Chemistry under extreme conditions: Pressure evolution of chemical bonding and structure in dense solids
Abstract
Recent advances in high-pressure technologies and large-scale experimental and computational facilities have enabled scientists, at an unprecedented rate, to discover and predict novel states and materials under the extreme pressure-temperature conditions found in deep, giant-planet interiors. Based on a well-documented body of work in this field of high-pressure research, we elucidate the fundamental principles that govern the chemistry of dense solids under extreme conditions. These include: (i) the pressure-induced evolution of chemical bonding and structure of molecular solids to extended covalent solids, ionic solids and, ultimately, metallic solids, as pressure increases to the terapascal regime; (ii) novel properties and complex transition mechanisms, arising from the subtle balance between electron hybridization (bonding) and electrostatic interaction (packing) in densely packed solids; and (iii) new dense framework solids with high energy densities, and with tunable properties and stabilities under ambient conditions. Examples are taken primarily fromlow-Z molecular systems that have scientific implications for giant-planet models, condensed materials physics, and solid-state core-electron chemistry.
- Authors:
-
- Washington State Univ., Pullman, WA (United States). Inst. of Shock Physics, and Materials Science and Engineering
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- National Science Foundation (NSF); USDOE National Nuclear Security Administration (NNSA); US Army Research Office (ARO); Defense Advanced Research Projects Agency (DARPA); USDOE Office of Science (SC), Basic Energy Sciences (BES); Agency for Defense Development (ADD)
- OSTI Identifier:
- 1598015
- Grant/Contract Number:
- DMR 1701360; NA0003342; W911NF-17-1-0468; W31P4Q-12-1-0009
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Matter and Radiation at Extremes
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 1; Journal ID: ISSN 2468-2047
- Publisher:
- China Academy of Engineering Physics (CAEP)/AIP Publishing
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yoo, Choong-Shik. Chemistry under extreme conditions: Pressure evolution of chemical bonding and structure in dense solids. United States: N. p., 2020.
Web. doi:10.1063/1.5127897.
Yoo, Choong-Shik. Chemistry under extreme conditions: Pressure evolution of chemical bonding and structure in dense solids. United States. https://doi.org/10.1063/1.5127897
Yoo, Choong-Shik. Thu .
"Chemistry under extreme conditions: Pressure evolution of chemical bonding and structure in dense solids". United States. https://doi.org/10.1063/1.5127897. https://www.osti.gov/servlets/purl/1598015.
@article{osti_1598015,
title = {Chemistry under extreme conditions: Pressure evolution of chemical bonding and structure in dense solids},
author = {Yoo, Choong-Shik},
abstractNote = {Recent advances in high-pressure technologies and large-scale experimental and computational facilities have enabled scientists, at an unprecedented rate, to discover and predict novel states and materials under the extreme pressure-temperature conditions found in deep, giant-planet interiors. Based on a well-documented body of work in this field of high-pressure research, we elucidate the fundamental principles that govern the chemistry of dense solids under extreme conditions. These include: (i) the pressure-induced evolution of chemical bonding and structure of molecular solids to extended covalent solids, ionic solids and, ultimately, metallic solids, as pressure increases to the terapascal regime; (ii) novel properties and complex transition mechanisms, arising from the subtle balance between electron hybridization (bonding) and electrostatic interaction (packing) in densely packed solids; and (iii) new dense framework solids with high energy densities, and with tunable properties and stabilities under ambient conditions. Examples are taken primarily fromlow-Z molecular systems that have scientific implications for giant-planet models, condensed materials physics, and solid-state core-electron chemistry.},
doi = {10.1063/1.5127897},
journal = {Matter and Radiation at Extremes},
number = 1,
volume = 5,
place = {United States},
year = {2020},
month = {1}
}
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Works referenced in this record:
Decomposition and Polymerization of Solid Carbon Monoxide under Pressure
journal, September 1998
- Bernard, Stéphane; Chiarotti, Guido; Scandolo, Sandro
- Physical Review Letters, Vol. 81, Issue 10
In situ X-ray diffraction measurement of shock-wave-driven twinning and lattice dynamics
journal, October 2017
- Wehrenberg, C. E.; McGonegle, D.; Bolme, C.
- Nature, Vol. 550, Issue 7677
Equation of state of shock‐compressed liquids: Carbon dioxide and air
journal, October 1991
- Nellis, W. J.; Mitchell, A. C.; Ree, F. H.
