Facile MoS 2 Growth on Reduced Graphene-Oxide via Liquid Phase Method
Abstract
Single and few-layers MoS 2 were uniformly grown on the surface of chemically reduced graphene oxide (r-GO), via a facile liquid phase approach. The method is based on a simple functionalization of r-GO with oleyl amine which seems to affect significantly the MoS 2 way of growth. Scanning-transmission-electron microscopy (STEM) analysis revealed the presence of single-layer MoS 2 on the surface of a few-layers r-GO. This result was also confirmed by atomic-force microscopy (AFM) images. X-ray photoemission spectroscopy (XPS) and Raman spectroscopy were used for in-depth structural characterization. Furthermore, we have successfully applied the method to synthesize MoS 2 nanocomposites with multi wall carbon nanotubes (CN) and carbon nanofibers (CNF). The results demonstrate clearly the selective MoS 2 growth on both carbon-based supports.
- Authors:
- Publication Date:
- Research Org.:
- Vanderbilt Univ., Nashville, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1597899
- Grant/Contract Number:
- [FG02-09ER46554]
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Frontiers in Materials
- Additional Journal Information:
- [ Journal Volume: 5]; Journal ID: ISSN 2296-8016
- Publisher:
- Frontiers Research Foundation
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE
Citation Formats
Tzitzios, Vasileios, Dimos, Konstantinos, Alhassan, Saeed M., Mishra, Rohan, Kouloumpis, Antonios, Gournis, Dimitrios, Boukos, Nikolaos, Roldan, Manuel A., Idrobo, Juan-Carlos, Karakassides, Michael A., Basina, Georgia, Alwahedi, Yasser, Jin Kim, Hae, Katsiotis, Marios S., Fardis, Michael, Borisevich, Albina, Pennycook, Stephen J., Pantelides, Sokrates T., and Papavassiliou, George. Facile MoS2 Growth on Reduced Graphene-Oxide via Liquid Phase Method. United States: N. p., 2018.
Web. doi:10.3389/fmats.2018.00029.
Tzitzios, Vasileios, Dimos, Konstantinos, Alhassan, Saeed M., Mishra, Rohan, Kouloumpis, Antonios, Gournis, Dimitrios, Boukos, Nikolaos, Roldan, Manuel A., Idrobo, Juan-Carlos, Karakassides, Michael A., Basina, Georgia, Alwahedi, Yasser, Jin Kim, Hae, Katsiotis, Marios S., Fardis, Michael, Borisevich, Albina, Pennycook, Stephen J., Pantelides, Sokrates T., & Papavassiliou, George. Facile MoS2 Growth on Reduced Graphene-Oxide via Liquid Phase Method. United States. doi:10.3389/fmats.2018.00029.
Tzitzios, Vasileios, Dimos, Konstantinos, Alhassan, Saeed M., Mishra, Rohan, Kouloumpis, Antonios, Gournis, Dimitrios, Boukos, Nikolaos, Roldan, Manuel A., Idrobo, Juan-Carlos, Karakassides, Michael A., Basina, Georgia, Alwahedi, Yasser, Jin Kim, Hae, Katsiotis, Marios S., Fardis, Michael, Borisevich, Albina, Pennycook, Stephen J., Pantelides, Sokrates T., and Papavassiliou, George. Mon .
"Facile MoS2 Growth on Reduced Graphene-Oxide via Liquid Phase Method". United States. doi:10.3389/fmats.2018.00029. https://www.osti.gov/servlets/purl/1597899.
@article{osti_1597899,
title = {Facile MoS2 Growth on Reduced Graphene-Oxide via Liquid Phase Method},
author = {Tzitzios, Vasileios and Dimos, Konstantinos and Alhassan, Saeed M. and Mishra, Rohan and Kouloumpis, Antonios and Gournis, Dimitrios and Boukos, Nikolaos and Roldan, Manuel A. and Idrobo, Juan-Carlos and Karakassides, Michael A. and Basina, Georgia and Alwahedi, Yasser and Jin Kim, Hae and Katsiotis, Marios S. and Fardis, Michael and Borisevich, Albina and Pennycook, Stephen J. and Pantelides, Sokrates T. and Papavassiliou, George},
abstractNote = {Single and few-layers MoS2 were uniformly grown on the surface of chemically reduced graphene oxide (r-GO), via a facile liquid phase approach. The method is based on a simple functionalization of r-GO with oleyl amine which seems to affect significantly the MoS2 way of growth. Scanning-transmission-electron microscopy (STEM) analysis revealed the presence of single-layer MoS2 on the surface of a few-layers r-GO. This result was also confirmed by atomic-force microscopy (AFM) images. X-ray photoemission spectroscopy (XPS) and Raman spectroscopy were used for in-depth structural characterization. Furthermore, we have successfully applied the method to synthesize MoS2 nanocomposites with multi wall carbon nanotubes (CN) and carbon nanofibers (CNF). The results demonstrate clearly the selective MoS2 growth on both carbon-based supports.},
doi = {10.3389/fmats.2018.00029},
journal = {Frontiers in Materials},
number = ,
volume = [5],
place = {United States},
year = {2018},
month = {7}
}
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Works referenced in this record:
Inkjet printing of graphene
journal, January 2014
- Arapov, Kirill; Abbel, Robert; de With, Gijsbertus
- Faraday Discuss., Vol. 173
Chemical Vapor Deposition of High-Quality Large-Sized MoS 2 Crystals on Silicon Dioxide Substrates
journal, March 2016
- Chen, Jianyi; Tang, Wei; Tian, Bingbing
- Advanced Science, Vol. 3, Issue 8
Two-Dimensional Nanosheets Produced by Liquid Exfoliation of Layered Materials
journal, February 2011
- Coleman, J. N.; Lotya, M.; O'Neill, A.
