanoflakes: A Facile and Mild Graphitization Method
journal, January 2017
- Peng, Junjun; Chen, Nanqing; He, Rui
- Angewandte Chemie, Vol. 129, Issue 7
Probing microstructure and electrolyte concentration dependent cell chemistry via operando small angle neutron scattering
journal, January 2019
- Jafta, Charl J.; Sun, Xiao-Guang; Veith, Gabriel M.
- Energy & Environmental Science, Vol. 12, Issue 6
Sintering and crystallization of ground hexagonal boron nitride powders
journal, January 1994
- Hagio, T.; Yoshida, H.
- Journal of Materials Science Letters, Vol. 13, Issue 9
Improved Graphite Anode for Lithium-Ion Batteries Chemically
journal, January 1996
- Peled, E.
- Journal of The Electrochemical Society, Vol. 143, Issue 1
Taming interfacial electronic properties of platinum nanoparticles on vacancy-abundant boron nitride nanosheets for enhanced catalysis
journal, June 2017
- Zhu, Wenshuai; Wu, Zili; Foo, Guo Shiou
- Nature Communications, Vol. 8, Issue 1
Low-Surface-Area Hard Carbon Anode for Na-Ion Batteries via Graphene Oxide as a Dehydration Agent
journal, January 2015
- Luo, Wei; Bommier, Clement; Jian, Zelang
- ACS Applied Materials & Interfaces, Vol. 7, Issue 4
Tailoring N-Terminated Defective Edges of Porous Boron Nitride for Enhanced Aerobic Catalysis
journal, October 2017
- Wu, Peiwen; Yang, Shize; Zhu, Wenshuai
- Small, Vol. 13, Issue 44
Flexible high-temperature dielectric materials from polymer nanocomposites
journal, July 2015
- Li, Qi; Chen, Lei; Gadinski, Matthew R.
- Nature, Vol. 523, Issue 7562
Construction of a Nanoporous Highly Crystalline Hexagonal Boron Nitride from an Amorphous Precursor for Catalytic Dehydrogenation
journal, June 2019
- Chen, Hao; Yang, Zhenzhen; Zhang, Zihao
- Angewandte Chemie International Edition, Vol. 58, Issue 31
Soft-Templated Mesoporous Carbon-Carbon Nanotube Composites for High Performance Lithium-ion Batteries
journal, September 2011
- Guo, Bingkun; Wang, Xiqing; Fulvio, Pasquale F.
- Advanced Materials, Vol. 23, Issue 40, p. 4661-4666
Simultaneous Production and Functionalization of Boron Nitride Nanosheets by Sugar-Assisted Mechanochemical Exfoliation
journal, January 2019
- Chen, Shaohua; Xu, Runzhang; Liu, Jiaman
- Advanced Materials, Vol. 31, Issue 10
Electrochemical Reduction of UO[sub 2] in Molten CaCl[sub 2] or LiCl
journal, January 2006
- Sakamura, Yoshiharu; Kurata, Masaki; Inoue, Tadashi
- Journal of The Electrochemical Society, Vol. 153, Issue 3
Growth of Manganese Oxide Nanoflowers on Vertically-Aligned Carbon Nanotube Arrays for High-Rate Electrochemical Capacitive Energy Storage
journal, September 2008
- Zhang, Hao; Cao, Gaoping; Wang, Zhiyong
- Nano Letters, Vol. 8, Issue 9
The Production of Ti–Mo Alloys from Mixed Oxide Precursors via the FFC Cambridge Process
journal, January 2008
- Bhagat, R.; Jackson, M.; Inman, D.
- Journal of The Electrochemical Society, Vol. 155, Issue 6
Extraction of titanium from different titania precursors by the FFC Cambridge process
journal, August 2006
- Ma, Meng; Wang, Dihua; Wang, Wenguang
- Journal of Alloys and Compounds, Vol. 420, Issue 1-2
Hot deformation behavior and the processing map of Zr–1.0Be alloy in single α phase
journal, October 2015
- Feng, Zhihao; Jiang, Xiaojun; Zhou, Yunkai
- Progress in Natural Science: Materials International, Vol. 25, Issue 5
EIS study on the formation of solid electrolyte interface in Li-ion battery
journal, January 2006
- Zhang, S. S.; Xu, K.; Jow, T. R.
- Electrochimica Acta, Vol. 51, Issue 8-9
Fluorinated Mn3O4 nanospheres for lithium-ion batteries: Low-cost synthesis with enhanced capacity, cyclability and charge-transport
journal, April 2018
- Palaniyandy, Nithyadharseni; Nkosi, Funeka P.; Raju, Kumar
- Materials Chemistry and Physics, Vol. 209