- The Journal of Chemical Physics, Vol. 95, Issue 7
Copolymerization of CO and N 2 to Extended CON 2 Framework Solid at High Pressures
journal, May 2018
- Yoo, Choong-Shik; Kim, Minseob; Lim, Jinhyuk
- The Journal of Physical Chemistry C, Vol. 122, Issue 24
Pressure-Induced Symmetry-Lowering Transition in Dense Nitrogen to Layered Polymeric Nitrogen (LP-N) with Colossal Raman Intensity
journal, November 2014
- Tomasino, Dane; Kim, Minseob; Smith, Jesse
- Physical Review Letters, Vol. 113, Issue 20
A hybrid polymer gel with controlled rates of cross-link rupture and self-repair
journal, October 2006
- Kersey, Farrell R.; Loveless, David M.; Craig, Stephen L.
- Journal of The Royal Society Interface, Vol. 4, Issue 13
Structure of exoplanets
journal, December 2013
- Spiegel, D. S.; Fortney, J. J.; Sotin, C.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 35
Pressure effects on the hydrogen bond in ice up to 80 GPa
journal, June 1994
- Pruzan, Ph.
- Journal of Molecular Structure, Vol. 322
Structural and spectroscopic studies of nitrogen-carbon monoxide mixtures: Photochemical response and observation of a novel phase
journal, May 2017
- Ciezak-Jenkins, Jennifer A.; Steele, Brad A.; Borstad, Gustav M.
- The Journal of Chemical Physics, Vol. 146, Issue 18
High-pressure structural studies of hematite
journal, January 2002
- Rozenberg, G. Kh.; Dubrovinsky, L. S.; Pasternak, M. P.
- Physical Review B, Vol. 65, Issue 6
High-pressure structures and metallization of sodium chloride
journal, October 2012
- Chen, Xin; Ma, Yanming
- EPL (Europhysics Letters), Vol. 100, Issue 2
Dynamic diamond anvil cell (dDAC): A novel device for studying the dynamic-pressure properties of materials
journal, July 2007
- Evans, William J.; Yoo, Choong-Shik; Lee, Geun Woo
- Review of Scientific Instruments, Vol. 78, Issue 7
Global inventory of methane clathrate: sensitivity to changes in the deep ocean
journal, November 2004
- Buffett, Bruce; Archer, David
- Earth and Planetary Science Letters, Vol. 227, Issue 3-4
Transformation and structure of silicatelike CO -V
journal, June 2013
- Yoo, Choong-Shik; Kim, Minseob; Morgenroth, Wolfgang
- Physical Review B, Vol. 87, Issue 21
High-Pressure Melt Curve and Phase Diagram of Lithium
journal, August 2019
- Frost, Mungo; Kim, Jongjin B.; McBride, Emma E.
- Physical Review Letters, Vol. 123, Issue 6
Prediction of New Low Compressibility Solids
journal, August 1989
- Liu, A. Y.; Cohen, M. L.
- Science, Vol. 245, Issue 4920
Polymeric nitrogen
journal, December 1992
- Mailhiot, C.; Yang, L. H.; McMahan, A. K.
- Physical Review B, Vol. 46, Issue 22
Aluminium at terapascal pressures
journal, July 2010
- Pickard, Chris J.; Needs, R. J.
- Nature Materials, Vol. 9, Issue 8
Carbon Dioxide Carbonates in the Earth’s Mantle: Implications to the Deep Carbon Cycle
journal, September 2011
- Yoo, Choong-Shik; Sengupta, Amartya; Kim, Minseob
- Angewandte Chemie, Vol. 123, Issue 47
A quantum fluid of metallic hydrogen suggested by first-principles calculations
journal, October 2004
- Bonev, Stanimir A.; Schwegler, Eric; Ogitsu, Tadashi
- Nature, Vol. 431, Issue 7009
Time-resolved absorption changes of thin carbon disulfide samples under shock compression: electronic and chemical implications
journal, April 1990
- Yoo, C. S.; Gupta, Y. M.
- The Journal of Physical Chemistry, Vol. 94, Issue 7
High pressure partially ionic phase of water ice
journal, September 2011
- Wang, Yanchao; Liu, Hanyu; Lv, Jian
- Nature Communications, Vol. 2, Issue 1
Pressure-induced chemistry in a nitrogen-hydrogen host–guest structure
journal, December 2014
- Spaulding, Dylan K.; Weck, Gunnar; Loubeyre, Paul
- Nature Communications, Vol. 5, Issue 1
Quartzlike Carbon Dioxide: An Optically Nonlinear Extended Solid at High Pressures and Temperatures
journal, March 1999
- Iota, V.
- Science, Vol. 283, Issue 5407
“Stubborn” triaminotrinitrobenzene: Unusually high chemical stability of a molecular solid to 150 GPa
journal, November 2011
- Davidson, Alistair J.; Dias, Ranga P.; Dattelbaum, Dana M.
