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Title: Characterization and analysis of FA x Cs (1-x) Pb(I y Br (1-y) ) 3 perovskite solar cells with thickness controlled transport layers for performance optimization

Abstract

Strong characterization methods are needed to fully comprehend the chemistry and composition of perovskite solar cells. Understanding the interaction between layers inside a cell and how they react with the environment is important to achieve optimum manufacturing processes, and improve efficiency of perovskite solar cells. Here, we probe a hybrid organic-inorganic perovskite cell structure formed by a fluorine-doped tin oxide (FTO), cassiterite (SnO 2), mixed halide perovskite, Spiro-OMeTAD and silver layers. We have demonstrated a power conversion efficiency (PCE) greater than 19% and aV oc of more than 1.1 V for a wide-band gap (1.6 eV) perovskite solar cell.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [2];  [3];  [1]
  1. Univ. of Texas at El Paso, TX (United States). Dept. of Electrical and Computer Engineering
  2. School of Engineering at Bilbao (Spain)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1595689
Alternate Identifier(s):
OSTI ID: 1567914
Report Number(s):
BNL-213573-2020-JAAM
Journal ID: ISSN 2158-3226
Grant/Contract Number:  
SC0012704; P120A160056
Resource Type:
Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 9; Journal Issue: 10; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
77 NANOSCIENCE AND NANOTECHNOLOGY; Solar cells; Quantum efficiency; Perovskites; Spin coating; Electronic bandstructure; X-ray photoelectron spectroscopy; Thin film deposition; Scanning electron microscopy; Atomic force microscopy; Photoluminescence spectroscopy

Citation Formats

Valerio, L., De La Rosa, A., Rodriguez, V., Enriquez, C., Telles, A., Ramirez, Y., Rivera, D., Hierro, J., Bustamante, L., Tong, X., and Hodges, D. Characterization and analysis of FA x Cs (1-x) Pb(I y Br (1-y) ) 3 perovskite solar cells with thickness controlled transport layers for performance optimization. United States: N. p., 2019. Web. doi:10.1063/1.5123400.
Valerio, L., De La Rosa, A., Rodriguez, V., Enriquez, C., Telles, A., Ramirez, Y., Rivera, D., Hierro, J., Bustamante, L., Tong, X., & Hodges, D. Characterization and analysis of FA x Cs (1-x) Pb(I y Br (1-y) ) 3 perovskite solar cells with thickness controlled transport layers for performance optimization. United States. doi:10.1063/1.5123400.
Valerio, L., De La Rosa, A., Rodriguez, V., Enriquez, C., Telles, A., Ramirez, Y., Rivera, D., Hierro, J., Bustamante, L., Tong, X., and Hodges, D. Tue . "Characterization and analysis of FA x Cs (1-x) Pb(I y Br (1-y) ) 3 perovskite solar cells with thickness controlled transport layers for performance optimization". United States. doi:10.1063/1.5123400. https://www.osti.gov/servlets/purl/1595689.
@article{osti_1595689,
title = {Characterization and analysis of FA x Cs (1-x) Pb(I y Br (1-y) ) 3 perovskite solar cells with thickness controlled transport layers for performance optimization},
author = {Valerio, L. and De La Rosa, A. and Rodriguez, V. and Enriquez, C. and Telles, A. and Ramirez, Y. and Rivera, D. and Hierro, J. and Bustamante, L. and Tong, X. and Hodges, D.},
abstractNote = {Strong characterization methods are needed to fully comprehend the chemistry and composition of perovskite solar cells. Understanding the interaction between layers inside a cell and how they react with the environment is important to achieve optimum manufacturing processes, and improve efficiency of perovskite solar cells. Here, we probe a hybrid organic-inorganic perovskite cell structure formed by a fluorine-doped tin oxide (FTO), cassiterite (SnO2), mixed halide perovskite, Spiro-OMeTAD and silver layers. We have demonstrated a power conversion efficiency (PCE) greater than 19% and aVoc of more than 1.1 V for a wide-band gap (1.6 eV) perovskite solar cell.},
doi = {10.1063/1.5123400},
journal = {AIP Advances},
number = 10,
volume = 9,
place = {United States},
year = {2019},
month = {10}
}

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