Near-ideal molecule-based Haldane spin chain

Williams, Robert C.; Blackmore, William J. A.; Curley, Samuel P. M.; Lees, Martin R.; Birnbaum, Serena M.; Singleton, John; Huddart, Benjamin M.; Hicken, Thomas J.; Lancaster, Tom; Blundell, Stephen J.; Xiao, Fan; Ozarowski, Andrew; Pratt, Francis L.; Voneshen, David J.; Guguchia, Zurab; Baines, Christopher; Schlueter, John A.; Villa, Danielle Y.; Manson, Jamie L.; Goddard, Paul A.

doi:10.1103/PhysRevResearch.2.013082

Title: Near-ideal molecule-based Haldane spin chain

Abstract

The molecular coordination complex ${NiI}_{2} {(3, 5 - lut)}_{4}$ [where (3,5-lut) $=$ (3,5-lutidine) $= (C_{7} H_{9} N$ )] has been synthesized and characterized by several techniques including synchrotron x-ray diffraction, electron-spin resonance, superconducting quantum interference device magnetometry, pulsed-field magnetization, inelastic neutron scattering, and muon spin relaxation. Templated by the configuration of 3,5-lut ligands the molecules pack in-registry with the Ni– $I ∙∙∙ I$ –Ni chains aligned along the $c$ axis. This arrangement leads to an uncommon through-space $I ∙∙∙ I$ magnetic coupling which is directly measured in this work. The net result is a near-ideal realization of the $S = 1$ Haldane chain with $J = 17.5 K$ and energy gaps of $Δ^{∥} = 5.3 K Δ^{⊥} = 7.7 K$ , split by the easy-axis single-ion anisotropy $D = - 1.2 K$ . The ratio $D / J = - 0.07$ affords one of the most isotropic Haldane systems yet discovered, while the ratio $Δ_{0} / J = 0.40 (1)$ (where $Δ_{0}$ is the average gap size) is close to its ideal theoretical value, suggesting a very high degree of magnetic isolation of the spin chains in this material. The Haldane gap is closed by orientation-dependent critical fields $μ_{0} H_{c}^{∥} = 5.3 T$ and $μ_{0} H_{c}^{⊥} = 4.3 T$ , which are readily accessible experimentally and permit investigations across the entirety of the Haldane phase, with the fully polarized state occurring at $μ_{0} H_{s}^{∥} = 46.0 T$ and $μ_{0} H_{s}^{⊥} = 50.7 T$ . The results are explicable within the so-called fermion model, in contrast to other reported easy-axis Haldane systems. Zero-field magnetic order is absent down to $20 mK$ and emergent end-chain effects are observed in the gapped state, as evidenced by detailed low-temperature measurements.

Publication Date:: 2020-01-27

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); European Research Council (ERC); National Science Foundation (NSF); Engineering and Physical Sciences Research Council (EPSRC)

OSTI Identifier:: 1595175

Alternate Identifier(s):: OSTI ID: 1783522

Report Number(s):: LA-UR-19-27659
Journal ID: ISSN 2643-1564; PPRHAI; 013082

Grant/Contract Number:: AC02-06CH11357; 89233218CNA000001; DMR-1157490; DMR-1703003; CHE-1834750; EP/N023803/1; EP/N024028/1; EP/N032128/1

Resource Type:: Published Article

Journal Name:: Physical Review Research

Additional Journal Information:: Journal Name: Physical Review Research Journal Volume: 2 Journal Issue: 1; Journal ID: ISSN 2643-1564

Publisher:: American Physical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; High magnetic field science; quantum phase transitions; topological phases of matter; 1-dimensional spin chains

Citation Formats


                    Williams, Robert C., Blackmore, William J. A., Curley, Samuel P. M., Lees, Martin R., Birnbaum, Serena M., Singleton, John, Huddart, Benjamin M., Hicken, Thomas J., Lancaster, Tom, Blundell, Stephen J., Xiao, Fan, Ozarowski, Andrew, Pratt, Francis L., Voneshen, David J., Guguchia, Zurab, Baines, Christopher, Schlueter, John A., Villa, Danielle Y., Manson, Jamie L., and Goddard, Paul A.. Near-ideal molecule-based Haldane spin chain.  United States: N. p., 2020. 
Web.  doi:10.1103/PhysRevResearch.2.013082.

