Bismuth as a Reactive Solvent in the Synthesis of Multicomponent Transition-Metal-Bearing Bismuthides

Ovchinnikov, Alexander; Bobev, Svilen

doi:10.1021/acs.inorgchem.9b02881

Title: Bismuth as a Reactive Solvent in the Synthesis of Multicomponent Transition-Metal-Bearing Bismuthides

Journal Article · 20 December 2019 · Inorganic Chemistry

DOI: https://doi.org/10.1021/acs.inorgchem.9b02881 · OSTI ID:1595734

^[1];

^[2]

Univ. of Delaware, Newark, DE (United States); Stockholm Univ. (Sweden)
Univ. of Delaware, Newark, DE (United States)

Employment of liquid bismuth (Bi) allows the facile single-crystal growth of compounds containing elements with high melting points, provided that these elements have reasonably high solubility in Bi. Utilization of the Bi flux approach yielded two new ternary bismuthides, SrNi_0.17(1)Bi₂ [a defect variant of the BaCuSn₂ type, space group Cmcm, α = 4.879(2) Å, b = 17.580(6) Å, and c = 4.696(2) Å] and CaTi₃Bi₄ [NdTi₃(Sn_0.1Sb_0.9)₄ structure type, space group Fmmm, a = 5.6295(7) Å, b = 9.8389(1) Å, and c = 23.905(3) Å]. In addition, the ternary antimonide CaV3Sb4, isostructural with CaTi₃Bi₄, was synthesized from antimony (Sb) flux, and analyzed with the goal of validating structural assessment of the bismuthide analogue, where the X-ray crystallographic work proved to be very challenging. All synthesized compounds exhibit complex crystal structures featuring quasi-two-dimensional building blocks of different topologies. First-principle calculations reveal hypervalent bonding in the homoatomic Bi subunits. Lastly, physical property measurements indicate metallic conductivity and the absence of localized magnetism in the studied compounds.

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Research Organization:: Univ. of Delaware, Newark, DE (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0008885

OSTI ID:: 1595734

Alternate ID(s):: OSTI ID: 1698007

Journal Information:: Inorganic Chemistry, Vol. 59, Issue 6; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 8 works

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References (75)

