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Title: Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol

Authors:
ORCiD logo [1];  [1];  [1];  [2];  [3];  [4]; ORCiD logo [5]
  1. School of Chemistry and BiochemistryGeorgia Institute of Technology Atlanta GA 30332 USA
  2. School of Chemistry and BiochemistryGeorgia Institute of Technology Atlanta GA 30332 USA, Center for Nanophase Materials SciencesOak Ridge National Laboratory Oak Ridge TN 37831 USA
  3. The Wallace H. Coulter Department of Biomedical EngineeringGeorgia Institute of Technology and Emory University Atlanta GA 30332 USA
  4. Center for Nanophase Materials SciencesOak Ridge National Laboratory Oak Ridge TN 37831 USA
  5. School of Chemistry and BiochemistryGeorgia Institute of Technology Atlanta GA 30332 USA, The Wallace H. Coulter Department of Biomedical EngineeringGeorgia Institute of Technology and Emory University Atlanta GA 30332 USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1595857
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Small Methods
Additional Journal Information:
Journal Name: Small Methods; Journal ID: ISSN 2366-9608
Publisher:
Wiley Blackwell (John Wiley & Sons)
Country of Publication:
United States
Language:
English

Citation Formats

Zhao, Ming, Lyu, Zhiheng, Xie, Minghao, Hood, Zachary D., Cao, Zhenming, Chi, Miaofang, and Xia, Younan. Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol. United States: N. p., 2020. Web. doi:10.1002/smtd.201900843.
Zhao, Ming, Lyu, Zhiheng, Xie, Minghao, Hood, Zachary D., Cao, Zhenming, Chi, Miaofang, & Xia, Younan. Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol. United States. doi:10.1002/smtd.201900843.
Zhao, Ming, Lyu, Zhiheng, Xie, Minghao, Hood, Zachary D., Cao, Zhenming, Chi, Miaofang, and Xia, Younan. Wed . "Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol". United States. doi:10.1002/smtd.201900843.
@article{osti_1595857,
title = {Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol},
author = {Zhao, Ming and Lyu, Zhiheng and Xie, Minghao and Hood, Zachary D. and Cao, Zhenming and Chi, Miaofang and Xia, Younan},
abstractNote = {},
doi = {10.1002/smtd.201900843},
journal = {Small Methods},
number = ,
volume = ,
place = {United States},
year = {2020},
month = {1}
}

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This content will become publicly available on January 28, 2021
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Works referenced in this record:

Nanoflowers of PdRu on PEDOT for Electrooxidation of Glycerol and Its Analysis
journal, October 2015


CO adsorption on close-packed transition and noble metal surfaces: trends from ab initio calculations
journal, February 2004

  • Gajdo, Marek; Eichler, Andreas; Hafner, Jürgen
  • Journal of Physics: Condensed Matter, Vol. 16, Issue 8
  • DOI: 10.1088/0953-8984/16/8/001

Ru Nanoframes with an fcc Structure and Enhanced Catalytic Properties
journal, March 2016


Synthesis of Palladium Nanoscale Octahedra through a One-Pot, Dual-Reductant Route and Kinetic Analysis
journal, March 2018

  • Figueroa-Cosme, Legna; Gilroy, Kyle D.; Yang, Tung-Han
  • Chemistry - A European Journal, Vol. 24, Issue 23
  • DOI: 10.1002/chem.201705720

Small Adsorbate-Assisted Shape Control of Pd and Pt Nanocrystals
journal, January 2012


Concave Pd–Ru nanocubes bounded with high active area for boosting ethylene glycol electrooxidation
journal, January 2018


Pt–Ag cubic nanocages with wall thickness less than 2 nm and their enhanced catalytic activity toward oxygen reduction
journal, January 2017

  • Sun, Xiaojun; Yang, Xuan; Zhang, Yun
  • Nanoscale, Vol. 9, Issue 39
  • DOI: 10.1039/C7NR04366J

Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages
journal, July 2018


Synthesis and Characterization of Ru Cubic Nanocages with a Face-Centered Cubic Structure by Templating with Pd Nanocubes
journal, August 2016


Best Practices in Pursuit of Topics in Heterogeneous Electrocatalysis
journal, August 2017


Rational design and synthesis of bifunctional metal nanocrystals for probing catalytic reactions by surface-enhanced Raman scattering
journal, January 2018