Copy to clipboard


                    Williams, Robert C., Blackmore, William J. A., Curley, Samuel P. M., Lees, Martin R., Birnbaum, Serena M., Singleton, John, Huddart, Benjamin M., Hicken, Thomas J., Lancaster, Tom, Blundell, Stephen J., Xiao, Fan, Ozarowski, Andrew, Pratt, Francis L., Voneshen, David J., Guguchia, Zurab, Baines, Christopher, Schlueter, John A., Villa, Danielle Y., Manson, Jamie L., & Goddard, Paul A.. Near-ideal molecule-based Haldane spin chain.  United States.  https://doi.org/10.1103/PhysRevResearch.2.013082

Copy to clipboard


                    Williams, Robert C., Blackmore, William J. A., Curley, Samuel P. M., Lees, Martin R., Birnbaum, Serena M., Singleton, John, Huddart, Benjamin M., Hicken, Thomas J., Lancaster, Tom, Blundell, Stephen J., Xiao, Fan, Ozarowski, Andrew, Pratt, Francis L., Voneshen, David J., Guguchia, Zurab, Baines, Christopher, Schlueter, John A., Villa, Danielle Y., Manson, Jamie L., and Goddard, Paul A.. Mon .  
"Near-ideal molecule-based Haldane spin chain".  United States.  https://doi.org/10.1103/PhysRevResearch.2.013082.

Copy to clipboard


                    
@article{osti_1595175,

  title        = {Near-ideal molecule-based Haldane spin chain},

  author       = {Williams, Robert C. and Blackmore, William J. A. and Curley, Samuel P. M. and Lees, Martin R. and Birnbaum, Serena M. and Singleton, John and Huddart, Benjamin M. and Hicken, Thomas J. and Lancaster, Tom and Blundell, Stephen J. and Xiao, Fan and Ozarowski, Andrew and Pratt, Francis L. and Voneshen, David J. and Guguchia, Zurab and Baines, Christopher and Schlueter, John A. and Villa, Danielle Y. and Manson, Jamie L. and Goddard, Paul A.},

  abstractNote = {The molecular coordination complex NiI2(3,5-lut)4 [where (3,5-lut) = (3,5-lutidine) =(C7H9N)] has been synthesized and characterized by several techniques including synchrotron x-ray diffraction, electron-spin resonance, superconducting quantum interference device magnetometry, pulsed-field magnetization, inelastic neutron scattering, and muon spin relaxation. Templated by the configuration of 3,5-lut ligands the molecules pack in-registry with the Ni–I∙∙∙I–Ni chains aligned along the c axis. This arrangement leads to an uncommon through-space I∙∙∙I magnetic coupling which is directly measured in this work. The net result is a near-ideal realization of the S=1 Haldane chain with J=17.5K and energy gaps of Δ∥=5.3K Δ⊥=7.7K, split by the easy-axis single-ion anisotropy D=-1.2K. The ratio D/J=-0.07 affords one of the most isotropic Haldane systems yet discovered, while the ratio Δ0/J=0.40(1) (where Δ0 is the average gap size) is close to its ideal theoretical value, suggesting a very high degree of magnetic isolation of the spin chains in this material. The Haldane gap is closed by orientation-dependent critical fields μ0Hc∥=5.3T and μ0Hc⊥=4.3T, which are readily accessible experimentally and permit investigations across the entirety of the Haldane phase, with the fully polarized state occurring at μ0Hs∥=46.0T and μ0Hs⊥=50.7T. The results are explicable within the so-called fermion model, in contrast to other reported easy-axis Haldane systems. Zero-field magnetic order is absent down to 20mK and emergent end-chain effects are observed in the gapped state, as evidenced by detailed low-temperature measurements.},

  doi          = {10.1103/PhysRevResearch.2.013082},

  journal      = {Physical Review Research},

  number       = 1,

  volume       = 2,

  place        = {United States},

  year         = {2020},

  month        = {1}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Publisher's Version of Record
https://doi.org/10.1103/PhysRevResearch.2.013082

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Zone-boundary excitations in coupled Haldane spin chain compounds PbNi 2 V 2 O 8 and SrNi 2 V 2 O 8
journal, September 2001

Zheludev, A.; Masuda, T.; Uchinokura, K.
Physical Review B, Vol. 64, Issue 13
DOI: 10.1103/PhysRevB.64.134415

Controlling Magnetic Order and Quantum Disorder in Molecule-Based Magnets
journal, May 2014