Growth of single crystals from metallic fluxes Canfield, P. C.; Fisk, Z. Philosophical Magazine B, Vol. 65, Issue 6 https://doi.org/10.1080/13642819208215073	journal	June 1992
The Metal Flux: A Preparative Tool for the Exploration of Intermetallic Compounds Kanatzidis, Mercouri G.; Pöttgen, Rainer; Jeitschko, Wolfgang Angewandte Chemie International Edition, Vol. 44, Issue 43 https://doi.org/10.1002/anie.200462170	journal	November 2005
Crystal Growth and the Search for Highly Correlated Intermetallics Thomas, Evan Lyle; Millican, Jasmine N.; Okudzeto, Edem K. Comments on Inorganic Chemistry, Vol. 27, Issue 1-2 https://doi.org/10.1080/02603590600666215	journal	August 2006
Adventures in Crystal Growth: Synthesis and Characterization of Single Crystals of Complex Intermetallic Compounds Phelan, W. Adam; Menard, Melissa C.; Kangas, Michael J. Chemistry of Materials, Vol. 24, Issue 3 https://doi.org/10.1021/cm2019873	journal	December 2011
Clusters, Assemble: Growth of Intermetallic Compounds from Metal Flux Reactions Latturner, Susan E. Accounts of Chemical Research, Vol. 51, Issue 1 https://doi.org/10.1021/acs.accounts.7b00483	journal	December 2017
Crystal Growth of Materials with the ThCr ₂ Si ₂ Structure Type Kliemt, Kristin; Peters, Marius; Feldmann, Fabian Crystal Research and Technology, Vol. 55, Issue 2 https://doi.org/10.1002/crat.201900116	journal	October 2019
Layered Quaternary Germanides—Synthesis and Crystal and Electronic Structures of AE Li ₂ In ₂ Ge ₂ ( AE = Sr, Ba, Eu) Ovchinnikov, Alexander; Bobev, Svilen Inorganic Chemistry, Vol. 58, Issue 12 https://doi.org/10.1021/acs.inorgchem.9b00588	journal	May 2019
On the effect of Ga and In substitutions in the Ca ₁₁ Bi ₁₀ and Yb ₁₁ Bi ₁₀ bismuthides crystallizing in the tetragonal Ho ₁₁ Ge ₁₀ structure type Ovchinnikov, Alexander; Bobev, Svilen Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 3 https://doi.org/10.1107/S2053229618001596	journal	February 2018
Multifaceted Sn–Sn bonding in the solid state. Synthesis and structural characterization of four new Ca–Li–Sn compounds Ovchinnikov, Alexander; Bobev, Svilen Dalton Transactions, Vol. 48, Issue 38 https://doi.org/10.1039/C9DT02803J	journal	January 2019
Yet again, new compounds found in systems with known binary phase diagrams. Synthesis, crystal and electronic structure of Nd 3 Bi 7 and Sm 3 Bi 7 Ovchinnikov, Alexander; Makongo, Julien P. A.; Bobev, Svilen Chemical Communications, Vol. 54, Issue 51 https://doi.org/10.1039/C8CC02563K	journal	January 2018
Discovery of FeBi ₂ Walsh, James P. S.; Clarke, Samantha M.; Meng, Yue ACS Central Science, Vol. 2, Issue 11 https://doi.org/10.1021/acscentsci.6b00287	journal	October 2016
Creating Binary Cu–Bi Compounds via High-Pressure Synthesis: A Combined Experimental and Theoretical Study Clarke, Samantha M.; Amsler, Maximilian; Walsh, James P. S. Chemistry of Materials, Vol. 29, Issue 12 https://doi.org/10.1021/acs.chemmater.7b01418	journal	May 2017
Growth and characterization of large weak topological insulator Bi2TeI single crystal by Bismuth self-flux method Ryu, Gihun; Son, Kwanghyo; Schütz, Gisela Journal of Crystal Growth, Vol. 440 https://doi.org/10.1016/j.jcrysgro.2016.01.018	journal	April 2016
Crystal Structure, Magnetism, ⁸⁹ Y Solid State NMR, and ¹²¹ Sb Mössbauer Spectroscopic Investigations of YIrSb: Crystal Structure, Magnetism, ⁸⁹ Y Solid State NMR, and ¹²¹ Sb Mössbauer Spectroscopic Investigations of YIrSb Benndorf, Christopher; Heletta, Lukas; Block, Theresa Zeitschrift für anorganische und allgemeine Chemie, Vol. 643, Issue 4 https://doi.org/10.1002/zaac.201600432	journal	January 2017
Structure and Bonding of Bi ₄ Ir: A Difficult-to-Access Bismuth Iridide with a Unique Framework Structure Isaeva, Anna; Ruck, Michael; Schäfer, Konrad Inorganic Chemistry, Vol. 54, Issue 3 https://doi.org/10.1021/ic502205k	journal	October 2014
