An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

Weng, Yu-Ting; Liu, Hao-Wen; Pei, Allen; Shi, FeiFei; Wang, Hansen; Lin, Chih-Yuan; Huang, Sheng-Siang; Su, Lin-Ya; Hsu, Jyh-Ping; Fang, Chia-Chen; Cui, Yi; Wu, Nae-Lih

doi:10.1038/s41467-019-13783-1

Title: An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

Journal Article · 19 December 2019 · Nature Communications

DOI: https://doi.org/10.1038/s41467-019-13783-1 · OSTI ID:1595320

Weng, Yu-Ting ^[1]; Liu, Hao-Wen ^[2];

^[3]; Shi, FeiFei ^[3];

^[3];

^[2]; Huang, Sheng-Siang ^[2]; Su, Lin-Ya ^[2]; Hsu, Jyh-Ping ^[2]; Fang, Chia-Chen ^[4];

^[5];

^[2]

National Taiwan Univ., Taipei (Taiwan); SLAC
National Taiwan Univ., Taipei (Taiwan)
Stanford Univ., CA (United States)
Industrial Technology Research Inst., Hsin-Chu (Taiwan)
Stanford Univ., CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Science (SIMES)

High coulombic efficiency and dendrite suppression in carbonate electrolytes remain challenges to the development of high-energy lithium ion batteries containing lithium metal anodes. Here we demonstrate an ultrathin (≤100 nm) lithium-ion ionomer membrane consisting of lithium-exchanged sulfonated polyether ether ketone embedded with polyhedral oligosilsesquioxane as a coating layer on copper or lithium for achieving efficient and stable lithium plating-stripping cycles in a carbonate-based electrolyte. Operando analyses and theoretical simulation reveal the remarkable ability of the ionomer coating to enable electric field homogenization over a considerably large lithium-plating surface. The membrane coating, serving as an artificial solid-electrolyte interphase filter in minimizing parasitic reactions at the electrolyte-electrode interface, enables dendrite-free lithium plating on copper with outstanding coulombic efficiencies at room and elevated (50 °C) temperatures. The membrane coated copper demonstrates itself as a promising current collector for manufacturing high-quality pre-plated lithium thin-film anode.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: Ministry of Science and Technology of Taiwan (MOST); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-76SF00515

OSTI ID:: 1595320

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 10; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

References (81)

Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Prestoring Lithium into Stable 3D Nickel Foam Host as Dendrite-Free Lithium Metal Anode Chi, Shang-Sen; Liu, Yongchang; Song, Wei-Li Advanced Functional Materials, Vol. 27, Issue 24 https://doi.org/10.1002/adfm.201700348	journal	May 2017
Dendrite-Free Lithium Deposition Induced by Uniformly Distributed Lithium Ions for Efficient Lithium Metal Batteries Cheng, Xin-Bing; Hou, Ting-Zheng; Zhang, Rui Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201506124	journal	February 2016
Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte Lu, Qingwen; He, Yan-Bing; Yu, Qipeng Advanced Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adma.201604460	journal	February 2017
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605531	journal	December 2016
Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries Guo, Yanpeng; Li, Huiqiao; Zhai, Tianyou Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201700007	journal	June 2017
Stable Li Metal Anodes via Regulating Lithium Plating/Stripping in Vertically Aligned Microchannels Wang, Shu-Hua; Yin, Ya-Xia; Zuo, Tong-Tong Advanced Materials, Vol. 29, Issue 40 https://doi.org/10.1002/adma.201703729	journal	September 2017
An Autotransferable g‐C ₃ N ₄ Li ⁺ ‐Modulating Layer toward Stable Lithium Anodes Guo, Yanpeng; Niu, Ping; Liu, Yayuan Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201900342	journal	May 2019
Low-Cost Hollow Mesoporous Polymer Spheres and All-Solid-State Lithium, Sodium Batteries Zhou, Weidong; Gao, Hongcai; Goodenough, John B. Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501802	journal	October 2015
Recent Developments of the Lithium Metal Anode for Rechargeable Non-Aqueous Batteries Zhang, Kai; Lee, Gi-Hyeok; Park, Mihui Advanced Energy Materials, Vol. 6, Issue 20 https://doi.org/10.1002/aenm.201600811	journal	July 2016
Flexible Composite Solid Electrolyte Facilitating Highly Stable “Soft Contacting” Li-Electrolyte Interface for Solid State Lithium-Ion Batteries Yang, Luyi; Wang, Zijian; Feng, Yancong Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701437	journal	September 2017
High Polarity Poly(vinylidene difluoride) Thin Coating for Dendrite-Free and High-Performance Lithium Metal Anodes Luo, Jing; Fang, Chia-Chen; Wu, Nae-Lih Advanced Energy Materials, Vol. 8, Issue 2 https://doi.org/10.1002/aenm.201701482	journal	September 2017
Enhanced Performance of a Lithium-Sulfur Battery Using a Carbonate-Based Electrolyte Xu, Zhixin; Wang, Jiulin; Yang, Jun Angewandte Chemie, Vol. 128, Issue 35 https://doi.org/10.1002/ange.201605931	journal	July 2016
Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna Angewandte Chemie International Edition, Vol. 56, Issue 42 https://doi.org/10.1002/anie.201707754	journal	September 2017
3D lithium metal embedded within lithiophilic porous matrix for stable lithium metal batteries Jin, Chengbin; Sheng, Ouwei; Luo, Jianmin Nano Energy, Vol. 37 https://doi.org/10.1016/j.nanoen.2017.05.015	journal	July 2017
Conformal, Nanoscale ZnO Surface Modification of Garnet-Based Solid-State Electrolyte for Lithium Metal Anodes Wang, Chengwei; Gong, Yunhui; Liu, Boyang Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04695	journal	December 2016
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes Yang, Yang; Xiong, Jian; Lai, Shaobo ACS Applied Materials & Interfaces, Vol. 11, Issue 6 https://doi.org/10.1021/acsami.8b20706	journal	January 2019
Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes Liu, Wei; Li, Weiyang; Zhuo, Denys ACS Central Science, Vol. 3, Issue 2 https://doi.org/10.1021/acscentsci.6b00389	journal	January 2017
Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution Markevich, Elena; Salitra, Gregory; Chesneau, Frederick ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00300	journal	May 2017
Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries Gao, Yue; Zhao, Yuming; Li, Yuguang C. Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b06437	journal	October 2017
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Nanodiamonds suppress the growth of lithium dendrites Cheng, Xin-Bing; Zhao, Meng-Qiang; Chen, Chi Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00519-2	journal	August 2017
Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries Li, Guoxing; Gao, Yue; He, Xin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00974-x	journal	October 2017
Directing lateral growth of lithium dendrites in micro-compartmented anode arrays for safe lithium metal batteries Zou, Peichao; Wang, Yang; Chiang, Sum-Wai Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02888-8	journal	January 2018
Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes Li, Chuanfa; Liu, Shaohong; Shi, Chenguang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09211-z	journal	March 2019
Dynamic spatial progression of isolated lithium during battery operations Liu, Fang; Xu, Rong; Wu, Yecun Nature, Vol. 600, Issue 7890 https://doi.org/10.1038/s41586-021-04168-w	journal	December 2021
Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix Lin, Dingchang; Zhao, Jie; Sun, Jie Proceedings of the National Academy of Sciences, Vol. 114, Issue 18 https://doi.org/10.1073/pnas.1619489114	journal	April 2017
An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing Proceedings of the National Academy of Sciences, Vol. 114, Issue 42 https://doi.org/10.1073/pnas.1708489114	journal	October 2017
Infrared spectra, structure and bonding in the LiO ₂ , LiO ₂ Li, LiO and Li ₂ O molecules in solid neon Wang, Xuefeng; Andrews, Lester Molecular Physics, Vol. 107, Issue 8-12 https://doi.org/10.1080/00268970802526583	journal	April 2009
Electrochemical aspects of the generation of ramified metallic electrodeposits Chazalviel, J. -N. Physical Review A, Vol. 42, Issue 12 https://doi.org/10.1103/physreva.42.7355	journal	December 1990
Anode-Free Rechargeable Lithium Metal Batteries Qian, Jiangfeng; Adams, Brian D.; Zheng, Jianming Advanced Functional Materials, Vol. 26, Issue 39 https://doi.org/10.1002/adfm.201602353	journal	August 2016
Fluoroethylene Carbonate Additives to Render Uniform Li Deposits in Lithium Metal Batteries Zhang, Xue-Qiang; Cheng, Xin-Bing; Chen, Xiang Advanced Functional Materials, Vol. 27, Issue 10 https://doi.org/10.1002/adfm.201605989	journal	January 2017
Prestoring Lithium into Stable 3D Nickel Foam Host as Dendrite-Free Lithium Metal Anode Chi, Shang-Sen; Liu, Yongchang; Song, Wei-Li Advanced Functional Materials, Vol. 27, Issue 24 https://doi.org/10.1002/adfm.201700348	journal	May 2017
Dendrite-Free Lithium Deposition Induced by Uniformly Distributed Lithium Ions for Efficient Lithium Metal Batteries Cheng, Xin-Bing; Hou, Ting-Zheng; Zhang, Rui Advanced Materials, Vol. 28, Issue 15 https://doi.org/10.1002/adma.201506124	journal	February 2016
Poly(dimethylsiloxane) Thin Film as a Stable Interfacial Layer for High-Performance Lithium-Metal Battery Anodes Zhu, Bin; Jin, Yan; Hu, Xiaozhen Advanced Materials, Vol. 29, Issue 2 https://doi.org/10.1002/adma.201603755	journal	October 2016
Dendrite-Free, High-Rate, Long-Life Lithium Metal Batteries with a 3D Cross-Linked Network Polymer Electrolyte Lu, Qingwen; He, Yan-Bing; Yu, Qipeng Advanced Materials, Vol. 29, Issue 13 https://doi.org/10.1002/adma.201604460	journal	February 2017
An Artificial Solid Electrolyte Interphase with High Li-Ion Conductivity, Mechanical Strength, and Flexibility for Stable Lithium Metal Anodes Liu, Yayuan; Lin, Dingchang; Yuen, Pak Yan Advanced Materials, Vol. 29, Issue 10 https://doi.org/10.1002/adma.201605531	journal	December 2016