- The Journal of Chemical Physics, Vol. 135, Issue 17
Ground state structure of high-energy-density polymeric carbon monoxide
journal, April 2017
- Xia, Kang; Sun, Jian; Pickard, Chris J.
- Physical Review B, Vol. 95, Issue 14
Decomposition and oligomerization of 2,3-naphthyridine under high-pressure and high-temperature conditions
journal, May 2019
- Shinozaki, Ayako; Mimura, Koichi; Nishida, Tamihito
- Scientific Reports, Vol. 9, Issue 1
High-Pressure Electrides: The Chemical Nature of Interstitial Quasiatoms
journal, March 2015
- Miao, Mao-sheng; Hoffmann, Roald
- Journal of the American Chemical Society, Vol. 137, Issue 10
Transformation of hydrazinium azide to molecular N 8 at 40 GPa
journal, April 2018
- Duwal, Sakun; Ryu, Young-Jay; Kim, Minseob
- The Journal of Chemical Physics, Vol. 148, Issue 13
Controlling the Bonding and Band Gaps of Solid Carbon Monoxide with Pressure
journal, April 2011
- Sun, Jian; Klug, Dennis D.; Pickard, Chris J.
- Physical Review Letters, Vol. 106, Issue 14
Pressure-Induced Solid Carbonates from Molecular CO2 by Computer Simulation
journal, April 1999
- Serra, S.
- Science, Vol. 284, Issue 5415
Light-Transparent Phase Formed by Room-Temperature Compression of Graphite
journal, June 1991
- Yagi, W. U. A. T.
- Science, Vol. 252, Issue 5012
Raman study of the solid‐state polymerization of acetylene at high pressure
journal, July 1988
- Aoki, K.; Usuba, S.; Yoshida, M.
- The Journal of Chemical Physics, Vol. 89, Issue 1
Structural Transformation and Melting in Gold Shock Compressed to 355 GPa
journal, July 2019
- Sharma, Surinder M.; Turneaure, Stefan J.; Winey, J. M.
- Physical Review Letters, Vol. 123, Issue 4
High Pressure Electrides: A Predictive Chemical and Physical Theory
journal, February 2014
- Miao, Mao-Sheng; Hoffmann, Roald
- Accounts of Chemical Research, Vol. 47, Issue 4
Phase transitions in nitrogen observed by Raman spectroscopy from 0.4 to 27.4 GPa at 15 K
journal, May 1985
- Schiferl, David; Buchsbaum, Steven; Mills, Robert L.
- The Journal of Physical Chemistry, Vol. 89, Issue 11
Secondary building units, nets and bonding in the chemistry of metal–organic frameworks
journal, January 2009
- Tranchemontagne, David J.; Mendoza-Cortés, José L.; O’Keeffe, Michael
- Chemical Society Reviews, Vol. 38, Issue 5, p. 1257-1283
Stability of dense liquid carbon dioxide
journal, August 2012
- Boates, B.; Teweldeberhan, A. M.; Bonev, S. A.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 37
The structure of N2 at 49 kbar and 299 K
journal, January 1981
- Cromer, D. T.; Mills, R. L.; Schiferi, D.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 37, Issue 1
Intercalation of solid hydrogen into graphite under pressures
journal, August 2016
- Lim, Jinhyuk; Yoo, Choong-Shik
- Applied Physics Letters, Vol. 109, Issue 5
Recovery of stishovite-structure at ambient conditions out of shock-generated amorphous silica
journal, November 2006
- Tschauner, O.; Luo, S. -N.; Asimow, P. D.
- American Mineralogist, Vol. 91, Issue 11-12
Time resolved small angle X-ray scattering experiments performed on detonating explosives at the advanced photon source: Calculation of the time and distance between the detonation front and the x-ray beam
journal, March 2017
- Gustavsen, R. L.; Dattelbaum, D. M.; Watkins, E. B.
- Journal of Applied Physics, Vol. 121, Issue 10
Bonding Changes in Compressed Superhard Graphite
journal, October 2003
- Mao, W. L.
- Science, Vol. 302, Issue 5644
Probing matter at Gbar pressures at the NIF
journal, March 2014
- Kritcher, A. L.; Döppner, T.; Swift, D.
- High Energy Density Physics, Vol. 10
Atypical compounds of gases, which have been called ‘noble’
journal, January 2007
- Grochala, Wojciech
- Chemical Society Reviews, Vol. 36, Issue 10
Direct observation of an abrupt insulator-to-metal transition in dense liquid deuterium
journal, June 2015
- Knudson, M. D.; Desjarlais, M. P.; Becker, A.
