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Precious metal-free solar-to-fuel generation: SSM-DSCs powering water splitting with NanoCOT and NiMoZn electrocatalysts
Abstract
A precious metal-free sequential series multijunction dye-sensitized solar cell (SSM-DSC)-powered water electrolysis system is shown using NanoCOT and NiMoZn electrodes. Furthermore, a stable 3.9% solar-to-hydrogen (STH) efficiency is achieved using a recently reported black organic dye and graphene electrodes for DSCs.
- Authors:
-
[1];
[1];
[2];
[1];
[2];
[1]
- Univ. of Mississippi, Oxford, MS (United States)
- Univ. of Alabama, Tuscaloosa, AL (United States)
- Publication Date:
- Research Org.:
- Univ. of Mississippi, Oxford, MS (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
- OSTI Identifier:
- 1596581
- Alternate Identifier(s):
- OSTI ID: 1582483
- Grant/Contract Number:
- SC0019131
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 56; Journal Issue: 10; Related Information: This document is an accepted manuscript version of a published article that appeared in final form in Chemical Communications, copyright © Royal Society of Chemistry after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.rsc.org/en/content/articlelanding/2020/cc/c9cc09209a/unauth#!divAbstract.; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Cheema, Hammad, Watson, Jonathon, Shinde, Pravin S., Rodrigues, Roberta R., Pan, Shanlin, and Delcamp, Jared H. Precious metal-free solar-to-fuel generation: SSM-DSCs powering water splitting with NanoCOT and NiMoZn electrocatalysts. United States: N. p., 2019.
Web. doi:10.1039/C9CC09209A.
Cheema, Hammad, Watson, Jonathon, Shinde, Pravin S., Rodrigues, Roberta R., Pan, Shanlin, & Delcamp, Jared H. Precious metal-free solar-to-fuel generation: SSM-DSCs powering water splitting with NanoCOT and NiMoZn electrocatalysts. United States. doi:10.1039/C9CC09209A.
Cheema, Hammad, Watson, Jonathon, Shinde, Pravin S., Rodrigues, Roberta R., Pan, Shanlin, and Delcamp, Jared H. Fri .
"Precious metal-free solar-to-fuel generation: SSM-DSCs powering water splitting with NanoCOT and NiMoZn electrocatalysts". United States. doi:10.1039/C9CC09209A.
@article{osti_1596581,
title = {Precious metal-free solar-to-fuel generation: SSM-DSCs powering water splitting with NanoCOT and NiMoZn electrocatalysts},
author = {Cheema, Hammad and Watson, Jonathon and Shinde, Pravin S. and Rodrigues, Roberta R. and Pan, Shanlin and Delcamp, Jared H.},
abstractNote = {A precious metal-free sequential series multijunction dye-sensitized solar cell (SSM-DSC)-powered water electrolysis system is shown using NanoCOT and NiMoZn electrodes. Furthermore, a stable 3.9% solar-to-hydrogen (STH) efficiency is achieved using a recently reported black organic dye and graphene electrodes for DSCs.},
doi = {10.1039/C9CC09209A},
journal = {ChemComm},
number = 10,
volume = 56,
place = {United States},
year = {2019},
month = {12}
}
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DOI: 10.1039/C9CC09209A
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Works referenced in this record:
Chemical approaches to artificial photosynthesis
journal, September 2012
- Concepcion, J. J.; House, R. L.; Papanikolas, J. M.
- Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
A High-Voltage Molecular-Engineered Organic Sensitizer-Iron Redox Shuttle Pair: 1.4 V DSSC and 3.3 V SSM-DSSC Devices
journal, April 2018
- Rodrigues, Roberta R.; Cheema, Hammad; Delcamp, Jared H.
- Angewandte Chemie International Edition, Vol. 57, Issue 19
Hydrogen production, storage, transportation and key challenges with applications: A review
journal, June 2018
- Abdalla, Abdalla M.; Hossain, Shahzad; Nisfindy, Ozzan B.
- Energy Conversion and Management, Vol. 165
Sequential series multijunction dye-sensitized solar cells (SSM-DSCs): 4.7 volts from a single illuminated area
journal, January 2017
- Cheema, Hammad; Rodrigues, Roberta R.; Delcamp, Jared H.
