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Title: A High‐Energy NASICON‐Type Cathode Material for Na‐Ion Batteries

 [1];  [2];  [2];  [1];  [1];  [1];  [3]; ORCiD logo [1]
  1. Materials Sciences DivisionLawrence Berkeley National Laboratory Berkeley CA 94720 USA, Department of Materials Science and EngineeringUniversity of California Berkeley CA 94720 USA
  2. Advanced Material LabSamsung Research America Burlington MA 01803 USA
  3. Materials Sciences DivisionLawrence Berkeley National Laboratory Berkeley CA 94720 USA
Publication Date:
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
Grant/Contract Number:  
DE‐AC02‐05CH11231; DE‐AC02‐06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials; Journal ID: ISSN 1614-6832
Wiley Blackwell (John Wiley & Sons)
Country of Publication:

Citation Formats

Wang, Jingyang, Wang, Yan, Seo, Dong‐Hwa, Shi, Tan, Chen, Shouping, Tian, Yaosen, Kim, Haegyeom, and Ceder, Gerbrand. A High‐Energy NASICON‐Type Cathode Material for Na‐Ion Batteries. Germany: N. p., 2020. Web. doi:10.1002/aenm.201903968.
Wang, Jingyang, Wang, Yan, Seo, Dong‐Hwa, Shi, Tan, Chen, Shouping, Tian, Yaosen, Kim, Haegyeom, & Ceder, Gerbrand. A High‐Energy NASICON‐Type Cathode Material for Na‐Ion Batteries. Germany. doi:10.1002/aenm.201903968.
Wang, Jingyang, Wang, Yan, Seo, Dong‐Hwa, Shi, Tan, Chen, Shouping, Tian, Yaosen, Kim, Haegyeom, and Ceder, Gerbrand. Mon . "A High‐Energy NASICON‐Type Cathode Material for Na‐Ion Batteries". Germany. doi:10.1002/aenm.201903968.
title = {A High‐Energy NASICON‐Type Cathode Material for Na‐Ion Batteries},
author = {Wang, Jingyang and Wang, Yan and Seo, Dong‐Hwa and Shi, Tan and Chen, Shouping and Tian, Yaosen and Kim, Haegyeom and Ceder, Gerbrand},
abstractNote = {},
doi = {10.1002/aenm.201903968},
journal = {Advanced Energy Materials},
number = ,
volume = ,
place = {Germany},
year = {2020},
month = {2}

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ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005

Bloch-wave channeling and HOLZ effects in high-energy electron diffraction
journal, October 1989

  • Peng, L. M.; Gjønnes, J. K.
  • Acta Crystallographica Section A Foundations of Crystallography, Vol. 45, Issue 10
  • DOI: 10.1107/S0108767389005982

Na 3 V 2 (PO 4 ) 3 : an advanced cathode for sodium-ion batteries
journal, January 2019

  • Zhang, Xianghua; Rui, Xianhong; Chen, Dong
  • Nanoscale, Vol. 11, Issue 6
  • DOI: 10.1039/C8NR09391A

Enhancing Na + Extraction Limit through High Voltage Activation of the NASICON-Type Na 4 MnV(PO 4 ) 3 Cathode
journal, October 2018

  • Zakharkin, Maxim V.; Drozhzhin, Oleg A.; Tereshchenko, Ivan V.
  • ACS Applied Energy Materials, Vol. 1, Issue 11
  • DOI: 10.1021/acsaem.8b01269

Electrochemical Li+ insertion capabilities of Na4−xCo3(PO4)2P2O7 and its application to novel hybrid-ion batteries
journal, January 2014

  • Nose, Masafumi; Nobuhara, Kunihiro; Shiotani, Shinya
  • RSC Advances, Vol. 4, Issue 18
  • DOI: 10.1039/c3ra45836a

SIR 97: a new tool for crystal structure determination and refinement
journal, February 1999

