Chemically fueled covalent crosslinking of polymer materials
Abstract
Non-equilibrium covalently crosslinked hydrogels are synthesized using carbodiimide fueled coupling of carboxylic acids to anhydrides which eventually dissipate by hydrolysis.
- Publication Date:
- Research Org.:
- Miami Univ., Oxford, OH (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1596011
- Alternate Identifier(s):
- OSTI ID: 1492742
- Grant/Contract Number:
- SC0018645
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 55; Journal Issue: 14; Related Information: Raw experimental data: http://hdl.handle.net/2374.MIA/6342; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; Dissipative assembly; polymer networks
Citation Formats
Zhang, Borui, Jayalath, Isuru M., Ke, Jun, Sparks, Jessica L., Hartley, C. Scott, and Konkolewicz, Dominik. Chemically fueled covalent crosslinking of polymer materials. United States: N. p., 2019.
Web. doi:10.1039/C8CC09823A.
Zhang, Borui, Jayalath, Isuru M., Ke, Jun, Sparks, Jessica L., Hartley, C. Scott, & Konkolewicz, Dominik. Chemically fueled covalent crosslinking of polymer materials. United States. https://doi.org/10.1039/C8CC09823A
Zhang, Borui, Jayalath, Isuru M., Ke, Jun, Sparks, Jessica L., Hartley, C. Scott, and Konkolewicz, Dominik. Mon .
"Chemically fueled covalent crosslinking of polymer materials". United States. https://doi.org/10.1039/C8CC09823A. https://www.osti.gov/servlets/purl/1596011.
@article{osti_1596011,
title = {Chemically fueled covalent crosslinking of polymer materials},
author = {Zhang, Borui and Jayalath, Isuru M. and Ke, Jun and Sparks, Jessica L. and Hartley, C. Scott and Konkolewicz, Dominik},
abstractNote = {Non-equilibrium covalently crosslinked hydrogels are synthesized using carbodiimide fueled coupling of carboxylic acids to anhydrides which eventually dissipate by hydrolysis.},
doi = {10.1039/C8CC09823A},
journal = {ChemComm},
number = 14,
volume = 55,
place = {United States},
year = {Mon Jan 21 00:00:00 EST 2019},
month = {Mon Jan 21 00:00:00 EST 2019}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 41 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Self-Assembly at All Scales
journal, March 2002
- Whitesides, George M.; Grzybowski, Bartosz
- Science, Vol. 295, Issue 5564, p. 2418-2421
Transient self-assembly of molecular nanostructures driven by chemical fuels
journal, August 2017
- della Sala, Flavio; Neri, Simona; Maiti, Subhabrata
- Current Opinion in Biotechnology, Vol. 46
Dissipative out-of-equilibrium assembly of man-made supramolecular materials
journal, January 2017
- van Rossum, Susan A. P.; Tena-Solsona, Marta; van Esch, Jan H.
- Chemical Society Reviews, Vol. 46, Issue 18
Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel
journal, May 2010
- Boekhoven, Job; Brizard, Aurelie M.; Kowlgi, Krishna N. K.
- Angewandte Chemie International Edition, Vol. 49, Issue 28
Transient assembly of active materials fueled by a chemical reaction
journal, September 2015
- Boekhoven, J.; Hendriksen, W. E.; Koper, G. J. M.
- Science, Vol. 349, Issue 6252
Fuel-Controlled Reassembly of Metal–Organic Architectures
journal, December 2015
- Wood, Christopher S.; Browne, Colm; Wood, Daniel M.
- ACS Central Science, Vol. 1, Issue 9
An autonomous chemically fuelled small-molecule motor
journal, June 2016
- Wilson, Miriam R.; Solà, Jordi; Carlone, Armando
- Nature, Vol. 534, Issue 7606
Supramolecular pathway selection of perylenediimides mediated by chemical fuels
journal, January 2016
- Leira-Iglesias, Jorge; Sorrenti, Alessandro; Sato, Akihiro
- Chemical Communications, Vol. 52, Issue 58
Fuel-Mediated Transient Clustering of Colloidal Building Blocks
journal, July 2017
- van Ravensteijn, Bas G. P.; Hendriksen, Wouter E.; Eelkema, Rienk
- Journal of the American Chemical Society, Vol. 139, Issue 29
Non-equilibrium dissipative supramolecular materials with a tunable lifetime
journal, July 2017
- Tena-Solsona, Marta; Rieß, Benedikt; Grötsch, Raphael K.