- Science, Vol. 348, Issue 6242
High pressure ices
journal, December 2011
- Hermann, A.; Ashcroft, N. W.; Hoffmann, R.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 3
High-energy-density extended CO solid
journal, February 2005
- Lipp, Magnus J.; Evans, William J.; Baer, Bruce J.
- Nature Materials, Vol. 4, Issue 3
High Energy Density Mixed Polymeric Phase from Carbon Monoxide and Nitrogen
journal, December 2013
- Raza, Zamaan; Pickard, Chris J.; Pinilla, Carlos
- Physical Review Letters, Vol. 111, Issue 23
Benzene under High Pressure: a Story of Molecular Crystals Transforming to Saturated Networks, with a Possible Intermediate Metallic Phase
journal, June 2011
- Wen, Xiao-Dong; Hoffmann, Roald; Ashcroft, N. W.
- Journal of the American Chemical Society, Vol. 133, Issue 23
Nanosecond freezing of water under multiple shock wave compression: Optical transmission and imaging measurements
journal, November 2004
- Dolan, D. H.; Gupta, Y. M.
- The Journal of Chemical Physics, Vol. 121, Issue 18
Solidification and fcc to metastable hcp phase transition in krypton under variable compression rates
journal, October 2014
- Chen, Jing-Yin; Yoo, Choong-Shik; Evans, William J.
- Physical Review B, Vol. 90, Issue 14
Effects of dilution on the ultraviolet and visible absorptivity of carbon disulfide under static and shock compression
journal, December 1987
- Yoo, C. S.; Furrer, J. J.; Duvall, G. E.
- The Journal of Physical Chemistry, Vol. 91, Issue 27
Formation of diamonds in laser-compressed hydrocarbons at planetary interior conditions
journal, August 2017
- Kraus, D.; Vorberger, J.; Pak, A.
- Nature Astronomy, Vol. 1, Issue 9
Shock‐induced martensitic transformation of highly oriented graphite to diamond
journal, May 1992
- Erskine, David J.; Nellis, William J.
- Journal of Applied Physics, Vol. 71, Issue 10
Crystal Structure of Carbon Dioxide at High Pressure: “Superhard” Polymeric Carbon Dioxide
journal, December 1999
- Yoo, C. S.; Cynn, H.; Gygi, F.
- Physical Review Letters, Vol. 83, Issue 26
Hydrogen bonding induced proton exchange reactions in dense D 2 -NH 3 and D 2 -CH 4 mixtures
journal, January 2014
- Borstad, Gustav M.; Yoo, Choong-Shik
- The Journal of Chemical Physics, Vol. 140, Issue 4
Portable high pressure sapphire anvil cell for gas hydrates research
journal, August 2010
- Wang, Zhao; He, Duanwei; Zhang, Wei
- Review of Scientific Instruments, Vol. 81, Issue 8
Transformation of shock-compressed graphite to hexagonal diamond in nanoseconds
journal, October 2017
- Turneaure, Stefan J.; Sharma, Surinder M.; Volz, Travis J.
- Science Advances, Vol. 3, Issue 10
Pressure Induced Reactivity of Solid CO by FTIR Studies
journal, May 2009
- Ceppatelli, Matteo; Serdyukov, Anton; Bini, Roberto
- The Journal of Physical Chemistry B, Vol. 113, Issue 19
Nanosecond X-ray diffraction of shock-compressed superionic water ice
journal, May 2019
- Millot, Marius; Coppari, Federica; Rygg, J. Ryan
- Nature, Vol. 569, Issue 7755
Dynamic pressure-induced dendritic and shock crystal growth of ice VI
journal, February 2007
- Lee, G. W.; Evans, W. J.; Yoo, C. -S.
- Proceedings of the National Academy of Sciences, Vol. 104, Issue 22
Ternary Inorganic Compounds Containing Carbon, Nitrogen, and Oxygen at High Pressures
journal, October 2017
- Steele, Brad A.; Oleynik, Ivan I.
- Inorganic Chemistry, Vol. 56, Issue 21
Ammonium Azide under High Pressure: A Combined Theoretical and Experimental Study
journal, September 2014
- Crowhurst, Jonathan C.; Zaug, Joseph M.; Radousky, Harry B.
- The Journal of Physical Chemistry A, Vol. 118, Issue 38
Disproportionation and Other Transformations of N 2 O at High Pressures and Temperatures to Lower Energy, Denser Phases
journal, June 2003
- Yoo, C. S.; Iota, V.; Cynn, H.
- The Journal of Physical Chemistry B, Vol. 107, Issue 24
Phase Diagram and Transformations of Iron Pentacarbonyl to nm Layered Hematite and Carbon-Oxygen Polymer under Pressure
journal, October 2015
- Ryu, Young Jay; Kim, Minseob; Yoo, Choong-Shik
- Scientific Reports, Vol. 5, Issue 1
New High-Pressure Phases of Ice
journal, May 1988
- Demontis, Pierfranco; LeSar, Richard; Klein, Michael L.
