skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on February 4, 2021

Title: Morphology and reactivity of size-selected titanium oxide nanoclusters on Au(111)

Authors:
 [1];  [1];  [1];  [2]; ORCiD logo [2]; ORCiD logo [3]
  1. Department of Chemistry, Stony Brook University, Stony Brook, New York 11794, USA
  2. Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton, New York 11973, USA
  3. Department of Chemistry, Stony Brook University, Stony Brook, New York 11794, USA, Chemistry Division, Brookhaven National Laboratory, Upton, New York 11973, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1597145
Grant/Contract Number:  
SC0012704; SC0012573
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Name: Journal of Chemical Physics Journal Volume: 152 Journal Issue: 5; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Goodman, Kenneth R., Wang, Jason, Ma, Yilin, Tong, Xiao, Stacchiola, Dario J., and White, Michael G. Morphology and reactivity of size-selected titanium oxide nanoclusters on Au(111). United States: N. p., 2020. Web. doi:10.1063/1.5134453.
Goodman, Kenneth R., Wang, Jason, Ma, Yilin, Tong, Xiao, Stacchiola, Dario J., & White, Michael G. Morphology and reactivity of size-selected titanium oxide nanoclusters on Au(111). United States. doi:10.1063/1.5134453.
Goodman, Kenneth R., Wang, Jason, Ma, Yilin, Tong, Xiao, Stacchiola, Dario J., and White, Michael G. Fri . "Morphology and reactivity of size-selected titanium oxide nanoclusters on Au(111)". United States. doi:10.1063/1.5134453.
@article{osti_1597145,
title = {Morphology and reactivity of size-selected titanium oxide nanoclusters on Au(111)},
author = {Goodman, Kenneth R. and Wang, Jason and Ma, Yilin and Tong, Xiao and Stacchiola, Dario J. and White, Michael G.},
abstractNote = {},
doi = {10.1063/1.5134453},
journal = {Journal of Chemical Physics},
number = 5,
volume = 152,
place = {United States},
year = {2020},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on February 4, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Identification of the Catalytic Site at the Interface Perimeter of Au Clusters on Rutile TiO 2 (110)
journal, April 2014

  • Vilhelmsen, Lasse B.; Hammer, Bjørk
  • ACS Catalysis, Vol. 4, Issue 6
  • DOI: 10.1021/cs500202f

CO Oxidation on Inverse CeO x /Cu(111) Catalysts: High Catalytic Activity and Ceria-Promoted Dissociation of O 2
journal, March 2011

  • Yang, Fan; Graciani, Jesús; Evans, Jaime
  • Journal of the American Chemical Society, Vol. 133, Issue 10
  • DOI: 10.1021/ja1087979

Inverse Oxide/Metal Catalysts in Fundamental Studies and Practical Applications: A Perspective of Recent Developments
journal, June 2016

  • Rodriguez, José A.; Liu, Ping; Graciani, Jesús
  • The Journal of Physical Chemistry Letters, Vol. 7, Issue 13
  • DOI: 10.1021/acs.jpclett.6b00499

2-Propanol dehydration on TiO2(110): The effect of bridge-bonded oxygen vacancy blocking
journal, January 2008


High Water−Gas Shift Activity in TiO 2 (110) Supported Cu and Au Nanoparticles: Role of the Oxide and Metal Particle Size
journal, April 2009

  • Rodríguez, José A.; Evans, Jaime; Graciani, Jesús
  • The Journal of Physical Chemistry C, Vol. 113, Issue 17
  • DOI: 10.1021/jp900483u

Inverse Catalysts for CO Oxidation: Enhanced Oxide–Metal Interactions in MgO/Au(111), CeO 2 /Au(111), and TiO 2 /Au(111)
journal, October 2017

  • Palomino, Robert M.; Gutiérrez, Ramón A.; Liu, Zongyuan
  • ACS Sustainable Chemistry & Engineering, Vol. 5, Issue 11
  • DOI: 10.1021/acssuschemeng.7b02744

