Synthesis of lead-free Cs 3 Sb 2 Br 9 perovskite alternative nanocrystals with enhanced photocatalytic CO 2 reduction activity

Lu, Chang; Itanze, Dominique S.; Aragon, Alexander G.; Ma, Xiao; Li, Hui; Ucer, Kamil B.; Hewitt, Corey; Carroll, David L.; Williams, Richard T.; Qiu, Yejun; Geyer, Scott M.

doi:10.1039/C9NR07722G

Title: Synthesis of lead-free Cs ₃ Sb ₂ Br ₉ perovskite alternative nanocrystals with enhanced photocatalytic CO ₂ reduction activity

Journal Article · 05 February 2020 · Nanoscale

DOI: https://doi.org/10.1039/C9NR07722G · OSTI ID:1595859

Lu, Chang ^[1]; Itanze, Dominique S. ^[1]; Aragon, Alexander G. ^[1]; Ma, Xiao ^[1]; Li, Hui ^[1];

^[2]; Hewitt, Corey ^[3]; Carroll, David L. ^[3]; Williams, Richard T. ^[2];

^[4];

^[1]

Department of Chemistry, Wake Forest University, Winston-Salem, USA
Center for Nanotechnology and Molecular Materials, Wake Forest University, Winston-Salem, USA
Center for Nanotechnology and Molecular Materials, Wake Forest University, Winston-Salem, USA, Department of Physics
Shenzhen Engineering Lab of Flexible Transparent Conductive Films, Department of Materials Science and Engineering, Harbin Institute of Technology, Shenzhen, China

High purity synthesis yields Cs ₃ Sb ₂ Br ₉ nanocrystals exhibiting 10-fold higher CO ₂ reduction activity then CsPbBr ₃ due to exposure of active site.

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Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1595859

Journal Information:: Nanoscale, Journal Name: Nanoscale Journal Issue: 5 Vol. 12; ISSN NANOHL; ISSN 2040-3364

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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Title: Synthesis of lead-free Cs ₃ Sb ₂ Br ₉ perovskite alternative nanocrystals with enhanced photocatalytic CO ₂ reduction activity