Reviving Lithium-Metal Anodes for Next-Generation High-Energy Batteries Guo, Yanpeng; Li, Huiqiao; Zhai, Tianyou Advanced Materials, Vol. 29, Issue 29 https://doi.org/10.1002/adma.201700007	journal	June 2017
Stable Li Metal Anodes via Regulating Lithium Plating/Stripping in Vertically Aligned Microchannels Wang, Shu-Hua; Yin, Ya-Xia; Zuo, Tong-Tong Advanced Materials, Vol. 29, Issue 40 https://doi.org/10.1002/adma.201703729	journal	September 2017
An Autotransferable g‐C ₃ N ₄ Li ⁺ ‐Modulating Layer toward Stable Lithium Anodes Guo, Yanpeng; Niu, Ping; Liu, Yayuan Advanced Materials, Vol. 31, Issue 27 https://doi.org/10.1002/adma.201900342	journal	May 2019
A Review of Solid Electrolyte Interphases on Lithium Metal Anode Cheng, Xin-Bing; Zhang, Rui; Zhao, Chen-Zi Advanced Science, Vol. 3, Issue 3 https://doi.org/10.1002/advs.201500213	journal	November 2015
Advanced Micro/Nanostructures for Lithium Metal Anodes Zhang, Rui; Li, Nian-Wu; Cheng, Xin-Bing Advanced Science, Vol. 4, Issue 3 https://doi.org/10.1002/advs.201600445	journal	February 2017
Low-Cost Hollow Mesoporous Polymer Spheres and All-Solid-State Lithium, Sodium Batteries Zhou, Weidong; Gao, Hongcai; Goodenough, John B. Advanced Energy Materials, Vol. 6, Issue 1 https://doi.org/10.1002/aenm.201501802	journal	October 2015
Highly Stable Operation of Lithium Metal Batteries Enabled by the Formation of a Transient High-Concentration Electrolyte Layer Zheng, Jianming; Yan, Pengfei; Mei, Donghai Advanced Energy Materials, Vol. 6, Issue 8 https://doi.org/10.1002/aenm.201502151	journal	February 2016
Recent Developments of the Lithium Metal Anode for Rechargeable Non-Aqueous Batteries Zhang, Kai; Lee, Gi-Hyeok; Park, Mihui Advanced Energy Materials, Vol. 6, Issue 20 https://doi.org/10.1002/aenm.201600811	journal	July 2016
Flexible Composite Solid Electrolyte Facilitating Highly Stable “Soft Contacting” Li-Electrolyte Interface for Solid State Lithium-Ion Batteries Yang, Luyi; Wang, Zijian; Feng, Yancong Advanced Energy Materials, Vol. 7, Issue 22 https://doi.org/10.1002/aenm.201701437	journal	September 2017
High Polarity Poly(vinylidene difluoride) Thin Coating for Dendrite-Free and High-Performance Lithium Metal Anodes Luo, Jing; Fang, Chia-Chen; Wu, Nae-Lih Advanced Energy Materials, Vol. 8, Issue 2 https://doi.org/10.1002/aenm.201701482	journal	September 2017
Tuning the Electron Density of Aromatic Solvent for Stable Solid-Electrolyte-Interphase Layer in Carbonate-Based Lithium Metal Batteries Yoo, Dong-Joo; Yang, Sungyun; Yun, Yang Sik Advanced Energy Materials, Vol. 8, Issue 33 https://doi.org/10.1002/aenm.201802365	journal	October 2018
Enhanced Performance of a Lithium-Sulfur Battery Using a Carbonate-Based Electrolyte Xu, Zhixin; Wang, Jiulin; Yang, Jun Angewandte Chemie, Vol. 128, Issue 35 https://doi.org/10.1002/ange.201605931	journal	July 2016
Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna Angewandte Chemie, Vol. 129, Issue 42 https://doi.org/10.1002/ange.201707754	journal	September 2017
Enhanced Performance of a Lithium-Sulfur Battery Using a Carbonate-Based Electrolyte Xu, Zhixin; Wang, Jiulin; Yang, Jun Angewandte Chemie International Edition, Vol. 55, Issue 35 https://doi.org/10.1002/anie.201605931	journal	July 2016
Electroless Formation of Hybrid Lithium Anodes for Fast Interfacial Ion Transport Choudhury, Snehashis; Tu, Zhengyuan; Stalin, Sanjuna Angewandte Chemie International Edition, Vol. 56, Issue 42 https://doi.org/10.1002/anie.201707754	journal	September 2017
Garnet/polymer hybrid ion-conducting protective layer for stable lithium metal anode Yang, Chunpeng; Liu, Boyang; Jiang, Feng Nano Research, Vol. 10, Issue 12 https://doi.org/10.1007/s12274-017-1498-2	journal	May 2017
