Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol

doi:10.1002/smtd.201900843

Title: Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol

Authors:

^[1]; Lyu, Zhiheng ^[1]; Xie, Minghao ^[1]; Hood, Zachary D. ^[2]; Cao, Zhenming ^[3]; Chi, Miaofang ^[4];

^[5]

School of Chemistry and BiochemistryGeorgia Institute of Technology Atlanta GA 30332 USA
School of Chemistry and BiochemistryGeorgia Institute of Technology Atlanta GA 30332 USA, Center for Nanophase Materials SciencesOak Ridge National Laboratory Oak Ridge TN 37831 USA
The Wallace H. Coulter Department of Biomedical EngineeringGeorgia Institute of Technology and Emory University Atlanta GA 30332 USA
Center for Nanophase Materials SciencesOak Ridge National Laboratory Oak Ridge TN 37831 USA
School of Chemistry and BiochemistryGeorgia Institute of Technology Atlanta GA 30332 USA, The Wallace H. Coulter Department of Biomedical EngineeringGeorgia Institute of Technology and Emory University Atlanta GA 30332 USA

Publication Date:: 2020-01-29

Sponsoring Org.:: USDOE

OSTI Identifier:: 1595857

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Small Methods

Additional Journal Information:: Journal Name: Small Methods Journal Volume: 4 Journal Issue: 5; Journal ID: ISSN 2366-9608

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: United States

Language:: English

Citation Formats


                    Zhao, Ming, Lyu, Zhiheng, Xie, Minghao, Hood, Zachary D., Cao, Zhenming, Chi, Miaofang, and Xia, Younan. Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol.  United States: N. p., 2020. 
        Web.  doi:10.1002/smtd.201900843.

Copy to clipboard


                    Zhao, Ming, Lyu, Zhiheng, Xie, Minghao, Hood, Zachary D., Cao, Zhenming, Chi, Miaofang, & Xia, Younan. Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol.  United States.  doi:10.1002/smtd.201900843.

Copy to clipboard


                    Zhao, Ming, Lyu, Zhiheng, Xie, Minghao, Hood, Zachary D., Cao, Zhenming, Chi, Miaofang, and Xia, Younan. Wed .  
        "Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol".  United States.  doi:10.1002/smtd.201900843.

Copy to clipboard


                    
@article{osti_1595857,

  title        = {Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol},

  author       = {Zhao, Ming and Lyu, Zhiheng and Xie, Minghao and Hood, Zachary D. and Cao, Zhenming and Chi, Miaofang and Xia, Younan},

  abstractNote = {},

  doi          = {10.1002/smtd.201900843},

  journal      = {Small Methods},

  number       = 5,

  volume       = 4,

  place        = {United States},

  year         = {2020},

  month        = {1}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Publisher's Version of Record
DOI: 10.1002/smtd.201900843

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Nanoflowers of PdRu on PEDOT for Electrooxidation of Glycerol and Its Analysis
journal, October 2015

Dash, Sthitaprajna; Munichandraiah, N.
Electrochimica Acta, Vol. 180
DOI: 10.1016/j.electacta.2015.07.020

CO adsorption on close-packed transition and noble metal surfaces: trends from ab initio calculations
journal, February 2004

Gajdo, Marek; Eichler, Andreas; Hafner, Jürgen
Journal of Physics: Condensed Matter, Vol. 16, Issue 8
DOI: 10.1088/0953-8984/16/8/001

Ru Nanoframes with an fcc Structure and Enhanced Catalytic Properties
journal, March 2016

Ye, Haihang; Wang, Qingxiao; Catalano, Massimo
Nano Letters, Vol. 16, Issue 4
DOI: 10.1021/acs.nanolett.6b00607

Synthesis of Palladium Nanoscale Octahedra through a One-Pot, Dual-Reductant Route and Kinetic Analysis
journal, March 2018

Figueroa-Cosme, Legna; Gilroy, Kyle D.; Yang, Tung-Han
Chemistry - A European Journal, Vol. 24, Issue 23
DOI: 10.1002/chem.201705720

Small Adsorbate-Assisted Shape Control of Pd and Pt Nanocrystals
journal, January 2012

Chen, Mei; Wu, Binghui; Yang, Jing
Advanced Materials, Vol. 24, Issue 7
DOI: 10.1002/adma.201104145

Concave Pd–Ru nanocubes bounded with high active area for boosting ethylene glycol electrooxidation
journal, January 2018

Xiong, Zhiping; Xu, Hui; Li, Shumin
Applied Surface Science, Vol. 427
DOI: 10.1016/j.apsusc.2017.08.170

Pt–Ag cubic nanocages with wall thickness less than 2 nm and their enhanced catalytic activity toward oxygen reduction
journal, January 2017

