A Water-Miscible Quinone Flow Battery with High Volumetric Capacity and Energy Density

Jin, Shijian; Jing, Yan; Kwabi, David G.; Ji, Yunlong; Tong, Liuchuan; De Porcellinis, Diana; Goulet, Marc-Antoni; Pollack, Daniel A.; Gordon, Roy G.; Aziz, Michael J.

doi:10.1021/acsenergylett.9b00739

Title: A Water-Miscible Quinone Flow Battery with High Volumetric Capacity and Energy Density

Abstract

A water-miscible anthraquinone with polyethylene glycol (PEG)-based solubilizing groups is introduced as the redox-active molecule in a negative electrolyte (negolyte) for aqueous redox flow batteries, exhibiting the highest volumetric capacity among aqueous organic negolytes. We synthesized and screened a series of PEG-substituted anthraquinones (PEGAQs) and carefully studied one of its isomers, namely, 1,8-bis(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)anthracene-9,10-dione (AQ-1,8-3E-OH), which has high electrochemical reversibility and is completely miscible in water of any pH. Here, a negolyte containing 1.5 M AQ-1,8-3E-OH, when paired with a ferrocyanide-based positive electrolyte across an inexpensive, nonfluorinated permselective polymer membrane at pH 7, exhibits an open-circuit potential of 1.0 V, a volumetric capacity of 80.4 Ah/L, and an energy density of 25.2 Wh/L.

Authors:

Jin, Shijian ^[1];

^[1]; Kwabi, David G. ^[2]; Ji, Yunlong ^[1];

^[1]; De Porcellinis, Diana ^[1]; Goulet, Marc-Antoni ^[1];

^[1];

^[1]

Harvard Univ., Cambridge, MA (United States)
Harvard Univ., Cambridge, MA (United States); Univ. of Michigan, Ann Arbor, MI (United States)

Publication Date:: Wed May 22 00:00:00 EDT 2019

Research Org.:: Harvard Univ., Cambridge, MA (United States)

Sponsoring Org.:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

OSTI Identifier:: 1597276

Grant/Contract Number:: AR0000767; AC05-76RL01830; DGE1144152; DGE1745303; 428977

Resource Type:: Accepted Manuscript

Journal Name:: ACS Energy Letters

Additional Journal Information:: Journal Volume: 4; Journal Issue: 6; Journal ID: ISSN 2380-8195

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; Potassium; Electrical properties; Energy density; Batteries; Electrolytes

Citation Formats


                    Jin, Shijian, Jing, Yan, Kwabi, David G., Ji, Yunlong, Tong, Liuchuan, De Porcellinis, Diana, Goulet, Marc-Antoni, Pollack, Daniel A., Gordon, Roy G., and Aziz, Michael J. A Water-Miscible Quinone Flow Battery with High Volumetric Capacity and Energy Density.  United States: N. p., 2019. 
Web.  doi:10.1021/acsenergylett.9b00739.

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                    Jin, Shijian, Jing, Yan, Kwabi, David G., Ji, Yunlong, Tong, Liuchuan, De Porcellinis, Diana, Goulet, Marc-Antoni, Pollack, Daniel A., Gordon, Roy G., & Aziz, Michael J. A Water-Miscible Quinone Flow Battery with High Volumetric Capacity and Energy Density.  United States.  https://doi.org/10.1021/acsenergylett.9b00739

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                    Jin, Shijian, Jing, Yan, Kwabi, David G., Ji, Yunlong, Tong, Liuchuan, De Porcellinis, Diana, Goulet, Marc-Antoni, Pollack, Daniel A., Gordon, Roy G., and Aziz, Michael J. Wed .  
"A Water-Miscible Quinone Flow Battery with High Volumetric Capacity and Energy Density".  United States.  https://doi.org/10.1021/acsenergylett.9b00739.  https://www.osti.gov/servlets/purl/1597276.

