Chemically fueled covalent crosslinking of polymer materials

Zhang, Borui; Jayalath, Isuru M.; Ke, Jun; Sparks, Jessica L.; Hartley, C. Scott; Konkolewicz, Dominik

doi:10.1039/C8CC09823A

Title: Chemically fueled covalent crosslinking of polymer materials

Journal Article · 21 January 2019 · ChemComm

DOI: https://doi.org/10.1039/C8CC09823A · OSTI ID:1596011

Zhang, Borui ^[1];

^[1]; Ke, Jun ^[1]; Sparks, Jessica L. ^[1];

^[1];

^[1]

Miami Univ., Oxford, OH (United States)

Non-equilibrium covalently crosslinked hydrogels are synthesized using carbodiimide fueled coupling of carboxylic acids to anhydrides which eventually dissipate by hydrolysis.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Miami Univ., Oxford, OH (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0018645

OSTI ID:: 1596011

Alternate ID(s):: OSTI ID: 1492742

Journal Information:: ChemComm, Vol. 55, Issue 14; Related Information: Raw experimental data: http://hdl.handle.net/2374.MIA/6342; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

References (28)

Self-Assembly at All Scales Whitesides, George M.; Grzybowski, Bartosz Science, Vol. 295, Issue 5564, p. 2418-2421 https://doi.org/10.1126/science.1070821	journal	March 2002
Transient self-assembly of molecular nanostructures driven by chemical fuels della Sala, Flavio; Neri, Simona; Maiti, Subhabrata Current Opinion in Biotechnology, Vol. 46 https://doi.org/10.1016/j.copbio.2016.10.014	journal	August 2017
Dissipative out-of-equilibrium assembly of man-made supramolecular materials van Rossum, Susan A. P.; Tena-Solsona, Marta; van Esch, Jan H. Chemical Society Reviews, Vol. 46, Issue 18 https://doi.org/10.1039/C7CS00246G	journal	January 2017
Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel Boekhoven, Job; Brizard, Aurelie M.; Kowlgi, Krishna N. K. Angewandte Chemie International Edition, Vol. 49, Issue 28 https://doi.org/10.1002/anie.201001511	journal	May 2010
Transient assembly of active materials fueled by a chemical reaction Boekhoven, J.; Hendriksen, W. E.; Koper, G. J. M. Science, Vol. 349, Issue 6252 https://doi.org/10.1126/science.aac6103	journal	September 2015
Fuel-Controlled Reassembly of Metal–Organic Architectures Wood, Christopher S.; Browne, Colm; Wood, Daniel M. ACS Central Science, Vol. 1, Issue 9 https://doi.org/10.1021/acscentsci.5b00279	journal	December 2015
An autonomous chemically fuelled small-molecule motor Wilson, Miriam R.; Solà, Jordi; Carlone, Armando Nature, Vol. 534, Issue 7606 https://doi.org/10.1038/nature18013	journal	June 2016
Supramolecular pathway selection of perylenediimides mediated by chemical fuels Leira-Iglesias, Jorge; Sorrenti, Alessandro; Sato, Akihiro Chemical Communications, Vol. 52, Issue 58 https://doi.org/10.1039/C6CC01192F	journal	January 2016
Fuel-Mediated Transient Clustering of Colloidal Building Blocks van Ravensteijn, Bas G. P.; Hendriksen, Wouter E.; Eelkema, Rienk Journal of the American Chemical Society, Vol. 139, Issue 29 https://doi.org/10.1021/jacs.7b03263	journal	July 2017
Non-equilibrium dissipative supramolecular materials with a tunable lifetime Tena-Solsona, Marta; Rieß, Benedikt; Grötsch, Raphael K. Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms15895	journal	July 2017
Self-selection of dissipative assemblies driven by primitive chemical reaction networks Tena-Solsona, Marta; Wanzke, Caren; Riess, Benedikt Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-04488-y	journal	May 2018
Dissipative assemblies that inhibit their deactivation Rieß, Benedikt; Wanzke, Caren; Tena-Solsona, Marta Soft Matter, Vol. 14, Issue 23 https://doi.org/10.1039/C8SM00822A	journal	January 2018
Dissipative Assembly of Aqueous Carboxylic Acid Anhydrides Fueled by Carbodiimides Kariyawasam, Lasith S.; Hartley, C. Scott Journal of the American Chemical Society, Vol. 139, Issue 34 https://doi.org/10.1021/jacs.7b06099	journal	August 2017
50th Anniversary Perspective : RAFT Polymerization—A User Guide Perrier, Sébastien Macromolecules, Vol. 50, Issue 19 https://doi.org/10.1021/acs.macromol.7b00767	journal	September 2017
The pyridine catalysed hydrolysis of carboxylic anhydrides Bunton, C. A.; Fuller, N. A.; Perry, S. G. Tetrahedron Letters, Vol. 2, Issue 14 https://doi.org/10.1016/S0040-4039(00)71753-9	journal	January 1961
Rheological Study and Molecular Dynamics Simulation of Biopolymer Blend Thermogels of Tunable Strength Dashtimoghadam, Erfan; Bahlakeh, Ghasem; Salimi-Kenari, Hamed Biomacromolecules, Vol. 17, Issue 11 https://doi.org/10.1021/acs.biomac.6b00846	journal	September 2016
Strength and sorption capacity modulation of carboxymethylcellulose hydrogels in presence of ester-bonded gemini surfactants Shalla, Aabid Hussain; Rangreez, Tauseef Ahmad; Rizvi, Masood Ahmad Journal of Molecular Liquids, Vol. 238 https://doi.org/10.1016/j.molliq.2017.04.125	journal	July 2017
Thermoreversible Hyaluronic Acid-PNIPAAm Hydrogel Systems for 3D Stem Cell Culture Ekerdt, Barbara L.; Fuentes, Christina M.; Lei, Yuguo Advanced Healthcare Materials, Vol. 7, Issue 12 https://doi.org/10.1002/adhm.201800225	journal	May 2018
Novel Mussel-Inspired Injectable Self-Healing Hydrogel with Anti-Biofouling Property Li, Lin; Yan, Bin; Yang, Jingqi Advanced Materials, Vol. 27, Issue 7 https://doi.org/10.1002/adma.201405166	journal	January 2015
Rheological Characterization of in Situ Crosslinkable Hydrogels Formulated from Oxidized Dextran and N -Carboxyethyl Chitosan Weng, Lihui; Chen, Xuming; Chen, Weiliam Biomacromolecules, Vol. 8, Issue 4 https://doi.org/10.1021/bm0610065	journal	April 2007
Stochastic pumping of non-equilibrium steady-states: how molecules adapt to a fluctuating environment Astumian, R. D. Chemical Communications, Vol. 54, Issue 5 https://doi.org/10.1039/C7CC06683J	journal	January 2018
A new approach for handling and transferring of thin semiconductor materials Bagdahn, J.; Knoll, H.; Wiemer, M. Microsystem Technologies, Vol. 9, Issue 3 https://doi.org/10.1007/s00542-002-0226-2	journal	January 2003
Peptide Nanofibers with Dynamic Instability through Nonequilibrium Biocatalytic Assembly Debnath, Sisir; Roy, Sangita; Ulijn, Rein V. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja4086353	journal	October 2013
Biocatalytic Feedback-Driven Temporal Programming of Self-Regulating Peptide Hydrogels Heuser, Thomas; Weyandt, Elisabeth; Walther, Andreas Angewandte Chemie International Edition, Vol. 54, Issue 45 https://doi.org/10.1002/anie.201505013	journal	August 2015
Sucrose-fueled, energy dissipative, transient formation of molecular hydrogels mediated by yeast activity Angulo-Pachón, César A.; Miravet, Juan F. Chemical Communications, Vol. 52, Issue 31 https://doi.org/10.1039/C6CC01183G	journal	January 2016
Kinetically Controlled Lifetimes in Redox-Responsive Transient Supramolecular Hydrogels Wojciechowski, Jonathan P.; Martin, Adam D.; Thordarson, Pall Journal of the American Chemical Society, Vol. 140, Issue 8 https://doi.org/10.1021/jacs.7b12198	journal	February 2018
Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel Boekhoven, Job; Brizard, Aurelie M.; Kowlgi, Krishna N. K. Angewandte Chemie, Vol. 122, Issue 28 https://doi.org/10.1002/ange.201001511	journal	May 2010
Biocatalytic Feedback‐Driven Temporal Programming of Self‐Regulating Peptide Hydrogels Heuser, Thomas; Weyandt, Elisabeth; Walther, Andreas Angewandte Chemie, Vol. 127, Issue 45 https://doi.org/10.1002/ange.201505013	journal	August 2015

