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Title: Fluorination and reduction of CaCrO 3 by topochemical methods

Abstract

CaCrO 3 synthesized by high pressure methods is topochemically treated with polyvinylidene difluoride and undergoes stepwise reduction followed by fluorine incorporation.

Authors:
ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [3]; ORCiD logo [4];  [3]; ORCiD logo [2]
  1. Research Center for Functional Materials, National Institute for Materials Science, Tsukuba, Japan, Department of Chemistry and Biochemistry
  2. Research Center for Functional Materials, National Institute for Materials Science, Tsukuba, Japan, Graduate School of Chemical Sciences and Engineering
  3. Department of Chemistry, The University of Tokyo, Tokyo 113-0033, Japan
  4. Faculty of Engineering, Hokkaido University, Sapporo 060-8628, Japan
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1595494
Grant/Contract Number:  
DE_SC00116574
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Dalton Transactions
Additional Journal Information:
Journal Name: Dalton Transactions Journal Volume: 49 Journal Issue: 6; Journal ID: ISSN 1477-9226
Publisher:
Royal Society of Chemistry (RSC)
Country of Publication:
United Kingdom
Language:
English

Citation Formats

Juillerat, Christian A., Tsujimoto, Yoshihiro, Chikamatsu, Akira, Masubuchi, Yuji, Hasegawa, Tetsuya, and Yamaura, Kazunari. Fluorination and reduction of CaCrO 3 by topochemical methods. United Kingdom: N. p., 2020. Web. doi:10.1039/C9DT04321G.
Juillerat, Christian A., Tsujimoto, Yoshihiro, Chikamatsu, Akira, Masubuchi, Yuji, Hasegawa, Tetsuya, & Yamaura, Kazunari. Fluorination and reduction of CaCrO 3 by topochemical methods. United Kingdom. doi:10.1039/C9DT04321G.
Juillerat, Christian A., Tsujimoto, Yoshihiro, Chikamatsu, Akira, Masubuchi, Yuji, Hasegawa, Tetsuya, and Yamaura, Kazunari. Tue . "Fluorination and reduction of CaCrO 3 by topochemical methods". United Kingdom. doi:10.1039/C9DT04321G.
@article{osti_1595494,
title = {Fluorination and reduction of CaCrO 3 by topochemical methods},
author = {Juillerat, Christian A. and Tsujimoto, Yoshihiro and Chikamatsu, Akira and Masubuchi, Yuji and Hasegawa, Tetsuya and Yamaura, Kazunari},
abstractNote = {CaCrO 3 synthesized by high pressure methods is topochemically treated with polyvinylidene difluoride and undergoes stepwise reduction followed by fluorine incorporation.},
doi = {10.1039/C9DT04321G},
journal = {Dalton Transactions},
number = 6,
volume = 49,
place = {United Kingdom},
year = {2020},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
This content will become publicly available on January 22, 2021
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Works referenced in this record:

(Sr 1– x Ba x )FeO 2 (0.4 ≤ x ≤ 1): A New Oxygen-Deficient Perovskite Structure
journal, July 2012

  • Yamamoto, Takafumi; Kobayashi, Yoji; Hayashi, Naoaki
  • Journal of the American Chemical Society, Vol. 134, Issue 28
  • DOI: 10.1021/ja3007403

Multistep synthesis of the SrFeO2F perovskite oxyfluoride via the SrFeO2 infinite-layer intermediate
journal, March 2014


Stepwise topochemical fluorination of SrCrO 3 perovskite via a super-structured oxide
journal, January 2019

  • Su, Yu; Tsujimoto, Yoshihiro; Fujii, Kotaro
  • Chemical Communications, Vol. 55, Issue 50
  • DOI: 10.1039/C9CC02512J

Oxygen diffusion pathways in brownmillerite SrCoO 2.5 : Influence of structure and chemical potential
journal, August 2014

  • Mitra, Chandrima; Meyer, Tricia; Lee, Ho Nyung
  • The Journal of Chemical Physics, Vol. 141, Issue 8
  • DOI: 10.1063/1.4893950

Crystal structure and chemical constitution
journal, January 1929


Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


Three-Dimensional Visualization in Powder Diffraction
journal, December 2007


CaFeO 2 : A New Type of Layered Structure with Iron in a Distorted Square Planar Coordination
journal, January 2009

  • Tassel, Cédric; Pruneda, José Miguel; Hayashi, Naoaki
  • Journal of the American Chemical Society, Vol. 131, Issue 1
  • DOI: 10.1021/ja8072269

Preparation and properties of SrCrO3
journal, August 1967


Transition from Orbital Liquid to Jahn-Teller Insulator in Orthorhombic Perovskites R TiO 3
journal, August 2008


