skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on January 30, 2021

Title: Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction

Authors:
 [1];  [1];  [1];  [2];  [3];  [2]; ORCiD logo [1]
  1. NanoScience Technology CenterDepartment of Materials Science and EngineeringEnergy Conversion and Propulsion ClusterUniversity of Central Florida Orlando FL 32826 USA
  2. School of ChemicalBiological, and Environmental EngineeringOregon State University Corvallis OR 97331 USA
  3. X‐Ray Science DivisionArgonne National Laboratory Argonne IL 60439 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1596383
Grant/Contract Number:  
DE‐AC02‐06CH11357
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Name: Advanced Energy Materials; Journal ID: ISSN 1614-6832
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
Germany
Language:
English

Citation Formats

Ju, Licheng, Wang, Guanzhi, Liang, Kun, Wang, Maoyu, Sterbinsky, George E., Feng, Zhenxing, and Yang, Yang. Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction. Germany: N. p., 2020. Web. doi:10.1002/aenm.201903333.
Ju, Licheng, Wang, Guanzhi, Liang, Kun, Wang, Maoyu, Sterbinsky, George E., Feng, Zhenxing, & Yang, Yang. Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction. Germany. doi:10.1002/aenm.201903333.
Ju, Licheng, Wang, Guanzhi, Liang, Kun, Wang, Maoyu, Sterbinsky, George E., Feng, Zhenxing, and Yang, Yang. Fri . "Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction". Germany. doi:10.1002/aenm.201903333.
@article{osti_1596383,
title = {Significantly Improved Cyclability of Conversion‐Type Transition Metal Oxyfluoride Cathodes by Homologous Passivation Layer Reconstruction},
author = {Ju, Licheng and Wang, Guanzhi and Liang, Kun and Wang, Maoyu and Sterbinsky, George E. and Feng, Zhenxing and Yang, Yang},
abstractNote = {},
doi = {10.1002/aenm.201903333},
journal = {Advanced Energy Materials},
number = ,
volume = ,
place = {Germany},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 30, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Crystal Chemistry and Selected Physical Properties of Inorganic Fluorides and Oxide-Fluorides
journal, August 2014

  • Leblanc, Marc; Maisonneuve, Vincent; Tressaud, Alain
  • Chemical Reviews, Vol. 115, Issue 2
  • DOI: 10.1021/cr500173c

Ultrathin ZnO coating for improved electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode material
journal, November 2014


TiO2 Nanotubes: Synthesis and Applications
journal, March 2011

  • Roy, Poulomi; Berger, Steffen; Schmuki, Patrik
  • Angewandte Chemie International Edition, Vol. 50, Issue 13
  • DOI: 10.1002/anie.201001374

Rapidly falling costs of battery packs for electric vehicles
journal, March 2015


Electrospun FeS 2 @Carbon Fiber Electrode as a High Energy Density Cathode for Rechargeable Lithium Batteries
journal, December 2015


Recent progress in surface coating of cathode materials for lithium ion secondary batteries
journal, June 2017


Conversion cathodes for rechargeable lithium and lithium-ion batteries
journal, January 2017

  • Wu, Feixiang; Yushin, Gleb
  • Energy & Environmental Science, Vol. 10, Issue 2
  • DOI: 10.1039/C6EE02326F

Photocatalytic Conversion of CO 2 into Renewable Hydrocarbon Fuels: State-of-the-Art Accomplishment, Challenges, and Prospects
journal, May 2014


Recent advances in the electrolytes for interfacial stability of high-voltage cathodes in lithium-ion batteries
journal, January 2015

  • Choi, Nam-Soon; Han, Jung-Gu; Ha, Se-Young
  • RSC Advances, Vol. 5, Issue 4
  • DOI: 10.1039/C4RA11575A

Influence of Fe Substitution into LaCoO 3 Electrocatalysts on Oxygen-Reduction Activity
journal, January 2019

  • Wang, Maoyu; Han, Binghong; Deng, Junjing
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 6
  • DOI: 10.1021/acsami.8b20780

Understanding Conversion-Type Electrodes for Lithium Rechargeable Batteries
journal, January 2018


Effect of CeO2-coating on the electrochemical performances of LiFePO4/C cathode material
journal, June 2011


30 Years of Lithium-Ion Batteries
journal, June 2018


Excellent cycle performance of Co-doped FeF3/C nanocomposite cathode material for lithium-ion batteries
journal, January 2012

  • Liu, Li; Zhou, Meng; Yi, Lanhua
  • Journal of Materials Chemistry, Vol. 22, Issue 34
  • DOI: 10.1039/c2jm32936k

Recent developments in cathode materials for lithium ion batteries
journal, February 2010


Activation and splitting of carbon dioxide on the surface of an inorganic electride material
journal, August 2013

  • Toda, Yoshitake; Hirayama, Hiroyuki; Kuganathan, Navaratnarajah
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3378

Challenges in the development of advanced Li-ion batteries: a review
journal, January 2011