Sun, Xiaojun; Yang, Xuan; Zhang, Yun
Nanoscale, Vol. 9, Issue 39
DOI: 10.1039/C7NR04366J

Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages
journal, July 2018

Nazemi, Mohammadreza; Panikkanvalappil, Sajanlal R.; El-Sayed, Mostafa A.
Nano Energy, Vol. 49
DOI: 10.1016/j.nanoen.2018.04.039

Synthesis and Characterization of Ru Cubic Nanocages with a Face-Centered Cubic Structure by Templating with Pd Nanocubes
journal, August 2016

Zhao, Ming; Figueroa-Cosme, Legna; Elnabawy, Ahmed O.
Nano Letters, Vol. 16, Issue 8
DOI: 10.1021/acs.nanolett.6b02795

Best Practices in Pursuit of Topics in Heterogeneous Electrocatalysis
journal, August 2017

Chen, Jingguang G.; Jones, Christopher W.; Linic, Suljo
ACS Catalysis, Vol. 7, Issue 9
DOI: 10.1021/acscatal.7b02839

Rational design and synthesis of bifunctional metal nanocrystals for probing catalytic reactions by surface-enhanced Raman scattering
journal, January 2018

Zhang, Yun; Wu, Yiren; Qin, Dong
Journal of Materials Chemistry C, Vol. 6, Issue 20
DOI: 10.1039/C8TC01394B

Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability
journal, January 2014

Kusada, Kohei; Kobayashi, Hirokazu; Ikeda, Ryuichi
Journal of the American Chemical Society, Vol. 136, Issue 5
DOI: 10.1021/ja409464g

Single-layered platinum nanocage: a highly selective and efficient catalyst for fuel cells
journal, January 2016

Mahata, Arup; Rawat, Kuber Singh; Choudhuri, Indrani
Journal of Materials Chemistry A, Vol. 4, Issue 33
DOI: 10.1039/C6TA03245A

Poisonous Species in Complete Ethanol Oxidation Reaction on Palladium Catalysts
journal, July 2019

Wu, Zhi-Peng; Miao, Bei; Hopkins, Emma
The Journal of Physical Chemistry C, Vol. 123, Issue 34
DOI: 10.1021/acs.jpcc.9b04229

Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells
journal, September 2009

Bianchini, Claudio; Shen, Pei Kang
Chemical Reviews, Vol. 109, Issue 9
DOI: 10.1021/cr9000995

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
journal, March 2008

Alayoglu, Selim; Nilekar, Anand U.; Mavrikakis, Manos
Nature Materials, Vol. 7, Issue 4, p. 333-338
DOI: 10.1038/nmat2156

Syntheses and Properties of Metal Nanomaterials with Novel Crystal Phases
journal, April 2018

Cheng, Hongfei; Yang, Nailiang; Lu, Qipeng
Advanced Materials, Vol. 30, Issue 26
DOI: 10.1002/adma.201707189

Vegard’s law
journal, March 1991

Denton, A. R.; Ashcroft, N. W.
Physical Review A, Vol. 43, Issue 6
DOI: 10.1103/PhysRevA.43.3161

CO Chemisorption at Metal Surfaces and Overlayers
journal, March 1996

Hammer, B.; Morikawa, Y.; Nørskov, J. K.
Physical Review Letters, Vol. 76, Issue 12
DOI: 10.1103/PhysRevLett.76.2141

Ru Octahedral Nanocrystals with a Face-Centered Cubic Structure, {111} Facets, Thermal Stability up to 400 °C, and Enhanced Catalytic Activity
journal, April 2019

Zhao, Ming; Chen, Zitao; Lyu, Zhiheng
Journal of the American Chemical Society, Vol. 141, Issue 17
DOI: 10.1021/jacs.9b01640

Synthesis of Pd nanocrystals enclosed by {100} facets and with sizes <10 nm for application in CO oxidation
journal, October 2010

Jin, Mingshang; Liu, Hongyang; Zhang, Hui
Nano Research, Vol. 4, Issue 1
DOI: 10.1007/s12274-010-0051-3

RuPd Alloy Nanoparticles Supported on N-Doped Carbon as an Efficient and Stable Catalyst for Benzoic Acid Hydrogenation
journal, March 2015

Tang, Minghui; Mao, Shanjun; Li, Mingming
ACS Catalysis, Vol. 5, Issue 5
DOI: 10.1021/acscatal.5b00037

Icosahedral nanocrystals of noble metals: Synthesis and applications
journal, August 2017

Wang, Helan; Zhou, Shan; Gilroy, Kyle D.
Nano Today, Vol. 15
DOI: 10.1016/j.nantod.2017.06.011

Decahedral nanocrystals of noble metals: Synthesis, characterization, and applications
journal, January 2019

