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Title: Atomic‐Resolution Imaging of Halide Perovskites Using Electron Microscopy

Authors:
 [1];  [1];  [2];  [3];  [3]; ORCiD logo [1]
  1. Advanced Membranes and Porous Materials CenterDivision of Physical Sciences and EngineeringKing Abdullah University of Science and Technology (KAUST) Thuwal 23955‐6900 Kingdom of Saudi Arabia
  2. Multi‐scale Porous Materials CenterInstitute of Advanced Interdisciplinary Studies &, School of Chemistry and Chemical EngineeringChongqing University Chongqing 400044 P. R. China
  3. Department of ChemistryUniversity of Wisconsin‐Madison 1101 University Avenue Madison WI 53706 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1597543
Grant/Contract Number:  
DE‐FG02‐09ER46664
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Song, Kepeng, Liu, Lingmei, Zhang, Daliang, Hautzinger, Matthew P., Jin, Song, and Han, Yu. Atomic‐Resolution Imaging of Halide Perovskites Using Electron Microscopy. Germany: N. p., 2020. Web. doi:10.1002/aenm.201904006.
Song, Kepeng, Liu, Lingmei, Zhang, Daliang, Hautzinger, Matthew P., Jin, Song, & Han, Yu. Atomic‐Resolution Imaging of Halide Perovskites Using Electron Microscopy. Germany. doi:10.1002/aenm.201904006.
Song, Kepeng, Liu, Lingmei, Zhang, Daliang, Hautzinger, Matthew P., Jin, Song, and Han, Yu. Wed . "Atomic‐Resolution Imaging of Halide Perovskites Using Electron Microscopy". Germany. doi:10.1002/aenm.201904006.
@article{osti_1597543,
title = {Atomic‐Resolution Imaging of Halide Perovskites Using Electron Microscopy},
author = {Song, Kepeng and Liu, Lingmei and Zhang, Daliang and Hautzinger, Matthew P. and Jin, Song and Han, Yu},
abstractNote = {},
doi = {10.1002/aenm.201904006},
journal = {Advanced Energy Materials},
number = ,
volume = ,
place = {Germany},
year = {2020},
month = {2}
}

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Works referenced in this record:

Intriguing Optoelectronic Properties of Metal Halide Perovskites
journal, June 2016


Atomic scale insights into structure instability and decomposition pathway of methylammonium lead iodide perovskite
journal, November 2018


Structural and Chemical Changes to CH 3 NH 3 PbI 3 Induced by Electron and Gallium Ion Beams
journal, April 2018


Self-Organized Superlattice and Phase Coexistence inside Thin Film Organometal Halide Perovskite
journal, January 2018

  • Kim, Tae Woong; Uchida, Satoshi; Matsushita, Tomonori
  • Advanced Materials, Vol. 30, Issue 8
  • DOI: 10.1002/adma.201705230

Investigation of Energy Levels and Crystal Structures of Cesium Lead Halides and Their Application in Full-Color Light-Emitting Diodes
journal, December 2016

  • Van Le, Quyet; Park, Minjoon; Sohn, Woonbae
  • Advanced Electronic Materials, Vol. 3, Issue 1
  • DOI: 10.1002/aelm.201600448

Temperature-dependent photoluminescence spectra and decay dynamics of MAPbBr 3 and MAPbI 3 thin films
journal, September 2018

  • Liu, Yiting; Lu, Haizhou; Niu, Jiaxin
  • AIP Advances, Vol. 8, Issue 9
  • DOI: 10.1063/1.5042489

Structures, Phase Transitions and Tricritical Behavior of the Hybrid Perovskite Methyl Ammonium Lead Iodide
journal, October 2016

  • Whitfield, P. S.; Herron, N.; Guise, W. E.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep35685

Direct Imaging of Atomically Dispersed Molybdenum that Enables Location of Aluminum in the Framework of Zeolite ZSM-5
journal, December 2019

  • Liu, Lingmei; Wang, Ning; Zhu, Chongzhi
  • Angewandte Chemie International Edition, Vol. 59, Issue 2
  • DOI: 10.1002/anie.201909834

Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
journal, January 2015


Multicolored Organic/Inorganic Hybrid Perovskite Light-Emitting Diodes
journal, November 2014

  • Kim, Young-Hoon; Cho, Himchan; Heo, Jin Hyuck
  • Advanced Materials, Vol. 27, Issue 7
  • DOI: 10.1002/adma.201403751

Low-Energy Electron-Induced Transformations in Organolead Halide Perovskite
journal, June 2016

