skip to main content
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

This content will become publicly available on January 17, 2021

Title: A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater

Abstract

An amidoxime and carboxylate containing chelating adsorbent derived from acrylic fiber shows a fast adsorption rate and high uranium and low vanadium adsorption capacities in real seawater tests.

Authors:
ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [2];  [1];  [3];  [4]
  1. Department of Chemistry, University of Idaho, Moscow, USA, LCW Supercritical Technologies
  2. Marine Sciences Laboratory, Pacific Northwest National Laboratory, Sequim, USA
  3. Department of Chemistry, University of Idaho, Moscow, USA
  4. Chemical Sciences Division, Oak Ridge National Lab, Oak Ridge, USA
Publication Date:
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1595497
Grant/Contract Number:  
SC0013731; AC05-76RL01830
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Pan, Horng-Bin, Wai, Chien M., Kuo, Li-Jung, Gill, Gary A., Wang, Joanna S., Joshi, Ruma, and Janke, Christopher J. A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater. United Kingdom: N. p., 2020. Web. doi:10.1039/C9DT04562G.
Pan, Horng-Bin, Wai, Chien M., Kuo, Li-Jung, Gill, Gary A., Wang, Joanna S., Joshi, Ruma, & Janke, Christopher J. A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater. United Kingdom. doi:10.1039/C9DT04562G.
Pan, Horng-Bin, Wai, Chien M., Kuo, Li-Jung, Gill, Gary A., Wang, Joanna S., Joshi, Ruma, and Janke, Christopher J. Wed . "A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater". United Kingdom. doi:10.1039/C9DT04562G.
@article{osti_1595497,
title = {A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater},
author = {Pan, Horng-Bin and Wai, Chien M. and Kuo, Li-Jung and Gill, Gary A. and Wang, Joanna S. and Joshi, Ruma and Janke, Christopher J.},
abstractNote = {An amidoxime and carboxylate containing chelating adsorbent derived from acrylic fiber shows a fast adsorption rate and high uranium and low vanadium adsorption capacities in real seawater tests.},
doi = {10.1039/C9DT04562G},
journal = {Dalton Transactions},
number = ,
volume = ,
place = {United Kingdom},
year = {2020},
month = {1}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 17, 2021
Publisher's Version of Record

Save / Share:

Works referenced in this record:

Bicarbonate Elution of Uranium from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater
journal, May 2017


Novel poly(imide dioxime) sorbents: Development and testing for enhanced extraction of uranium from natural seawater
journal, August 2016


Elution of Uranium and Transition Metals from Amidoxime-Based Polymer Adsorbents for Sequestering Uranium from Seawater
journal, December 2015

  • Pan, Horng-Bin; Kuo, Li-Jung; Wai, Chien M.
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03307

A Study on the Degree of Amidoximation of Polyacrylonitrile Fibers and Its Effect on Their Capacity to Adsorb Uranyl Ions
journal, March 2015

  • Zhao, Huanhuan; Liu, Xiyan; Yu, Ming
  • Industrial & Engineering Chemistry Research, Vol. 54, Issue 12
  • DOI: 10.1021/ie5045605

Characterization and Testing of Amidoxime-Based Adsorbent Materials to Extract Uranium from Natural Seawater
journal, December 2015

  • Kuo, Li-Jung; Janke, Christopher J.; Wood, Jordana R.
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03267

Theoretical Insights on the Interaction of Uranium with Amidoxime and Carboxyl Groups
journal, August 2014

  • Wang, Cong-Zhi; Lan, Jian-Hui; Wu, Qun-Yan
  • Inorganic Chemistry, Vol. 53, Issue 18
  • DOI: 10.1021/ic500202g

Origin of the unusually strong and selective binding of vanadium by polyamidoximes in seawater
journal, November 2017

  • Ivanov, Alexander S.; Leggett, Christina J.; Parker, Bernard F.
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/s41467-017-01443-1

Synthesis, Development, and Testing of High-Surface-Area Polymer-Based Adsorbents for the Selective Recovery of Uranium from Seawater
journal, December 2015

