The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Postmodification

Kim, In Soo; Ahn, Sol; Vermeulen, Nicolaas A.; Webber, Thomas E.; Gallington, Leighanne C.; Chapman, Karena W.; Penn, R. Lee; Hupp, Joseph T.; Farha, Omar K.; Notestein, Justin M.; Martinson, Alex B. F.

doi:10.1021/jacs.9b10034

Title: The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Postmodification

Journal Article · 18 December 2019 · Journal of the American Chemical Society

DOI: https://doi.org/10.1021/jacs.9b10034 · OSTI ID:1595952

Kim, In Soo ^[1];

^[2]; Vermeulen, Nicolaas A. ^[3];

^[4];

^[5];

^[6];

^[4];

^[3];

^[7]

Argonne National Lab. (ANL), Lemont, IL (United States); Korea Inst. of Science and Technology (KIST), Seoul (Korea)
Northwestern Univ., Evanston, IL (United States); Univ. of California, Berkeley, CA (United States)
Northwestern Univ., Evanston, IL (United States)
Univ. of Minnesota, Minneapolis, MN (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Stony Brook Univ., NY (United States)
Argonne National Lab. (ANL), Lemont, IL (United States)

The postmodification of metal organic frameworks (MOFs) affords exceedingly high surface area materials with precisely installed chemical features, which provide new opportunities for detailed structure function correlation in the field of catalysis. Here, we significantly expand upon the number of vapor-phase postmodification processes reported to date through screening a library of atomic layer deposition (ALD) precursors, which span metals across the periodic table and which include ligands from four distinct precursor classes. Furthermore, with a large library of precursors and synthesis conditions, we discern trends in the compatibility of precursor classes for well-behaved ALD in MOFs (AIM) and identify challenges and solutions to more precise postsynthetic modification.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; SC0012702

OSTI ID:: 1595952

Journal Information:: Journal of the American Chemical Society, Vol. 142, Issue 1; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 25 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
oxides
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precursors
metal organic frameworks
atomic layer deposition
vapor phase
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Title: The Synthesis Science of Targeted Vapor-Phase Metal–Organic Framework Postmodification

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