Oxidation states in perovskite layers formed using various deposition techniques
Abstract
Organic–inorganic halide perovskites have quickly become emerging materials for photovoltaic applications, but a major factor causing instability in perovskite solar cells could be the elemental shift due to oxygen. The present work demonstrates the oxidation states of perovskite layers formed by (i) one-step deposition, (ii) solvent-to-solvent extraction, (iii) hot casting, and (iv) mixed-cation solution processing. X-ray photoelectron spectroscopy is used to explore the compositional changes due to oxygen, and the spectra confirm the diffusion of oxygen in the perovskite layer. Mixed-cation perovskites show the most promising results among the four deposition techniques. The best photovoltaic performance is achieved by an SnO2-based mixed-cation perovskite solar cell with a power conversion efficiency of 18.75%. A power conversion efficiency of 16.74% is obtained by a TiO2-based mixed-cation perovskite solar cell when the optimum thickness of the TiO2 blocking layer is 60–65 nm.
- Authors:
-
[1];
[1];
[3];
- Univ. of Texas at El Paso, TX (United States)
- Univ. of Oxford (United Kingdom)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1597257
- Report Number(s):
- BNL-213600-2020-JAAM
Journal ID: ISSN 1941-7012
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Renewable and Sustainable Energy
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 5; Journal ID: ISSN 1941-7012
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Shahriar, Shaimum, Castaneda, Vanessa, Martinez, Manuel, Mishra, Aditya Kumar, Akter, Tahmina, Schutt, Kelly, Boscoboinik, J. Anibal, and Hodges, Deidra. Oxidation states in perovskite layers formed using various deposition techniques. United States: N. p., 2019.
Web. doi:10.1063/1.5108656.
Shahriar, Shaimum, Castaneda, Vanessa, Martinez, Manuel, Mishra, Aditya Kumar, Akter, Tahmina, Schutt, Kelly, Boscoboinik, J. Anibal, & Hodges, Deidra. Oxidation states in perovskite layers formed using various deposition techniques. United States. doi:10.1063/1.5108656.
Shahriar, Shaimum, Castaneda, Vanessa, Martinez, Manuel, Mishra, Aditya Kumar, Akter, Tahmina, Schutt, Kelly, Boscoboinik, J. Anibal, and Hodges, Deidra. Mon .
"Oxidation states in perovskite layers formed using various deposition techniques". United States. doi:10.1063/1.5108656. https://www.osti.gov/servlets/purl/1597257.
@article{osti_1597257,
title = {Oxidation states in perovskite layers formed using various deposition techniques},
author = {Shahriar, Shaimum and Castaneda, Vanessa and Martinez, Manuel and Mishra, Aditya Kumar and Akter, Tahmina and Schutt, Kelly and Boscoboinik, J. Anibal and Hodges, Deidra},
abstractNote = {Organic–inorganic halide perovskites have quickly become emerging materials for photovoltaic applications, but a major factor causing instability in perovskite solar cells could be the elemental shift due to oxygen. The present work demonstrates the oxidation states of perovskite layers formed by (i) one-step deposition, (ii) solvent-to-solvent extraction, (iii) hot casting, and (iv) mixed-cation solution processing. X-ray photoelectron spectroscopy is used to explore the compositional changes due to oxygen, and the spectra confirm the diffusion of oxygen in the perovskite layer. Mixed-cation perovskites show the most promising results among the four deposition techniques. The best photovoltaic performance is achieved by an SnO2-based mixed-cation perovskite solar cell with a power conversion efficiency of 18.75%. A power conversion efficiency of 16.74% is obtained by a TiO2-based mixed-cation perovskite solar cell when the optimum thickness of the TiO2 blocking layer is 60–65 nm.},
doi = {10.1063/1.5108656},
journal = {Journal of Renewable and Sustainable Energy},
number = 5,
volume = 11,
place = {United States},
year = {2019},
month = {10}
}
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Works referenced in this record:
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
journal, May 2009
- Kojima, Akihiro; Teshima, Kenjiro; Shirai, Yasuo
- Journal of the American Chemical Society, Vol. 131, Issue 17, p. 6050-6051
6.5% efficient perovskite quantum-dot-sensitized solar cell
journal, January 2011
- Im, Jeong-Hyeok; Lee, Chang-Ryul; Lee, Jin-Wook
- Nanoscale, Vol. 3, Issue 10, p. 4088-4093
Lead Iodide Perovskite Sensitized All-Solid-State Submicron Thin Film Mesoscopic Solar Cell with Efficiency Exceeding 9%
journal, August 2012
- Kim, Hui-Seon; Lee, Chang-Ryul; Im, Jeong-Hyeok
- Scientific Reports, Vol. 2, Issue 1
Efficient Hybrid Solar Cells Based on Meso-Superstructured Organometal Halide Perovskites
journal, October 2012
- Lee, M. M.; Teuscher, J.; Miyasaka, T.
- Science, Vol. 338, Issue 6107, p. 643-647
Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013
- Xing, G.; Mathews, N.; Sun, S.