  • Oyola, Yatsandra; Janke, Christopher J.; Dai, Sheng
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03981

Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization from Chlorinated Polypropylene and Polyethylene Trunk Fibers
journal, December 2015

  • Brown, Suree; Chatterjee, Sabornie; Li, Meijun
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03667

Recovery of Uranium from Seawater
journal, October 1981


Sequestering uranium from seawater: binding strength and modes of uranyl complexes with glutarimidedioxime
journal, January 2012

  • Tian, Guoxin; Teat, Simon J.; Zhang, Zhiyong
  • Dalton Transactions, Vol. 41, Issue 38
  • DOI: 10.1039/c2dt30978e

Comparison of Analytical Methods for the Determination of Uranium in Seawater Using Inductively Coupled Plasma Mass Spectrometry
journal, December 2015

  • Wood, Jordana R.; Gill, Gary A.; Kuo, Li-Jung
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03680

Structural and spectroscopic studies of a rare non-oxido V( v ) complex crystallized from aqueous solution
journal, January 2016

  • Leggett, C. J.; Parker, B. F.; Teat, S. J.
  • Chemical Science, Vol. 7, Issue 4
  • DOI: 10.1039/C5SC03958D

Recovery of Uranium from Seawater: A Review of Current Status and Future Research Needs
journal, January 2013


Structural clues to UO 2 2+ /VO 2 + competition in seawater extraction using amidoxime-based extractants
journal, January 2014

  • Kelley, Steven P.; Barber, Patrick S.; Mullins, Peter H. K.
  • Chem. Commun., Vol. 50, Issue 83
  • DOI: 10.1039/C4CC06370H

A New Type of Amidoxime-Group-Containing Adsorbent for the Recovery of Uranium from Seawater
journal, April 1985


Temperature Dependence of Uranium and Vanadium Adsorption on Amidoxime-Based Adsorbents in Natural Seawater
journal, January 2018


Assessment of Impacts of Dissolved Organic Matter and Dissolved Iron on the Performance of Amidoxime-Based Adsorbents for Seawater Uranium Extraction
journal, April 2019

  • Kuo, Li-Jung; Pan, Horng-Bin; Strivens, Jonathan E.
  • Industrial & Engineering Chemistry Research, Vol. 58, Issue 19
  • DOI: 10.1021/acs.iecr.9b00670

Extracting Uranium from Seawater: Promising AF Series Adsorbents
journal, November 2015

  • Das, S.; Oyola, Y.; Mayes, Richard T.
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03136

Studies of the preparation, structure, and properties of an acrylic chelating fiber containing amidoxime groups
journal, January 1993


Extracting Uranium from Seawater: Promising AI Series Adsorbents
journal, November 2015

  • Das, S.; Oyola, Y.; Mayes, R. T.
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03135

Uranium Adsorbent Fibers Prepared by Atom-Transfer Radical Polymerization (ATRP) from Poly(vinyl chloride)- co -chlorinated Poly(vinyl chloride) (PVC- co -CPVC) Fiber
journal, December 2015

  • Brown, Suree; Yue, Yanfeng; Kuo, Li-Jung
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03355

Acidity of the Poly(acrylamidoxime) Adsorbent in Aqueous Solution: Determination of the Proton Affinity Distribution via Potentiometric Titrations
journal, December 2015

  • Mehio, Nada; Williamson, Ben; Oyola, Yatsandra
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 15
  • DOI: 10.1021/acs.iecr.5b03211

Materials for the Recovery of Uranium from Seawater
journal, June 2017


Development of Sorbers for the Recovery of Uranium from Seawater. 1. Assessment of Key Parameters and Screening Studies of Sorber Materials
journal, August 1982

  • Schenk, H. J.; Astheimer, L.; Witte, E. G.
  • Separation Science and Technology, Vol. 17, Issue 11
  • DOI: 10.1080/01496398208056103

XAFS investigation of polyamidoxime-bound uranyl contests the paradigm from small molecule studies
journal, January 2016