  • Altomare, Angela; Burla, Maria Cristina; Camalli, Mercedes
  • Journal of Applied Crystallography, Vol. 32, Issue 1
  • DOI: 10.1107/S0021889898007717

Sodium Extraction from NASICON-Structured Na 3 MnTi(PO 4 ) 3 through Mn(III)/Mn(II) and Mn(IV)/Mn(III) Redox Couples
journal, September 2016

High voltage cathode materials for Na-ion batteries of general formula Na3V2O2x(PO4)2F3−2x
journal, January 2012

  • Serras, Paula; Palomares, Verónica; Goñi, Aintzane
  • Journal of Materials Chemistry, Vol. 22, Issue 41
  • DOI: 10.1039/c2jm35293a

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Highly Reversible and Ultrafast Sodium Storage in NaTi 2 (PO 4 ) 3 Nanoparticles Embedded in Nanocarbon Networks
journal, December 2015

  • Jiang, Yu; Shi, Jinan; Wang, Min
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 1
  • DOI: 10.1021/acsami.5b09811

Kinetics of non-equilibrium lithium incorporation in LiFePO4
journal, July 2011

  • Malik, Rahul; Zhou, Fei; Ceder, G.
  • Nature Materials, Vol. 10, Issue 8
  • DOI: 10.1038/nmat3065

First-Principles Prediction of Insertion Potentials in Li-Mn Oxides for Secondary Li Batteries
journal, January 1997

  • Aydinol, M. K.
  • Journal of The Electrochemical Society, Vol. 144, Issue 11
  • DOI: 10.1149/1.1838099

First-principles prediction of redox potentials in transition-metal compounds with LDA + U
journal, December 2004

Na 3 MnZr(PO 4 ) 3 : A High-Voltage Cathode for Sodium Batteries
journal, December 2018

  • Gao, Hongcai; Seymour, Ieuan D.; Xin, Sen
  • Journal of the American Chemical Society, Vol. 140, Issue 51
  • DOI: 10.1021/jacs.8b11388

Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study
journal, January 1998

  • Dudarev, S. L.; Botton, G. A.; Savrasov, S. Y.
  • Physical Review B, Vol. 57, Issue 3, p. 1505-1509
  • DOI: 10.1103/PhysRevB.57.1505

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

The electrochemical insertion properties of sodium vanadium fluorophosphate, Na3V2(PO4)2F3
journal, July 2006

Sodium and sodium-ion energy storage batteries
journal, August 2012

  • Ellis, Brian L.; Nazar, Linda F.
  • Current Opinion in Solid State and Materials Science, Vol. 16, Issue 4, p. 168-177
  • DOI: 10.1016/j.cossms.2012.04.002

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013

  • Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
  • Energy & Environmental Science, Vol. 6, Issue 8
  • DOI: 10.1039/c3ee40847g

Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries
journal, June 2017

A comparison of destabilization mechanisms of the layered NaxMO2 and LixMO2 compounds upon alkali de-intercalation
journal, January 2012

  • Kim, Sangtae; Ma, Xiaohua; Ong, Shyue Ping
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 44
  • DOI: 10.1039/c2cp43377j

High-Voltage Cr 4+ /Cr 3+ Redox Couple in Polyanion Compounds
journal, February 2018

  • Kawai, Kosuke; Zhao, Wenwen; Nishimura, Shin-ichi
  • ACS Applied Energy Materials, Vol. 1, Issue 3
  • DOI: 10.1021/acsaem.7b00105

Electrochemical investigations of high-voltage Na4Ni3(PO4)2P2O7 cathode for sodium-ion batteries
journal, November 2019

  • Kumar, P. Ramesh; Yahia, H. B.; Belharouak, I.
  • Journal of Solid State Electrochemistry, Vol. 24, Issue 1
  • DOI: 10.1007/s10008-019-04448-6

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012

  • Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
  • Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
  • DOI: 10.1002/aenm.201200026