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@article{osti_1597276,

  title        = {A Water-Miscible Quinone Flow Battery with High Volumetric Capacity and Energy Density},

  author       = {Jin, Shijian and Jing, Yan and Kwabi, David G. and Ji, Yunlong and Tong, Liuchuan and De Porcellinis, Diana and Goulet, Marc-Antoni and Pollack, Daniel A. and Gordon, Roy G. and Aziz, Michael J.},

  abstractNote = {A water-miscible anthraquinone with polyethylene glycol (PEG)-based solubilizing groups is introduced as the redox-active molecule in a negative electrolyte (negolyte) for aqueous redox flow batteries, exhibiting the highest volumetric capacity among aqueous organic negolytes. We synthesized and screened a series of PEG-substituted anthraquinones (PEGAQs) and carefully studied one of its isomers, namely, 1,8-bis(2-(2-(2-hydroxyethoxy)ethoxy)ethoxy)anthracene-9,10-dione (AQ-1,8-3E-OH), which has high electrochemical reversibility and is completely miscible in water of any pH. Here, a negolyte containing 1.5 M AQ-1,8-3E-OH, when paired with a ferrocyanide-based positive electrolyte across an inexpensive, nonfluorinated permselective polymer membrane at pH 7, exhibits an open-circuit potential of 1.0 V, a volumetric capacity of 80.4 Ah/L, and an energy density of 25.2 Wh/L.},

  doi          = {10.1021/acsenergylett.9b00739},

  journal      = {ACS Energy Letters},

  number       = 6,

  volume       = 4,

  place        = {United States},

  year         = {Wed May 22 00:00:00 EDT 2019},

  month        = {Wed May 22 00:00:00 EDT 2019}

}

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Abstract

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An Aqueous Redox-Flow Battery with High Capacity and Power: The TEMPTMA/MV System
journal, October 2016

High-Performance Alkaline Organic Redox Flow Batteries Based on 2-Hydroxy-3-carboxy-1,4-naphthoquinone
journal, September 2018

Alkaline quinone flow battery
journal, September 2015

A redox-flow battery with an alloxazine-based organic electrolyte
journal, July 2016

Metal acetylacetonate complexes for high energy density non-aqueous redox flow batteries
journal, January 2015

Multi-redox Molecule for High-Energy Redox Flow Batteries
journal, September 2018

Two electron utilization of methyl viologen anolyte in nonaqueous organic redox flow battery
journal, September 2018

An Inexpensive Aqueous Flow Battery for Large-Scale Electrical Energy Storage Based on Water-Soluble Organic Redox Couples
journal, January 2014

A High-Current, Stable Nonaqueous Organic Redox Flow Battery
journal, September 2016

Long-Cycling Aqueous Organic Redox Flow Battery (AORFB) toward Sustainable and Safe Energy Storage
journal, January 2017

Radical Compatibility with Nonaqueous Electrolytes and Its Impact on an All-Organic Redox Flow Battery
journal, April 2015

Cycling of a Quinone-Bromide Flow Battery for Large-Scale Electrochemical Energy Storage
journal, September 2014

Redox flow cells for energy conversion
journal, September 2006

New strapped porphyrins as hosts for fullerenes: synthesis and complexation study
journal, January 2012

Voltammetry of Quinones in Unbuffered Aqueous Solution: Reassessing the Roles of Proton Transfer and Hydrogen Bonding in the Aqueous Electrochemistry of Quinones
journal, October 2007

Constitutive modeling of the rate, temperature, and hydration dependent deformation response of Nafion to monotonic and cyclic loading
journal, September 2010

Dissection of the Voltage Losses of an Acidic Quinone Redox Flow Battery
journal, January 2017

Quantifying Mass Transfer Rates in Redox Flow Batteries
journal, January 2017

The Critical Role of Supporting Electrolyte Selection on Flow Battery Cost
journal, January 2017

The Effect of Interdigitated Channel and Land Dimensions on Flow Cell Performance
journal, January 2018

Micromechanics of actuation of ionic polymer-metal composites
journal, September 2002

A pH‐Neutral, Metal‐Free Aqueous Organic Redox Flow Battery Employing an Ammonium Anthraquinone Anolyte
journal, November 2019

Electrochemical Evaluation of a Napthalene Diimide Derivative for Potential Application in Aqueous Organic Redox Flow Batteries
journal, August 2019

A pH‐Neutral, Metal‐Free Aqueous Organic Redox Flow Battery Employing an Ammonium Anthraquinone Anolyte
journal, September 2019