Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis

Clarke, Samantha M.; Walsh, James P.  S.; Amsler, Maximilian; Malliakas, Christos D.; Yu, Tony; Goedecker, Stefan; Wang, Yanbin; Wolverton, Chris; Freedman, Danna E.

doi:10.1002/anie.201605902

Title: Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis

Abstract

A new intermetallic compound, the first to be structurally identified in the Cu–Bi binary system, is reported herein. This compound is accessed by high-pressure reaction of the elements. Its detailed characterization, physical property measurements, and ab initio calculations are described. The commensurate crystal structure of Cu₁₁Bi₇ is a unique variation of the NiAs structure type. Temperature-dependent electrical resistivity and heat capacity measurements reveal a bulk superconducting transition at T_c=1.36 K. Density functional theory calculations further demonstrate that Cu₁₁Bi₇ can be stabilized (relative to decomposition into the elements) at high pressure and temperature. These results highlight the ability of high-pressure syntheses to allow for inroads into heretofore-undiscovered intermetallic systems for which no thermodynamically stable binaries are known.

Authors:

Clarke, Samantha M. ^[1]; Walsh, James P. S. ^[1]; Amsler, Maximilian ^[2]; Malliakas, Christos D. ^[1]; Yu, Tony ^[3]; Goedecker, Stefan ^[4]; Wang, Yanbin ^[3]; Wolverton, Chris ^[2]; Freedman, Danna E. ^[1]

Northwestern Univ., Evanston, IL (United States). Dept. of Chemistry
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Univ. of Chicago, IL (United States). Center for Advanced Radiation Sources
Univ. Basel (Switzerland). Dept. of Physics

Publication Date:: Mon Sep 26 00:00:00 EDT 2016

Research Org.:: Northwestern Univ., Evanston, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Org.:: Defense Advanced Research Projects Agency (DARPA); US Air Force Office of Scientific Research (AFOSR); National Science Foundation (NSF); Swiss National Science Foundation (SNF); USDOE Office of Science (SC), Advanced Scientific Computing Research (ASCR); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

OSTI Identifier:: 1596770

Grant/Contract Number:: FG02-94ER14466; FG02-07ER46433; AC02-06CH11357; AC02-05CH11231; W911NF15100069; FA95501410358; EAR-1128799; DGE-1324585; NNCI-1542205

Resource Type:: Accepted Manuscript

Journal Name:: Angewandte Chemie (International Edition)

Additional Journal Information:: Journal Name: Angewandte Chemie (International Edition); Journal Volume: 55; Journal Issue: 43; Journal ID: ISSN 1433-7851

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; bismuth; copper; high-pressure synthesis; intermetallics; superconductivity

Citation Formats


                    Clarke, Samantha M., Walsh, James P.  S., Amsler, Maximilian, Malliakas, Christos D., Yu, Tony, Goedecker, Stefan, Wang, Yanbin, Wolverton, Chris, and Freedman, Danna E. Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis.  United States: N. p., 2016. 
Web.  doi:10.1002/anie.201605902.

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                    Clarke, Samantha M., Walsh, James P.  S., Amsler, Maximilian, Malliakas, Christos D., Yu, Tony, Goedecker, Stefan, Wang, Yanbin, Wolverton, Chris, & Freedman, Danna E. Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis.  United States.  https://doi.org/10.1002/anie.201605902

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                    Clarke, Samantha M., Walsh, James P.  S., Amsler, Maximilian, Malliakas, Christos D., Yu, Tony, Goedecker, Stefan, Wang, Yanbin, Wolverton, Chris, and Freedman, Danna E. Mon .  
"Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis".  United States.  https://doi.org/10.1002/anie.201605902.  https://www.osti.gov/servlets/purl/1596770.

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@article{osti_1596770,

  title        = {Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis},

  author       = {Clarke, Samantha M. and Walsh, James P.  S. and Amsler, Maximilian and Malliakas, Christos D. and Yu, Tony and Goedecker, Stefan and Wang, Yanbin and Wolverton, Chris and Freedman, Danna E.},

  abstractNote = {A new intermetallic compound, the first to be structurally identified in the Cu–Bi binary system, is reported herein. This compound is accessed by high-pressure reaction of the elements. Its detailed characterization, physical property measurements, and ab initio calculations are described. The commensurate crystal structure of Cu11Bi7 is a unique variation of the NiAs structure type. Temperature-dependent electrical resistivity and heat capacity measurements reveal a bulk superconducting transition at Tc=1.36 K. Density functional theory calculations further demonstrate that Cu11Bi7 can be stabilized (relative to decomposition into the elements) at high pressure and temperature. These results highlight the ability of high-pressure syntheses to allow for inroads into heretofore-undiscovered intermetallic systems for which no thermodynamically stable binaries are known.},

  doi          = {10.1002/anie.201605902},

  journal      = {Angewandte Chemie (International Edition)},

  number       = 43,

  volume       = 55,

  place        = {United States},

  year         = {Mon Sep 26 00:00:00 EDT 2016},

  month        = {Mon Sep 26 00:00:00 EDT 2016}

}

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Works referencing / citing this record:

Discovery of Cu ₃ Pb
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Title: Discovery of a Superconducting Cu-Bi Intermetallic Compound by High-Pressure Synthesis

Abstract

Citation Formats

Metallische Schmelzen - Reaktionsmedien zur Präparation intermetallischer Verbindungen journal, November 2005

CoBi 3 : Binäre Cobalt-Bismut-Verbindung und Supraleiter journal, July 2013

Ein metastabiles Metall mit lokaler dekagonaler Symmetrie aus einer Niedertemperatur-Pseudomorphose journal, May 2011