Theoretical and Experimental Study of Vanadium-Based Fluorophosphate Cathodes for Rechargeable Batteries
journal, May 2014

  • Xu, Maowen; Xiao, Penghao; Stauffer, Shannon
  • Chemistry of Materials, Vol. 26, Issue 10
  • DOI: 10.1021/cm500106w

High-Performance P2-Type Na 2/3 (Mn 1/2 Fe 1/4 Co 1/4 )O 2 Cathode Material with Superior Rate Capability for Na-Ion Batteries
journal, September 2015

Na x MV(PO 4 ) 3 (M = Mn, Fe, Ni) Structure and Properties for Sodium Extraction
journal, November 2016

Research Development on Sodium-Ion Batteries
journal, October 2014

  • Yabuuchi, Naoaki; Kubota, Kei; Dahbi, Mouad
  • Chemical Reviews, Vol. 114, Issue 23
  • DOI: 10.1021/cr500192f

Mixed conductivity of the NASICON phase Na2+x+yZr1−yFeIIxFeIII1−x+y(PO4)3
journal, February 1991

Review—Practical Issues and Future Perspective for Na-Ion Batteries
journal, January 2015

  • Kubota, Kei; Komaba, Shinichi
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0151514jes

A comprehensive review of sodium layered oxides: powerful cathodes for Na-ion batteries
journal, January 2015

  • Han, Man Huon; Gonzalo, Elena; Singh, Gurpreet
  • Energy & Environmental Science, Vol. 8, Issue 1
  • DOI: 10.1039/C4EE03192J

The Emerging Chemistry of Sodium Ion Batteries for Electrochemical Energy Storage
journal, February 2015

  • Kundu, Dipan; Talaie, Elahe; Duffort, Victor
  • Angewandte Chemie International Edition, Vol. 54, Issue 11
  • DOI: 10.1002/anie.201410376

The First Report on Excellent Cycling Stability and Superior Rate Capability of Na 3 V 2 (PO 4 ) 3 for Sodium Ion Batteries
journal, November 2012

  • Saravanan, Kuppan; Mason, Chad W.; Rudola, Ashish
  • Advanced Energy Materials, Vol. 3, Issue 4
  • DOI: 10.1002/aenm.201200803

Polyanionic (Phosphates, Silicates, Sulfates) Frameworks as Electrode Materials for Rechargeable Li (or Na) Batteries
journal, June 2013

  • Masquelier, Christian; Croguennec, Laurence
  • Chemical Reviews, Vol. 113, Issue 8
  • DOI: 10.1021/cr3001862

Understanding the Electrochemical Mechanism of the New Iron-Based Mixed-Phosphate Na 4 Fe 3 (PO 4 ) 2 (P 2 O 7 ) in a Na Rechargeable Battery
journal, August 2013

  • Kim, Hyungsub; Park, Inchul; Lee, Seongsu
  • Chemistry of Materials, Vol. 25, Issue 18
  • DOI: 10.1021/cm4013816

Electrochemical and Thermal Properties of NASICON Structured Na 3 V 2 (PO 4 ) 3 as a Sodium Rechargeable Battery Cathode: A Combined Experimental and Theoretical Study
journal, January 2012

  • Lim, Soo Yeon; Kim, Heejin; Shakoor, R. A.
  • Journal of The Electrochemical Society, Vol. 159, Issue 9
  • DOI: 10.1149/2.015209jes

Polyanion-Type Electrode Materials for Sodium-Ion Batteries
journal, January 2017

A NASICON‐Type Positive Electrode for Na Batteries with High Energy Density: Na 4 MnV(PO 4 ) 3
journal, August 2018

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Improved Cycling Performance of Li-Excess Cation-Disordered Cathode Materials upon Fluorine Substitution
journal, November 2018

  • Lun, Zhengyan; Ouyang, Bin; Kitchaev, Daniil A.
  • Advanced Energy Materials, Vol. 9, Issue 2
  • DOI: 10.1002/aenm.201802959