- Physical Review Letters, Vol. 60, Issue 22
Direct Conversion of Graphite to Diamond in Static Pressure Apparatus
journal, February 1963
- Bundy, F. P.
- The Journal of Chemical Physics, Vol. 38, Issue 3
Pressure‐Induced Phase Transformation in NaCl
journal, January 1968
- Bassett, William A.; Takahashi, Taro; Mao, Ho‐Kwang
- Journal of Applied Physics, Vol. 39, Issue 1
Crystal structure and equation of state of Fe-Si alloys at super-Earth core conditions
journal, April 2018
- Wicks, June K.; Smith, Raymond F.; Fratanduono, Dayne E.
- Science Advances, Vol. 4, Issue 4
Metallization of Fluid Molecular Hydrogen at 140 GPa (1.4 Mbar)
journal, March 1996
- Weir, S. T.; Mitchell, A. C.; Nellis, W. J.
- Physical Review Letters, Vol. 76, Issue 11
Crystallization of water in a dynamic diamond-anvil cell: Evidence for ice VII-like local order in supercompressed water
journal, October 2006
- Lee, Geun Woo; Evans, William J.; Yoo, Choong-Shik
- Physical Review B, Vol. 74, Issue 13
Structural transformation of molecular nitrogen to a single-bonded atomic state at high pressures
journal, January 2004
- Eremets, M. I.; Gavriliuk, A. G.; Serebryanaya, N. R.
- The Journal of Chemical Physics, Vol. 121, Issue 22
Metal–Organic Frameworks as Platforms for Functional Materials
journal, February 2016
- Cui, Yuanjing; Li, Bin; He, Huajun
- Accounts of Chemical Research, Vol. 49, Issue 3
Multiple superionic states in helium–water compounds
journal, July 2019
- Liu, Cong; Gao, Hao; Wang, Yong
- Nature Physics, Vol. 15, Issue 10
Synthesis of quenchable amorphous diamond
journal, August 2017
- Zeng, Zhidan; Yang, Liuxiang; Zeng, Qiaoshi
- Nature Communications, Vol. 8, Issue 1
Metallization and molecular dissociation of dense fluid nitrogen
journal, July 2018
- Jiang, Shuqing; Holtgrewe, Nicholas; Lobanov, Sergey S.
- Nature Communications, Vol. 9, Issue 1
Transformation of molecular nitrogen to nonmolecular phases at megabar pressures by direct laser heating
journal, July 2007
- Lipp, M. J.; Klepeis, J. Park; Baer, B. J.
- Physical Review B, Vol. 76, Issue 1
Materials discovery at high pressures
journal, February 2017
- Zhang, Lijun; Wang, Yanchao; Lv, Jian
- Nature Reviews Materials, Vol. 2, Issue 4
Ramp compression of diamond to five terapascals
journal, July 2014
- Smith, R. F.; Eggert, J. H.; Jeanloz, R.
- Nature, Vol. 511, Issue 7509
The high-pressure dimension in earth and planetary science
journal, May 2007
- Mao, H. -k.; Hemley, R. J.
- Proceedings of the National Academy of Sciences, Vol. 104, Issue 22
Moissanite: A Window for High-Pressure Experiments
journal, October 2000
- Xu, J. -a.
- Science, Vol. 290, Issue 5492
Equation of state of the NaCl-B2 phase up to 304 GPa
journal, April 2011
- Sakai, Takeshi; Ohtani, Eiji; Hirao, Naohisa
- Journal of Applied Physics, Vol. 109, Issue 8
Cubic boron nitride competing with diamond as a superhard engineering material – an overview
journal, January 2013
- Monteiro, Sergio Neves; Skury, Ana Lúcia Diegues; de Azevedo, Márcia Giardinieri
- Journal of Materials Research and Technology, Vol. 2, Issue 1
Exploring High-Pressure Structures of N 2 CO
journal, November 2014
- Zhu, Chunye; Li, Qian; Zhou, Yuanyuan
- The Journal of Physical Chemistry C, Vol. 118, Issue 47
Single‐Crystal X‐Ray Diffraction Study of β Nitrogen
journal, December 1962
- Streib, William E.; Jordan, Truman H.; Lipscomb, William N.