Zhou, Shan; Zhao, Ming; Yang, Tung-Han
Materials Today, Vol. 22
DOI: 10.1016/j.mattod.2018.04.003

Comprehensive Mechanism and Structure-Sensitivity of Ethanol Oxidation on Platinum: New Transition-State Searching Method for Resolving the Complex Reaction Network
journal, August 2008

Wang, Hui-Fang; Liu, Zhi-Pan
Journal of the American Chemical Society, Vol. 130, Issue 33
DOI: 10.1021/ja801648h

Recent Advances in Materials for Fuel Cells
journal, August 2003

Brandon, N. P.; Skinner, S.; Steele, B. C. H.
Annual Review of Materials Research, Vol. 33, Issue 1
DOI: 10.1146/annurev.matsci.33.022802.094122

Synthesis of Ru Icosahedral Nanocages with a Face-Centered-Cubic Structure and Evaluation of Their Catalytic Properties
journal, May 2018

Zhao, Ming; Xu, Lang; Vara, Madeline
ACS Catalysis, Vol. 8, Issue 8
DOI: 10.1021/acscatal.8b00910

Shape-controlled synthesis of ruthenium nanocrystals and their catalytic applications
journal, January 2014

Chen, Guozhu; Zhang, Jianming; Gupta, Akanksha
New J. Chem., Vol. 38, Issue 5
DOI: 10.1039/C3NJ01155K

Ruthenium Nanoframes in the Face-Centered Cubic Phase: Facile Synthesis and Their Enhanced Catalytic Performance
journal, May 2019

Zhao, Ming; Hood, Zachary D.; Vara, Madeline
ACS Nano, Vol. 13, Issue 6
DOI: 10.1021/acsnano.9b02890

Direct fabrication of bi-metallic PdRu nanorod assemblies for electrochemical ammonia synthesis
journal, January 2019

Wang, Hongjing; Li, Yinghao; Yang, Dandan
Nanoscale, Vol. 11, Issue 12
DOI: 10.1039/C8NR10398D

One-Pot Synthesis of Cubic PtCu ₃ Nanocages with Enhanced Electrocatalytic Activity for the Methanol Oxidation Reaction
journal, August 2012

Xia, Bao Yu; Wu, Hao Bin; Wang, Xin
Journal of the American Chemical Society, Vol. 134, Issue 34
DOI: 10.1021/ja3051662

Polyol Syntheses of Palladium Decahedra and Icosahedra as Pure Samples by Maneuvering the Reaction Kinetics with Additives
journal, June 2014

Huang, Hongwen; Wang, Yi; Ruditskiy, Aleksey
ACS Nano, Vol. 8, Issue 7
DOI: 10.1021/nn501919e

Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells
journal, November 2019

Tian, Xinlong; Zhao, Xiao; Su, Ya-Qiong
Science, Vol. 366, Issue 6467
DOI: 10.1126/science.aaw7493

Platinum Group Nanowires for Efficient Electrocatalysis
journal, January 2019

Shao, Qi; Lu, Kunyan; Huang, Xiaoqing
Small Methods, Vol. 3, Issue 5
DOI: 10.1002/smtd.201800545

Halide-regulated growth of electrocatalytic metal nanoparticles directly onto a carbon paper electrode
journal, January 2016

Holade, Yaovi; Hickey, David P.; Minteer, Shelley D.
Journal of Materials Chemistry A, Vol. 4, Issue 43
DOI: 10.1039/C6TA08288B

Recent achievements in direct ethylene glycol fuel cells (DEGFC)
journal, June 2010

Serov, Alexey; Kwak, Chan
Applied Catalysis B: Environmental, Vol. 97, Issue 1-2
DOI: 10.1016/j.apcatb.2010.04.011

Octahedral Pd nanocages with porous shells converted from Co(OH) 2 nanocages with nanosheet surfaces as robust electrocatalysts for ethanol oxidation
journal, January 2018

Sheng, Jiali; Kang, Jiahui; Hu, Zhixiong
Journal of Materials Chemistry A, Vol. 6, Issue 32
DOI: 10.1039/C8TA04181D

Shape-Controlled Synthesis of Pd Nanocrystals and Their Catalytic Applications
journal, November 2012

Zhang, Hui; Jin, Mingshang; Xiong, Yujie
Accounts of Chemical Research, Vol. 46, Issue 8
DOI: 10.1021/ar300209w

Relationships between Atomic Level Surface Structure and Stability/Activity of Platinum Surface Atoms in Aqueous Environments
journal, March 2016

Lopes, Pietro P.; Strmcnik, Dusan; Tripkovic, Dusan
ACS Catalysis, Vol. 6, Issue 4
DOI: 10.1021/acscatal.5b02920

