skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on February 4, 2021

Title: Strong-field control of H3+ production from methanol dications: Selecting between local and extended formation mechanisms

Authors:
 [1];  [1]; ORCiD logo [2];  [2];  [2];  [1]; ORCiD logo [2];  [1];  [1];  [1];  [2];  [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [2]; ORCiD logo [1]
  1. Department of Physics, Augustana University, Sioux Falls, South Dakota 57197, USA
  2. J.R. Macdonald Laboratory, Department of Physics, Kansas State University, Manhattan, Kansas 66506, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1597141
Grant/Contract Number:  
FG02-86ER13491
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Chemical Physics
Additional Journal Information:
Journal Name: Journal of Chemical Physics Journal Volume: 152 Journal Issue: 5; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Iwamoto, Naoki, Schwartz, Charles J., Jochim, Bethany, Raju P., Kanaka, Feizollah, Peyman, Napierala, J. L., Severt, T., Tegegn, S. N., Solomon, A., Zhao, S., Lam, Huynh, Wangjam, Tomthin Nganba, Kumarappan, V., Carnes, K. D., Ben-Itzhak, I., and Wells, E. Strong-field control of H3+ production from methanol dications: Selecting between local and extended formation mechanisms. United States: N. p., 2020. Web. doi:10.1063/1.5129946.
Iwamoto, Naoki, Schwartz, Charles J., Jochim, Bethany, Raju P., Kanaka, Feizollah, Peyman, Napierala, J. L., Severt, T., Tegegn, S. N., Solomon, A., Zhao, S., Lam, Huynh, Wangjam, Tomthin Nganba, Kumarappan, V., Carnes, K. D., Ben-Itzhak, I., & Wells, E. Strong-field control of H3+ production from methanol dications: Selecting between local and extended formation mechanisms. United States. doi:10.1063/1.5129946.
Iwamoto, Naoki, Schwartz, Charles J., Jochim, Bethany, Raju P., Kanaka, Feizollah, Peyman, Napierala, J. L., Severt, T., Tegegn, S. N., Solomon, A., Zhao, S., Lam, Huynh, Wangjam, Tomthin Nganba, Kumarappan, V., Carnes, K. D., Ben-Itzhak, I., and Wells, E. Fri . "Strong-field control of H3+ production from methanol dications: Selecting between local and extended formation mechanisms". United States. doi:10.1063/1.5129946.
@article{osti_1597141,
title = {Strong-field control of H3+ production from methanol dications: Selecting between local and extended formation mechanisms},
author = {Iwamoto, Naoki and Schwartz, Charles J. and Jochim, Bethany and Raju P., Kanaka and Feizollah, Peyman and Napierala, J. L. and Severt, T. and Tegegn, S. N. and Solomon, A. and Zhao, S. and Lam, Huynh and Wangjam, Tomthin Nganba and Kumarappan, V. and Carnes, K. D. and Ben-Itzhak, I. and Wells, E.},
abstractNote = {},
doi = {10.1063/1.5129946},
journal = {Journal of Chemical Physics},
number = 5,
volume = 152,
place = {United States},
year = {2020},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on February 4, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Coherent two-dimensional electronic mass spectrometry
journal, June 2018


Ultrafast optical pulse shaping: A tutorial review
journal, July 2011


Coherent pulse sequence induced control of selectivity of reactions: Exact quantum mechanical calculations
journal, November 1986

  • Tannor, David J.; Kosloff, Ronnie; Rice, Stuart A.
  • The Journal of Chemical Physics, Vol. 85, Issue 10
  • DOI: 10.1063/1.451542

Control of quantum phenomena: past, present and future
journal, July 2010


Formation of fragment ions (H+, H3+, CH3+) from ethane in intense femtosecond laser fields – from understanding to control
journal, January 2013

  • Schirmel, Nora; Reusch, Nicola; Horsch, Philipp
  • Faraday Discussions, Vol. 163
  • DOI: 10.1039/c3fd20152j

Time-resolved 3D imaging of ultrafast spin–orbit wave packet dynamics
journal, March 2019

  • Bayer, Tim; Gräfing, Daniela; Kerbstadt, Stefanie
  • New Journal of Physics, Vol. 21, Issue 3
  • DOI: 10.1088/1367-2630/aafb87

The Roaming Atom: Straying from the Reaction Path in Formaldehyde Decomposition
journal, November 2004


From Roaming Atoms to Hopping Surfaces: Mapping Out Global Reaction Routes in Photochemistry
journal, March 2015

  • Maeda, Satoshi; Taketsugu, Tetsuya; Ohno, Koichi
  • Journal of the American Chemical Society, Vol. 137, Issue 10
  • DOI: 10.1021/ja512394y

