An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

Weng, Yu-Ting; Liu, Hao-Wen; Pei, Allen; Shi, FeiFei; Wang, Hansen; Lin, Chih-Yuan; Huang, Sheng-Siang; Su, Lin-Ya; Hsu, Jyh-Ping; Fang, Chia-Chen; Cui, Yi; Wu, Nae-Lih

doi:10.1038/s41467-019-13783-1

Title: An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

Journal Article · 20 December 2019 · Nature Communications

DOI: https://doi.org/10.1038/s41467-019-13783-1 · OSTI ID:1595320

Weng, Yu-Ting ^[1]; Liu, Hao-Wen ^[1];

^[2]; Shi, FeiFei ^[2];

^[2];

^[1]; Huang, Sheng-Siang ^[1]; Su, Lin-Ya ^[1]; Hsu, Jyh-Ping ^[1]; Fang, Chia-Chen ^[3];

^[4];

^[1]

National Taiwan Univ., Taipei (Taiwan)
Stanford Univ., CA (United States)
Industrial Technology Research Inst., Hsin-Chu (Taiwan)
Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)

High coulombic efficiency and dendrite suppression in carbonate electrolytes remain challenges to the development of high-energy lithium ion batteries containing lithium metal anodes. Here we demonstrate an ultrathin (≤100 nm) lithium-ion ionomer membrane consisting of lithium-exchanged sulfonated polyether ether ketone embedded with polyhedral oligosilsesquioxane as a coating layer on copper or lithium for achieving efficient and stable lithium plating-stripping cycles in a carbonate-based electrolyte. Operando analyses and theoretical simulation reveal the remarkable ability of the ionomer coating to enable electric field homogenization over a considerably large lithium-plating surface. The membrane coating, serving as an artificial solid-electrolyte interphase filter in minimizing parasitic reactions at the electrolyte-electrode interface, enables dendrite-free lithium plating on copper with outstanding coulombic efficiencies at room and elevated (50 °C) temperatures. The membrane coated copper demonstrates itself as a promising current collector for manufacturing high-quality pre-plated lithium thin-film anode.

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Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); Ministry of Science and Technology of Taiwan (MOST)

Grant/Contract Number:: AC02-76SF00515; 108C4604; 108-3017-F-002-002, and also of -107-2221-E-002 -106 -MY3, 107-2923-E-011-002; 108-2119-M-002-010; 108-3116-F-301-001-F

OSTI ID:: 1595320

Journal Information:: Nature Communications, Vol. 10, Issue 1; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 50 works