  • Etacheri, Vinodkumar; Marom, Rotem; Elazari, Ran
  • Energy & Environmental Science, Vol. 4, Issue 9
  • DOI: 10.1039/c1ee01598b

Charge transfer kinetics at the solid–solid interface in porous electrodes
journal, April 2014

  • Bai, Peng; Bazant, Martin Z.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4585

First-principles study of iron oxyfluorides and lithiation of FeOF
journal, March 2013


The lithium-ion battery: State of the art and future perspectives
journal, June 2018

  • Zubi, Ghassan; Dufo-López, Rodolfo; Carvalho, Monica
  • Renewable and Sustainable Energy Reviews, Vol. 89
  • DOI: 10.1016/j.rser.2018.03.002

Freestanding NiFe Oxyfluoride Holey Film with Ultrahigh Volumetric Capacitance for Flexible Asymmetric Supercapacitors
journal, November 2017


Mitigating the capacity and voltage decay of lithium-rich layered oxide cathodes by fabricating Ni/Mn graded surface
journal, January 2017

  • Li, Feng; Wang, Yangyang; Gao, Shilun
  • Journal of Materials Chemistry A, Vol. 5, Issue 47
  • DOI: 10.1039/C7TA07659B

Suppressing Surface Lattice Oxygen Release of Li-Rich Cathode Materials via Heterostructured Spinel Li 4 Mn 5 O 12 Coating
journal, May 2018

  • Zhang, Xu-Dong; Shi, Ji-Lei; Liang, Jia-Yan
  • Advanced Materials, Vol. 30, Issue 29
  • DOI: 10.1002/adma.201801751

In Situ X-ray Absorption Spectroscopy Studies of Nanoscale Electrocatalysts
journal, June 2019


Thermal runaway mechanism of lithium ion battery for electric vehicles: A review
journal, January 2018


Oxygen Release Induced Chemomechanical Breakdown of Layered Cathode Materials
journal, April 2018


Effect of Mg doping and MgO-surface modification on the cycling stability of LiCoO2 electrodes
journal, August 2001


Role of surface coating on cathode materials for lithium-ion batteries
journal, January 2010

  • Chen, Zonghai; Qin, Yan; Amine, Khalil
  • Journal of Materials Chemistry, Vol. 20, Issue 36, p. 7606-7612
  • DOI: 10.1039/c0jm00154f

Flexible Three-Dimensional Nanoporous Metal-Based Energy Devices
journal, April 2014

  • Yang, Yang; Ruan, Gedeng; Xiang, Changsheng
  • Journal of the American Chemical Society, Vol. 136, Issue 17
  • DOI: 10.1021/ja501247f

A comprehensive review of lithium-ion batteries used in hybrid and electric vehicles at cold temperatures
journal, February 2016


Promises and challenges of nanomaterials for lithium-based rechargeable batteries
journal, June 2016


Cathode materials modified by surface coating for lithium ion batteries
journal, May 2006


Overall Water Splitting with Room-Temperature Synthesized NiFe Oxyfluoride Nanoporous Films
journal, November 2017


Li-ion battery materials: present and future
journal, June 2015


Understanding and recent development of carbon coating on LiFePO 4 cathode materials for lithium-ion batteries
journal, January 2012

  • Wang, Jiajun; Sun, Xueliang
  • Energy Environ. Sci., Vol. 5, Issue 1
  • DOI: 10.1039/C1EE01263K

A review of state of health and remaining useful life estimation methods for lithium-ion battery in electric vehicles: Challenges and recommendations
journal, December 2018


The Co-estimation of State of Charge, State of Health, and State of Function for Lithium-Ion Batteries in Electric Vehicles
journal, January 2018

  • Shen, Ping; Ouyang, Minggao; Lu, Languang
  • IEEE Transactions on Vehicular Technology, Vol. 67, Issue 1
  • DOI: 10.1109/TVT.2017.2751613

Layered Li[Ni[sub x]Co[sub 1−2x]Mn[sub x]]O[sub 2] Cathode Materials for Lithium-Ion Batteries
journal, January 2001

  • Lu, Zhonghua; MacNeil, D. D.; Dahn, J. R.
  • Electrochemical and Solid-State Letters, Vol. 4, Issue 12
  • DOI: 10.1149/1.1413182

Total-electron-yield current measurements for near-surface extended x-ray-absorption fine structure
journal, February 1988


Dissolution, migration, and deposition of transition metal ions in Li-ion batteries exemplified by Mn-based cathodes – a critical review
journal, January 2018

  • Zhan, Chun; Wu, Tianpin; Lu, Jun
  • Energy & Environmental Science, Vol. 11, Issue 2
  • DOI: 10.1039/C7EE03122J

Promise and reality of post-lithium-ion batteries with high energy densities
journal, March 2016


Chemical vapor deposition and atomic layer deposition for advanced lithium ion batteries and supercapacitors
journal, January 2015

  • Wang, Xinran; Yushin, Gleb
  • Energy & Environmental Science, Vol. 8, Issue 7
  • DOI: 10.1039/C5EE01254F