Selective Bond Dissociation and Rearrangement with Optimally Tailored, Strong-Field Laser Pulses
journal, March 2001

  • Levis, Robert J.; Menkir, Getahun M.; Rabitz, Herschel
  • Science, Vol. 292, Issue 5517, p. 709-713
  • DOI: 10.1126/science.1059133

Dynamic Stark Control of Photochemical Processes
journal, October 2006


Full vector-field control of ultrashort laser pulses utilizing a single dual-layer spatial light modulator in a common-path setup
journal, January 2015

  • Schwarz, Christoph; Hüter, Ole; Brixner, Tobias
  • Journal of the Optical Society of America B, Vol. 32, Issue 5
  • DOI: 10.1364/josab.32.000933

Femtosecond pulse shaping using spatial light modulators
journal, May 2000

  • Weiner, A. M.
  • Review of Scientific Instruments, Vol. 71, Issue 5, p. 1929-1960
  • DOI: 10.1063/1.1150614

Roaming Radical Reactions
journal, February 2011

  • Herath, Nuradhika; Suits, Arthur G.
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 6
  • DOI: 10.1021/jz101731q

Steering Proton Migration in Hydrocarbons Using Intense Few-Cycle Laser Fields
journal, May 2016


Metastable decomposition and hydrogen migration of ethane dication produced in an intense femtosecond near-infrared laser field
journal, February 2011

  • Hoshina, Kennosuke; Kawamura, Haruna; Tsuge, Masashi
  • The Journal of Chemical Physics, Vol. 134, Issue 6
  • DOI: 10.1063/1.3549137

Hydrogen migration in methanol studied under asymmetric fs laser irradiation
journal, June 2014


Roaming
journal, April 2014


Thick-lens velocity-map imaging spectrometer with high resolution for high-energy charged particles
journal, May 2014


Complete Photoionization Experiments via Ultrafast Coherent Control with Polarization Multiplexing
journal, June 2014


Quantum control of energy flow in light harvesting
journal, May 2002

  • Herek, Jennifer L.; Wohlleben, Wendel; Cogdell, Richard J.
  • Nature, Vol. 417, Issue 6888, p. 533-535
  • DOI: 10.1038/417533a

Incorporating real time velocity map image reconstruction into closed-loop coherent control
journal, November 2014

  • Rallis, C. E.; Burwitz, T. G.; Andrews, P. R.
  • Review of Scientific Instruments, Vol. 85, Issue 11
  • DOI: 10.1063/1.4899267

Ejection of triatomic hydrogen molecular ion from methanol in intense laser fields
journal, October 2005


Examining the feedback signals used in closed-loop control of intense laser fragmentation of CO +
journal, December 2009


Strong-field Fourier transform vibrational spectroscopy of methanol cation and its isotopologues using few-cycle near-infrared laser pulses
journal, December 2018


Photoelectron angular distributions from strong-field coherent electronic excitation
journal, February 2009


Rapid multiple-quantum three-dimensional fluorescence spectroscopy disentangles quantum pathways
journal, October 2019


Coincidence momentum imaging of ultrafast hydrogen migration in methanol and its isotopomers in intense laser fields
journal, May 2006


Quantum coherent control of H 3 + formation in strong fields
journal, January 2019

  • Michie, Matthew J.; Ekanayake, Nagitha; Weingartz, Nicholas P.
  • The Journal of Chemical Physics, Vol. 150, Issue 4
  • DOI: 10.1063/1.5070067

Control of bond-selective photochemistry in CH $\scriptstyle \mathsf {2}$ BrCl using adaptive femtosecond pulse shaping
journal, July 2002

  • Damrauer, N. H.; Dietl, C.; Krampert, G.
  • The European Physical Journal D - Atomic, Molecular and Optical Physics, Vol. 20, Issue 1
  • DOI: 10.1140/epjd/e2002-00101-8

Control of Chemical Reactions by Feedback-Optimized Phase-Shaped Femtosecond Laser Pulses
journal, October 1998


Observation of Hydrogen Migration in Cyclohexane under an Intense Femtosecond Laser Field
journal, February 2015

  • Wu, Hua; Zhang, Shian; Zhang, Jian
  • The Journal of Physical Chemistry A, Vol. 119, Issue 10
  • DOI: 10.1021/jp510667z

Stereodynamical Origin of Anti-Arrhenius Kinetics: Negative Activation Energy and Roaming for a Four-Atom Reaction
journal, April 2015

  • Coutinho, Nayara D.; Silva, Valter H. C.; de Oliveira, Heibbe C. B.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 9
  • DOI: 10.1021/acs.jpclett.5b00384

Transition State Theory
journal, October 1981


Applications of polarization-shaped femtosecond laser pulses
journal, July 2016


Training Schrödinger’s cat: quantum optimal control: Strategic report on current status, visions and goals for research in Europe
journal, December 2015