  • Zhang, Yun; Wu, Yiren; Qin, Dong
  • Journal of Materials Chemistry C, Vol. 6, Issue 20
  • DOI: 10.1039/C8TC01394B

Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability
journal, January 2014

  • Kusada, Kohei; Kobayashi, Hirokazu; Ikeda, Ryuichi
  • Journal of the American Chemical Society, Vol. 136, Issue 5
  • DOI: 10.1021/ja409464g

Single-layered platinum nanocage: a highly selective and efficient catalyst for fuel cells
journal, January 2016

  • Mahata, Arup; Rawat, Kuber Singh; Choudhuri, Indrani
  • Journal of Materials Chemistry A, Vol. 4, Issue 33
  • DOI: 10.1039/C6TA03245A

Poisonous Species in Complete Ethanol Oxidation Reaction on Palladium Catalysts
journal, July 2019

  • Wu, Zhi-Peng; Miao, Bei; Hopkins, Emma
  • The Journal of Physical Chemistry C, Vol. 123, Issue 34
  • DOI: 10.1021/acs.jpcc.9b04229

Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells
journal, September 2009

  • Bianchini, Claudio; Shen, Pei Kang
  • Chemical Reviews, Vol. 109, Issue 9
  • DOI: 10.1021/cr9000995

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
journal, March 2008

  • Alayoglu, Selim; Nilekar, Anand U.; Mavrikakis, Manos
  • Nature Materials, Vol. 7, Issue 4, p. 333-338
  • DOI: 10.1038/nmat2156

Syntheses and Properties of Metal Nanomaterials with Novel Crystal Phases
journal, April 2018

  • Cheng, Hongfei; Yang, Nailiang; Lu, Qipeng
  • Advanced Materials, Vol. 30, Issue 26
  • DOI: 10.1002/adma.201707189

Vegard’s law
journal, March 1991


CO Chemisorption at Metal Surfaces and Overlayers
journal, March 1996


Ru Octahedral Nanocrystals with a Face-Centered Cubic Structure, {111} Facets, Thermal Stability up to 400 °C, and Enhanced Catalytic Activity
journal, April 2019

  • Zhao, Ming; Chen, Zitao; Lyu, Zhiheng
  • Journal of the American Chemical Society, Vol. 141, Issue 17
  • DOI: 10.1021/jacs.9b01640

Synthesis of Pd nanocrystals enclosed by {100} facets and with sizes <10 nm for application in CO oxidation
journal, October 2010


RuPd Alloy Nanoparticles Supported on N-Doped Carbon as an Efficient and Stable Catalyst for Benzoic Acid Hydrogenation
journal, March 2015


Icosahedral nanocrystals of noble metals: Synthesis and applications
journal, August 2017


Decahedral nanocrystals of noble metals: Synthesis, characterization, and applications
journal, January 2019


Recent Advances in Materials for Fuel Cells
journal, August 2003


Shape-controlled synthesis of ruthenium nanocrystals and their catalytic applications
journal, January 2014

  • Chen, Guozhu; Zhang, Jianming; Gupta, Akanksha
  • New J. Chem., Vol. 38, Issue 5
  • DOI: 10.1039/C3NJ01155K

Ruthenium Nanoframes in the Face-Centered Cubic Phase: Facile Synthesis and Their Enhanced Catalytic Performance
journal, May 2019


Direct fabrication of bi-metallic PdRu nanorod assemblies for electrochemical ammonia synthesis
journal, January 2019

  • Wang, Hongjing; Li, Yinghao; Yang, Dandan
  • Nanoscale, Vol. 11, Issue 12
  • DOI: 10.1039/C8NR10398D

One-Pot Synthesis of Cubic PtCu 3 Nanocages with Enhanced Electrocatalytic Activity for the Methanol Oxidation Reaction
journal, August 2012

  • Xia, Bao Yu; Wu, Hao Bin; Wang, Xin
  • Journal of the American Chemical Society, Vol. 134, Issue 34
  • DOI: 10.1021/ja3051662

Polyol Syntheses of Palladium Decahedra and Icosahedra as Pure Samples by Maneuvering the Reaction Kinetics with Additives
journal, June 2014

  • Huang, Hongwen; Wang, Yi; Ruditskiy, Aleksey
  • ACS Nano, Vol. 8, Issue 7
  • DOI: 10.1021/nn501919e

Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells
journal, November 2019


Platinum Group Nanowires for Efficient Electrocatalysis
journal, January 2019


Halide-regulated growth of electrocatalytic metal nanoparticles directly onto a carbon paper electrode
journal, January 2016

  • Holade, Yaovi; Hickey, David P.; Minteer, Shelley D.
  • Journal of Materials Chemistry A, Vol. 4, Issue 43
  • DOI: 10.1039/C6TA08288B

Recent achievements in direct ethylene glycol fuel cells (DEGFC)
journal, June 2010


Octahedral Pd nanocages with porous shells converted from Co(OH) 2 nanocages with nanosheet surfaces as robust electrocatalysts for ethanol oxidation
journal, January 2018

  • Sheng, Jiali; Kang, Jiahui; Hu, Zhixiong
  • Journal of Materials Chemistry A, Vol. 6, Issue 32
  • DOI: 10.1039/C8TA04181D

Shape-Controlled Synthesis of Pd Nanocrystals and Their Catalytic Applications
journal, November 2012

  • Zhang, Hui; Jin, Mingshang; Xiong, Yujie
  • Accounts of Chemical Research, Vol. 46, Issue 8
  • DOI: 10.1021/ar300209w

Relationships between Atomic Level Surface Structure and Stability/Activity of Platinum Surface Atoms in Aqueous Environments
journal, March 2016


Toward affordable and sustainable use of precious metals in catalysis and nanomedicine
journal, November 2018


Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges
journal, April 2012

  • Rabis, Annett; Rodriguez, Paramaconi; Schmidt, Thomas J.
  • ACS Catalysis, Vol. 2, Issue 5
  • DOI: 10.1021/cs3000864

Facile Synthesis of Ru-Based Octahedral Nanocages with Ultrathin Walls in a Face-Centered Cubic Structure
journal, October 2017


25th Anniversary Article: Galvanic Replacement: A Simple and Versatile Route to Hollow Nanostructures with Tunable and Well-Controlled Properties
journal, September 2013


Shape‐Controlled Synthesis of Colloidal Metal Nanocrystals by Replicating the Surface Atomic Structure on the Seed
journal, April 2018


New understandings of ethanol oxidation reaction mechanism on Pd/C and Pd2Ru/C catalysts in alkaline direct ethanol fuel cells
journal, May 2018


Ru-assisted synthesis of Pd/Ru nanodendrites with high activity for ethanol electrooxidation
journal, January 2015


Porous octahedral PdCu nanocages as highly efficient electrocatalysts for the methanol oxidation reaction
journal, January 2018

  • Sheng, Jiali; Kang, Jiahui; Ye, Huangqing
  • Journal of Materials Chemistry A, Vol. 6, Issue 9
  • DOI: 10.1039/C7TA07879J

Hollow and Cage-Bell Structured Nanomaterials of Noble Metals
journal, July 2012

  • Liu, Hui; Qu, Jianglan; Chen, Yunfa
  • Journal of the American Chemical Society, Vol. 134, Issue 28
  • DOI: 10.1021/ja302518n

Template Synthesis of Noble Metal Nanocrystals with Unusual Crystal Structures and Their Catalytic Applications
journal, November 2016


Crystallographic control of noble metal nanocrystals
journal, June 2011


Bimetallic PdRu nanosponges with a tunable composition for ethylene glycol oxidation
journal, January 2016

  • Bi, Peiyan; Hong, Wei; Shang, Changshuai
  • RSC Advances, Vol. 6, Issue 15
  • DOI: 10.1039/C5RA26823K

Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications
journal, September 2015


Hollow nanoparticles as emerging electrocatalysts for renewable energy conversion reactions
journal, January 2018

  • Park, Jongsik; Kwon, Taehyun; Kim, Jun
  • Chemical Society Reviews, Vol. 47, Issue 22
  • DOI: 10.1039/C8CS00336J

Recent advances in catalysts for direct methanol fuel cells
journal, January 2011

  • Zhao, Xiao; Yin, Min; Ma, Liang
  • Energy & Environmental Science, Vol. 4, Issue 8
  • DOI: 10.1039/c1ee01307f

Discovery of Face-Centered-Cubic Ruthenium Nanoparticles: Facile Size-Controlled Synthesis Using the Chemical Reduction Method
journal, April 2013

  • Kusada, Kohei; Kobayashi, Hirokazu; Yamamoto, Tomokazu
  • Journal of the American Chemical Society, Vol. 135, Issue 15
  • DOI: 10.1021/ja311261s