Direct Observation of Infrared Plasmonic Fano Antiresonances by a Nanoscale Electron Probe

Smith, Kevin C; Olafsson, Agust; Hu, Xuan; Quillin, Steven C; Idrobo, Juan Carlos; Collette, Robyn; Rack, Philip D; Camden, Jon P; Masiello, David J

doi:10.1103/PhysRevLett.123.177401

Title: Direct Observation of Infrared Plasmonic Fano Antiresonances by a Nanoscale Electron Probe

Journal Article · 21 October 2019 · Physical Review Letters

DOI: https://doi.org/10.1103/PhysRevLett.123.177401 · OSTI ID:1597420

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Univ. of Washington, Seattle, WA (United States); Dept. of Physics; University of Washington
Univ. of Notre Dame, IN (United States). Dept. of Chemistry and Biochemistry
Univ. of Washington, Seattle, WA (United States). Dept. of Chemistry
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS)
Univ. of Tennessee, Knoxville, TN (United States) Dept. of Materials Science and Engineering
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science (CNMS) Dept. of Materials Science and Engineering
Univ. of Notre Dame, IN (United States). Dept. of Chemistry and Biochemistry; Univ. of Tennessee, Knoxville, TN (United States) Dept of Materials Science and Engineering

In this report, we exploit recent breakthroughs in monochromated aberration-corrected scanning transmission electron microscopy (STEM) to resolve infrared plasmonic Fano antiresonances in individual nanofabricated disk-rod dimers. Using a combination of electron energy-loss spectroscopy and theoretical modeling, we investigate and characterize a subspace of the weak coupling regime between quasi-discrete and quasi-continuum localized surface plasmon resonances where infrared plasmonic Fano antiresonances appear. Our research illustrates the capability of STEM instrumentation to experimentally observe nanoscale plasmonic responses that were previously the domain only of higher-resolution infrared spectroscopies.

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Research Organization:: Univ. of Washington, Seattle, WA (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Laboratory Directed Research and Development (LDRD) Program

Grant/Contract Number:: SC0018040; AC05-00OR22725; SC0018169

OSTI ID:: 1597420

Journal Information:: Physical Review Letters, Journal Name: Physical Review Letters Journal Issue: 17 Vol. 123; ISSN 0031-9007

Publisher:: American Physical Society (APS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Direct Observation of Infrared Plasmonic Fano Antiresonances by a Nanoscale Electron Probe

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