Competitive Oxidation and Reduction of Aliphatic Alcohols over (WO 3 ) 3 Clusters
journal, May 2009

  • Kim, Yu Kwon; Dohnálek, Z.; Kay, Bruce D.
  • The Journal of Physical Chemistry C, Vol. 113, Issue 22
  • DOI: 10.1021/jp8109463

Activity of CeOx and TiOx Nanoparticles Grown on Au(111) in the Water-Gas Shift Reaction
journal, December 2007


Preparation of TiO 2 Nanocrystallites by Oxidation of Ti−Au(111) Surface Alloy
journal, June 2009

  • Potapenko, Denis V.; Osgood, Richard M.
  • Nano Letters, Vol. 9, Issue 6
  • DOI: 10.1021/nl900904s

Molecular Structures and Energetics of the (TiO 2 ) n ( n = 1−4) Clusters and Their Anions
journal, July 2008

  • Li, Shenggang; Dixon, David A.
  • The Journal of Physical Chemistry A, Vol. 112, Issue 29
  • DOI: 10.1021/jp800170q

Water-Gas Shift Reaction on a Highly Active Inverse CeO x /Cu(111) Catalyst: Unique Role of Ceria Nanoparticles
journal, October 2009

  • Rodriguez, José A.; Graciani, Jesús; Evans, Jaime
  • Angewandte Chemie International Edition, Vol. 48, Issue 43
  • DOI: 10.1002/anie.200903918

Controlling island size distributions: a comparison of nickel and copper growth on TiO2
journal, July 2003


Scanning tunneling microscopy studies of metal clusters supported on TiO2 (110): Morphology and electronic structure
journal, September 1998


Selective Oxidation of Propanol on Au(111): Mechanistic Insights into Aerobic Oxidation of Alcohols
journal, December 2008


Reversibility of strong metal-support interactions on Rh/TiO2
journal, July 1989


Electronic Interactions of Size-Selected Oxide Clusters on Metallic and Thin Film Oxide Supports
journal, September 2017

  • Xue, Meng; Nakayama, Miki; Liu, Ping
  • The Journal of Physical Chemistry C, Vol. 121, Issue 40
  • DOI: 10.1021/acs.jpcc.7b07889

Role of Defects in the Adsorption of Aliphatic Alcohols on the TiO 2 (110) Surface
journal, October 2002

  • Farfan-Arribas, Enrique; Madix, Robert J.
  • The Journal of Physical Chemistry B, Vol. 106, Issue 41
  • DOI: 10.1021/jp020729p

CO Oxidation at the Au/TiO 2 Boundary: The Role of the Au/Ti 5c Site
journal, February 2015

  • Duan, Zhiyao; Henkelman, Graeme
  • ACS Catalysis, Vol. 5, Issue 3
  • DOI: 10.1021/cs501610a

Formation of TiO 2 Nanoparticles by Reactive-Layer-Assisted Deposition and Characterization by XPS and STM
journal, July 2005

  • Song, Zhen; Hrbek, Jan; Osgood, Richard
  • Nano Letters, Vol. 5, Issue 7
  • DOI: 10.1021/nl0505703

Inverse oxide/metal catalysts: A versatile approach for activity tests and mechanistic studies
journal, February 2010


Adsorption and decomposition of aliphatic alcohols on titania
journal, May 1988

  • Kim, K. S.; Barteau, M. A.; Farneth, W. E.
  • Langmuir, Vol. 4, Issue 3
  • DOI: 10.1021/la00081a007

Spectroscopic Observation of Dual Catalytic Sites During Oxidation of CO on a Au/TiO2 Catalyst
journal, August 2011


Reactions on Inverse Model Catalyst Surfaces: Atomic Views by STM
journal, August 2005


Reactions of aliphatic alcohols on the {011}-facetted Ti02 (001) surface
journal, November 1990