Neue Vertreter ternärer Verbindungen mit C 1-Struktur Nowotny, H.; Glatzl, B. Monatshefte für Chemie und verwandte Teile anderer Wissenschaften, Vol. 83, Issue 1 https://doi.org/10.1007/BF00897823	journal	January 1952
Synthesis, Crystal and Electronic Structure of the Titanium Bismuthides Sr ₅ Ti ₁₂ Bi _{19+ x} , Ba ₅ Ti ₁₂ Bi _{19+ x} , and Sr _5- _δ Eu _δ Ti ₁₂ Bi _{19+ x} ( x ≈ 0.5-1.0; δ ≈ 2.4, 4.0) : Synthesis, Crystal and Electronic Structure of the Titanium Bismuthides Sr5Ti12Bi19+x, Ba5Ti12Bi19+x, and Sr5-δEuδTi12Bi19+x (x ≈ 0.5-1.0; δ ≈ 2.4, 4. Ovchinnikov, Alexander; Bobev, Svilen European Journal of Inorganic Chemistry, Vol. 2018, Issue 11 https://doi.org/10.1002/ejic.201701426	journal	March 2018
Synthesis, and Crystal and Electronic Structures, of the Titanium-Rich Bismuthides AE 3 Ti 8 Bi 10 ( AE = Sr, Ba, Eu) Ovchinnikov, Alexander; Bobev, Svilen Inorganic Chemistry, Vol. 58, Issue 5 https://doi.org/10.1021/acs.inorgchem.8b01952	journal	September 2018
Zintl phases with group 15 elements and the transition metals: A brief overview of pnictides with diverse and complex structures Ovchinnikov, Alexander; Bobev, Svilen Journal of Solid State Chemistry, Vol. 270 https://doi.org/10.1016/j.jssc.2018.11.029	journal	February 2019
Chemical Bonding in TiSb ₂ and VSb ₂ : A Quantum Chemical and Experimental Study Armbrüster, Marc; Schnelle, Walter; Schwarz, Ulrich Inorganic Chemistry, Vol. 46, Issue 16 https://doi.org/10.1021/ic070284p	journal	August 2007
Ternary rare-earth titanium antimonides: Phase equilibria in the RE–Ti–Sb (RE=La, Er) systems and crystal structures of RE2Ti7Sb12 (RE=La, Ce, Pr, Nd) and RETi3(SnxSb1–x)4 (RE=Nd, Sm) Bie, Haiying; Devon Moore, S. H.; Piercey, Davin G. Journal of Solid State Chemistry, Vol. 180, Issue 8 https://doi.org/10.1016/j.jssc.2007.05.030	journal	August 2007
Crystallographic Computing System JANA2006: General features Petříček, Václav; Dušek, Michal; Palatinus, Lukáš Zeitschrift für Kristallographie - Crystalline Materials, Vol. 229, Issue 5 https://doi.org/10.1515/zkri-2014-1737	journal	January 2014
SHELXT – Integrated space-group and crystal-structure determination Sheldrick, George M. Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053273314026370	journal	January 2015
Crystal structure refinement with SHELXL Sheldrick, George M. Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8 https://doi.org/10.1107/S2053229614024218	journal	January 2015
STRUCTURE TIDY – a computer program to standardize crystal structure data Gelato, L. M.; Parthé, E. Journal of Applied Crystallography, Vol. 20, Issue 2 https://doi.org/10.1107/S0021889887086965	journal	April 1987
A local exchange-correlation potential for the spin polarized case. i Barth, U. von; Hedin, L. Journal of Physics C: Solid State Physics, Vol. 5, Issue 13 https://doi.org/10.1088/0022-3719/5/13/012	journal	July 1972
The Crystal Orbital Hamilton Population (COHP) Method as a Tool to Visualize and Analyze Chemical Bonding in Intermetallic Compounds Steinberg, Simon; Dronskowski, Richard Crystals, Vol. 8, Issue 5 https://doi.org/10.3390/cryst8050225	journal	May 2018
ELF: The Electron Localization Function Savin, Andreas; Nesper, Reinhard; Wengert, Steffen Angewandte Chemie International Edition in English, Vol. 36, Issue 17 https://doi.org/10.1002/anie.199718081	journal	September 1997
Surface-induced magnetic fluctuations in a single-crystal NiBi 3 superconductor Zhu, Xiangde; Lei, Hechang; Petrovic, Cedomir Physical Review B, Vol. 86, Issue 2 https://doi.org/10.1103/PhysRevB.86.024527	journal	July 2012
Single-crystal studies of non-stoichiometric CeNiSi2-type phases in the Ce-Co-Si and Lu-Co-Si systems Chabot, B.; Parthé, E.; Steinmetz, J. Journal of the Less Common Metals, Vol. 125 https://doi.org/10.1016/0022-5088(86)90089-5	journal	November 1986