  • Milosavljević, Aleksandar R.; Huang, Weixin; Sadhu, Subha
  • Angewandte Chemie International Edition, Vol. 55, Issue 34
  • DOI: 10.1002/anie.201605013

Convergent-beam electron diffraction
journal, May 1994

  • Tanaka, M.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 50, Issue 3
  • DOI: 10.1107/S0108767393010426

Dynamics of Soft Nanomaterials Captured by Transmission Electron Microscopy in Liquid Water
journal, January 2014

  • Proetto, Maria T.; Rush, Anthony M.; Chien, Miao-Ping
  • Journal of the American Chemical Society, Vol. 136, Issue 4
  • DOI: 10.1021/ja408513m

Perovskite-based photodetectors: materials and devices
journal, January 2017

  • Wang, Huan; Kim, Dong Ha
  • Chemical Society Reviews, Vol. 46, Issue 17
  • DOI: 10.1039/C6CS00896H

Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009

  • Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
  • Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
  • DOI: 10.1021/ja809598r

Direct measurement of the exciton binding energy and effective masses for charge carriers in organic–inorganic tri-halide perovskites
journal, June 2015

  • Miyata, Atsuhiko; Mitioglu, Anatolie; Plochocka, Paulina
  • Nature Physics, Vol. 11, Issue 7
  • DOI: 10.1038/nphys3357

Organic–Inorganic Hybrid Perovskite Nanowire Laser Arrays
journal, May 2017


Origin and temperature dependence of radiation damage in biological samples at cryogenic temperatures
journal, December 2009

  • Meents, A.; Gutmann, S.; Wagner, A.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 3
  • DOI: 10.1073/pnas.0905481107

Atomically thin two-dimensional organic-inorganic hybrid perovskites
journal, September 2015


Metal halide perovskite nanostructures for optoelectronic applications and the study of physical properties
journal, February 2019


Lasing in robust cesium lead halide perovskite nanowires
journal, February 2016

  • Eaton, Samuel W.; Lai, Minliang; Gibson, Natalie A.
  • Proceedings of the National Academy of Sciences, Vol. 113, Issue 8
  • DOI: 10.1073/pnas.1600789113

Crystal Growth of the Perovskite Semiconductor CsPbBr 3 : A New Material for High-Energy Radiation Detection
journal, June 2013

  • Stoumpos, Constantinos C.; Malliakas, Christos D.; Peters, John A.
  • Crystal Growth & Design, Vol. 13, Issue 7
  • DOI: 10.1021/cg400645t

Structural Study on Cubic–Tetragonal Transition of CH 3 NH 3 PbI 3
journal, July 2002

  • Kawamura, Yukihiko; Mashiyama, Hiroyuki; Hasebe, Katsuhiko
  • Journal of the Physical Society of Japan, Vol. 71, Issue 7
  • DOI: 10.1143/JPSJ.71.1694

Present status and future prospects of perovskite photovoltaics
journal, April 2018


Shape Evolution and Single Particle Luminescence of Organometal Halide Perovskite Nanocrystals
journal, February 2015


Determination of 60° polarization nanodomains in a relaxor-based ferroelectric single crystal
journal, October 2015

  • Kim, Kyou-Hyun; Payne, David A.; Zuo, Jian-Min
  • Applied Physics Letters, Vol. 107, Issue 16
  • DOI: 10.1063/1.4932955

A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014

  • Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
  • Angewandte Chemie International Edition, Vol. 53, Issue 42
  • DOI: 10.1002/anie.201406466

Unique characteristics of 2D Ruddlesden–Popper (2DRP) perovskite for future photovoltaic application
journal, January 2019

  • Zheng, Yiting; Niu, Tingting; Ran, Xueqin
  • Journal of Materials Chemistry A, Vol. 7, Issue 23
  • DOI: 10.1039/C9TA03217G

Light-Induced Self-Assembly of Cubic CsPbBr 3 Perovskite Nanocrystals into Nanowires
journal, December 2018


Electron ptychographic microscopy for three-dimensional imaging
journal, July 2017


A Phase Transition in Cæsium Plumbochloride
journal, November 1957


Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015


Fully Inorganic Ruddlesden–Popper Double Cl–I and Triple Cl–Br–I Lead Halide Perovskite Nanocrystals
journal, June 2018


Investigating materials formation with liquid-phase and cryogenic TEM
journal, June 2016


Passivated Single-Crystalline CH 3 NH 3 PbI 3 Nanowire Photodetector with High Detectivity and Polarization Sensitivity
journal, November 2016