  • Glaser, Steffen J.; Boscain, Ugo; Calarco, Tommaso
  • The European Physical Journal D, Vol. 69, Issue 12
  • DOI: 10.1140/epjd/e2015-60464-1

Theoretical study of unimolecular decomposition of allene cations
journal, December 2008

  • Mebel, A. M.; Bandrauk, A. D.
  • The Journal of Chemical Physics, Vol. 129, Issue 22
  • DOI: 10.1063/1.3037204

Quantum control of photodissociation using intense, femtosecond pulses shaped with third order dispersion
journal, September 2015

  • Lev, U.; Graham, L.; Madsen, C. B.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 48, Issue 20
  • DOI: 10.1088/0953-4075/48/20/201001

Gaining Mechanistic Insight with Control Pulse Slicing: Application to the Dissociative Ionization of CH 2 BrI
journal, November 2017

  • Xing, Xi; Rey-de-Castro, Roberto; Rabitz, Herschel
  • The Journal of Physical Chemistry A, Vol. 121, Issue 45
  • DOI: 10.1021/acs.jpca.7b08835

Strong-field-induced bond rearrangement in triatomic molecules
journal, May 2019


Substituent effects on H 3 + formation via H 2 roaming mechanisms from organic molecules under strong-field photodissociation
journal, December 2018

  • Ekanayake, Nagitha; Nairat, Muath; Weingartz, Nicholas P.
  • The Journal of Chemical Physics, Vol. 149, Issue 24
  • DOI: 10.1063/1.5065387

Coherent vibrations in methanol cation probed by periodic H3+ ejection after double ionization
journal, March 2018


Order of Magnitude Dissociative Ionization Enhancement Observed for Pulses with High Order Dispersion
journal, October 2016

  • Nairat, Muath; Lozovoy, Vadim V.; Dantus, Marcos
  • The Journal of Physical Chemistry A, Vol. 120, Issue 43
  • DOI: 10.1021/acs.jpca.6b08659

Mapping Excited-State Dynamics by Coherent Control of a Dendrimer's Photoemission Efficiency
journal, October 2009


Adaptive strong-field control of chemical dynamics guided by three-dimensional momentum imaging
journal, December 2013

  • Wells, E.; Rallis, C. E.; Zohrabi, M.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3895

Control of selectivity of chemical reaction via control of wave packet evolution
journal, November 1985

  • Tannor, David J.; Rice, Stuart A.
  • The Journal of Chemical Physics, Vol. 83, Issue 10, p. 5013-5018
  • DOI: 10.1063/1.449767

Coherent control of strong field multiphoton absorption in the presence of dynamic Stark shifts
journal, January 2005


Evidence for a second molecular channel in the fragmentation of formaldehyde
journal, August 1993

  • van Zee, Roger D.; Foltz, M. Frances; Moore, C. Bradley
  • The Journal of Chemical Physics, Vol. 99, Issue 3
  • DOI: 10.1063/1.465335

Extracting quantum dynamics from genetic learning algorithms through principal control analysis
journal, December 2004

  • White, J. L.; Pearson, B. J.; Bucksbaum, P. H.
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 37, Issue 24
  • DOI: 10.1088/0953-4075/37/24/l02

Wave packet bifurcation in ultrafast hydrogen migration in CH3OH+ by pump-probe coincidence momentum imaging with few-cycle laser pulses
journal, March 2015


Visible/Infrared Dissociation of NO 3 : Roaming in the Dark or Roaming on the Ground?
journal, December 2014

  • Fernando, Ravin; Dey, Arghya; Broderick, Bernadette M.
  • The Journal of Physical Chemistry A, Vol. 119, Issue 28
  • DOI: 10.1021/jp509902d

Communication: Long-lived neutral H 2 in hydrogen migration within methanol dication
journal, November 2013

  • Nakai, K.; Kato, T.; Kono, H.
  • The Journal of Chemical Physics, Vol. 139, Issue 18
  • DOI: 10.1063/1.4830397

Time-resolved molecular dynamics of single and double hydrogen migration in ethanol
journal, June 2019


Vibrational and Vibronic Structure in the Valence Electron Spectra of CH 3 X Molecules (X=F, Cl, Br, I, OH)
journal, November 1977


Efficient ejection of H3+ from hydrocarbon molecules induced by ultrashort intense laser fields
journal, September 2008

  • Hoshina, Kennosuke; Furukawa, Yusuke; Okino, Tomoya
  • The Journal of Chemical Physics, Vol. 129, Issue 10
  • DOI: 10.1063/1.2973588

Velocity map imaging as a tool for gaining mechanistic insight from closed-loop control studies of molecular fragmentation
journal, April 2011