CoBi 3 –the first binary compound of cobalt with bismuth: high-pressure synthesis and superconductivity journal, September 2014

Topochemische Pseudomorphose eines Chlorids in ein Bismutid journal, February 2014

Many More Superconducting Bismuth Phases journal, September 1966

Colloidal Synthesis of Non-Equilibrium Wurtzite-Type MnSe journal, May 2010

Superstructure Ordering of Intermetallics: B8 Structures in the Pseudo-Cubic Regime journal, April 1998

Einige Strukturdaten metallischer Phasen: 13. Mitteilung journal, November 1968

The incommensurately modulated structure of NiBi journal, May 2000

Strukturuntersuchungen in einigen Mischungen TB3B4 (TMn,Fe,Co,Ir,Ni,Pd; B3 Al,Ga,Tl; B4Si,Ge) journal, July 1969

Superconducting and Normal State Properties of NiBi 3 journal, September 2000

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds journal, November 2005

CoBi 3 : A Binary Cobalt-Bismuth Compound and Superconductor journal, July 2013

A Metastable Metal with Decagonal Local Symmetry Obtained by Low-Temperature Pseudomorphosis journal, May 2011

Superconductivity and magnetic ordering in Bi 3 Sr 1 − x Eu x journal, March 1978

Superconductivity in Cu x Bi 2 Se 3 and its Implications for Pairing in the Undoped Topological Insulator journal, February 2010

The Topochemical Pseudomorphosis of a Chloride into a Bismuthide journal, February 2014

Observation of topological order in a superconducting doped topological insulator journal, September 2010

Low-Temperature Solution Synthesis of the Non-Equilibrium Ordered Intermetallic Compounds Au 3 Fe, Au 3 Co, and Au 3 Ni as Nanocrystals journal, September 2008

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Die Kristallstruktur von BiNi: eine komplexe Ausdünnungsvariante des InNi2-Typs journal, December 1999

Colloidal Synthesis of Non-Equilibrium Wurtzite-Type MnSe journal, May 2010

Yb 14 MnSb 11 : New High Efficiency Thermoelectric Material for Power Generation journal, April 2006

Ion beam mixing and superconductivity in Cu-Bi journal, March 1985

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds journal, January 2006

Discovery of Cu 3 Pb journal, September 2018

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The Intermetalloid Cluster Cation (CuBi 8 ) 3+ journal, October 2017

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Metallische Schmelzen - Reaktionsmedien zur Präparation intermetallischer Verbindungen
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CoBi ₃ : Binäre Cobalt-Bismut-Verbindung und Supraleiter
journal, July 2013

Ein metastabiles Metall mit lokaler dekagonaler Symmetrie aus einer Niedertemperatur-Pseudomorphose
journal, May 2011

CoBi ₃ –the first binary compound of cobalt with bismuth: high-pressure synthesis and superconductivity
journal, September 2014

Topochemische Pseudomorphose eines Chlorids in ein Bismutid
journal, February 2014

Many More Superconducting Bismuth Phases
journal, September 1966

Colloidal Synthesis of Non-Equilibrium Wurtzite-Type MnSe
journal, May 2010

Superstructure Ordering of Intermetallics: B8 Structures in the Pseudo-Cubic Regime
journal, April 1998

Einige Strukturdaten metallischer Phasen: 13. Mitteilung
journal, November 1968

The incommensurately modulated structure of NiBi
journal, May 2000

Strukturuntersuchungen in einigen Mischungen TB3B4 (TMn,Fe,Co,Ir,Ni,Pd; B3 Al,Ga,Tl; B4Si,Ge)
journal, July 1969

Superconducting and Normal State Properties of NiBi ₃
journal, September 2000

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
journal, November 2005

CoBi ₃ : A Binary Cobalt-Bismuth Compound and Superconductor
journal, July 2013

A Metastable Metal with Decagonal Local Symmetry Obtained by Low-Temperature Pseudomorphosis
journal, May 2011

Superconductivity and magnetic ordering in ${Bi}_{3} {Sr}_{1 - x} {Eu}_{x}$
journal, March 1978

Superconductivity in ${Cu}_{x} {Bi}_{2} {Se}_{3}$ and its Implications for Pairing in the Undoped Topological Insulator
journal, February 2010

The Topochemical Pseudomorphosis of a Chloride into a Bismuthide
journal, February 2014

Observation of topological order in a superconducting doped topological insulator
journal, September 2010

Low-Temperature Solution Synthesis of the Non-Equilibrium Ordered Intermetallic Compounds Au ₃ Fe, Au ₃ Co, and Au ₃ Ni as Nanocrystals
journal, September 2008

Pressure-Induced Superconductivity and Its Scaling with Doping-Induced Superconductivity in the Iron Pnictide with Skutterudite Intermediary Layers
journal, January 2014

Die Kristallstruktur von BiNi: eine komplexe Ausdünnungsvariante des InNi2-Typs
journal, December 1999

Colloidal Synthesis of Non-Equilibrium Wurtzite-Type MnSe
journal, May 2010

Yb ₁₄ MnSb ₁₁ : New High Efficiency Thermoelectric Material for Power Generation
journal, April 2006

Ion beam mixing and superconductivity in Cu-Bi
journal, March 1985

The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds
journal, January 2006

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journal, September 2018

Metal‐Free Dearomatization: Direct Access to Spiroindol(en)ines in Batch and Continuous‐Flow
journal, January 2019

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