- The Journal of Chemical Physics, Vol. 37, Issue 12
Hydrogen-Doped Polymeric Carbon Monoxide at High Pressure
journal, May 2017
- Ryu, Young-Jay; Yoo, Choong-Shik; Kim, Minseob
- The Journal of Physical Chemistry C, Vol. 121, Issue 18
Reactivity of He with ionic compounds under high pressure
journal, March 2018
- Liu, Zhen; Botana, Jorge; Hermann, Andreas
- Nature Communications, Vol. 9, Issue 1
Pressure-Induced Polymerization of Carbon Monoxide: Disproportionation and Synthesis of an Energetic Lactonic Polymer
journal, May 2006
- Evans, W. J.; Lipp, M. J.; Yoo, C. -S.
- Chemistry of Materials, Vol. 18, Issue 10
Superconductivity in highly disordered dense carbon disulfide
journal, July 2013
- Dias, R. P.; Yoo, C. -S.; Struzhkin, V. V.
- Proceedings of the National Academy of Sciences, Vol. 110, Issue 29
X-ray Diffraction to 302 Gigapascals: High-Pressure Crystal Structure of Cesium Iodide
journal, November 1989
- Mao, H. K.; Hemley, R. J.; Chen, L. C.
- Science, Vol. 246, Issue 4930
Single-bonded cubic form of nitrogen
journal, July 2004
- Eremets, Mikhail I.; Gavriliuk, Alexander G.; Trojan, Ivan A.
- Nature Materials, Vol. 3, Issue 8
Insulator-metal transition in dense fluid deuterium
journal, August 2018
- Celliers, Peter M.; Millot, Marius; Brygoo, Stephanie
- Science, Vol. 361, Issue 6403
Single crystal toroidal diamond anvils for high pressure experiments beyond 5 megabar
journal, September 2018
- Jenei, Zs.; O’Bannon, E. F.; Weir, S. T.
- Nature Communications, Vol. 9, Issue 1
Insulator-metal transition of highly compressed carbon disulfide
journal, October 2011
- Dias, Ranga P.; Yoo, Choong-Shik; Kim, Minseob
- Physical Review B, Vol. 84, Issue 14
High-Pressure Photoinduced Synthesis of Polynitrogen in δ and ϵ Nitrogen Crystals Substitutionally Doped with CO
journal, December 2014
- Ceppatelli, Matteo; Pagliai, Marco; Bini, Roberto
- The Journal of Physical Chemistry C, Vol. 119, Issue 1
Shock growth of ice crystal near equilibrium melting pressure under dynamic compression
journal, April 2019
- Kim, Yong-Jae; Lee, Yun-Hee; Lee, Sooheyong
- Proceedings of the National Academy of Sciences, Vol. 116, Issue 18
Synthesis of Xenon and Iron-Nickel Intermetallic Compounds at Earth’s Core Thermodynamic Conditions
journal, February 2018
- Stavrou, Elissaios; Yao, Yansun; Goncharov, Alexander F.
- Physical Review Letters, Vol. 120, Issue 9
Pressure-induced metallization of dense (H2S)2H2 with high-Tc superconductivity
journal, November 2014
- Duan, Defang; Liu, Yunxian; Tian, Fubo
- Scientific Reports, Vol. 4, Issue 1
Metallic CsI at Pressures of up to 220 Gigapascals
journal, August 1998
- Eremets, M. I.
- Science, Vol. 281, Issue 5381
Porous, Crystalline, Covalent Organic Frameworks
journal, November 2005
- Côté, Adrien P.; Benin, Annabelle I.; Ockwig, Nathan W.
- Science, Vol. 310, Issue 5751, p. 1166-1170
How Evolutionary Crystal Structure Prediction Works—and Why
journal, March 2011
- Oganov, Artem R.; Lyakhov, Andriy O.; Valle, Mario
- Accounts of Chemical Research, Vol. 44, Issue 3
Superconducting high-pressure phase of cesium iodide
journal, April 2009
- Xu, Ying; Tse, John S.; Oganov, Artem R.
- Physical Review B, Vol. 79, Issue 14
Crystal structures and dynamical properties of dense CO 2
journal, September 2016
- Yong, Xue; Liu, Hanyu; Wu, Min
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 40
Physical Chemistry at Ultrahigh Pressures and Temperatures
journal, October 1989
- Jeanloz, R.
- Annual Review of Physical Chemistry, Vol. 40, Issue 1
Liquid-liquid phase transition in compressed hydrogen from first-principles simulations
journal, March 2003
- Scandolo, S.
- Proceedings of the National Academy of Sciences, Vol. 100, Issue 6
Azole-Based Energetic Salts
journal, November 2011
- Gao, Haixiang; Shreeve, Jean’ne M.
- Chemical Reviews, Vol. 111, Issue 11
Conductive dense hydrogen
journal, November 2011
- Eremets, M. I.; Troyan, I. A.