- Nature Communications, Vol. 8, Issue 1
Self-selection of dissipative assemblies driven by primitive chemical reaction networks
journal, May 2018
- Tena-Solsona, Marta; Wanzke, Caren; Riess, Benedikt
- Nature Communications, Vol. 9, Issue 1
Dissipative assemblies that inhibit their deactivation
journal, January 2018
- Rieß, Benedikt; Wanzke, Caren; Tena-Solsona, Marta
- Soft Matter, Vol. 14, Issue 23
Dissipative Assembly of Aqueous Carboxylic Acid Anhydrides Fueled by Carbodiimides
journal, August 2017
- Kariyawasam, Lasith S.; Hartley, C. Scott
- Journal of the American Chemical Society, Vol. 139, Issue 34
50th Anniversary Perspective : RAFT Polymerization—A User Guide
journal, September 2017
- Perrier, Sébastien
- Macromolecules, Vol. 50, Issue 19
The pyridine catalysed hydrolysis of carboxylic anhydrides
journal, January 1961
- Bunton, C. A.; Fuller, N. A.; Perry, S. G.
- Tetrahedron Letters, Vol. 2, Issue 14
Rheological Study and Molecular Dynamics Simulation of Biopolymer Blend Thermogels of Tunable Strength
journal, September 2016
- Dashtimoghadam, Erfan; Bahlakeh, Ghasem; Salimi-Kenari, Hamed
- Biomacromolecules, Vol. 17, Issue 11
Strength and sorption capacity modulation of carboxymethylcellulose hydrogels in presence of ester-bonded gemini surfactants
journal, July 2017
- Shalla, Aabid Hussain; Rangreez, Tauseef Ahmad; Rizvi, Masood Ahmad
- Journal of Molecular Liquids, Vol. 238
Thermoreversible Hyaluronic Acid-PNIPAAm Hydrogel Systems for 3D Stem Cell Culture
journal, May 2018
- Ekerdt, Barbara L.; Fuentes, Christina M.; Lei, Yuguo
- Advanced Healthcare Materials, Vol. 7, Issue 12
Novel Mussel-Inspired Injectable Self-Healing Hydrogel with Anti-Biofouling Property
journal, January 2015
- Li, Lin; Yan, Bin; Yang, Jingqi
- Advanced Materials, Vol. 27, Issue 7
Rheological Characterization of in Situ Crosslinkable Hydrogels Formulated from Oxidized Dextran and N -Carboxyethyl Chitosan
journal, April 2007
- Weng, Lihui; Chen, Xuming; Chen, Weiliam
- Biomacromolecules, Vol. 8, Issue 4
Stochastic pumping of non-equilibrium steady-states: how molecules adapt to a fluctuating environment
journal, January 2018
- Astumian, R. D.
- Chemical Communications, Vol. 54, Issue 5
A new approach for handling and transferring of thin semiconductor materials
journal, January 2003
- Bagdahn, J.; Knoll, H.; Wiemer, M.
- Microsystem Technologies, Vol. 9, Issue 3
Peptide Nanofibers with Dynamic Instability through Nonequilibrium Biocatalytic Assembly
journal, October 2013
- Debnath, Sisir; Roy, Sangita; Ulijn, Rein V.
- Journal of the American Chemical Society, Vol. 135, Issue 45
Biocatalytic Feedback-Driven Temporal Programming of Self-Regulating Peptide Hydrogels
journal, August 2015
- Heuser, Thomas; Weyandt, Elisabeth; Walther, Andreas
- Angewandte Chemie International Edition, Vol. 54, Issue 45
Sucrose-fueled, energy dissipative, transient formation of molecular hydrogels mediated by yeast activity
journal, January 2016
- Angulo-Pachón, César A.; Miravet, Juan F.
- Chemical Communications, Vol. 52, Issue 31
Kinetically Controlled Lifetimes in Redox-Responsive Transient Supramolecular Hydrogels
journal, February 2018
- Wojciechowski, Jonathan P.; Martin, Adam D.; Thordarson, Pall
- Journal of the American Chemical Society, Vol. 140, Issue 8
Dissipative Self-Assembly of a Molecular Gelator by Using a Chemical Fuel
journal, May 2010
- Boekhoven, Job; Brizard, Aurelie M.; Kowlgi, Krishna N. K.
- Angewandte Chemie, Vol. 122, Issue 28
Biocatalytic Feedback‐Driven Temporal Programming of Self‐Regulating Peptide Hydrogels
journal, August 2015
- Heuser, Thomas; Weyandt, Elisabeth; Walther, Andreas
- Angewandte Chemie, Vol. 127, Issue 45
Works referencing / citing this record:
Hydrogels with Preprogrammable Lifetime via UV‐Induced Polymerization and Degradation
journal, January 2020
- Scheiger, Johannes M.; Levkin, Pavel A.
- Advanced Functional Materials, Vol. 30, Issue 26
Temporally‐Programmed Transient Supramolecular Gels
journal, June 2019
- Panja, Santanu; Patterson, Courtenay; Adams, Dave J.
- Macromolecular Rapid Communications
Chemically Fuelled Self‐Regulating Gel‐to‐Gel Transition
journal, October 2019
- Panja, Santanu; Dietrich, Bart; Adams, Dave J.
- ChemSystemsChem, Vol. 2, Issue 1