Toward affordable and sustainable use of precious metals in catalysis and nanomedicine
journal, November 2018

Xia, Younan; Zhao, Ming; Wang, Xue
MRS Bulletin, Vol. 43, Issue 11
DOI: 10.1557/mrs.2018.262

Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges
journal, April 2012

Rabis, Annett; Rodriguez, Paramaconi; Schmidt, Thomas J.
ACS Catalysis, Vol. 2, Issue 5
DOI: 10.1021/cs3000864

Facile Synthesis of Ru-Based Octahedral Nanocages with Ultrathin Walls in a Face-Centered Cubic Structure
journal, October 2017

Zhao, Ming; Elnabawy, Ahmed O.; Vara, Madeline
Chemistry of Materials, Vol. 29, Issue 21
DOI: 10.1021/acs.chemmater.7b03092

25th Anniversary Article: Galvanic Replacement: A Simple and Versatile Route to Hollow Nanostructures with Tunable and Well-Controlled Properties
journal, September 2013

Xia, Xiaohu; Wang, Yi; Ruditskiy, Aleksey
Advanced Materials, Vol. 25, Issue 44
DOI: 10.1002/adma.201302820

Shape‐Controlled Synthesis of Colloidal Metal Nanocrystals by Replicating the Surface Atomic Structure on the Seed
journal, April 2018

Gilroy, Kyle D.; Yang, Xuan; Xie, Shuifen
Advanced Materials, Vol. 30, Issue 25
DOI: 10.1002/adma.201706312

New understandings of ethanol oxidation reaction mechanism on Pd/C and Pd2Ru/C catalysts in alkaline direct ethanol fuel cells
journal, May 2018

Guo, Junsong; Chen, Rongrong; Zhu, Fu-Chun
Applied Catalysis B: Environmental, Vol. 224
DOI: 10.1016/j.apcatb.2017.10.037

Ru-assisted synthesis of Pd/Ru nanodendrites with high activity for ethanol electrooxidation
journal, January 2015

Zhang, Ke; Bin, Duan; Yang, Beibei
Nanoscale, Vol. 7, Issue 29
DOI: 10.1039/C5NR02713F

Porous octahedral PdCu nanocages as highly efficient electrocatalysts for the methanol oxidation reaction
journal, January 2018

Sheng, Jiali; Kang, Jiahui; Ye, Huangqing
Journal of Materials Chemistry A, Vol. 6, Issue 9
DOI: 10.1039/C7TA07879J

Hollow and Cage-Bell Structured Nanomaterials of Noble Metals
journal, July 2012

Liu, Hui; Qu, Jianglan; Chen, Yunfa
Journal of the American Chemical Society, Vol. 134, Issue 28
DOI: 10.1021/ja302518n

A High-Performance Direct Methanol Fuel Cell Technology Enabled by Mediating High-Concentration Methanol through a Graphene Aerogel
journal, July 2018

Liu, Xiaoteng; Xi, Jiabin; Xu, Ben Bin
Small Methods, Vol. 2, Issue 10
DOI: 10.1002/smtd.201800138

Graphene-supported Pd–Ru nanoparticles with superior methanol electrooxidation activity
journal, January 2013

Awasthi, R.; Singh, R. N.
Carbon, Vol. 51
DOI: 10.1016/j.carbon.2012.08.055

Template Synthesis of Noble Metal Nanocrystals with Unusual Crystal Structures and Their Catalytic Applications
journal, November 2016

Fan, Zhanxi; Zhang, Hua
Accounts of Chemical Research, Vol. 49, Issue 12
DOI: 10.1021/acs.accounts.6b00527

Ruthenium–platinum core–shell nanocatalysts with substantially enhanced activity and durability towards methanol oxidation
journal, March 2016

Xie, Jin; Zhang, Qinghua; Gu, Lin
Nano Energy, Vol. 21
DOI: 10.1016/j.nanoen.2016.01.013

Crystallographic control of noble metal nanocrystals
journal, June 2011

Niu, Wenxin; Xu, Guobao
Nano Today, Vol. 6, Issue 3
DOI: 10.1016/j.nantod.2011.04.006

Bimetallic PdRu nanosponges with a tunable composition for ethylene glycol oxidation
journal, January 2016

Bi, Peiyan; Hong, Wei; Shang, Changshuai
RSC Advances, Vol. 6, Issue 15
DOI: 10.1039/C5RA26823K

Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications
journal, September 2015

Chen, Aicheng; Ostrom, Cassandra
Chemical Reviews, Vol. 115, Issue 21
DOI: 10.1021/acs.chemrev.5b00324

Hollow nanoparticles as emerging electrocatalysts for renewable energy conversion reactions
journal, January 2018