  • Abney, C. W.; Mayes, R. T.; Piechowicz, M.
  • Energy & Environmental Science, Vol. 9, Issue 2
  • DOI: 10.1039/C5EE02913A

Investigations into the Reusability of Amidoxime-Based Polymeric Adsorbents for Seawater Uranium Extraction
journal, September 2017

  • Kuo, Li-Jung; Pan, Horng-Bin; Wai, Chien M.
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 40
  • DOI: 10.1021/acs.iecr.7b02893

Highly Preorganized Ligand 1,10-Phenanthroline-2,9-dicarboxylic Acid for the Selective Recovery of Uranium from Seawater in the Presence of Competing Vanadium Species
journal, September 2016


Carbonate–H 2 O 2 leaching for sequestering uranium from seawater
journal, January 2014

  • Pan, Horng-Bin; Liao, Weisheng; Wai, Chien M.
  • Dalton Trans., Vol. 43, Issue 28
  • DOI: 10.1039/C3DT53404A

Extraction of Uranium from Sea Water
journal, September 1964

  • Davies, R. V.; Kennedy, J.; McILROY, R. W.
  • Nature, Vol. 203, Issue 4950
  • DOI: 10.1038/2031110a0

Fractional Elution and Determination of Uranium and Vanadium Adsorbed on Amidoxime Fiber from Seawater.
journal, January 2000

  • Suzuki, Toshihiro; Saito, Kyoichi; Sugo, Takanobu
  • Analytical Sciences, Vol. 16, Issue 4
  • DOI: 10.2116/analsci.16.429

Setting up13C CP/MAS experiments
journal, January 2004


Results of an Ocean Trial of the Symbiotic Machine for Ocean uRanium Extraction
journal, January 2019

  • Haji, Maha N.; Drysdale, Jessica A.; Buesseler, Ken O.
  • Environmental Science & Technology, Vol. 53, Issue 4
  • DOI: 10.1021/acs.est.8b05100

Review of cost estimates for uranium recovery from seawater
journal, May 2015


An overview and recent progress in the chemistry of uranium extraction from seawater
journal, January 2018

  • Parker, B. F.; Zhang, Z.; Rao, L.
  • Dalton Transactions, Vol. 47, Issue 3
  • DOI: 10.1039/C7DT04058J

Towards understanding KOH conditioning of amidoxime-based polymer adsorbents for sequestering uranium from seawater
journal, January 2015

  • Pan, Horng-Bin; Kuo, Li-Jung; Wood, Jordana
  • RSC Advances, Vol. 5, Issue 122
  • DOI: 10.1039/C5RA14095A

Rational Design of Porous Nanofiber Adsorbent by Blow-Spinning with Ultrahigh Uranium Recovery Capacity from Seawater
journal, November 2018

  • Yuan, Yihui; Zhao, Shilei; Wen, Jun
  • Advanced Functional Materials, Vol. 29, Issue 2
  • DOI: 10.1002/adfm.201805380

Efficient Continuous Flow Synthesis of Hydroxamic Acids and Suberoylanilide Hydroxamic Acid Preparation
journal, May 2009

  • Riva, Elena; Gagliardi, Stefania; Mazzoni, Caterina
  • The Journal of Organic Chemistry, Vol. 74, Issue 9
  • DOI: 10.1021/jo900144h

Thermodynamic studies of U(vi) complexation with glutardiamidoxime for sequestration of uranium from seawater
journal, January 2013

  • Tian, Guoxin; Teat, Simon J.; Rao, Linfeng
  • Dalton Transactions, Vol. 42, Issue 16
  • DOI: 10.1039/c3dt32940b

Imidedioxime as a Significant Component in So-Called Amidoxime Resin for Uranyl Adsorption from Seawater
journal, February 1990

  • Kobuke, Yoshiaki; Tanaka, Hiromitsu; Ogoshi, Hisanobu
  • Polymer Journal, Vol. 22, Issue 2
  • DOI: 10.1295/polymj.22.179