- Science, Vol. 342, Issue 6156, p. 344-347
Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013
- Stranks, S. D.; Eperon, G. E.; Grancini, G.
- Science, Vol. 342, Issue 6156, p. 341-344
CH 3 NH 3 PbI 3 Perovskite/Fullerene Planar-Heterojunction Hybrid Solar Cells
journal, June 2013
- Jeng, Jun-Yuan; Chiang, Yi-Fang; Lee, Mu-Huan
- Advanced Materials, Vol. 25, Issue 27
Morphological Control for High Performance, Solution-Processed Planar Heterojunction Perovskite Solar Cells
journal, September 2013
- Eperon, Giles E.; Burlakov, Victor M.; Docampo, Pablo
- Advanced Functional Materials, Vol. 24, Issue 1, p. 151-157
Efficient planar heterojunction perovskite solar cells by vapour deposition
journal, September 2013
- Liu, Mingzhen; Johnston, Michael B.; Snaith, Henry J.
- Nature, Vol. 501, Issue 7467, p. 395-398
Interface engineering of highly efficient perovskite solar cells
journal, July 2014
- Zhou, H.; Chen, Q.; Li, G.
- Science, Vol. 345, Issue 6196
Highly efficient and stable planar perovskite solar cells by solution-processed tin oxide
journal, January 2016
- Anaraki, Elham Halvani; Kermanpur, Ahmad; Steier, Ludmilla
- Energy & Environmental Science, Vol. 9, Issue 10
Sub-150 °C processed meso-superstructured perovskite solar cells with enhanced efficiency
journal, January 2014
- Wojciechowski, Konrad; Saliba, Michael; Leijtens, Tomas
- Energy Environ. Sci., Vol. 7, Issue 3
Room-temperature crystallization of hybrid-perovskite thin films via solvent–solvent extraction for high-performance solar cells
journal, January 2015
- Zhou, Yuanyuan; Yang, Mengjin; Wu, Wenwen
- Journal of Materials Chemistry A, Vol. 3, Issue 15
High-efficiency solution-processed perovskite solar cells with millimeter-scale grains
journal, January 2015
- Nie, W.; Tsai, H.; Asadpour, R.
- Science, Vol. 347, Issue 6221, p. 522-525
Stabilized Wide Bandgap Perovskite Solar Cells by Tin Substitution
journal, November 2016
- Yang, Zhibin; Rajagopal, Adharsh; Jo, Sae Byeok
- Nano Letters, Vol. 16, Issue 12
Compositional engineering of perovskite materials for high-performance solar cells
journal, January 2015
- Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok
- Nature, Vol. 517, Issue 7535
Chemical Management for Colorful, Efficient, and Stable Inorganic–Organic Hybrid Nanostructured Solar Cells
journal, March 2013
- Noh, Jun Hong; Im, Sang Hyuk; Heo, Jin Hyuck
- Nano Letters, Vol. 13, Issue 4, p. 1764-1769
Morphology-photovoltaic property correlation in perovskite solar cells: One-step versus two-step deposition of CH 3 NH 3 PbI 3
journal, August 2014
- Im, Jeong-Hyeok; Kim, Hui-Seon; Park, Nam-Gyu
- APL Materials, Vol. 2, Issue 8
Efficient and Stable Perovskite Solar Cells Using Molybdenum Tris(dithiolene)s as p-Dopants for Spiro-OMeTAD
journal, August 2017
- Pellaroque, Alba; Noel, Nakita K.; Habisreutinger, Severin N.
- ACS Energy Letters, Vol. 2, Issue 9
XPS study of polymer/organometallic interaction: Trimethyl aluminum on polyvinyl alcohol polymer
journal, January 1989
- Akhter, S.; Zhou, X. -L.; White, J. M.
- Applied Surface Science, Vol. 37, Issue 2
The interaction of trimethyl amine with a polyvinyl alcohol surface
journal, February 1989
- Rogers, J. W.; Kelber, J. A.; Henderson, M. A.
- Applied Surface Science, Vol. 35, Issue 4
XPS study on the dispersion of carbon additives in silicon carbide powders
journal, September 1991
- Contarini, S.; Howlett, S. P.; Rizzo, C.
- Applied Surface Science, Vol. 51, Issue 3-4
Preparation and characterization of amorphous SiC:H thin films
journal, May 1991
- Delplancke, M. P.; Powers, J. M.; Vandentop, G. J.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 9, Issue 3
XPS surface studies of injection-molded poly(phenylene ether)/nylon 6,6 and poly(phenylene ether)/HIPS blends
journal, December 1992
- Bhatia, Qamar S.; Burrell, Michael C.; Chera, J. J.
- Journal of Applied Polymer Science, Vol. 46, Issue 11
An XPS study of ion-induced compositional changes with group II and group IV compounds
journal, April 1983
- Christie, A. B.; Lee, J.; Sutherland, I.