Park, Jongsik; Kwon, Taehyun; Kim, Jun
Chemical Society Reviews, Vol. 47, Issue 22
DOI: 10.1039/C8CS00336J

Recent advances in catalysts for direct methanol fuel cells
journal, January 2011

Zhao, Xiao; Yin, Min; Ma, Liang
Energy & Environmental Science, Vol. 4, Issue 8
DOI: 10.1039/c1ee01307f

Discovery of Face-Centered-Cubic Ruthenium Nanoparticles: Facile Size-Controlled Synthesis Using the Chemical Reduction Method
journal, April 2013

Kusada, Kohei; Kobayashi, Hirokazu; Yamamoto, Tomokazu
Journal of the American Chemical Society, Vol. 135, Issue 15
DOI: 10.1021/ja311261s

Similar Records in DOE PAGES and OSTI.GOV collections:

Facile Synthesis of Ru-Based Octahedral Nanocages with Ultrathin Walls in a Face-Centered Cubic Structure

Journal Article Zhao, Ming ; Elnabawy, Ahmed O. ; Vara, Madeline ; ... - Chemistry of Materials

Noble-metal nanocages with ultrathin (less than 2 nm) walls and well-defined facets have received great interest owing to their remarkable utilization efficiency of atoms and facet-dependent catalytic activities toward various reactions. Here, we report the synthesis of Ru-based octahedral nanocages covered by {111} facets, together with ultrathin walls in a face-centered cubic (fcc) structure rather than the hexagonal close-packed (hcp) of bulk Ru. The involvement of slow injection for the Ru(III) precursor, the introduction of KBr, and the use of elevated temperature were all instrumental to the formation of Pd@Ru core–shell octahedra with a conformal, uniform shell and a smoothmore »« less
DOI: 10.1021/acs.chemmater.7b03092
Synthesis of Ru Icosahedral Nanocages with a Face-Centered-Cubic Structure and Evaluation of Their Catalytic Properties

Journal Article Zhao, Ming ; Xu, Lang ; Vara, Madeline ; ... - ACS Catalysis

Owing to the presence of {111} facets, twin boundaries, and strain fields on the surface, noble-metal nanocrystals with an icosahedral shape have been reported with stellar performance toward an array of catalytic reactions. Here, we report the successful synthesis of Ru icosahedral nanocages with a face-centered cubic (fcc) structure by conformally coating Pd icosahedral seeds with ultrathin Ru shells, followed by selective removal of the Pd cores via chemical etching. We discovered that the presence of bromide ions was critical to the layer-by-layer deposition of Ru atoms. According to in situ XRD, the fcc structure in the Ru nanocages couldmore »« less
Cited by 19
DOI: 10.1021/acscatal.8b00910

Full Text Available
Pt–Ag cubic nanocages with wall thickness less than 2 nm and their enhanced catalytic activity toward oxygen reduction

Journal Article Sun, Xiaojun ; Yang, Xuan ; Zhang, Yun ; ... - Nanoscale

We report a facile synthesis of Pt–Ag nanocages with walls thinner than 2 nm by depositing a few atomic layers of Pt as conformal shells on Ag nanocubes and then selectively removing the Ag templateviawet etching.
Cited by 9
DOI: 10.1039/C7NR04366J

Full Text Available
Design of Pd-Pb Catalysts for Glycerol and Ethylene Glycol Electrooxidation in Alkaline Medium

Journal Article Asset, Tristan ; Serov, Alexey ; Padilla, Monica ; ... - Electrocatalysis

Unsupported Pd_xPb_1-x electrocatalysts were synthesized by a modified sacrificial support method (SSM) and thoroughly characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM). Their electrochemical activity was evaluated for the electrooxidation reactions of ethylene glycol (EGOR) and glycerol (GOR) in alkaline electrolytes, reaching an onset of - 510 mV vs. the normal hydrogen electrode (NHE) for the EGOR and the GOR vs. - 430 mV vs. NHE for the EGOR and the GOR on the Pd-black. Additional mechanistic insights were provided by DFT calculations, showing that the presence of Pb resulted in a stronger bindingmore »« less
DOI: 10.1007/s12678-017-0449-8
Synthesis and Characterization of Pt–Ag Alloy Nanocages with Enhanced Activity and Durability toward Oxygen Reduction

Journal Article Yang, Xuan ; Roling, Luke T. ; Vara, Madeline ; ... - Nano Letters

Engineering the elemental composition of metal nanocrystals offers an effective strategy for the development of catalysts or electrocatalysts with greatly enhanced activity. Herein, we report the synthesis of Pt–Ag alloy nanocages with an outer edge length of 18 nm and a wall thickness of about 3 nm. Such nanocages with a composition of Pt₁₉Ag₈₁ could be readily prepared in one step through the galvanic replacement reaction between Ag nanocubes and a Pt(II) precursor. Here, after 10 000 cycles of potential cycling in the range of 0.60–1.0 V as in an accelerated durability test, the composition of the nanocages changed tomore »« less
Cited by 58
DOI: 10.1021/acs.nanolett.6b03395