Uniaxial Expansion of the 2D Ruddlesden–Popper Perovskite Family for Improved Environmental Stability
journal, March 2019

  • Spanopoulos, Ioannis; Hadar, Ido; Ke, Weijun
  • Journal of the American Chemical Society, Vol. 141, Issue 13
  • DOI: 10.1021/jacs.9b01327

Radiolysis to knock-on damage transition in zeolites under electron beam irradiation
journal, March 2011


Perovskite Materials for Light-Emitting Diodes and Lasers
journal, May 2016

  • Veldhuis, Sjoerd A.; Boix, Pablo P.; Yantara, Natalia
  • Advanced Materials, Vol. 28, Issue 32
  • DOI: 10.1002/adma.201600669

Growth and characterization of all-inorganic lead halide perovskite semiconductor CsPbBr 3 single crystals
journal, January 2017

  • Zhang, Mingzhi; Zheng, Zhiping; Fu, Qiuyun
  • CrystEngComm, Vol. 19, Issue 45
  • DOI: 10.1039/C7CE01709J

The study of nanostructured liquids by cryogenic-temperature electron microscopy — A status report
journal, October 2015


Textured CH3NH3PbI3 thin film with enhanced stability for high performance perovskite solar cells
journal, March 2017


Benefit of Grain Boundaries in Organic–Inorganic Halide Planar Perovskite Solar Cells
journal, February 2015

  • Yun, Jae S.; Ho-Baillie, Anita; Huang, Shujuan
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 5
  • DOI: 10.1021/acs.jpclett.5b00182

Crystal Structure of Individual CsPbBr 3 Perovskite Nanocubes
journal, December 2018


Low-Temperature Electron Beam-Induced Transformations of Cesium Lead Halide Perovskite Nanocrystals
journal, September 2017


Growth and Anion Exchange Conversion of CH 3 NH 3 PbX 3 Nanorod Arrays for Light-Emitting Diodes
journal, July 2015


CryoTEM as an Advanced Analytical Tool for Materials Chemists
journal, June 2017


Extended carrier lifetimes and diffusion in hybrid perovskites revealed by Hall effect and photoconductivity measurements
journal, August 2016


Atomic-resolution chemical mapping using energy-dispersive x-ray spectroscopy
journal, March 2010


A Review on Organic-Inorganic Halide Perovskite Photodetectors: Device Engineering and Fundamental Physics
journal, September 2017


Guanidinium: A Route to Enhanced Carrier Lifetime and Open-Circuit Voltage in Hybrid Perovskite Solar Cells
journal, January 2016


Properties and potential optoelectronic applications of lead halide perovskite nanocrystals
journal, November 2017

  • Kovalenko, Maksym V.; Protesescu, Loredana; Bodnarchuk, Maryna I.
  • Science, Vol. 358, Issue 6364
  • DOI: 10.1126/science.aam7093

Pb clustering and PbI2 nanofragmentation during methylammonium lead iodide perovskite degradation
journal, May 2019

  • Alberti, Alessandra; Bongiorno, Corrado; Smecca, Emanuele
  • Nature Communications, Vol. 10, Issue 1
  • DOI: 10.1038/s41467-019-09909-0

Organometal Halide Perovskites: Bulk Low-Dimension Materials and Nanoparticles
journal, February 2015

  • González-Carrero, Soranyel; Galian, Raquel E.; Pérez-Prieto, Julia
  • Particle & Particle Systems Characterization, Vol. 32, Issue 7
  • DOI: 10.1002/ppsc.201400214

Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013

  • Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong
  • Nature Photonics, Vol. 7, Issue 6, p. 486-491
  • DOI: 10.1038/nphoton.2013.80

Electron Ptychographic Diffractive Imaging of Boron Atoms in LaB6 Crystals
journal, June 2017


Determination of the structural phase and octahedral rotation angle in halide perovskites
journal, February 2018

  • dos Reis, Roberto; Yang, Hao; Ophus, Colin
  • Applied Physics Letters, Vol. 112, Issue 7
  • DOI: 10.1063/1.5017537

Impact of microstructure on local carrier lifetime in perovskite solar cells
journal, April 2015


Optical Properties of Photovoltaic Organic–Inorganic Lead Halide Perovskites
journal, November 2015

  • Green, Martin A.; Jiang, Yajie; Soufiani, Arman Mahboubi
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 23
  • DOI: 10.1021/acs.jpclett.5b01865

Perovskite–fullerene hybrid materials suppress hysteresis in planar diodes
journal, May 2015