Gas-phase oxidation of 2-propanol over Au/TiO 2 catalysts to probe metal-support interactions
journal, March 2013

  • Holz, Marie C.; Kähler, Kevin; Tölle, Katharina
  • physica status solidi (b), Vol. 250, Issue 6
  • DOI: 10.1002/pssb.201248504

The mechanism of emerging catalytic activity of gold nano-clusters on rutile TiO 2 (110) in CO oxidation reaction
journal, March 2012

  • Mitsuhara, K.; Tagami, M.; Matsuda, T.
  • The Journal of Chemical Physics, Vol. 136, Issue 12
  • DOI: 10.1063/1.3697478

Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions
journal, February 2015

  • Lunkenbein, Thomas; Schumann, Julia; Behrens, Malte
  • Angewandte Chemie International Edition, Vol. 54, Issue 15
  • DOI: 10.1002/anie.201411581

Ultrathin metal films on a metal oxide surface: Growth of Au on TiO 2 (110)
journal, October 1997


Gas phase vibrational spectroscopy of cold (TiO2)n− ( n = 3–8) clusters
journal, March 2016

  • Weichman, Marissa L.; Song, Xiaowei; Fagiani, Matias R.
  • The Journal of Chemical Physics, Vol. 144, Issue 12
  • DOI: 10.1063/1.4942194

Theoretical Study of the Electronic Structure and Stability of Titanium Dioxide Clusters (TiO 2 ) n with n = 1−9
journal, May 2006

  • Qu, Zheng-wang; Kroes, Geert-Jan
  • The Journal of Physical Chemistry B, Vol. 110, Issue 18
  • DOI: 10.1021/jp056607p

The use of the perimeter-area method to calculate the fractal dimension of aggregates
journal, February 2019


Catalytic Dehydration of 2-Propanol on (WO 3 ) 3 Clusters on TiO 2 (110)
journal, April 2008

  • Kim, Yu Kwon; Rousseau, Roger; Kay, Bruce D.
  • Journal of the American Chemical Society, Vol. 130, Issue 15
  • DOI: 10.1021/ja800730g

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996


Surface Chemistry of 2-Propanol on TiO 2 (110):  Low- and High-Temperature Dehydration, Isotope Effects, and Influence of Local Surface Structure
journal, July 2007

  • Bondarchuk, Oleksandr; Kim, Yu Kwon; White, J. M.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 29
  • DOI: 10.1021/jp072298m

Electronic perturbations
journal, July 2012


Electronic interactions and charge transfers of metal atoms and clusters on oxide surfaces
journal, January 2013

  • Pacchioni, Gianfranco
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 6
  • DOI: 10.1039/c2cp43731g

Some recent theoretical advances in the understanding of the catalytic activity of Au
journal, September 2005


Probing properties of the interfacial perimeter sites in TiOx/Au/SiO2 with 2-propanol decomposition
journal, November 2017


Synthesis of TiO2 nanoparticles on the Au(111) surface
journal, September 2005

  • Biener, Jürgen; Farfan-Arribas, Enrique; Biener, Monika
  • The Journal of Chemical Physics, Vol. 123, Issue 9
  • DOI: 10.1063/1.1999607

A New Type of Strong Metal–Support Interaction and the Production of H 2 through the Transformation of Water on Pt/CeO 2 (111) and Pt/CeO x /TiO 2 (110) Catalysts
journal, May 2012

  • Bruix, Albert; Rodriguez, José A.; Ramírez, Pedro J.
  • Journal of the American Chemical Society, Vol. 134, Issue 21
  • DOI: 10.1021/ja302070k

Interaction of nanostructured metal overlayers with oxide surfaces
journal, November 2007


Nucleation and growth of thin metal films on clean and modified metal substrates studied by scanning tunneling microscopy
journal, July 1992

  • Hwang, R. Q.; Günther, C.; Schröder, J.
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 10, Issue 4
  • DOI: 10.1116/1.578012

Elucidation of Active Sites for the Reaction of Ethanol on TiO 2 /Au(111)
journal, March 2017