- Science, Vol. 331, Issue 6017, p. 568-571
Bandgap Engineering of Strained Monolayer and Bilayer MoS2
journal, July 2013
- Conley, Hiram J.; Wang, Bin; Ziegler, Jed I.
- Nano Letters, Vol. 13, Issue 8, p. 3626-3630
MoS 2 /Graphene Composite Paper for Sodium-Ion Battery Electrodes
journal, January 2014
- David, Lamuel; Bhandavat, Romil; Singh, Gurpreet
- ACS Nano, Vol. 8, Issue 2
Boron nitride substrates for high-quality graphene electronics
journal, August 2010
- Dean, C. R.; Young, A. F.; Meric, I.
- Nature Nanotechnology, Vol. 5, Issue 10, p. 722-726
Top-down and bottom-up approaches to transparent, flexible and luminescent nitrogen-doped carbon nanodot-clay hybrid films
journal, January 2017
- Dimos, Konstantinos; Arcudi, Francesca; Kouloumpis, Antonios
- Nanoscale, Vol. 9, Issue 29
The rise of graphene
journal, March 2007
- Geim, A. K.; Novoselov, K. S.
- Nature Materials, Vol. 6, Issue 3, p. 183-191
Large-Yield Preparation of High-Electronic-Quality Graphene by a LangmuirâSchaefer Approach
journal, January 2010
- Gengler, Régis Y. N.; Veligura, Alina; Enotiadis, Apostolos
- Small, Vol. 6, Issue 1
Identification of Active Edge Sites for Electrochemical H2 Evolution from MoS2 Nanocatalysts
journal, July 2007
- Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J.
- Science, Vol. 317, Issue 5834, p. 100-102
Engineering the surface structure of MoS2 to preferentially expose active edge sites for electrocatalysis
journal, October 2012
- Kibsgaard, Jakob; Chen, Zhebo; Reinecke, Benjamin N.
- Nature Materials, Vol. 11, Issue 11, p. 963-969
Synthesis of MoS2 and MoSe2 Films with Vertically Aligned Layers
journal, February 2013
- Kong, Desheng; Wang, Haotian; Cha, Judy J.
- Nano Letters, Vol. 13, Issue 3, p. 1341-1347
Formation of MoS2 nanoparticles on the surface of reduced graphite oxide
journal, August 2011
- Koroteev, V. O.; Bulusheva, L. G.; Okotrub, A. V.
- physica status solidi (b), Vol. 248, Issue 11
Graphene/Carbon Dot Hybrid Thin Films Prepared by a Modified Langmuir–Schaefer Method
journal, May 2017
- Kouloumpis, Antonios; Thomou, Eleni; Chalmpes, Nikolaos
- ACS Omega, Vol. 2, Issue 5
Anomalous Lattice Vibrations of Single- and Few-Layer MoS 2
journal, March 2010
- Lee, Changgu; Yan, Hugen; Brus, Louis E.