Coincidence momentum imaging of ejection of hydrogen molecular ions from methanol in intense laser fields
journal, February 2006


Deciphering the Reaction Dynamics Underlying Optimal Control Laser Fields
journal, January 2003

  • Daniel, Chantal; Full, Jurgen; Gonzalez, Leticia
  • Science, Vol. 299, Issue 5606, p. 536-539
  • DOI: 10.1126/science.1078517

Roaming Radicals
journal, May 2011


Roaming Under the Microscope: Trajectory Study of Formaldehyde Dissociation
journal, February 2016

  • Houston, Paul L.; Conte, Riccardo; Bowman, Joel M.
  • The Journal of Physical Chemistry A, Vol. 120, Issue 27
  • DOI: 10.1021/acs.jpca.6b00488

Phase dependence of OD+, HOD+, and H3+ ions released from the deuterated dication of methanol under ω/2ω laser field irradiation
journal, April 2015


Perspective: Stimulated Raman adiabatic passage: The status after 25 years
journal, May 2015

  • Bergmann, Klaas; Vitanov, Nikolay V.; Shore, Bruce W.
  • The Journal of Chemical Physics, Vol. 142, Issue 17
  • DOI: 10.1063/1.4916903

Recoil-ion and electron momentum spectroscopy: reaction-microscopes
journal, August 2003


Mechanisms and time-resolved dynamics for trihydrogen cation (H3 +) formation from organic molecules in strong laser fields
journal, July 2017


Shaper-assisted removal of the direction-of-time ambiguity in second-harmonic generation frequency-resolved optical gating
journal, July 2010


Closed-loop control of intense-laser fragmentation of S 8
journal, December 2005


Unusual mechanism for H 3 + formation from ethane as obtained by femtosecond laser pulse ionization and quantum chemical calculations
journal, March 2011

  • Kraus, Peter M.; Schwarzer, Martin C.; Schirmel, Nora
  • The Journal of Chemical Physics, Vol. 134, Issue 11
  • DOI: 10.1063/1.3561311

Toward Understanding the Roaming Mechanism in H + MgH → Mg + HH Reaction
journal, February 2016

  • Mauguière, Frédéric A. L.; Collins, Peter; Stamatiadis, Stamatis
  • The Journal of Physical Chemistry A, Vol. 120, Issue 27
  • DOI: 10.1021/acs.jpca.6b00682

Tabletop imaging of structural evolutions in chemical reactions demonstrated for the acetylene cation
journal, July 2014

  • Ibrahim, Heide; Wales, Benji; Beaulieu, Samuel
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5422

Control of Molecular Fragmentation Using Shaped Femtosecond Pulses
journal, May 2008

  • Lozovoy, Vadim V.; Zhu, Xin; Gunaratne, Tissa C.
  • The Journal of Physical Chemistry A, Vol. 112, Issue 17
  • DOI: 10.1021/jp071691p

What is special about how roaming chemical reactions traverse their potential surfaces? Differences in geodesic paths between roaming and non-roaming events
journal, June 2017

  • Cofer-Shabica, D. Vale; Stratt, Richard M.
  • The Journal of Chemical Physics, Vol. 146, Issue 21
  • DOI: 10.1063/1.4984617

A velocity map imaging detector with an integrated gas injection system
journal, March 2009

  • Ghafur, O.; Siu, W.; Johnsson, P.
  • Review of Scientific Instruments, Vol. 80, Issue 3
  • DOI: 10.1063/1.3085799

The fragmentation of doubly charged methanol
journal, March 1992

  • Eland, J. H. D.; Treves-Brown, B. J.
  • International Journal of Mass Spectrometry and Ion Processes, Vol. 113, Issue 2
  • DOI: 10.1016/0168-1176(92)80029-z

A newcomer's guide to ultrashort pulse shaping and characterization
journal, May 2010

  • Monmayrant, Antoine; Weber, Sébastien; Chatel, Béatrice
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 43, Issue 10
  • DOI: 10.1088/0953-4075/43/10/103001

Rapid formation of H + 3 from ammonia and methane following 4 MeV proton impact
journal, April 2009

  • Jochim, Bethany; Lueking, Amy; Doshier, Laura
  • Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 42, Issue 9
  • DOI: 10.1088/0953-4075/42/9/091002

Roaming reactions: The third way
journal, November 2011

  • Bowman, Joel M.; Suits, Arthur G.
  • Physics Today, Vol. 64, Issue 11
  • DOI: 10.1063/pt.3.1330

Roaming dynamics in radical addition–elimination reactions
journal, June 2014

  • Joalland, Baptiste; Shi, Yuanyuan; Kamasah, Alexander
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5064

H2 roaming chemistry and the formation of H3+ from organic molecules in strong laser fields
journal, December 2018