Nouveaux isotypes de CeNiSi2 dans les systemes R-M-X (R ≡ La-Lu, M ≡ metaux des groupes 7 A 11 ET X ≡ Ge, Sn). I Compositions et parametres cristallins François, M.; Venturini, G.; Malaman, B. Journal of the Less Common Metals, Vol. 160, Issue 2 https://doi.org/10.1016/0022-5088(90)90381-S	journal	May 1990
New phases in the thorium-iron-tin system: ThFe0.22Sn2 and Th4Fe13Sn5 Manfrinetti, P.; Canepa, F.; Palenzona, A. Journal of Alloys and Compounds, Vol. 247, Issue 1-2 https://doi.org/10.1016/S0925-8388(96)02591-1	journal	January 1997
Synthesis and crystal structure of NdFe0.45Ge2 and HoFe0.33Ge2 Zeng, Lingmin; Franzen, Hugo F. Journal of Alloys and Compounds, Vol. 267, Issue 1-2 https://doi.org/10.1016/S0925-8388(97)00518-5	journal	March 1998
Tb ₄ FeGe ₈ Grown in Liquid Gallium: Trans − Cis Chains from the Distortion of a Planar Ge Square Net Zhuravleva, Marina A.; Bilc, Daniel; Pcionek, Robert J. Inorganic Chemistry, Vol. 44, Issue 7 https://doi.org/10.1021/ic0487878	journal	March 2005
Structural and magnetic characterization of DyFexSn2 (0≤x≤0.3) intermetallics Pereira, L. C. J.; Rojas, D. P.; Waerenborgh, J. C. Intermetallics, Vol. 13, Issue 1 https://doi.org/10.1016/j.intermet.2004.05.009	journal	January 2005
The Stannides YNi x Sn2 (x = 0, 0.14, 0.21, 1) – Syntheses, Structure, and 119Sn Mössbauer Spectroscopy Peter Sebastian, C.; Pöttgen, Rainer Monatshefte für Chemie - Chemical Monthly, Vol. 138, Issue 5 https://doi.org/10.1007/s00706-007-0597-2	journal	February 2007
Structure and magnetic properties of rare-earth chromium germanides RECrxGe2 (RE=Sm, Gd–Er) Bie, Haiying; Tkachuk, Andriy V.; Mar, Arthur Journal of Solid State Chemistry, Vol. 182, Issue 1 https://doi.org/10.1016/j.jssc.2008.10.013	journal	January 2009
Structural Modulations in the Rare-Earth Metal Digermanides REAl _{1– x} Ge ₂ (RE = Gd–Tm, Lu, Y; 0.8 < x < 0.9). Correlations between Long- and Short-Range Vacancy Ordering Zhang, Jiliang; Wang, Yingmin; Bobev, Svilen Inorganic Chemistry, Vol. 54, Issue 3 https://doi.org/10.1021/ic501002j	journal	June 2014
Notizen:Neue Verbindungen mit CeNiSi ₂ -Struktur / New Compounds with C eNiSi ₂ -Type Structure Johrendt, Dirk; Lux, Christine; Mewis, Albrecht Zeitschrift für Naturforschung B, Vol. 51, Issue 8 https://doi.org/10.1515/znb-1996-0824	journal	August 1996
The Ternary Alkaline-Earth Metal Manganese Bismuthides Sr ₂ MnBi ₂ and Ba ₂ Mn _{1– x} Bi ₂ ( x ≈ 0.15) Ovchinnikov, Alexander; Saparov, Bayrammurad; Xia, Sheng-Qing Inorganic Chemistry, Vol. 56, Issue 20 https://doi.org/10.1021/acs.inorgchem.7b01851	journal	October 2017
Oscillatory dependence of superconductive critical temperature on number of valency electrons in Cu3Au-type alloys Havinga, E. E.; Damsma, H.; Van Maaren, M. H. Journal of Physics and Chemistry of Solids, Vol. 31, Issue 12 https://doi.org/10.1016/0022-3697(70)90261-1	journal	December 1970
Eine neue Verzerrungsvariante des CaBe2Ge2-Typs – Die Kristallstrukturen von SrPd2Bi2, BaPd2Bi2 und BaAu2Sb2 Frik, Lars; Johrendt, Dirk; Mewis, Albrecht Zeitschrift für anorganische und allgemeine Chemie, Vol. 632, Issue 8-9 https://doi.org/10.1002/zaac.200600065	journal	July 2006
A ₁₄ MgBi ₁₁ ( A = Ca, Sr, Eu): Magnesium Bismuth Based Zintl Phases as Potential Thermoelectric Materials Tan, Wenjie; Wu, Zhen; Zhu, Min Inorganic Chemistry, Vol. 56, Issue 17 https://doi.org/10.1021/acs.inorgchem.7b01548	journal	August 2017
Synthesis, Crystal Structures and Properties of the Zintl Phases Sr2ZnP2, Sr2ZnAs2, A2ZnSb2 and A2ZnBi2 (A = Sr and Eu) Wilson, Dereck K.; Saparov, Bayrammurad; Bobev, Svilen Zeitschrift für anorganische und allgemeine Chemie, Vol. 637, Issue 13 https://doi.org/10.1002/zaac.201100177	journal	August 2011