Full Text Available

Similar Records

Title: Pd‐Ru Alloy Nanocages with a Face‐Centered Cubic Structure and Their Enhanced Activity toward the Oxidation of Ethylene Glycol and Glycerol

Citation Formats

Nanoflowers of PdRu on PEDOT for Electrooxidation of Glycerol and Its Analysis journal, October 2015

CO adsorption on close-packed transition and noble metal surfaces: trends from ab initio calculations journal, February 2004

Ru Nanoframes with an fcc Structure and Enhanced Catalytic Properties journal, March 2016

Synthesis of Palladium Nanoscale Octahedra through a One-Pot, Dual-Reductant Route and Kinetic Analysis journal, March 2018

Small Adsorbate-Assisted Shape Control of Pd and Pt Nanocrystals journal, January 2012

Concave Pd–Ru nanocubes bounded with high active area for boosting ethylene glycol electrooxidation journal, January 2018

Pt–Ag cubic nanocages with wall thickness less than 2 nm and their enhanced catalytic activity toward oxygen reduction journal, January 2017

Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages journal, July 2018

Synthesis and Characterization of Ru Cubic Nanocages with a Face-Centered Cubic Structure by Templating with Pd Nanocubes journal, August 2016

Best Practices in Pursuit of Topics in Heterogeneous Electrocatalysis journal, August 2017

Rational design and synthesis of bifunctional metal nanocrystals for probing catalytic reactions by surface-enhanced Raman scattering journal, January 2018

Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability journal, January 2014

Single-layered platinum nanocage: a highly selective and efficient catalyst for fuel cells journal, January 2016

Poisonous Species in Complete Ethanol Oxidation Reaction on Palladium Catalysts journal, July 2019

Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells journal, September 2009

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen journal, March 2008

Syntheses and Properties of Metal Nanomaterials with Novel Crystal Phases journal, April 2018

Vegard’s law journal, March 1991

CO Chemisorption at Metal Surfaces and Overlayers journal, March 1996

Ru Octahedral Nanocrystals with a Face-Centered Cubic Structure, {111} Facets, Thermal Stability up to 400 °C, and Enhanced Catalytic Activity journal, April 2019

Synthesis of Pd nanocrystals enclosed by {100} facets and with sizes <10 nm for application in CO oxidation journal, October 2010

RuPd Alloy Nanoparticles Supported on N-Doped Carbon as an Efficient and Stable Catalyst for Benzoic Acid Hydrogenation journal, March 2015

Icosahedral nanocrystals of noble metals: Synthesis and applications journal, August 2017

Decahedral nanocrystals of noble metals: Synthesis, characterization, and applications journal, January 2019

Comprehensive Mechanism and Structure-Sensitivity of Ethanol Oxidation on Platinum: New Transition-State Searching Method for Resolving the Complex Reaction Network journal, August 2008

Recent Advances in Materials for Fuel Cells journal, August 2003

Synthesis of Ru Icosahedral Nanocages with a Face-Centered-Cubic Structure and Evaluation of Their Catalytic Properties journal, May 2018

Shape-controlled synthesis of ruthenium nanocrystals and their catalytic applications journal, January 2014

Ruthenium Nanoframes in the Face-Centered Cubic Phase: Facile Synthesis and Their Enhanced Catalytic Performance journal, May 2019

Direct fabrication of bi-metallic PdRu nanorod assemblies for electrochemical ammonia synthesis journal, January 2019

One-Pot Synthesis of Cubic PtCu 3 Nanocages with Enhanced Electrocatalytic Activity for the Methanol Oxidation Reaction journal, August 2012

Polyol Syntheses of Palladium Decahedra and Icosahedra as Pure Samples by Maneuvering the Reaction Kinetics with Additives journal, June 2014

Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells journal, November 2019

Platinum Group Nanowires for Efficient Electrocatalysis journal, January 2019

Halide-regulated growth of electrocatalytic metal nanoparticles directly onto a carbon paper electrode journal, January 2016

Recent achievements in direct ethylene glycol fuel cells (DEGFC) journal, June 2010

Octahedral Pd nanocages with porous shells converted from Co(OH) 2 nanocages with nanosheet surfaces as robust electrocatalysts for ethanol oxidation journal, January 2018

Shape-Controlled Synthesis of Pd Nanocrystals and Their Catalytic Applications journal, November 2012