Review of gel-type polymer electrolytes for lithium-ion batteries Song, J. Y.; Wang, Y. Y.; Wan, C. C. Journal of Power Sources, Vol. 77, Issue 2, p. 183-197 https://doi.org/10.1016/S0378-7753(98)00193-1	journal	February 1999
Designing Artificial Solid-Electrolyte Interphases for Single-Ion and High-Efficiency Transport in Batteries Tu, Zhengyuan; Choudhury, Snehashis; Zachman, Michael J. Joule, Vol. 1, Issue 2 https://doi.org/10.1016/j.joule.2017.06.002	journal	October 2017
Improved cycling performances of lithium sulfur batteries with LiNO3-modified electrolyte Liang, Xiao; Wen, Zhaoyin; Liu, Yu Journal of Power Sources, Vol. 196, Issue 22 https://doi.org/10.1016/j.jpowsour.2011.08.027	journal	November 2011
3D lithium metal embedded within lithiophilic porous matrix for stable lithium metal batteries Jin, Chengbin; Sheng, Ouwei; Luo, Jianmin Nano Energy, Vol. 37 https://doi.org/10.1016/j.nanoen.2017.05.015	journal	July 2017
A strategy of selective and dendrite-free lithium deposition for lithium batteries Xiang, Jingwei; Zhao, Ying; Yuan, Lixia Nano Energy, Vol. 42 https://doi.org/10.1016/j.nanoen.2017.10.065	journal	December 2017
Conformal, Nanoscale ZnO Surface Modification of Garnet-Based Solid-State Electrolyte for Lithium Metal Anodes Wang, Chengwei; Gong, Yunhui; Liu, Boyang Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b04695	journal	December 2016
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes Yang, Yang; Xiong, Jian; Lai, Shaobo ACS Applied Materials & Interfaces, Vol. 11, Issue 6 https://doi.org/10.1021/acsami.8b20706	journal	January 2019
Core–Shell Nanoparticle Coating as an Interfacial Layer for Dendrite-Free Lithium Metal Anodes Liu, Wei; Li, Weiyang; Zhuo, Denys ACS Central Science, Vol. 3, Issue 2 https://doi.org/10.1021/acscentsci.6b00389	journal	January 2017
Very Stable Lithium Metal Stripping–Plating at a High Rate and High Areal Capacity in Fluoroethylene Carbonate-Based Organic Electrolyte Solution Markevich, Elena; Salitra, Gregory; Chesneau, Frederick ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00300	journal	May 2017
Lithium Metal Anodes with an Adaptive “Solid-Liquid” Interfacial Protective Layer Liu, Kai; Pei, Allen; Lee, Hye Ryoung Journal of the American Chemical Society, Vol. 139, Issue 13 https://doi.org/10.1021/jacs.6b13314	journal	March 2017
Interfacial Chemistry Regulation via a Skin-Grafting Strategy Enables High-Performance Lithium-Metal Batteries Gao, Yue; Zhao, Yuming; Li, Yuguang C. Journal of the American Chemical Society, Vol. 139, Issue 43 https://doi.org/10.1021/jacs.7b06437	journal	October 2017
Electrolyte additive enabled fast charging and stable cycling lithium metal batteries Zheng, Jianming; Engelhard, Mark H.; Mei, Donghai Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2017.12	journal	March 2017
Layered reduced graphene oxide with nanoscale interlayer gaps as a stable host for lithium metal anodes Lin, Dingchang; Liu, Yayuan; Liang, Zheng Nature Nanotechnology, Vol. 11, Issue 7 https://doi.org/10.1038/nnano.2016.32	journal	March 2016
Air-stable and freestanding lithium alloy/graphene foil as an alternative to lithium metal anodes Zhao, Jie; Zhou, Guangmin; Yan, Kai Nature Nanotechnology, Vol. 12, Issue 10 https://doi.org/10.1038/nnano.2017.129	journal	July 2017
Reviving the lithium metal anode for high-energy batteries Lin, Dingchang; Liu, Yayuan; Cui, Yi Nature Nanotechnology, Vol. 12, Issue 3 https://doi.org/10.1038/nnano.2017.16	journal	March 2017
Nanodiamonds suppress the growth of lithium dendrites Cheng, Xin-Bing; Zhao, Meng-Qiang; Chen, Chi Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00519-2	journal	August 2017
Organosulfide-plasticized solid-electrolyte interphase layer enables stable lithium metal anodes for long-cycle lithium-sulfur batteries Li, Guoxing; Gao, Yue; He, Xin Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/s41467-017-00974-x	journal	October 2017