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Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Prestoring Lithium into Stable 3D Nickel Foam Host as Dendrite-Free Lithium Metal Anode Chi, Shang-Sen; Liu, Yongchang; Song, Wei-Li Advanced Functional Materials, Vol. 27, Issue 24 https://doi.org/10.1002/adfm.201700348	journal	May 2017
Dendrite-Free Lithium Deposition Induced by Uniformly Distributed Lithium Ions for Efficient Lithium Metal Batteries Cheng, Xin-Bing; Hou, Ting-Zheng; Zhang, Rui Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201506124	journal	February 2016
Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte Lu, Qingwen; He, Yan-Bing; Yu, Qipeng Advanced Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adma.201604460	journal	February 2017
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605531	journal	December 2016
Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries Guo, Yanpeng; Li, Huiqiao; Zhai, Tianyou Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201700007	journal	June 2017
Stable Li Metal Anodes via Regulating Lithium Plating/Stripping in Vertically Aligned Microchannels Wang, Shu-Hua; Yin, Ya-Xia; Zuo, Tong-Tong Advanced Materials, Vol. 29, Issue 40 https://doi.org/10.1002/adma.201703729	journal	September 2017
An Autotransferable g‐C ₃ N ₄ Li ⁺ ‐Modulating Layer toward Stable Lithium Anodes Guo, Yanpeng; Niu, Ping; Liu, Yayuan Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201900342	journal	May 2019
Low-Cost Hollow Mesoporous Polymer Spheres and All-Solid-State Lithium, Sodium Batteries Zhou, Weidong; Gao, Hongcai; Goodenough, John B. Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501802	journal	October 2015
Recent Developments of the Lithium Metal Anode for Rechargeable Non-Aqueous Batteries Zhang, Kai; Lee, Gi-Hyeok; Park, Mihui Advanced Energy Materials, Vol. 6, Issue 20 https://doi.org/10.1002/aenm.201600811	journal	July 2016
Flexible Composite Solid Electrolyte Facilitating Highly Stable “Soft Contacting” Li-Electrolyte Interface for Solid State Lithium-Ion Batteries Yang, Luyi; Wang, Zijian; Feng, Yancong Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701437	journal	September 2017
High Polarity Poly(vinylidene difluoride) Thin Coating for Dendrite-Free and High-Performance Lithium Metal Anodes Luo, Jing; Fang, Chia-Chen; Wu, Nae-Lih Advanced Energy Materials, Vol. 8, Issue 2 https://doi.org/10.1002/aenm.201701482	journal	September 2017
Enhanced Performance of a Lithium-Sulfur Battery Using a Carbonate-Based Electrolyte Xu, Zhixin; Wang, Jiulin; Yang, Jun Angewandte Chemie, Vol. 128, Issue 35 https://doi.org/10.1002/ange.201605931	journal	July 2016
Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna Angewandte Chemie International Edition, Vol. 56, Issue 42 https://doi.org/10.1002/anie.201707754	journal	September 2017
3D lithium metal embedded within lithiophilic porous matrix for stable lithium metal batteries Jin, Chengbin; Sheng, Ouwei; Luo, Jianmin Nano Energy, Vol. 37 https://doi.org/10.1016/j.nanoen.2017.05.015	journal	July 2017
Conformal, Nanoscale ZnO Surface Modification of Garnet-Based Solid-State Electrolyte for Lithium Metal Anodes Wang, Chengwei; Gong, Yunhui; Liu, Boyang Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04695	journal	December 2016
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes Yang, Yang; Xiong, Jian; Lai, Shaobo ACS Applied Materials & Interfaces, Vol. 11, Issue 6 https://doi.org/10.1021/acsami.8b20706	journal	January 2019
Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes Liu, Wei; Li, Weiyang; Zhuo, Denys ACS Central Science, Vol. 3, Issue 2 https://doi.org/10.1021/acscentsci.6b00389	journal	January 2017
Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution Markevich, Elena; Salitra, Gregory; Chesneau, Frederick ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00300	journal	May 2017
Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries Gao, Yue; Zhao, Yuming; Li, Yuguang C. Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b06437	journal	October 2017
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Nanodiamonds suppress the growth of lithium dendrites Cheng, Xin-Bing; Zhao, Meng-Qiang; Chen, Chi Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00519-2	journal	August 2017
Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries Li, Guoxing; Gao, Yue; He, Xin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00974-x	journal	October 2017
Directing lateral growth of lithium dendrites in micro-compartmented anode arrays for safe lithium metal batteries Zou, Peichao; Wang, Yang; Chiang, Sum-Wai Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02888-8	journal	January 2018
Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes Li, Chuanfa; Liu, Shaohong; Shi, Chenguang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09211-z	journal	March 2019
Dynamic spatial progression of isolated lithium during battery operations Liu, Fang; Xu, Rong; Wu, Yecun Nature, Vol. 600, Issue 7890 https://doi.org/10.1038/s41586-021-04168-w	journal	December 2021
Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix Lin, Dingchang; Zhao, Jie; Sun, Jie Proceedings of the National Academy of Sciences, Vol. 114, Issue 18 https://doi.org/10.1073/pnas.1619489114	journal	April 2017
An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing Proceedings of the National Academy of Sciences, Vol. 114, Issue 42 https://doi.org/10.1073/pnas.1708489114	journal	October 2017
Infrared spectra, structure and bonding in the LiO ₂ , LiO ₂ Li, LiO and Li ₂ O molecules in solid neon Wang, Xuefeng; Andrews, Lester Molecular Physics, Vol. 107, Issue 8-12 https://doi.org/10.1080/00268970802526583	journal	April 2009

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Title: An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

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