  • Boyle, David T.; Wilke, Jeremy A.; Palomino, Robert M.
  • The Journal of Physical Chemistry C, Vol. 121, Issue 14
  • DOI: 10.1021/acs.jpcc.6b11764

Classical strong metal–support interactions between gold nanoparticles and titanium dioxide
journal, October 2017


Support nanostructure boosts oxygen transfer to catalytically active platinum nanoparticles
journal, March 2011

  • Vayssilov, Georgi N.; Lykhach, Yaroslava; Migani, Annapaola
  • Nature Materials, Vol. 10, Issue 4
  • DOI: 10.1038/nmat2976

Density Functional Theory Study of Active Oxygen at the Perimeter of Au/TiO 2 Catalysts
journal, November 2015

  • Koga, Hiroaki; Tada, Kohei; Okumura, Mitsutaka
  • The Journal of Physical Chemistry C, Vol. 119, Issue 46
  • DOI: 10.1021/acs.jpcc.5b07633

Metal supported oxide nanostructures: model systems for advanced catalysis
journal, September 2007


Choice of U for DFT+ U Calculations for Titanium Oxides
journal, March 2011

  • Hu, Zhenpeng; Metiu, Horia
  • The Journal of Physical Chemistry C, Vol. 115, Issue 13
  • DOI: 10.1021/jp111350u

Insights into Catalytic Oxidation at the Au/TiO 2 Dual Perimeter Sites
journal, December 2013

  • Green, Isabel X.; Tang, Wenjie; Neurock, Matthew
  • Accounts of Chemical Research, Vol. 47, Issue 3
  • DOI: 10.1021/ar400196f

Reactivity and sintering kinetics of Au/TiO2(110) model catalysts: particle size effects
journal, June 2007


2-Propanol reactivity on in situ prepared Au(1 1 1)-supported TiO 2 nanocrystals
journal, January 2013


Surface Dipoles and Electron Transfer at the Metal Oxide–Metal Interface: A 2PPE Study of Size-Selected Metal Oxide Clusters Supported on Cu(111)
journal, June 2014

  • Yang, Yixiong; Zhou, Jia; Nakayama, Miki
  • The Journal of Physical Chemistry C, Vol. 118, Issue 25
  • DOI: 10.1021/jp503646u

Water-gas shift activity of Cu surfaces and Cu nanoparticles supported on metal oxides
journal, May 2009


Influence of Cluster–Support Interactions on Reactivity of Size-Selected Nb x O y Clusters
journal, April 2015

  • Nakayama, Miki; Xue, Meng; An, Wei
  • The Journal of Physical Chemistry C, Vol. 119, Issue 26
  • DOI: 10.1021/acs.jpcc.5b00691

Strong metal–support interactions on rhodium model catalysts
journal, January 2011


Determination of the nature and reactivity of copper sites in Cu–TiO2 catalysts
journal, January 2000

  • Coloma, Fernando; Marquez, Francisco; Rochester, Colin H.
  • Physical Chemistry Chemical Physics, Vol. 2, Issue 22
  • DOI: 10.1039/b005331g

Controlling size distributions of copper islands grown on TiO2()-(1×2)
journal, March 2003


WSXM : A software for scanning probe microscopy and a tool for nanotechnology
journal, January 2007

  • Horcas, I.; Fernández, R.; Gómez-Rodríguez, J. M.
  • Review of Scientific Instruments, Vol. 78, Issue 1
  • DOI: 10.1063/1.2432410

Study of ethanol reactions on H 2 reduced Au/TiO 2 anatase and rutile: effect of metal loading on reaction selectivity
journal, January 2015

  • Nadeem, Muhammad A.; Majeed, Imran; Waterhouse, Geoffrey I. N.
  • Catalysis, Structure & Reactivity, Vol. 1, Issue 2
  • DOI: 10.1179/2055075814y.0000000008

Strong metal-support interactions
journal, November 1987