Directing lateral growth of lithium dendrites in micro-compartmented anode arrays for safe lithium metal batteries Zou, Peichao; Wang, Yang; Chiang, Sum-Wai Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-02888-8	journal	January 2018
Two-dimensional molecular brush-functionalized porous bilayer composite separators toward ultrastable high-current density lithium metal anodes Li, Chuanfa; Liu, Shaohong; Shi, Chenguang Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09211-z	journal	March 2019
Decoupling the origins of irreversible coulombic efficiency in anode-free lithium metal batteries Huang, Chen-Jui; Thirumalraj, Balamurugan; Tao, Hsien-Chu Nature Communications, Vol. 12, Issue 1 https://doi.org/10.1038/s41467-021-21683-6	journal	March 2021
Ionomer-Liquid Electrolyte Hybrid Ionic Conductor for High Cycling Stability of Lithium Metal Electrodes Song, Jongchan; Lee, Hongkyung; Choo, Min-Ju Scientific Reports, Vol. 5, Issue 1 https://doi.org/10.1038/srep14458	journal	September 2015
Lithium metal anodes for rechargeable batteries Xu, Wu; Wang, Jiulin; Ding, Fei Energy Environ. Sci., Vol. 7, Issue 2 https://doi.org/10.1039/C3EE40795K	journal	January 2014
Garnet-type solid-state fast Li ion conductors for Li batteries: critical review Thangadurai, Venkataraman; Narayanan, Sumaletha; Pinzaru, Dana Chemical Society Reviews, Vol. 43, Issue 13 https://doi.org/10.1039/c4cs00020j	journal	January 2014
High-capacity, low-tortuosity, and channel-guided lithium metal anode Zhang, Ying; Luo, Wei; Wang, Chengwei Proceedings of the National Academy of Sciences, Vol. 114, Issue 14 https://doi.org/10.1073/pnas.1618871114	journal	March 2017
Three-dimensional stable lithium metal anode with nanoscale lithium islands embedded in ionically conductive solid matrix Lin, Dingchang; Zhao, Jie; Sun, Jie Proceedings of the National Academy of Sciences, Vol. 114, Issue 18 https://doi.org/10.1073/pnas.1619489114	journal	April 2017
An anion-immobilized composite electrolyte for dendrite-free lithium metal anodes Zhao, Chen-Zi; Zhang, Xue-Qiang; Cheng, Xin-Bing Proceedings of the National Academy of Sciences, Vol. 114, Issue 42 https://doi.org/10.1073/pnas.1708489114	journal	October 2017
Infrared spectra, structure and bonding in the LiO ₂ , LiO ₂ Li, LiO and Li ₂ O molecules in solid neon Wang, Xuefeng; Andrews, Lester Molecular Physics, Vol. 107, Issue 8-12 https://doi.org/10.1080/00268970802526583	journal	April 2009
Electrochemical aspects of the generation of ramified metallic electrodeposits Chazalviel, J. -N. Physical Review A, Vol. 42, Issue 12 https://doi.org/10.1103/PhysRevA.42.7355	journal	December 1990

Similar Records

An ethyl methyl sulfone co-solvent eliminates macroscopic morphological instabilities of lithium metal anode

Journal Article · 2019 · ChemComm · OSTI ID:1530189

Shin, Woochul; So, Kang Pyo; Stickle, William F.; +4 more

Novel ALD Chemistry Enabled Low-Temperature Synthesis of Lithium Fluoride Coatings for Durable Lithium Anodes

Journal Article · 2018 · ACS Applied Materials and Interfaces · OSTI ID:1476140

Chen, Lin; Chen, Kan -Sheng; Chen, Xinjie; +9 more

Excellent cycling stability of sodium anode enabled by a stable solid electrolyte interphase formed in ether-based electrolytes

Journal Article · 2020 · Advanced Energy Materials · OSTI ID:1634902

Le, Phung ML; Vo, Thanh D.; Pan, Huilin; +8 more

Related Subjects

25 ENERGY STORAGE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Batteries
energy storage
materials for energy and catalysis
nanoscale materials

Title: An ultrathin ionomer interphase for high efficiency lithium anode in carbonate based electrolyte

Citation Formats

References (81)

Similar Records

Related Subjects