  • Xu, Jixian; Buin, Andrei; Ip, Alexander H.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8081

Stability of zeolites under electron irradiation and imaging of heavy cations in silicates
journal, January 1981

  • Bursill, L. A.; Thomas, J. M.; Rao, K. J.
  • Nature, Vol. 289, Issue 5794
  • DOI: 10.1038/289157a0

Elucidating the charge carrier separation and working mechanism of CH3NH3PbI3−xClx perovskite solar cells
journal, March 2014

  • Edri, Eran; Kirmayer, Saar; Mukhopadhyay, Sabyasachi
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4461

Improving cyclability of Li metal batteries at elevated temperatures and its origin revealed by cryo-electron microscopy
journal, July 2019


Control of radiation damage in the TEM
journal, April 2013


Unravelling Degradation Mechanisms and Atomic Structure of Organic-Inorganic Halide Perovskites by Cryo-EM
journal, November 2019


Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013

  • Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
  • Nature, Vol. 501, Issue 7467, p. 395-398
  • DOI: 10.1038/nature12509

Cryo-electron microscopy for structural analysis of dynamic biological macromolecules
journal, February 2018

  • Murata, Kazuyoshi; Wolf, Matthias
  • Biochimica et Biophysica Acta (BBA) - General Subjects, Vol. 1862, Issue 2
  • DOI: 10.1016/j.bbagen.2017.07.020

Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012


Optimal accelerating voltage for HRTEM imaging of zeolite
journal, December 2012


Nonstoichiometry and the Electrical Activity of Grain Boundaries in SrTiO 3
journal, April 2001


Mechanisms of Electron-Beam-Induced Damage in Perovskite Thin Films Revealed by Cathodoluminescence Spectroscopy
journal, November 2015

  • Xiao, Chuanxiao; Li, Zhen; Guthrey, Harvey
  • The Journal of Physical Chemistry C, Vol. 119, Issue 48
  • DOI: 10.1021/acs.jpcc.5b09698

Cryo Focused Ion Beam Applications in High Resolution Electron Microscopy Studies of Beam Sensitive Crystals
journal, August 2019


Electron-beam irradiation-hard metal-halide perovskite nanocrystals
journal, January 2019

  • Liu, Wenna; Zheng, Jinju; Shang, Minghui
  • Journal of Materials Chemistry A, Vol. 7, Issue 18
  • DOI: 10.1039/C9TA01898K

Highly Emissive Divalent-Ion-Doped Colloidal CsPb 1– x M x Br 3 Perovskite Nanocrystals through Cation Exchange
journal, March 2017

  • van der Stam, Ward; Geuchies, Jaco J.; Altantzis, Thomas
  • Journal of the American Chemical Society, Vol. 139, Issue 11
  • DOI: 10.1021/jacs.6b13079

Recording and Using 4D-STEM Datasets in Materials Science
journal, August 2014

  • Ophus, Colin; Ercius, Peter; Sarahan, Michael
  • Microscopy and Microanalysis, Vol. 20, Issue S3
  • DOI: 10.1017/S1431927614002037

Atomic structure of sensitive battery materials and interfaces revealed by cryo–electron microscopy
journal, October 2017


Nanocrystals of Cesium Lead Halide Perovskites (CsPbX 3 , X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut
journal, February 2015

  • Protesescu, Loredana; Yakunin, Sergii; Bodnarchuk, Maryna I.
  • Nano Letters, Vol. 15, Issue 6
  • DOI: 10.1021/nl5048779

Atomic Structure and Electrical Activity of Grain Boundaries and Ruddlesden-Popper Faults in Cesium Lead Bromide Perovskite
journal, December 2018

  • Thind, Arashdeep Singh; Luo, Guangfu; Hachtel, Jordan A.
  • Advanced Materials, Vol. 31, Issue 4
  • DOI: 10.1002/adma.201805047

CH 3 NH 3 PbI 3 : precise structural consequences of water absorption at ambient conditions
journal, September 2016

  • Arakcheeva, Alla; Chernyshov, Dmitry; Spina, Massimo
  • Acta Crystallographica Section B Structural Science, Crystal Engineering and Materials, Vol. 72, Issue 5
  • DOI: 10.1107/S2052520616010428

Intrinsic Instability of the Hybrid Halide Perovskite Semiconductor CH 3 NH 3 PbI 3 *
journal, March 2018


Atomic-resolution transmission electron microscopy of electron beam–sensitive crystalline materials
journal, January 2018


Atomic Resolution Imaging of Halide Perovskites
journal, November 2016