Lancaster, T.; Goddard, P. A.; Blundell, S. J.
Physical Review Letters, Vol. 112, Issue 20
DOI: 10.1103/PhysRevLett.112.207201

Rigorous results on valence-bond ground states in antiferromagnets
journal, August 1987

Affleck, Ian; Kennedy, Tom; Lieb, Elliott H.
Physical Review Letters, Vol. 59, Issue 7
DOI: 10.1103/PhysRevLett.59.799

μSR frequency spectra using the maximum entropy method
journal, December 1994

Rainford, B. D.; Daniell, G. J.
Hyperfine Interactions, Vol. 87, Issue 1
DOI: 10.1007/BF02068515

Continuum in the Spin-Excitation Spectrum of a Haldane Chain Observed by Neutron Scattering in ${CsNiCl}_{3}$
journal, June 2001

Zaliznyak, I. A.; Lee, S. -H.; Petrov, S. V.
Physical Review Letters, Vol. 87, Issue 1
DOI: 10.1103/PhysRevLett.87.017202

Numerical renormalization-group study of low-lying eigenstates of the antiferromagnetic S =1 Heisenberg chain
journal, August 1993

White, Steven R.; Huse, David A.
Physical Review B, Vol. 48, Issue 6
DOI: 10.1103/PhysRevB.48.3844

Multiparticle States in the $S = 1$ Chain System ${CsNiCl}_{3}$
journal, June 2001

Kenzelmann, M.; Cowley, R. A.; Buyers, W. J. L.
Physical Review Letters, Vol. 87, Issue 1
DOI: 10.1103/PhysRevLett.87.017201

Static properties of the S =1 one-dimensional antiferromagnet ${AgVP}_{2}$ $S_{6}$
journal, November 1995

Takigawa, M.; Asano, T.; Ajiro, Y.
Physical Review B, Vol. 52, Issue 18
DOI: 10.1103/PhysRevB.52.R13087

Impurities in s =1 Heisenberg antiferromagnets
journal, June 1995

So/rensen, Erik S.; Affleck, Ian
Physical Review B, Vol. 51, Issue 22
DOI: 10.1103/PhysRevB.51.16115

Effect of the Haldane gap on quasi-one-dimensional systems
journal, September 1990

Sakai, Tôru; Takahashi, Minoru
Physical Review B, Vol. 42, Issue 7
DOI: 10.1103/PhysRevB.42.4537

Dimensionality Selection in a Molecule-Based Magnet
journal, February 2012

Goddard, Paul A.; Manson, Jamie L.; Singleton, John
Physical Review Letters, Vol. 108, Issue 7
DOI: 10.1103/PhysRevLett.108.077208

Dynamics of an anisotropic Haldane antiferromagnet in a strong magnetic field
journal, February 2004

Zheludev, A.; Shapiro, S. M.; Honda, Z.
Physical Review B, Vol. 69, Issue 5
DOI: 10.1103/PhysRevB.69.054414

Quantum criticality
journal, February 2011

Sachdev, Subir; Keimer, Bernhard
Physics Today, Vol. 64, Issue 2
DOI: 10.1063/1.3554314

Molecular magnets
journal, September 2007

Blundell, Stephen J.
Contemporary Physics, Vol. 48, Issue 5
DOI: 10.1080/00107510801967415

Spectral function for the $S = 1$ Heisenberg antiferromagetic chain
journal, April 2008

White, Steven R.; Affleck, Ian
Physical Review B, Vol. 77, Issue 13
DOI: 10.1103/PhysRevB.77.134437

Magnetic Spin Ladder ( C 5 H 12 N ) 2 Cu Br 4 : High-Field Magnetization and Scaling near Quantum Criticality
journal, May 2001

Watson, B. C.; Kotov, V. N.; Meisel, M. W.
Physical Review Letters, Vol. 86, Issue 22
DOI: 10.1103/PhysRevLett.86.5168

The crystal and molecular structure of diiodotetrakis(pyridine)nickel(II) [Nipy4I2]
journal, January 1973

Hamm, D. J.; Bordner, J.; Schreiner, A. F.
Inorganica Chimica Acta, Vol. 7
DOI: 10.1016/S0020-1693(00)94900-4

Bose-Einstein Condensation of $S = 1$ Nickel Spin Degrees of Freedom in ${NiCl}_{2} − 4 SC ({NH}_{2})_{2}$
journal, February 2006