Synthesis and crystal chemistry of new ternary pnictides containing lithium—adding structural complexity one step at a time Schäfer, Marion C.; Suen, Nian-Tzu; Bobev, Svilen Dalton Trans., Vol. 43, Issue 44 https://doi.org/10.1039/C4DT02220C	journal	January 2014
Interplay between Size and Electronic Effects in Determining the Homogeneity Range of the A ₉ Zn ₄₊ _x Pn ₉ and A ₉ Cd ₄₊ _x Pn ₉ Phases (0 ≤ x ≤ 0.5), A = Ca, Sr, Yb, Eu; Pn = Sb, Bi Xia, Sheng-qing; Bobev, Svilen Journal of the American Chemical Society, Vol. 129, Issue 32 https://doi.org/10.1021/ja0728425	journal	August 2007
Ternary pnictides MNi2−xPn2 (M ≡ Sr and rare earth metals, Pn ≡ Sb, Bi) with defect CaBe2Ge2 and defect ThCr2Si2 structures Hofmann, W. K.; Jeitschko, W. Journal of the Less Common Metals, Vol. 138, Issue 2 https://doi.org/10.1016/0022-5088(88)90119-1	journal	March 1988
Crystal and magnetic structures of the superconductor CeNi 0 . 8 Bi 2 Kodama, K.; Wakimoto, S.; Igawa, N. Physical Review B, Vol. 83, Issue 21 https://doi.org/10.1103/PhysRevB.83.214512	journal	June 2011
Die Kristallstruktur von BiNi: eine komplexe Ausdünnungsvariante des InNi2-Typs Ruck, Michael Zeitschrift für anorganische und allgemeine Chemie, Vol. 625, Issue 12 https://doi.org/10.1002/(SICI)1521-3749(199912)625:12<2050::AID-ZAAC2050>3.0.CO;2-R	journal	December 1999
A Metastable Metal with Decagonal Local Symmetry Obtained by Low-Temperature Pseudomorphosis Kaiser, Martin; Isaeva, Anna; Ruck, Michael Angewandte Chemie International Edition, Vol. 50, Issue 27 https://doi.org/10.1002/anie.201101248	journal	May 2011
The RELixSn2 (RE=La–Nd, Sm, and Gd; 0≤x<1) series revisited. Synthesis, crystal chemistry, and magnetic susceptibilities Makongo, Julien P. A.; Suen, Nian-Tzu; Guo, Shengping Journal of Solid State Chemistry, Vol. 211 https://doi.org/10.1016/j.jssc.2013.12.010	journal	March 2014
Hypervalent Bismuthides La ₃ MBi ₅ (M = Ti, Zr, Hf) and Related Antimonides: Absence of Superconductivity Murakami, Taito; Yamamoto, Takafumi; Takeiri, Fumitaka Inorganic Chemistry, Vol. 56, Issue 9 https://doi.org/10.1021/acs.inorgchem.7b00031	journal	April 2017
Undistorted linear Bi chains with hypervalent bonding in La ₃ TiBi ₅ from single-crystal X-ray diffraction Ovchinnikov, Alexander; Bobev, Svilen Acta Crystallographica Section C Structural Chemistry, Vol. 74, Issue 5 https://doi.org/10.1107/S205322961800565X	journal	April 2018
Crystal chemistry and magnetic properties of the solid solutions Ca _14−x RE _x MnBi ₁₁ (RE = La–Nd, Sm, and Gd–Ho; x ≈ 0.6–0.8) Ovchinnikov, Alexander; Prakash, Jai; Bobev, Svilen Dalton Transactions, Vol. 46, Issue 46 https://doi.org/10.1039/C7DT03715E	journal	January 2017
Yb ₁₄ MgBi ₁₁ : structure, thermoelectric properties and the effect of the structure on low lattice thermal conductivity Hu, Yufei; Kauzlarich, Susan M. Dalton Transactions, Vol. 46, Issue 12 https://doi.org/10.1039/C7DT00183E	journal	January 2017
Neue ternäre erdalkali-übergangselement-pnictide Brechtel, Erwin; Cordier, Gerhard; Schäfer, Herbert Journal of the Less Common Metals, Vol. 79, Issue 1 https://doi.org/10.1016/0022-5088(81)90057-6	journal	May 1981
Effect of Eu magnetism on the electronic properties of the candidate Dirac material EuMnBi 2 May, Andrew F.; McGuire, Michael A.; Sales, Brian C. Physical Review B, Vol. 90, Issue 7 https://doi.org/10.1103/PhysRevB.90.075109	journal	August 2014
The Zintl-Klemm Concept - A Historical Survey: The Zintl-Klemm Concept - A Historical Survey Nesper, Reinhard Zeitschrift für anorganische und allgemeine Chemie, Vol. 640, Issue 14 https://doi.org/10.1002/zaac.201400403	journal	November 2014
Neue tern�re Verbindungen des Caesiums mit Elementen der 8. Nebengruppe und 5. Hauptgruppe Noack, Marion; Schuster, Hans-Uwe Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 620, Issue 10 https://doi.org/10.1002/zaac.19946201019	journal	October 1994