- Energy & Environmental Science, Vol. 10, Issue 8
Porphyrin Sensitizers with Donor Structural Engineering for Superior Performance Dye-Sensitized Solar Cells and Tandem Solar Cells for Water Splitting Applications
journal, December 2016
- Kang, Sung Ho; Jeong, Myung Jin; Eom, Yu Kyung
- Advanced Energy Materials, Vol. 7, Issue 7
Design of Organic Dyes and Cobalt Polypyridine Redox Mediators for High-Efficiency Dye-Sensitized Solar Cells
journal, November 2010
- Feldt, Sandra M.; Gibson, Elizabeth A.; Gabrielsson, Erik
- Journal of the American Chemical Society, Vol. 132, Issue 46
Symmetric and unsymmetric donor functionalization. comparing structural and spectral benefits of chromophores for dye-sensitized solar cells
journal, January 2009
- Hagberg, Daniel P.; Jiang, Xiao; Gabrielsson, Erik
- Journal of Materials Chemistry, Vol. 19, Issue 39
Low-Recombination Thieno[3,4-b]thiophene-Based Photosensitizers for Dye-Sensitized Solar Cells with Panchromatic Photoresponses
journal, August 2017
- Brogdon, Phillip; Cheema, Hammad; Delcamp, Jared H.
- ChemSusChem, Vol. 10, Issue 18
An overview of hydrogen production technologies
journal, January 2009
- Holladay, J. D.; Hu, J.; King, D. L.
- Catalysis Today, Vol. 139, Issue 4
Solar-hydrogen: Environmentally safe fuel for the future
journal, April 2005
- Nowotny, J.; Sorrell, C.; Sheppard, L.
- International Journal of Hydrogen Energy, Vol. 30, Issue 5
A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films
journal, October 1991
- O'Regan, Brian; Grätzel, Michael
- Nature, Vol. 353, Issue 6346, p. 737-740
A perspective on the production of dye-sensitized solar modules
journal, January 2014
- Fakharuddin, Azhar; Jose, Rajan; Brown, Thomas M.
- Energy Environ. Sci., Vol. 7, Issue 12
A cobalt complex redox shuttle for dye-sensitized solar cells with high open-circuit potentials
journal, January 2012
- Yum, Jun-Ho; Baranoff, Etienne; Kessler, Florian
- Nature Communications, Vol. 3, Issue 1
Photo-electrochemical hydrogen generation from water using solar energy. Materials-related aspects
journal, October 2002
- Bak, T.; Nowotny, J.; Rekas, M.
- International Journal of Hydrogen Energy, Vol. 27, Issue 10
Dye-Sensitized Solar Cells
journal, November 2010
- Hagfeldt, Anders; Boschloo, Gerrit; Sun, Licheng
- Chemical Reviews, Vol. 110, Issue 11
Wideband dye-sensitized solar cells employing a phosphine-coordinated ruthenium sensitizer
journal, June 2013
- Kinoshita, Takumi; Dy, Joanne Ting; Uchida, Satoshi
- Nature Photonics, Vol. 7, Issue 7
Water photolysis at 12.3% efficiency via perovskite photovoltaics and Earth-abundant catalysts
journal, September 2014
- Luo, J.; Im, J. -H.; Mayer, M. T.
- Science, Vol. 345, Issue 6204
Series-connected tandem dye-sensitized solar cell for improving efficiency to more than 10%
journal, June 2009
- Yamaguchi, Takeshi; Uchida, Yuki; Agatsuma, Shinya
- Solar Energy Materials and Solar Cells, Vol. 93, Issue 6-7
PEDOT counter electrodes for dye-sensitized solar cells prepared by aqueous micellar electrodeposition
journal, September 2013
- Ellis, Hanna; Vlachopoulos, Nick; Häggman, Leif
- Electrochimica Acta, Vol. 107
Metal free sensitizer and catalyst for dye sensitized solar cells
journal, January 2013
- Ahmad, Shahzada; Guillén, Elena; Kavan, Ladislav
- Energy & Environmental Science, Vol. 6, Issue 12
A 25 mA/cm 2 Dye-Sensitized Solar Cell Based on a Near-Infrared-Absorbing Organic Dye and Application of the Device in SSM-DSCs
journal, January 2020
- Cheema, Hammad; Watson, Jonathon; peddapuram, adithya
- Chemical Communications
NanoCOT: Low-Cost Nanostructured Electrode Containing Carbon, Oxygen, and Titanium for Efficient Oxygen Evolution Reaction
journal, September 2015
- Shan, Zhichao; Archana, Panikar Sathyaseelan; Shen, Gang
- Journal of the American Chemical Society, Vol. 137, Issue 37
A Stable Blue Photosensitizer for Color Palette of Dye-Sensitized Solar Cells Reaching 12.6% Efficiency
journal, February 2018
- Ren, Yameng; Sun, Danyang; Cao, Yiming
- Journal of the American Chemical Society, Vol. 140, Issue 7
Materials for solar fuels and chemicals
journal, December 2016
- Montoya, Joseph H.; Seitz, Linsey C.; Chakthranont, Pongkarn
- Nature Materials, Vol. 16, Issue 1
Harnessing Photovoltage: Effects of Film Thickness, TiO 2 Nanoparticle Size, MgO and Surface Capping with DSCs
journal, January 2017
- Cheema, Hammad; Delcamp, Jared H.
