Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts

doi:10.1002/ange.201912857

Title: Understanding the Origin of Highly Selective CO ₂ Electroreduction to CO on Ni,N‐doped Carbon Catalysts

Authors:

Koshy, David M. ^[1]; Chen, Shucheng ^[1]; Lee, Dong Un ^[1]; Stevens, Michaela Burke ^[1]; Abdellah, Ahmed M. ^[2]; Dull, Samuel M. ^[1]; Chen, Gan ^[3]; Nordlund, Dennis ^[4]; Gallo, Alessandro ^[5]; Hahn, Christopher ^[5];

^[2]; Bao, Zhenan ^[1]; Jaramillo, Thomas F. ^[6]

SUNCAT Center for Interface Science and CatalysisDepartment of Chemical EngineeringStanford University Stanford CA 94305 USA
Department of Chemical EngineeringMcMaster University Hamilton ON Canada
Department of Materials Science and EngineeringStanford University Stanford CA 94305 USA
Stanford Synchotron Radiation LightsourceSLAC National Accelerator Laboratory Menlo Park CA 94025 USA
SUNCAT Center for Interface Science and CatalysisSLAC National Accelerator Laboratory Menlo Park CA 94025 USA
SUNCAT Center for Interface Science and CatalysisDepartment of Chemical EngineeringStanford University Stanford CA 94305 USA, SUNCAT Center for Interface Science and CatalysisSLAC National Accelerator Laboratory Menlo Park CA 94025 USA

Publication Date:: 2020-01-28

Sponsoring Org.:: USDOE

OSTI Identifier:: 1595529

Grant/Contract Number:: SC0004993; AC02-76SF00515

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie

Additional Journal Information:: Journal Name: Angewandte Chemie Journal Volume: 132 Journal Issue: 10; Journal ID: ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Koshy, David M., Chen, Shucheng, Lee, Dong Un, Stevens, Michaela Burke, Abdellah, Ahmed M., Dull, Samuel M., Chen, Gan, Nordlund, Dennis, Gallo, Alessandro, Hahn, Christopher, Higgins, Drew C., Bao, Zhenan, and Jaramillo, Thomas F. Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts.  Germany: N. p., 2020. 
        Web.  doi:10.1002/ange.201912857.

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                    Koshy, David M., Chen, Shucheng, Lee, Dong Un, Stevens, Michaela Burke, Abdellah, Ahmed M., Dull, Samuel M., Chen, Gan, Nordlund, Dennis, Gallo, Alessandro, Hahn, Christopher, Higgins, Drew C., Bao, Zhenan, & Jaramillo, Thomas F. Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts.  Germany.  doi:10.1002/ange.201912857.

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                    Koshy, David M., Chen, Shucheng, Lee, Dong Un, Stevens, Michaela Burke, Abdellah, Ahmed M., Dull, Samuel M., Chen, Gan, Nordlund, Dennis, Gallo, Alessandro, Hahn, Christopher, Higgins, Drew C., Bao, Zhenan, and Jaramillo, Thomas F. Tue .  
        "Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts".  Germany.  doi:10.1002/ange.201912857.

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@article{osti_1595529,

  title        = {Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts},

  author       = {Koshy, David M. and Chen, Shucheng and Lee, Dong Un and Stevens, Michaela Burke and Abdellah, Ahmed M. and Dull, Samuel M. and Chen, Gan and Nordlund, Dennis and Gallo, Alessandro and Hahn, Christopher and Higgins, Drew C. and Bao, Zhenan and Jaramillo, Thomas F.},

  abstractNote = {},

  doi          = {10.1002/ange.201912857},

  journal      = {Angewandte Chemie},

  number       = 10,

  volume       = 132,

  place        = {Germany},

  year         = {2020},

  month        = {1}

}

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DOI: 10.1002/ange.201912857

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Title: Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts

Citation Formats

Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities journal, April 2001

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Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER journal, January 2019

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Nickel-Nitrogen-Modified Graphene: An Efficient Electrocatalyst for the Reduction of Carbon Dioxide to Carbon Monoxide journal, September 2016

Multitechnique Characterization of a Polyaniline–Iron–Carbon Oxygen Reduction Catalyst journal, July 2012

Highly Efficient Electroreduction of CO 2 on Nickel Single‐Atom Catalysts: Atom Trapping and Nitrogen Anchoring journal, October 2019

O 2 Reduction in PEM Fuel Cells: Activity and Active Site Structural Information for Catalysts Obtained by the Pyrolysis at High Temperature of Fe Precursors journal, November 2000

General Techno-Economic Analysis of CO 2 Electrolysis Systems journal, February 2018

X-ray photoelectron spectroscopy of graphitic carbon nanomaterials doped with heteroatoms journal, January 2015

Powerful CO 2 electroreduction performance with N–carbon doped with single Ni atoms journal, January 2019

Carbon-based electrocatalysts for advanced energy conversion and storage journal, August 2015

Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces journal, August 2014

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Correlations between Mass Activity and Physicochemical Properties of Fe/N/C Catalysts for the ORR in PEM Fuel Cell via 57 Fe Mössbauer Spectroscopy and Other Techniques journal, January 2014

X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases journal, March 1991

High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt journal, April 2011

Achieving highly efficient CO 2 to CO electroreduction exceeding 300 mA cm −2 with single-atom nickel electrocatalysts journal, January 2019

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Investigation of the Ligand Exchange Behavior of Square-Planar Nickel(II) Complexes by X-ray Absorption Spectroscopy and X-ray Diffraction journal, March 2003

Influence of chemical bond of carbon on Ni catalyzed graphitization journal, June 1997

Simultaneous reduction of carbon dioxide and nitrate ions at gas-diffusion electrodes with various metallophthalocyanine catalysts journal, November 2003

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces journal, January 2012

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Nature of WO x Sites on SiO 2 and Their Molecular Structure–Reactivity/Selectivity Relationships for Propylene Metathesis journal, April 2016

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Title: Understanding the Origin of Highly Selective CO ₂ Electroreduction to CO on Ni,N‐doped Carbon Catalysts

Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
journal, April 2001

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Highly Tunable and Facile Synthesis of Uniform Carbon Flower Particles
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journal, March 1991

High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt
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Achieving highly efficient CO 2 to CO electroreduction exceeding 300 mA cm −2 with single-atom nickel electrocatalysts
journal, January 2019

Atomically dispersed Ni(i) as the active site for electrochemical CO2 reduction
journal, February 2018

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journal, March 2003

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journal, June 1997

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journal, November 2003

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
journal, January 2012

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journal, January 2018

Nature of WO _x Sites on SiO ₂ and Their Molecular Structure–Reactivity/Selectivity Relationships for Propylene Metathesis
journal, April 2016

Direct atomic-level insight into the active sites of a high-performance PGM-free ORR catalyst
journal, August 2017

Growth of single-crystal graphite by pyrolysis of acetylene over metals
journal, February 1969

Combining theory and experiment in electrocatalysis: Insights into materials design
journal, January 2017

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
journal, January 2018

Isolated Ni single atoms in graphene nanosheets for high-performance CO ₂ reduction
journal, January 2018

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journal, October 2017

Computational and experimental evidence for a new TM–N ₃ /C moiety family in non-PGM electrocatalysts
journal, January 2015

Opportunities and challenges in the electrocatalysis of CO2 and CO reduction using bifunctional surfaces: A theoretical and experimental study of Au–Cd alloys
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