Cited By (3)

Hydrogels with Preprogrammable Lifetime via UV‐Induced Polymerization and Degradation Scheiger, Johannes M.; Levkin, Pavel A. Advanced Functional Materials, Vol. 30, Issue 26 https://doi.org/10.1002/adfm.201909800	journal	January 2020
Temporally‐Programmed Transient Supramolecular Gels Panja, Santanu; Patterson, Courtenay; Adams, Dave J. Macromolecular Rapid Communications https://doi.org/10.1002/marc.201900251	journal	June 2019
Chemically Fuelled Self‐Regulating Gel‐to‐Gel Transition Panja, Santanu; Dietrich, Bart; Adams, Dave J. ChemSystemsChem, Vol. 2, Issue 1 https://doi.org/10.1002/syst.201900038	journal	October 2019

Similar Records

Photoresponsive polymers for carbodiimide-fueled transient hydrogels

Journal Article · 2025 · Polymer Chemistry · OSTI ID:2519292

Raji, Ibrahim O.; Wilcox, Torin C.; Hartley, C. Scott; +1 more

Chemically Fueled Reinforcement of Polymer Hydrogels

Journal Article · 2023 · Journal of the American Chemical Society · OSTI ID:1963799

Rajawasam, Chamoni W. H.; Tran, Corvo; Weeks, Michael; +6 more

Tailoring Lifetimes and Properties of Carbodiimide-Fueled Covalently Cross-linked Polymer Networks

Journal Article · 2021 · Macromolecules · OSTI ID:1879882

Dodo, Obed J.; Petit, Leilah; Rajawasam, Chamoni W. H.; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
Dissipative assembly
polymer networks

Title: Chemically fueled covalent crosslinking of polymer materials

Citation Formats

References (28)

Cited By (3)

Similar Records

Related Subjects