- Applications of Surface Science, Vol. 15, Issue 1-4
XPS core level spectra and Auger parameters for some silver compounds
journal, June 1991
- Kaushik, Vijay Kumar
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 56, Issue 3
X-ray photoelectron spectroscopy investigation of pumice-supported nickel catalysts
journal, April 1995
- Venezia, A. M.; Bertoncello, R.; Deganello, G.
- Surface and Interface Analysis, Vol. 23, Issue 4
The interaction of thin NiO layers with single crystalline α-Al2O3(112̄0) substrates
journal, May 1995
- Bolt, P. H.; ten Grotenhuis, E.; Geus, J. W.
- Surface Science, Vol. 329, Issue 3
Characterization of coprecipitated nickel on silica methanation catalysts by X-ray photoelectron spectroscopy
journal, March 1979
- Shalvoy, R.
- Journal of Catalysis, Vol. 56, Issue 3
XPS O 1s binding energies for polymers containing hydroxyl, ether, ketone and ester groups
journal, May 1991
- López, Gabriel P.; Castner, David G.; Ratner, Buddy D.
- Surface and Interface Analysis, Vol. 17, Issue 5
N(ls) photoelectron spectra of transition metal biguanide complexes
journal, January 1974
- Swartz, W. E.; Alfonso, R. A.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 4, Issue 4
The Auger spectrum of solid ammonia
journal, January 1979
- Larkins, F. P.; Lubenfeld, A.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 15, Issue 1
X-ray photoelectron spectroscopic studies of some iodine compounds
journal, January 1976
- Sherwood, Peter M. A.
- Journal of the Chemical Society, Faraday Transactions 2, Vol. 72
Hysteresis-less inverted CH 3 NH 3 PbI 3 planar perovskite hybrid solar cells with 18.1% power conversion efficiency
journal, January 2015
- Heo, Jin Hyuck; Han, Hye Ji; Kim, Dasom
- Energy & Environmental Science, Vol. 8, Issue 5
Stable semi-transparent CH 3 NH 3 PbI 3 planar sandwich solar cells
journal, January 2015
- Heo, Jin Hyuck; Han, Hye Ji; Lee, Minho
- Energy & Environmental Science, Vol. 8, Issue 10
Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques
journal, December 2013
- Liu, Dianyi; Kelly, Timothy L.
- Nature Photonics, Vol. 8, Issue 2, p. 133-138
Low-Temperature Solution-Processed Tin Oxide as an Alternative Electron Transporting Layer for Efficient Perovskite Solar Cells
journal, May 2015
- Ke, Weijun; Fang, Guojia; Liu, Qin
- Journal of the American Chemical Society, Vol. 137, Issue 21
Non-approximated series resistance evaluation by considering high ideality factor in organic solar cell
journal, December 2018
- Rana, Aniket; Kumar, Amit; Rahman, Md. Wazedur
- AIP Advances, Vol. 8, Issue 12
A comparative study of o,p-dimethoxyphenyl-based hole transport materials by altering π-linker units for highly efficient and stable perovskite solar cells
journal, January 2017
- Li, Xing; Cai, Molang; Zhou, Zhongmin
- Journal of Materials Chemistry A, Vol. 5, Issue 21
Energetically favored formation of SnO2 nanocrystals as electron transfer layer in perovskite solar cells with high efficiency exceeding 19%
journal, October 2017
- Dong, Qingshun; Shi, Yantao; Zhang, Chunyang
- Nano Energy, Vol. 40
Systematically Optimized Bilayered Electron Transport Layer for Highly Efficient Planar Perovskite Solar Cells (η = 21.1%)
journal, October 2017
- Song, Seulki; Kang, Gyeongho; Pyeon, Limok
- ACS Energy Letters, Vol. 2, Issue 12
Tin oxide as a photoanode for dye-sensitised solar cells: Current progress and future challenges
journal, October 2015
- Wali, Qamar; Fakharuddin, Azhar; Jose, Rajan
- Journal of Power Sources, Vol. 293
Highly efficient planar perovskite solar cells through band alignment engineering
journal, January 2015
- Correa Baena, Juan Pablo; Steier, Ludmilla; Tress, Wolfgang
- Energy & Environmental Science, Vol. 8, Issue 10
Efficient and stable planar hole-transport-material-free perovskite solar cells using low temperature processed SnO2 as electron transport material
journal, February 2018
- Lin, Siyuan; Yang, Bingchu; Qiu, Xincan
- Organic Electronics, Vol. 53
A sintering-free, nanocrystalline tin oxide electron selective layer for organometal perovskite solar cells
journal, February 2017
- Zhao, Jinjin; Wei, Liyu; Liu, Jinxi
- Science China Materials, Vol. 60, Issue 3
Parameters Affecting I – V Hysteresis of CH 3 NH 3 PbI 3 Perovskite Solar Cells: Effects of Perovskite Crystal Size and Mesoporous TiO 2 Layer
journal, August 2014
- Kim, Hui-Seon; Park, Nam-Gyu
- The Journal of Physical Chemistry Letters, Vol. 5, Issue 17