Relationships between Atomic Level Surface Structure and Stability/Activity of Platinum Surface Atoms in Aqueous Environments journal, March 2016

Toward affordable and sustainable use of precious metals in catalysis and nanomedicine journal, November 2018

Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges journal, April 2012

Facile Synthesis of Ru-Based Octahedral Nanocages with Ultrathin Walls in a Face-Centered Cubic Structure journal, October 2017

25th Anniversary Article: Galvanic Replacement: A Simple and Versatile Route to Hollow Nanostructures with Tunable and Well-Controlled Properties journal, September 2013

Shape‐Controlled Synthesis of Colloidal Metal Nanocrystals by Replicating the Surface Atomic Structure on the Seed journal, April 2018

New understandings of ethanol oxidation reaction mechanism on Pd/C and Pd2Ru/C catalysts in alkaline direct ethanol fuel cells journal, May 2018

Ru-assisted synthesis of Pd/Ru nanodendrites with high activity for ethanol electrooxidation journal, January 2015

Porous octahedral PdCu nanocages as highly efficient electrocatalysts for the methanol oxidation reaction journal, January 2018

Hollow and Cage-Bell Structured Nanomaterials of Noble Metals journal, July 2012

A High-Performance Direct Methanol Fuel Cell Technology Enabled by Mediating High-Concentration Methanol through a Graphene Aerogel journal, July 2018

Graphene-supported Pd–Ru nanoparticles with superior methanol electrooxidation activity journal, January 2013

Template Synthesis of Noble Metal Nanocrystals with Unusual Crystal Structures and Their Catalytic Applications journal, November 2016

Ruthenium–platinum core–shell nanocatalysts with substantially enhanced activity and durability towards methanol oxidation journal, March 2016

Crystallographic control of noble metal nanocrystals journal, June 2011

Bimetallic PdRu nanosponges with a tunable composition for ethylene glycol oxidation journal, January 2016

Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications journal, September 2015

Hollow nanoparticles as emerging electrocatalysts for renewable energy conversion reactions journal, January 2018

Recent advances in catalysts for direct methanol fuel cells journal, January 2011

Discovery of Face-Centered-Cubic Ruthenium Nanoparticles: Facile Size-Controlled Synthesis Using the Chemical Reduction Method journal, April 2013

Nanoflowers of PdRu on PEDOT for Electrooxidation of Glycerol and Its Analysis
journal, October 2015

CO adsorption on close-packed transition and noble metal surfaces: trends from ab initio calculations
journal, February 2004

Ru Nanoframes with an fcc Structure and Enhanced Catalytic Properties
journal, March 2016

Synthesis of Palladium Nanoscale Octahedra through a One-Pot, Dual-Reductant Route and Kinetic Analysis
journal, March 2018

Small Adsorbate-Assisted Shape Control of Pd and Pt Nanocrystals
journal, January 2012

Concave Pd–Ru nanocubes bounded with high active area for boosting ethylene glycol electrooxidation
journal, January 2018

Pt–Ag cubic nanocages with wall thickness less than 2 nm and their enhanced catalytic activity toward oxygen reduction
journal, January 2017

Enhancing the rate of electrochemical nitrogen reduction reaction for ammonia synthesis under ambient conditions using hollow gold nanocages
journal, July 2018

Synthesis and Characterization of Ru Cubic Nanocages with a Face-Centered Cubic Structure by Templating with Pd Nanocubes
journal, August 2016

Best Practices in Pursuit of Topics in Heterogeneous Electrocatalysis
journal, August 2017

Rational design and synthesis of bifunctional metal nanocrystals for probing catalytic reactions by surface-enhanced Raman scattering
journal, January 2018

Solid Solution Alloy Nanoparticles of Immiscible Pd and Ru Elements Neighboring on Rh: Changeover of the Thermodynamic Behavior for Hydrogen Storage and Enhanced CO-Oxidizing Ability
journal, January 2014

Single-layered platinum nanocage: a highly selective and efficient catalyst for fuel cells
journal, January 2016

Poisonous Species in Complete Ethanol Oxidation Reaction on Palladium Catalysts
journal, July 2019

Palladium-Based Electrocatalysts for Alcohol Oxidation in Half Cells and in Direct Alcohol Fuel Cells
journal, September 2009

Ru–Pt core–shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen
journal, March 2008

Syntheses and Properties of Metal Nanomaterials with Novel Crystal Phases
journal, April 2018

Vegard’s law
journal, March 1991

CO Chemisorption at Metal Surfaces and Overlayers
journal, March 1996

Ru Octahedral Nanocrystals with a Face-Centered Cubic Structure, {111} Facets, Thermal Stability up to 400 °C, and Enhanced Catalytic Activity
journal, April 2019

Synthesis of Pd nanocrystals enclosed by {100} facets and with sizes <10 nm for application in CO oxidation
journal, October 2010