Zapf, V. S.; Zocco, D.; Hansen, B. R.
Physical Review Letters, Vol. 96, Issue 7
DOI: 10.1103/PhysRevLett.96.077204

Spin-Vacancy-Induced Long-Range Order in a New Haldane-Gap Antiferromagnet
journal, July 1999

Uchiyama, Y.; Sasago, Y.; Tsukada, I.
Physical Review Letters, Vol. 83, Issue 3
DOI: 10.1103/PhysRevLett.83.632

Quantum phase transitions driven by rhombic-type single-ion anisotropy in the $S = 1$ Haldane chain
journal, August 2017

Tzeng, Yu-Chin; Onishi, Hiroaki; Okubo, Tsuyoshi
Physical Review B, Vol. 96, Issue 6
DOI: 10.1103/PhysRevB.96.060404

Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an $S = 1$ quantum antiferromagnet
journal, April 2017

Brambleby, Jamie; Manson, Jamie L.; Goddard, Paul A.
Physical Review B, Vol. 95, Issue 13
DOI: 10.1103/PhysRevB.95.134435

Gap of the linear spin-1 Heisenberg antiferromagnet: A Monte Carlo calculation
journal, January 1986

Nightingale, M. P.; Blöte, H. W. J.
Physical Review B, Vol. 33, Issue 1
DOI: 10.1103/PhysRevB.33.659

Cluster Algorithms for General- $S$ Quantum Spin Systems
journal, July 2001

Todo, Synge; Kato, Kiyoshi
Physical Review Letters, Vol. 87, Issue 4
DOI: 10.1103/PhysRevLett.87.047203

Finite-lattice extrapolations for a Haldane-gap antiferromagnet
journal, August 1994

Golinelli, O.; Jolicoeur, Th.; Lacaze, R.
Physical Review B, Vol. 50, Issue 5
DOI: 10.1103/PhysRevB.50.3037

Theory of electron spin resonance in Haldane-gap antiferromagnets
journal, October 1992

Affleck, Ian
Physical Review B, Vol. 46, Issue 14
DOI: 10.1103/PhysRevB.46.9002

Spin dynamics of the anisotropic spin-1 antiferromagnetic chain at finite magnetic fields
journal, February 2015

Rahnavard, Yousef; Brenig, Wolfram
Physical Review B, Vol. 91, Issue 5
DOI: 10.1103/PhysRevB.91.054405

Antiferromagnetism in a Family of S = 1 Square Lattice Coordination Polymers NiX ₂ (pyz) ₂ (X = Cl, Br, I, NCS; pyz = Pyrazine)
journal, March 2016

Liu, Junjie; Goddard, Paul A.; Singleton, John
Inorganic Chemistry, Vol. 55, Issue 7
DOI: 10.1021/acs.inorgchem.5b02991

Superexchange interaction and symmetry properties of electron orbitals
journal, July 1959

Kanamori, Junjiro
Journal of Physics and Chemistry of Solids, Vol. 10, Issue 2-3
DOI: 10.1016/0022-3697(59)90061-7

Magnetic properties of the Haldane-gap material [Ni(C 2 H 8 N 2 ) 2 NO 2 ](BF 4 )
journal, March 2008

Čižmár, E.; Ozerov, M.; Ignatchik, O.
New Journal of Physics, Vol. 10, Issue 3
DOI: 10.1088/1367-2630/10/3/033008

Neutron Scattering Study of Magnetic Excitations in the Spin S = 1 One-Dimensional Heisenberg Antiferromagnet Y 2 B a N i O 5
journal, September 1996

Sakaguchi, Takehiro; Kakurai, Kazuhisa; Yokoo, Tetsuya
Journal of the Physical Society of Japan, Vol. 65, Issue 9
DOI: 10.1143/JPSJ.65.3025

Magnetic order in the quasi-one-dimensional spin- $1 ∕ 2$ molecular chain compound copper pyrazine dinitrate
journal, January 2006

Lancaster, T.; Blundell, S. J.; Brooks, M. L.
Physical Review B, Vol. 73, Issue 2
DOI: 10.1103/PhysRevB.73.020410

Consequences of critical interchain couplings and anisotropy on a Haldane chain
journal, April 2015

Bera, A. K.; Lake, B.; Islam, A. T. M. N.
Physical Review B, Vol. 91, Issue 14
DOI: 10.1103/PhysRevB.91.144414

