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Title: Perdeuteration of poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene] (d-MEH-PPV): control of microscopic charge-carrier spin–spin coupling and of magnetic-field effects in optoelectronic devices

Abstract

Replacing all protons on a polymer by deuterium has a dramatic impact on spin-dependent properties of the material in devices.

Authors:
 [1];  [2];  [2];  [2];  [2];  [3]; ORCiD logo [3];  [3];  [2];  [2];  [2];  [4]; ORCiD logo [4]; ORCiD logo [2]; ORCiD logo [1];  [5]; ORCiD logo [2]
+ Show Author Affiliations
  1. Centre for Organic Photonics & Electronics, School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Australia
  2. Department of Physics and Astronomy, University of Utah, Salt Lake City, USA
  3. Institut für Experimentelle und Angewandte Physik, Universität Regensburg, 93053 Regensburg, Germany
  4. National Deuteration Facility, Australian Nuclear Science and Technology Organization (ANSTO), Kirrawee DC, Australia
  5. Department of Physics and Astronomy, University of Utah, Salt Lake City, USA, Institut für Experimentelle und Angewandte Physik
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1595845
Grant/Contract Number:  
SC0000909
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Name: Journal of Materials Chemistry C Journal Volume: 8 Journal Issue: 8; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Stoltzfus, Dani M., Joshi, Gajadhar, Popli, Henna, Jamali, Shirin, Kavand, Marzieh, Milster, Sebastian, Grünbaum, Tobias, Bange, Sebastian, Nahlawi, Adnan, Teferi, Mandefro Y., Atwood, Sabastian I., Leung, Anna E., Darwish, Tamim A., Malissa, Hans, Burn, Paul L., Lupton, John M., and Boehme, Christoph. Perdeuteration of poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene] (d-MEH-PPV): control of microscopic charge-carrier spin–spin coupling and of magnetic-field effects in optoelectronic devices. United Kingdom: N. p., 2020. Web. doi:10.1039/C9TC05322K.
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Stoltzfus, Dani M., Joshi, Gajadhar, Popli, Henna, Jamali, Shirin, Kavand, Marzieh, Milster, Sebastian, Grünbaum, Tobias, Bange, Sebastian, Nahlawi, Adnan, Teferi, Mandefro Y., Atwood, Sabastian I., Leung, Anna E., Darwish, Tamim A., Malissa, Hans, Burn, Paul L., Lupton, John M., & Boehme, Christoph. Perdeuteration of poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene] (d-MEH-PPV): control of microscopic charge-carrier spin–spin coupling and of magnetic-field effects in optoelectronic devices. United Kingdom. doi:10.1039/C9TC05322K.
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Stoltzfus, Dani M., Joshi, Gajadhar, Popli, Henna, Jamali, Shirin, Kavand, Marzieh, Milster, Sebastian, Grünbaum, Tobias, Bange, Sebastian, Nahlawi, Adnan, Teferi, Mandefro Y., Atwood, Sabastian I., Leung, Anna E., Darwish, Tamim A., Malissa, Hans, Burn, Paul L., Lupton, John M., and Boehme, Christoph. Thu . "Perdeuteration of poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene] (d-MEH-PPV): control of microscopic charge-carrier spin–spin coupling and of magnetic-field effects in optoelectronic devices". United Kingdom. doi:10.1039/C9TC05322K.
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@article{osti_1595845,
title = {Perdeuteration of poly[2-methoxy-5-(2′-ethylhexyloxy)-1,4-phenylenevinylene] (d-MEH-PPV): control of microscopic charge-carrier spin–spin coupling and of magnetic-field effects in optoelectronic devices},
author = {Stoltzfus, Dani M. and Joshi, Gajadhar and Popli, Henna and Jamali, Shirin and Kavand, Marzieh and Milster, Sebastian and Grünbaum, Tobias and Bange, Sebastian and Nahlawi, Adnan and Teferi, Mandefro Y. and Atwood, Sabastian I. and Leung, Anna E. and Darwish, Tamim A. and Malissa, Hans and Burn, Paul L. and Lupton, John M. and Boehme, Christoph},
abstractNote = {Replacing all protons on a polymer by deuterium has a dramatic impact on spin-dependent properties of the material in devices.},
doi = {10.1039/C9TC05322K},
journal = {Journal of Materials Chemistry C},
number = 8,
volume = 8,
place = {United Kingdom},
year = {2020},
month = {2}
}
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Journal Article:
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DOI: 10.1039/C9TC05322K
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Works referenced in this record:

Solution-processed organic spin–charge converter
journal, May 2013

  • Ando, Kazuya; Watanabe, Shun; Mooser, Sebastian
  • Nature Materials, Vol. 12, Issue 7
  • DOI: 10.1038/nmat3634

Revealing weak spin-orbit coupling effects on charge carriers in a π -conjugated polymer
journal, April 2018

Monolithic OLED-Microwire Devices for Ultrastrong Magnetic Resonant Excitation
journal, July 2017

Organic magnetoresistance under resonant ac drive
journal, September 2013

Effects of Magnetic Field on Conductance and Electroluminescence in Organic Devices
journal, June 2012

  • Ehrenfreund, Eitan; Vardeny, Zeev Valy
  • Israel Journal of Chemistry, Vol. 52, Issue 6
  • DOI: 10.1002/ijch.201100120