Data from the electronic band structures of several Zintl phases with group 15 elements and the transition metals Ovchinnikov, Alexander; Bobev, Svilen Data in Brief, Vol. 22 https://doi.org/10.1016/j.dib.2018.12.040	journal	February 2019
Superconductivity in CaBi ₂ Winiarski, M. J.; Wiendlocha, B.; Gołąb, S. Physical Chemistry Chemical Physics, Vol. 18, Issue 31 https://doi.org/10.1039/C6CP02856J	journal	January 2016
Synthesis and crystal structure of EuBi2 Sun, Zhong-Ming; Mao, Jiang-Gao Journal of Solid State Chemistry, Vol. 177, Issue 10 https://doi.org/10.1016/j.jssc.2004.07.006	journal	October 2004
Crystal structure of some phases and alloying behaviour in alkaline earths, europium and ytterbium pnictides Merlo, F.; Fornasini, M. L. Materials Research Bulletin, Vol. 29, Issue 2 https://doi.org/10.1016/0025-5408(94)90135-X	journal	February 1994
Ba5Ti12Sb19+x, a polar intermetallic compound with a stuffed γ-brass structure Bie, Haiying; Mar, Arthur Journal of Solid State Chemistry, Vol. 182, Issue 11 https://doi.org/10.1016/j.jssc.2009.08.030	journal	November 2009
Magnetic properties of new antiferromagnetic heavy-fermion compounds, Ce3TiBi5 and CeTi3Bi4 Motoyama, Gaku; Sezaki, Masumi; Gouchi, Jun Physica B: Condensed Matter, Vol. 536 https://doi.org/10.1016/j.physb.2017.10.005	journal	May 2018
Preparation and Crystal Structure of the Titanium and Hafnium Bismuthides Ti8Bi9and Hf8Bi9 Richter, Carolin G.; Jeitschko, Wolfgang Journal of Solid State Chemistry, Vol. 134, Issue 1 https://doi.org/10.1006/jssc.1997.7525	journal	November 1997
Structural, thermal, and electrical properties of CrSi2 Dasgupta, T.; Etourneau, J.; Chevalier, B. Journal of Applied Physics, Vol. 103, Issue 11 https://doi.org/10.1063/1.2917347	journal	June 2008
Cs2Pt3S4 und Rb2Pt3S4, synthese und struktur Günther, O.; Bronger, W. Journal of the Less Common Metals, Vol. 31, Issue 2 https://doi.org/10.1016/0022-5088(73)90162-8	journal	May 1973
Schichtstrukturen tern�rer Chalkogenide A2M3X4 (A ? K, Rb, Cs; M ? Ni, Pd, Pt; X ? S, Se) Bronger, W.; Rennau, R.; Schmitz, D. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 597, Issue 1 https://doi.org/10.1002/zaac.19915970105	journal	May 1991
Temperature-dependent crystallographic studies and electronic structure of Ba2Cd3Bi4 Xia, Sheng-qing; Bobev, Svilen Journal of Solid State Chemistry, Vol. 179, Issue 11 https://doi.org/10.1016/j.jssc.2006.07.003	journal	November 2006
Five new ternary indium-arsenides discovered. Synthesis and structural characterization of the Zintl phases Sr3In2As4, Ba3In2As4, Eu3In2As4, Sr5In2As6 and Eu5In2As6 Childs, Amanda B.; Baranets, Sviatoslav; Bobev, Svilen Journal of Solid State Chemistry, Vol. 278 https://doi.org/10.1016/j.jssc.2019.07.050	journal	October 2019
Hypervalent Bonding in One, Two, and Three Dimensions: Extending the Zintl-Klemm Concept to Nonclassical Electron-Rich Networks A. Papoian, Garegin; Hoffmann, Roald Angewandte Chemie International Edition, Vol. 39, Issue 14 https://doi.org/10.1002/1521-3773(20000717)39:14<2408::AID-ANIE2408>3.0.CO;2-U	journal	July 2000
Die thermomagnetischen Eigenschaften der Elemente Honda, Kōtarō Annalen der Physik, Vol. 337, Issue 10 https://doi.org/10.1002/andp.19103371006	journal	January 1910
Magnetochemische Untersuchungen. Die thermomagnetischen Eigenschaften der Elemente. II Owen, Morris Annalen der Physik, Vol. 342, Issue 4 https://doi.org/10.1002/andp.19123420404	journal	January 1912
Electrical Resistivity of Aluminum and Manganese Desai, P. D.; James, H. M.; Ho, C. Y. Journal of Physical and Chemical Reference Data, Vol. 13, Issue 4 https://doi.org/10.1063/1.555725	journal	October 1984

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