Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts

doi:10.1002/ange.201912857

This content will become publicly available on January 27, 2021

Title: Understanding the Origin of Highly Selective CO ₂ Electroreduction to CO on Ni,N‐doped Carbon Catalysts

Authors:

Koshy, David M. ^[1]; Chen, Shucheng ^[1]; Lee, Dong Un ^[1]; Stevens, Michaela Burke ^[1]; Abdellah, Ahmed M. ^[2]; Dull, Samuel M. ^[1]; Chen, Gan ^[3]; Nordlund, Dennis ^[4]; Gallo, Alessandro ^[5]; Hahn, Christopher ^[5];

^[2]; Bao, Zhenan ^[1]; Jaramillo, Thomas F. ^[6]

SUNCAT Center for Interface Science and CatalysisDepartment of Chemical EngineeringStanford University Stanford CA 94305 USA
Department of Chemical EngineeringMcMaster University Hamilton ON Canada
Department of Materials Science and EngineeringStanford University Stanford CA 94305 USA
Stanford Synchotron Radiation LightsourceSLAC National Accelerator Laboratory Menlo Park CA 94025 USA
SUNCAT Center for Interface Science and CatalysisSLAC National Accelerator Laboratory Menlo Park CA 94025 USA
SUNCAT Center for Interface Science and CatalysisDepartment of Chemical EngineeringStanford University Stanford CA 94305 USA, SUNCAT Center for Interface Science and CatalysisSLAC National Accelerator Laboratory Menlo Park CA 94025 USA

Publication Date:: 2020-01-28

Sponsoring Org.:: USDOE

OSTI Identifier:: 1595529

Grant/Contract Number:: SC0004993; AC02-76SF00515

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Angewandte Chemie

Additional Journal Information:: Journal Name: Angewandte Chemie Journal Volume: 132 Journal Issue: 10; Journal ID: ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)

Country of Publication:: Germany

Language:: English

Citation Formats


                    Koshy, David M., Chen, Shucheng, Lee, Dong Un, Stevens, Michaela Burke, Abdellah, Ahmed M., Dull, Samuel M., Chen, Gan, Nordlund, Dennis, Gallo, Alessandro, Hahn, Christopher, Higgins, Drew C., Bao, Zhenan, and Jaramillo, Thomas F. Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts.  Germany: N. p., 2020. 
        Web.  doi:10.1002/ange.201912857.

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                    Koshy, David M., Chen, Shucheng, Lee, Dong Un, Stevens, Michaela Burke, Abdellah, Ahmed M., Dull, Samuel M., Chen, Gan, Nordlund, Dennis, Gallo, Alessandro, Hahn, Christopher, Higgins, Drew C., Bao, Zhenan, & Jaramillo, Thomas F. Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts.  Germany.  doi:10.1002/ange.201912857.

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                    Koshy, David M., Chen, Shucheng, Lee, Dong Un, Stevens, Michaela Burke, Abdellah, Ahmed M., Dull, Samuel M., Chen, Gan, Nordlund, Dennis, Gallo, Alessandro, Hahn, Christopher, Higgins, Drew C., Bao, Zhenan, and Jaramillo, Thomas F. Tue .  
        "Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts".  Germany.  doi:10.1002/ange.201912857.

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@article{osti_1595529,

  title        = {Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts},

  author       = {Koshy, David M. and Chen, Shucheng and Lee, Dong Un and Stevens, Michaela Burke and Abdellah, Ahmed M. and Dull, Samuel M. and Chen, Gan and Nordlund, Dennis and Gallo, Alessandro and Hahn, Christopher and Higgins, Drew C. and Bao, Zhenan and Jaramillo, Thomas F.},

  abstractNote = {},

  doi          = {10.1002/ange.201912857},

  journal      = {Angewandte Chemie},

  number       = 10,

  volume       = 132,

  place        = {Germany},

  year         = {2020},

  month        = {1}

}

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DOI: 10.1002/ange.201912857

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This content will become publicly available on January 27, 2021

Title: Understanding the Origin of Highly Selective CO 2 Electroreduction to CO on Ni,N‐doped Carbon Catalysts

Citation Formats

Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities journal, April 2001

Structural stability and O 2 dissociation on nitrogen-doped graphene with transition metal atoms embedded: A first-principles study journal, June 2015

Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER journal, January 2019

Understanding and Breaking Scaling Relations in Single-Site Catalysis: Methane to Methanol Conversion by Fe IV ═O journal, January 2018

Nickel-Nitrogen-Modified Graphene: An Efficient Electrocatalyst for the Reduction of Carbon Dioxide to Carbon Monoxide journal, September 2016

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Highly Efficient Electroreduction of CO 2 on Nickel Single‐Atom Catalysts: Atom Trapping and Nitrogen Anchoring journal, October 2019

O 2 Reduction in PEM Fuel Cells: Activity and Active Site Structural Information for Catalysts Obtained by the Pyrolysis at High Temperature of Fe Precursors journal, November 2000

General Techno-Economic Analysis of CO 2 Electrolysis Systems journal, February 2018

X-ray photoelectron spectroscopy of graphitic carbon nanomaterials doped with heteroatoms journal, January 2015

Powerful CO 2 electroreduction performance with N–carbon doped with single Ni atoms journal, January 2019

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Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces journal, August 2014

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Highly Tunable and Facile Synthesis of Uniform Carbon Flower Particles journal, July 2018

Correlations between Mass Activity and Physicochemical Properties of Fe/N/C Catalysts for the ORR in PEM Fuel Cell via 57 Fe Mössbauer Spectroscopy and Other Techniques journal, January 2014

X-ray spectroscopic studies of nickel complexes, with application to the structure of nickel sites in hydrogenases journal, March 1991

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Title: Understanding the Origin of Highly Selective CO ₂ Electroreduction to CO on Ni,N‐doped Carbon Catalysts

Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
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Defect-rich and ultrathin N doped carbon nanosheets as advanced trifunctional metal-free electrocatalysts for the ORR, OER and HER
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Understanding and Breaking Scaling Relations in Single-Site Catalysis: Methane to Methanol Conversion by Fe ^IV ═O
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Highly Efficient Electroreduction of CO 2 on Nickel Single‐Atom Catalysts: Atom Trapping and Nitrogen Anchoring
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journal, March 1991

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journal, January 2019

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Influence of chemical bond of carbon on Ni catalyzed graphitization
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journal, November 2003

New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
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journal, January 2018

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journal, August 2017

Growth of single-crystal graphite by pyrolysis of acetylene over metals
journal, February 1969

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journal, January 2017

General synthesis and definitive structural identification of MN4C4 single-atom catalysts with tunable electrocatalytic activities
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Isolated Ni single atoms in graphene nanosheets for high-performance CO ₂ reduction
journal, January 2018

Exclusive Ni–N ₄ Sites Realize Near-Unity CO Selectivity for Electrochemical CO ₂ Reduction
journal, October 2017

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journal, January 2015

Opportunities and challenges in the electrocatalysis of CO2 and CO reduction using bifunctional surfaces: A theoretical and experimental study of Au–Cd alloys
journal, November 2016