- ACS Applied Materials & Interfaces, Vol. 9, Issue 3
Toward Cost-Effective Solar Energy Use
journal, February 2007
- Lewis, N. S.
- Science, Vol. 315, Issue 5813
Renewable hydrogen production
journal, January 2008
- Turner, John; Sverdrup, George; Mann, Margaret K.
- International Journal of Energy Research, Vol. 32, Issue 5
Solar Water Splitting Cells
journal, November 2010
- Walter, Michael G.; Warren, Emily L.; McKone, James R.
- Chemical Reviews, Vol. 110, Issue 11, p. 6446-6473
Near-Infrared-Absorbing Metal-Free Organic, Porphyrin, and Phthalocyanine Sensitizers for Panchromatic Dye-Sensitized Solar Cells
journal, December 2017
- Brogdon, Phillip; Cheema, Hammad; Delcamp, Jared H.
- ChemSusChem, Vol. 11, Issue 1
Precious-metal free photoelectrochemical water splitting with immobilised molecular Ni and Fe redox catalysts
journal, January 2016
- Rosser, Timothy E.; Gross, Manuela A.; Lai, Yi-Hsuan
- Chemical Science, Vol. 7, Issue 7
Application of transparent dye-sensitized solar cells to building integrated photovoltaic systems
journal, October 2011
- Yoon, Sanghoon; Tak, Sehyun; Kim, Jinsoo
- Building and Environment, Vol. 46, Issue 10
Solar water splitting by photovoltaic-electrolysis with a solar-to-hydrogen efficiency over 30%
journal, October 2016
- Jia, Jieyang; Seitz, Linsey C.; Benck, Jesse D.
- Nature Communications, Vol. 7, Issue 1
Cyclopentadithiophene Bridged Donor-Acceptor Dyes Achieve High Power Conversion Efficiencies in Dye-Sensitized Solar Cells Based on the tris-Cobalt Bipyridine Redox Couple
journal, May 2011
- Tsao , Hoi Nok; Yi , Chenyi; Moehl, Thomas
- ChemSusChem, Vol. 4, Issue 5
Efficient solar-to-fuels production from a hybrid microbial–water-splitting catalyst system
journal, February 2015
- Torella, Joseph P.; Gagliardi, Christopher J.; Chen, Janice S.
- Proceedings of the National Academy of Sciences, Vol. 112, Issue 8
The Role of Antireflective Coating CYTOP, Immersion Oil, and Sensitizer Selection in Fabricating a 2.3 V, 10% Power Conversion Efficiency SSM‐DSC Device
journal, February 2019
- Cheema, Hammad; Delcamp, Jared H.
- Advanced Energy Materials, Vol. 9, Issue 15
Ultrafast Fabrication of Flexible Dye-Sensitized Solar Cells by Ultrasonic Spray-Coating Technology
journal, September 2015
- Han, Hyun-Gyu; Weerasinghe, Hashitha C.; Min Kim, Kwang
- Scientific Reports, Vol. 5, Issue 1
Toward practical solar hydrogen production – an artificial photosynthetic leaf-to-farm challenge
journal, January 2019
- Kim, Jin Hyun; Hansora, Dharmesh; Sharma, Pankaj
- Chemical Society Reviews, Vol. 48, Issue 7
Artificial photosynthesis: opportunities and challenges of molecular catalysts
journal, January 2019
- Zhang, Biaobiao; Sun, Licheng
- Chemical Society Reviews, Vol. 48, Issue 7
Graphene Nanoplatelets Outperforming Platinum as the Electrocatalyst in Co-Bipyridine-Mediated Dye-Sensitized Solar Cells
journal, December 2011
- Kavan, Ladislav; Yum, Jun-Ho; Grätzel, Michael
- Nano Letters, Vol. 11, Issue 12