- Nature Materials, Vol. 10, Issue 12
Formation and phase transitions of methane hydrates under dynamic loadings: Compression rate dependent kinetics
journal, March 2012
- Chen, Jing-Yin; Yoo, Choong-Shik
- The Journal of Chemical Physics, Vol. 136, Issue 11
Evidence for the Insulator-Metal Transition in Xenon from Optical, X-Ray, and Band-Structure Studies to 170 GPa
journal, February 1989
- Reichlin, Robin; Brister, Keith E.; McMahan, Andrew K.
- Physical Review Letters, Vol. 62, Issue 6
Transition Temperature of Strong-Coupled Superconductors
journal, March 1968
- McMillan, W. L.
- Physical Review, Vol. 167, Issue 2
First-Order Liquid-Liquid Phase Transition in Compressed Nitrogen
journal, January 2009
- Boates, Brian; Bonev, Stanimir A.
- Physical Review Letters, Vol. 102, Issue 1
Transparent dense sodium
journal, March 2009
- Ma, Yanming; Eremets, Mikhail; Oganov, Artem R.
- Nature, Vol. 458, Issue 7235
Calculation of bulk moduli of diamond and zinc-blende solids
journal, December 1985
- Cohen, Marvin L.
- Physical Review B, Vol. 32, Issue 12
Polymerization of Carbon Dioxide: A Chemistry View of Molecular-to-Nonmolecular Phase Transitions
journal, November 2011
- Sengupta, Amartya; Kim, Minseob; Yoo, Choong-Shik
- The Journal of Physical Chemistry C, Vol. 116, Issue 3
Molecular mechanics modeling of shear and the crystal orientation dependence of the elastic precursor shock strength in pentaerythritol tetranitrate
journal, September 1994
- Dick, J. J.; Ritchie, J. P.
- Journal of Applied Physics, Vol. 76, Issue 5
Dense Carbon Monoxide to 160 GPa: Stepwise Polymerization to Two-Dimensional Layered Solid
journal, November 2016
- Ryu, Young-Jay; Kim, Minseob; Lim, Jinhyuk
- The Journal of Physical Chemistry C, Vol. 120, Issue 48
High-Pressure Phases of Silane
journal, July 2006
- Pickard, Chris J.; Needs, R. J.
- Physical Review Letters, Vol. 97, Issue 4
Superionic and Metallic States of Water and Ammonia at Giant Planet Conditions
journal, January 1999
- Cavazzoni, C.
- Science, Vol. 283, Issue 5398
Man-Made Diamonds
journal, July 1955
- Bundy, F. P.; Hall, H. T.; Strong, H. M.
- Nature, Vol. 176, Issue 4471
Toroidal diamond anvil cell for detailed measurements under extreme static pressures
journal, July 2018
- Dewaele, Agnès; Loubeyre, Paul; Occelli, Florent
- Nature Communications, Vol. 9, Issue 1
Equation of state and metallization of CsI
journal, March 1984
- Aidun, John; Bukowinski, M. S. T.; Ross, Marvin
- Physical Review B, Vol. 29, Issue 5
A little bit of lithium does a lot for hydrogen
journal, October 2009
- Zurek, E.; Hoffmann, R.; Ashcroft, N. W.
- Proceedings of the National Academy of Sciences, Vol. 106, Issue 42
The Revealing Role of Pressure in the Condensed Matter Sciences
journal, August 1998
- Hemley, Russell J.; Ashcroft, Neil W.
- Physics Today, Vol. 51, Issue 8
Metallic Hydrogen: A High-Temperature Superconductor?
journal, December 1968
- Ashcroft, N. W.
- Physical Review Letters, Vol. 21, Issue 26
New phases and chemical reactions in solid carbon monoxide under pressure
journal, July 1984
- Katz, Allen I.; Schiferl, David; Mills, Robert L.
- The Journal of Physical Chemistry, Vol. 88, Issue 15
Highly repulsive interaction in novel inclusion D 2 –N 2 compound at high pressure: Raman and x-ray evidence
journal, January 2011
- Kim, Minseob; Yoo, Choong-Shik
- The Journal of Chemical Physics, Vol. 134, Issue 4
Structure of Polymeric Carbon Dioxide
journal, March 2012
- Datchi, Frédéric; Mallick, Bidyut; Salamat, Ashkan
- Physical Review Letters, Vol. 108, Issue 12
New high-pressure phases of lithium
journal, November 2000
- Hanfland, M.; Syassen, K.; Christensen, N. E.