Commentary: The Materials Project: A materials genome approach to accelerating materials innovation
journal, July 2013

  • Jain, Anubhav; Ong, Shyue Ping; Hautier, Geoffroy
  • APL Materials, Vol. 1, Issue 1
  • DOI: 10.1063/1.4812323

High performance manganese-based layered oxide cathodes: overcoming the challenges of sodium ion batteries
journal, January 2017

  • Ortiz-Vitoriano, Nagore; Drewett, Nicholas E.; Gonzalo, Elena
  • Energy & Environmental Science, Vol. 10, Issue 5
  • DOI: 10.1039/C7EE00566K

NASICON-Structured Materials for Energy Storage
journal, February 2017

Improving the energy density of Na 3 V 2 (PO 4 ) 3 -based positive electrodes through V/Al substitution
journal, January 2015

  • Lalère, F.; Seznec, V.; Courty, M.
  • Journal of Materials Chemistry A, Vol. 3, Issue 31
  • DOI: 10.1039/C5TA03528G

Superior Electrochemical Performance and Storage Mechanism of Na 3 V 2 (PO 4 ) 3 Cathode for Room-Temperature Sodium-Ion Batteries
journal, October 2012

Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries
journal, August 2015

Sodium-Ion Batteries
journal, May 2012

  • Slater, Michael D.; Kim, Donghan; Lee, Eungje
  • Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
  • DOI: 10.1002/adfm.201200691

Improved Reversibility of Fe 3+ /Fe 4+ Redox Couple in Sodium Super Ion Conductor Type Na 3 Fe 2 (PO 4 ) 3 for Sodium-Ion Batteries
journal, January 2017

  • Rajagopalan, Ranjusha; Chen, Bo; Zhang, Zhicheng
  • Advanced Materials, Vol. 29, Issue 12
  • DOI: 10.1002/adma.201605694

Toward high energy density cathode materials for sodium-ion batteries: investigating the beneficial effect of aluminum doping on the P2-type structure
journal, January 2017

  • Hasa, Ivana; Passerini, Stefano; Hassoun, Jusef
  • Journal of Materials Chemistry A, Vol. 5, Issue 9
  • DOI: 10.1039/C6TA08667E

P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012

  • Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
  • Nature Materials, Vol. 11, Issue 6
  • DOI: 10.1038/nmat3309

NASICON-type NaMo2(PO4)3: Electrochemical activity of the Mo+4 polyanion compound in Na-cell
journal, November 2018

A profile refinement method for nuclear and magnetic structures
journal, June 1969

Sodium Manganese Oxide Thin Films as Cathodes for Na-Ion Batteries
journal, February 2014

Realizing Three-Electron Redox Reactions in NASICON-Structured Na 3 MnTi(PO 4 ) 3 for Sodium-Ion Batteries
journal, January 2019

Is lithium the new gold?
journal, June 2010

Additional Sodium Insertion into Polyanionic Cathodes for Higher-Energy Na-Ion Batteries
journal, May 2017

  • Bianchini, Matteo; Xiao, Penghao; Wang, Yan
  • Advanced Energy Materials, Vol. 7, Issue 18
  • DOI: 10.1002/aenm.201700514

A nasicon-type phase as intercalation electrode: NaTi2(PO4)3
journal, May 1987

Exploring Highly Reversible 1.5-Electron Reactions (V 3+ /V 4+ /V 5+ ) in Na 3 VCr(PO 4 ) 3 Cathode for Sodium-Ion Batteries
journal, December 2017

  • Liu, Rui; Xu, Guiliang; Li, Qi
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 50
  • DOI: 10.1021/acsami.7b13018

Differential redox and sorption of Cr (III/VI) on natural silicate and oxide minerals: EXAFS and XANES results
journal, August 1997

Jahn–Teller Assisted Na Diffusion for High Performance Na Ion Batteries
journal, September 2016