Topotactic Synthesis and Crystal Structure of a Highly Fluorinated Ruddlesden–Popper-Type Iron Oxide, Sr 3 Fe 2 O 5+ x F 2– x ( x ≈ 0.44)
journal, August 2011

  • Tsujimoto, Yoshihiro; Yamaura, Kazunari; Hayashi, Naoaki
  • Chemistry of Materials, Vol. 23, Issue 16
  • DOI: 10.1021/cm201075g

Infinite-layer iron oxide with a square-planar coordination
journal, December 2007

  • Tsujimoto, Y.; Tassel, C.; Hayashi, N.
  • Nature, Vol. 450, Issue 7172, p. 1062-1065
  • DOI: 10.1038/nature06382

CaCrO 3 : An Anomalous Antiferromagnetic Metallic Oxide
journal, October 2008


Hard–soft synthesis of a new series of vacancy-ordered perovskites, CaCrO 3−δ
journal, January 2014

  • Arevalo-Lopez, Angel M.; Liang, Bing; Senn, Mark S.
  • J. Mater. Chem. C, Vol. 2, Issue 44
  • DOI: 10.1039/C4TC01808G

“Hard-Soft” Synthesis of SrCrO 3− δ Superstructure Phases
journal, September 2012

  • Arévalo-López, Angel M.; Rodgers, Jennifer A.; Senn, Mark S.
  • Angewandte Chemie International Edition, Vol. 51, Issue 43
  • DOI: 10.1002/anie.201206203

Electronic structure of an antiferromagnetic metal: CaCrO 3
journal, April 2011


Synthesis and characterization of the La1−xSrxFeO3−δ system and the fluorinated phases La1−xSrxFeO3−xFx
journal, November 2011

  • Clemens, Oliver; Kuhn, Melanie; Haberkorn, Robert
  • Journal of Solid State Chemistry, Vol. 184, Issue 11
  • DOI: 10.1016/j.jssc.2011.08.037

Topochemical modifications of mixed metal oxide compounds by low-temperature fluorination routes
journal, January 2013

  • Clemens, Oliver; Slater, Peter R.
  • Reviews in Inorganic Chemistry, Vol. 33, Issue 2-3
  • DOI: 10.1515/revic-2013-0002

Synthesis and superconducting properties of the strontium copper oxy-fluoride Sr2CuO2F2+δ
journal, June 1994

  • AI-Mamouri, M.; Edwards, P. P.; Greaves, C.
  • Nature, Vol. 369, Issue 6479
  • DOI: 10.1038/369382a0

Magnetic order, transport and infrared optical properties in the A CrO 3 system ( A = Ca, Sr, and Pb)
journal, September 2011


LaSr 3 NiRuO 4 H 4 : A 4d Transition-Metal Oxide-Hydride Containing Metal Hydride Sheets
journal, March 2018

  • Jin, Lun; Lane, Michael; Zeng, Dihao
  • Angewandte Chemie International Edition, Vol. 57, Issue 18
  • DOI: 10.1002/anie.201800989

LaSrCoFeO5, LaSrCoFeO5F and LaSrCoFeO5.5: new La–Sr–Co–Fe perovskites
journal, January 2010

  • El Shinawi, H.; Marco, J. F.; Berry, F. J.
  • Journal of Materials Chemistry, Vol. 20, Issue 16
  • DOI: 10.1039/b927141d

Zigzag ladders with staggered magnetic chirality in the S = 3 2 compound β -CaCr 2 O 4
journal, June 2010


Expanding frontiers in materials chemistry and physics with multiple anions
journal, February 2018


Crystal and magnetic structures of the brownmillerite Ca 2 Cr 2 O 5
journal, January 2015

  • Arevalo-Lopez, Angel M.; Attfield, J. Paul
  • Dalton Transactions, Vol. 44, Issue 23
  • DOI: 10.1039/C4DT03780D

La 2 SrCr 2 O 7 F 2 : A Ruddlesden–Popper Oxyfluoride Containing Octahedrally Coordinated Cr 4+ Centers
journal, March 2016


Frustrated Superexchange Interaction Versus Orbital Order in a LaVO 3 Crystal
journal, January 2008


Investigation of hole-doped insulating La 1 x Sr x CrO 3 by soft-x-ray absorption spectroscopy
journal, May 1996


Oxyfluoride Chemistry of Layered Perovskite Compounds
journal, March 2012

  • Tsujimoto, Yoshihiro; Yamaura, Kazunari; Takayama-Muromachi, Eiji
  • Applied Sciences, Vol. 2, Issue 1
  • DOI: 10.3390/app2010206

Magnetic and electrical transport properties of CaCrO3
journal, November 1971