- Nature, Vol. 408, Issue 6809
New states of matter and chemistry at extreme pressures: Low-Z extended solid
journal, October 2017
- Yoo, Choong-Shik
- MRS Bulletin, Vol. 42, Issue 10
Improved Ductility of Boron Carbide by Microalloying with Boron Suboxide
journal, October 2015
- Tang, Bin; An, Qi; Goddard, William A.
- The Journal of Physical Chemistry C, Vol. 119, Issue 43
Coesite-like : An analog to
journal, July 2010
- Sengupta, Amartya; Yoo, Choong-Shik
- Physical Review B, Vol. 82, Issue 1
Physical and chemical transformations of highly compressed carbon dioxide at bond energies
journal, January 2013
- Yoo, Choong-Shik
- Physical Chemistry Chemical Physics, Vol. 15, Issue 21
The Chemical Imagination at Work inVery Tight Places
journal, May 2007
- Grochala, Wojciech; Hoffmann, Roald; Feng, Ji
- Angewandte Chemie International Edition, Vol. 46, Issue 20
Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system
journal, August 2015
- Drozdov, A. P.; Eremets, M. I.; Troyan, I. A.
- Nature, Vol. 525, Issue 7567
Melting and phase transitions of nitrogen under high pressures and temperatures
journal, June 2014
- Tomasino, Dane; Jenei, Zsolt; Evans, William
- The Journal of Chemical Physics, Vol. 140, Issue 24
Six-fold coordinated carbon dioxide VI
journal, December 2006
- Iota, Valentin; Yoo, Choong-Shik; Klepeis, Jae-Hyun
- Nature Materials, Vol. 6, Issue 1
Observation of the Wigner-Huntington transition to metallic hydrogen
journal, January 2017
- Dias, Ranga P.; Silvera, Isaac F.
- Science, Vol. 355, Issue 6326
Compression of Ice to 210 Gigapascals: Infrared Evidence for a Symmetric Hydrogen-Bonded Phase
journal, July 1996
- Goncharov, A. F.; Struzhkin, V. V.; Somayazulu, M. S.
- Science, Vol. 273, Issue 5272
Demixing of Hydrogen and Helium at Megabar Pressures
journal, March 2009
- Lorenzen, Winfried; Holst, Bastian; Redmer, Ronald
- Physical Review Letters, Vol. 102, Issue 11
Cryogenic loading of large volume presses for high-pressure experimentation and synthesis of novel materials
journal, May 2005
- Lipp, M. J.; Evans, W. J.; Yoo, C. S.
- Review of Scientific Instruments, Vol. 76, Issue 5
Kinetics of a pressure-induced polymerization reaction of cyanogen
journal, December 1986
- Yoo, Choong Shik; Nicol, Malcolm
- The Journal of Physical Chemistry, Vol. 90, Issue 25
Chemical and phase transformations of cyanogen at high pressures
journal, December 1986
- Yoo, Choong Shik; Nicol, Malcolm
- The Journal of Physical Chemistry, Vol. 90, Issue 25
Modulated phases and proton centring in ice observed by X-ray diffraction up to 170?GPa
journal, February 1999
- Loubeyre, Paul; LeToullec, René; Wolanin, Elodie
- Nature, Vol. 397, Issue 6719
N5+: A Novel Homoleptic Polynitrogen Ion as a High Energy Density Material
journal, July 1999
- Christe, Karl O.; Wilson, William W.; Sheehy, Jeffrey A.
- Angewandte Chemie International Edition, Vol. 38, Issue 13-14
H 2 O and D 2 mixtures under pressure: Spectroscopy and proton exchange kinetics
journal, November 2011
- Borstad, Gustav M.; Yoo, Choong-Shik
- The Journal of Chemical Physics, Vol. 135, Issue 17
Terapascal static pressure generation with ultrahigh yield strength nanodiamond
journal, July 2016
- Dubrovinskaia, Natalia; Dubrovinsky, Leonid; Solopova, Natalia A.
- Science Advances, Vol. 2, Issue 7
Novel High Pressure Structures of Polymeric Nitrogen
journal, February 2009
- Ma, Yanming; Oganov, Artem R.; Li, Zhenwei
- Physical Review Letters, Vol. 102, Issue 6
Solidification and crystal growth of highly compressed hydrogen and deuterium: Time-resolved study under ramp compression in dynamic-diamond anvil cell
journal, August 2013
- Tomasino, Dane; Yoo, Choong-Shik
- Applied Physics Letters, Vol. 103, Issue 6
Two- and three-dimensional extended solids and metallization of compressed XeF2
journal, July 2010
- Kim, Minseob; Debessai, Mathew; Yoo, Choong-Shik
- Nature Chemistry, Vol. 2, Issue 9
High density amorphous ice at room temperature
journal, April 2011
- Chen, J. -Y.; Yoo, C. -S.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 19