RuPd Alloy Nanoparticles Supported on N-Doped Carbon as an Efficient and Stable Catalyst for Benzoic Acid Hydrogenation
journal, March 2015

Icosahedral nanocrystals of noble metals: Synthesis and applications
journal, August 2017

Decahedral nanocrystals of noble metals: Synthesis, characterization, and applications
journal, January 2019

Comprehensive Mechanism and Structure-Sensitivity of Ethanol Oxidation on Platinum: New Transition-State Searching Method for Resolving the Complex Reaction Network
journal, August 2008

Recent Advances in Materials for Fuel Cells
journal, August 2003

Synthesis of Ru Icosahedral Nanocages with a Face-Centered-Cubic Structure and Evaluation of Their Catalytic Properties
journal, May 2018

Shape-controlled synthesis of ruthenium nanocrystals and their catalytic applications
journal, January 2014

Ruthenium Nanoframes in the Face-Centered Cubic Phase: Facile Synthesis and Their Enhanced Catalytic Performance
journal, May 2019

Direct fabrication of bi-metallic PdRu nanorod assemblies for electrochemical ammonia synthesis
journal, January 2019

One-Pot Synthesis of Cubic PtCu ₃ Nanocages with Enhanced Electrocatalytic Activity for the Methanol Oxidation Reaction
journal, August 2012

Polyol Syntheses of Palladium Decahedra and Icosahedra as Pure Samples by Maneuvering the Reaction Kinetics with Additives
journal, June 2014

Engineering bunched Pt-Ni alloy nanocages for efficient oxygen reduction in practical fuel cells
journal, November 2019

Platinum Group Nanowires for Efficient Electrocatalysis
journal, January 2019

Halide-regulated growth of electrocatalytic metal nanoparticles directly onto a carbon paper electrode
journal, January 2016

Recent achievements in direct ethylene glycol fuel cells (DEGFC)
journal, June 2010

Octahedral Pd nanocages with porous shells converted from Co(OH) 2 nanocages with nanosheet surfaces as robust electrocatalysts for ethanol oxidation
journal, January 2018

Shape-Controlled Synthesis of Pd Nanocrystals and Their Catalytic Applications
journal, November 2012

Relationships between Atomic Level Surface Structure and Stability/Activity of Platinum Surface Atoms in Aqueous Environments
journal, March 2016

Toward affordable and sustainable use of precious metals in catalysis and nanomedicine
journal, November 2018

Electrocatalysis for Polymer Electrolyte Fuel Cells: Recent Achievements and Future Challenges
journal, April 2012

Facile Synthesis of Ru-Based Octahedral Nanocages with Ultrathin Walls in a Face-Centered Cubic Structure
journal, October 2017

25th Anniversary Article: Galvanic Replacement: A Simple and Versatile Route to Hollow Nanostructures with Tunable and Well-Controlled Properties
journal, September 2013

Shape‐Controlled Synthesis of Colloidal Metal Nanocrystals by Replicating the Surface Atomic Structure on the Seed
journal, April 2018

New understandings of ethanol oxidation reaction mechanism on Pd/C and Pd2Ru/C catalysts in alkaline direct ethanol fuel cells
journal, May 2018

Ru-assisted synthesis of Pd/Ru nanodendrites with high activity for ethanol electrooxidation
journal, January 2015

Porous octahedral PdCu nanocages as highly efficient electrocatalysts for the methanol oxidation reaction
journal, January 2018

Hollow and Cage-Bell Structured Nanomaterials of Noble Metals
journal, July 2012

A High-Performance Direct Methanol Fuel Cell Technology Enabled by Mediating High-Concentration Methanol through a Graphene Aerogel
journal, July 2018

Graphene-supported Pd–Ru nanoparticles with superior methanol electrooxidation activity
journal, January 2013

Template Synthesis of Noble Metal Nanocrystals with Unusual Crystal Structures and Their Catalytic Applications
journal, November 2016

Ruthenium–platinum core–shell nanocatalysts with substantially enhanced activity and durability towards methanol oxidation
journal, March 2016

Crystallographic control of noble metal nanocrystals
journal, June 2011

Bimetallic PdRu nanosponges with a tunable composition for ethylene glycol oxidation
journal, January 2016

Palladium-Based Nanomaterials: Synthesis and Electrochemical Applications
journal, September 2015

Hollow nanoparticles as emerging electrocatalysts for renewable energy conversion reactions
journal, January 2018

Recent advances in catalysts for direct methanol fuel cells
journal, January 2011

Discovery of Face-Centered-Cubic Ruthenium Nanoparticles: Facile Size-Controlled Synthesis Using the Chemical Reduction Method
journal, April 2013