- ACS Nano, Vol. 4, Issue 5
Breakdown of High-Performance Monolayer MoS 2 Transistors
journal, October 2012
- Lembke, Dominik; Kis, Andras
- ACS Nano, Vol. 6, Issue 11
MoS2 Nanoparticles Grown on Graphene An Advanced Catalyst for the Hydrogen Evolution Reaction
journal, May 2011
- Li, Yanguang; Wang, Hailiang; Xie, Liming
- Journal of the American Chemical Society, Vol. 133, Issue 19, p. 7296-7299
MoS 2 Formed on Mesoporous Graphene as a Highly Active Catalyst for Hydrogen Evolution
journal, May 2013
- Liao, Lei; Zhu, Jie; Bian, Xiaojun
- Advanced Functional Materials, Vol. 23, Issue 42
Cationic surfactant-assisted hydrothermal synthesis of few-layer molybdenum disulfide/graphene composites: Microstructure and electrochemical lithium storage
journal, October 2014
- Ma, Lin; Huang, Guochuang; Chen, Weixiang
- Journal of Power Sources, Vol. 264
Graphene adhesion on MoS2 monolayer: An ab initio study
journal, January 2011
- Ma, Yandong; Dai, Ying; Guo, Meng
- Nanoscale, Vol. 3, Issue 9
Single-layer MoS2 transistors
journal, January 2011
- Radisavljevic, B.; Radenovic, A.; Brivio, J.
- Nature Nanotechnology, Vol. 6, Issue 3, p. 147-150
Layer-Controlled Chemical Vapor Deposition Growth of MoS 2 Vertical Heterostructures via van der Waals Epitaxy
journal, July 2016
- Samad, Leith; Bladow, Sage M.; Ding, Qi
- ACS Nano, Vol. 10, Issue 7
van der Waals Epitaxy of MoS2 Layers Using Graphene As Growth Templates
journal, May 2012
- Shi, Yumeng; Zhou, Wu; Lu, Ang-Yu
- Nano Letters, Vol. 12, Issue 6, p. 2784-2791
A Raman and XPS investigation of supported molybdenum oxide thin films. 2. Reactions with hydrogen sulfide
journal, October 1993
- Spevack, Perry A.; McIntyre, N. S.
- The Journal of Physical Chemistry, Vol. 97, Issue 42
Verfahren zur Darstellung der Graphitsäure
journal, May 1898
- Staudenmaier, L.
- Berichte der deutschen chemischen Gesellschaft, Vol. 31, Issue 2
Comparative study of different types of graphenes as electrocatalysts for ascorbic acid
journal, October 2010
- Stergiou, Dimitrios V.; Diamanti, Evmorfia K.; Gournis, Dimitrios
- Electrochemistry Communications, Vol. 12, Issue 10
Electroluminescence in Single Layer MoS2
journal, March 2013
- Sundaram, R. S.; Engel, M.; Lombardo, A.
- Nano Letters, Vol. 13, Issue 4, p. 1416-1421
Uniform growth of fct FePt nanoparticles on the surface of reduced-GO via a green facile approach. Ferromagnetic r-GO nanocomposites with high coercivity and surface area
journal, September 2017
- Tzitzios, Vasileios; Hu, Xiaocao; Dimos, Konstantinos
- Carbon, Vol. 121
Electrochemical Tuning of MoS 2 Nanoparticles on Three-Dimensional Substrate for Efficient Hydrogen Evolution
journal, April 2014
- Wang, Haotian; Lu, Zhiyi; Kong, Desheng
- ACS Nano, Vol. 8, Issue 5
Integrated Circuits Based on Bilayer MoS2 Transistors
journal, January 2012
- Wang, Han; Yu, Lili; Lee, Yi-Hsien
- Nano Letters, Vol. 12, Issue 9, p. 4674-4680
Synergetic Effect of MoS 2 and Graphene as Cocatalysts for Enhanced Photocatalytic H 2 Production Activity of TiO 2 Nanoparticles
journal, April 2012
- Xiang, Quanjun; Yu, Jiaguo; Jaroniec, Mietek
- Journal of the American Chemical Society, Vol. 134, Issue 15
Ultrahigh-Gain Photodetectors Based on Atomically Thin Graphene-MoS2 Heterostructures
journal, January 2014
- Zhang, Wenjing; Chuu, Chih-Piao; Huang, Jing-Kai
- Scientific Reports, Vol. 4, Issue 1
Raman spectroscopy of shear and layer breathing modes in multilayer MoS
journal, March 2013
- Zhang, X.; Han, W. P.; Wu, J. B.
- Physical Review B, Vol. 87, Issue 11
Space-Confined Growth of MoS 2 Nanosheets within Graphite: The Layered Hybrid of MoS 2 and Graphene as an Active Catalyst for Hydrogen Evolution Reaction
journal, March 2014
- Zheng, Xiaoli; Xu, Jianbo; Yan, Keyou
- Chemistry of Materials, Vol. 26, Issue 7
Chemical vapour deposition and characterization of uniform bilayer and trilayer MoS 2 crystals
journal, January 2016
- Zobel, Adam; Boson, Alex; Wilson, Peter M.
- Journal of Materials Chemistry C, Vol. 4, Issue 47