Bootstrap Methods: Another Look at the Jackknife
journal, January 1979

Slow Hopping and Spin Dephasing of Coulombically Bound Polaron Pairs in an Organic Semiconductor at Room Temperature
journal, June 2012

Quantitative inverse spin Hall effect detection via precise control of the driving-field amplitude
journal, April 2017

Magnetic Field Effects in π -Conjugated Polymer-Fullerene Blends: Evidence for Multiple Components
journal, December 2008

Robust absolute magnetometry with organic thin-film devices
journal, January 2012

  • Baker, W. J.; Ambal, K.; Waters, D. P.
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1895

Spin Echoes in the Charge Transport through Phosphorus Donors in Silicon
journal, April 2008

Spin Rabi flopping in the photocurrent of a polymer light-emitting diode
journal, August 2008

  • McCamey, D. R.; Seipel, H. A.; Paik, S. -Y.
  • Nature Materials, Vol. 7, Issue 9
  • DOI: 10.1038/nmat2252

Magnetic resonance studies of tris-(8-hydroxyquinoline) aluminum-based organic light-emitting devices
journal, April 2004

The spin-Dicke effect in OLED magnetoresistance
journal, September 2015

  • Waters, D. P.; Joshi, G.; Kavand, M.
  • Nature Physics, Vol. 11, Issue 11
  • DOI: 10.1038/nphys3453

Magnetic field effects in hybrid perovskite devices
journal, March 2015

  • Zhang, C.; Sun, D.; Sheng, C-X.
  • Nature Physics, Vol. 11, Issue 5
  • DOI: 10.1038/nphys3277

Spectral Diffusion Decay in Spin Resonance Experiments
journal, February 1962

Single-step multiphonon emission model of spin-dependent exciton formation in organic semiconductors
journal, April 2005

Isotope effect in spin response of π-conjugated polymer films and devices
journal, February 2010

  • Nguyen, Tho D.; Hukic-Markosian, Golda; Wang, Fujian
  • Nature Materials, Vol. 9, Issue 4
  • DOI: 10.1038/nmat2633

Elucidating the role of hyperfine interactions on organic magnetoresistance using deuterated aluminium tris(8-hydroxyquinoline)
journal, December 2009

The isotopic effects of deuteration on optoelectronic properties of conducting polymers
journal, January 2014

  • Shao, Ming; Keum, Jong; Chen, Jihua
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms4180

Spin-dependent recombination probed through the dielectric polarizability
journal, October 2015

  • Bayliss, Sam L.; Greenham, Neil C.; Friend, Richard H.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms9534

Electrical detection of electron-spin-echo envelope modulations in thin-film silicon solar cells
journal, November 2011

The many Faces of Organic Magnetoresistance
journal, June 2011

Morphology effects on spin-dependent transport and recombination in polyfluorene thin films
journal, December 2016

Room-temperature coupling between electrical current and nuclear spins in OLEDs
journal, September 2014

Isotropic Effective Spin-Orbit Coupling in a Conjugated Polymer
journal, April 2018

  • Joshi, Gajadhar; Teferi, Mandefro Y.; Miller, Richards
  • Journal of the American Chemical Society, Vol. 140, Issue 22
  • DOI: 10.1021/jacs.8b03069

Inverse spin Hall effect from pulsed spin current in organic semiconductors with tunable spin–orbit coupling
journal, April 2016

  • Sun, Dali; van Schooten, Kipp J.; Kavand, Marzieh
  • Nature Materials, Vol. 15, Issue 8
  • DOI: 10.1038/nmat4618

Conversion of spin current into charge current at room temperature: Inverse spin-Hall effect
journal, May 2006

  • Saitoh, E.; Ueda, M.; Miyajima, H.
  • Applied Physics Letters, Vol. 88, Issue 18
  • DOI: 10.1063/1.2199473

Short-lived charge-transfer excitons in organic photovoltaic cells studied by high-field magneto-photocurrent
journal, July 2014

  • Devir-Wolfman, Ayeleth H.; Khachatryan, Bagrat; Gautam, Bhoj R.
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5529

EasySpin, a comprehensive software package for spectral simulation and analysis in EPR
journal, January 2006

Theory of time-domain measurement of spin-dependent recombination with pulsed electrically detected magnetic resonance
journal, December 2003

Large magnetoresistance in nonmagnetic π -conjugated semiconductor thin film devices
journal, November 2005

Tuning Hyperfine Fields in Conjugated Polymers for Coherent Organic Spintronics
journal, February 2011

  • Lee, Sang-Yun; Paik, Seo-Young; McCamey, Dane R.
  • Journal of the American Chemical Society, Vol. 133, Issue 7
  • DOI: 10.1021/ja108352d

Probing long-range carrier-pair spin–spin interactions in a conjugated polymer by detuning of electrically detected spin beating
journal, April 2015

  • van Schooten, Kipp J.; Baird, Douglas L.; Limes, Mark E.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7688

Tuning organic magnetoresistance in polymer-fullerene blends by controlling spin reaction pathways
journal, August 2013

  • Janssen, P.; Cox, M.; Wouters, S. H. W.
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3286

Transport and recombination through weakly coupled localized spin pairs in semiconductors during coherent spin excitation
journal, December 2006

Tuning effective hyperfine fields in PEDOT:PSS thin films by doping
journal, December 2018

Microscopic modeling of magnetic-field effects on charge transport in organic semiconductors
journal, August 2011

High-Field Magnetoresistance of Organic Semiconductors
journal, August 2018

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