Dynamics of paramagnets at zero temperature
journal, May 2007

Farutin, A. M.; Marchenko, V. I.
Journal of Experimental and Theoretical Physics, Vol. 104, Issue 5
DOI: 10.1134/S1063776107050093

Evidence of a magnetic Bose glass in ${({CH}_{3})}_{2} {CHNH}_{3} Cu {({Cl}_{{0.95}} {Br}_{{0.05}})}_{3}$ from neutron diffraction
journal, February 2010

Hong, Tao; Zheludev, A.; Manaka, H.
Physical Review B, Vol. 81, Issue 6
DOI: 10.1103/PhysRevB.81.060410

Sensitive SQUID magnetometry for studying nanomagnetism
journal, April 2011

Sawicki, M.; Stefanowicz, W.; Ney, A.
Semiconductor Science and Technology, Vol. 26, Issue 6
DOI: 10.1088/0268-1242/26/6/064006

NMR relaxation in the spin-1 Heisenberg chain
journal, September 2019

Capponi, Sylvain; Dupont, Maxime; Sandvik, Anders W.
Physical Review B, Vol. 100, Issue 9
DOI: 10.1103/PhysRevB.100.094411

Bose-Einstein condensation in quantum magnets
journal, May 2014

Zapf, Vivien; Jaime, Marcelo; Batista, C. D.
Reviews of Modern Physics, Vol. 86, Issue 2
DOI: 10.1103/RevModPhys.86.563

Quasiparticle breakdown in a quantum spin liquid
journal, March 2006

Stone, Matthew B.; Zaliznyak, Igor A.; Hong, Tao
Nature, Vol. 440, Issue 7081
DOI: 10.1038/nature04593

Padé approximations for the magnetic susceptibilities of Heisenberg antiferromagnetic spin chains for various spin values
journal, January 2013

Law, J. M.; Benner, H.; Kremer, R. K.
Journal of Physics: Condensed Matter, Vol. 25, Issue 6
DOI: 10.1088/0953-8984/25/6/065601

Critical properties of coupled anisotropic Haldane spin chains in a magnetic field
journal, August 2015

Bera, A. K.; Lake, B.; Islam, A. T. M. N.
Physical Review B, Vol. 92, Issue 6
DOI: 10.1103/PhysRevB.92.060412

Field-induced magnetic ordering and single-ion anisotropy in the quasi-one-dimensional Haldane chain compound SrNi 2 V 2 O 8 : A single-crystal investigation
journal, June 2013

Bera, A. K.; Lake, B.; Islam, A. T. M. N.
Physical Review B, Vol. 87, Issue 22
DOI: 10.1103/PhysRevB.87.224423

Triplet spin resonance of the Haldane magnet Pb Ni 2 V 2 O 8 with interchain coupling
journal, March 2008

Smirnov, A. I.; Glazkov, V. N.; Kashiwagi, T.
Physical Review B, Vol. 77, Issue 10
DOI: 10.1103/PhysRevB.77.100401

Dynamic structure factor [ S ( Q ,ω)] of the S =1 quasi-one-dimensional Heisenberg antiferromagnet: Neutron-scattering study on ${AgVP}_{2}$ $S_{6}$
journal, July 1991

Mutka, H.; Payen, C.; Molinié, P.
Physical Review Letters, Vol. 67, Issue 4
DOI: 10.1103/PhysRevLett.67.497

Nonlinear Field Theory of Large-Spin Heisenberg Antiferromagnets: Semiclassically Quantized Solitons of the One-Dimensional Easy-Axis Néel State
journal, April 1983

Haldane, F. D. M.
Physical Review Letters, Vol. 50, Issue 15
DOI: 10.1103/PhysRevLett.50.1153

Bose glass and Mott glass of quasiparticles in a doped quantum magnet
journal, September 2012

Yu, Rong; Yin, Liang; Sullivan, Neil S.
Nature, Vol. 489, Issue 7416
DOI: 10.1038/nature11406

Massive triplet excitations in a magnetized anisotropic Haldane spin chain
journal, October 2003

Zheludev, A.; Honda, Z.; Broholm, C. L.
Physical Review B, Vol. 68, Issue 13
DOI: 10.1103/PhysRevB.68.134438

Linear Magnetic Chains with Anisotropic Coupling
journal, August 1964

Bonner, Jill C.; Fisher, Michael E.
Physical Review, Vol. 135, Issue 3A
DOI: 10.1103/PhysRev.135.A640

Field-Induced Tomonaga-Luttinger Liquid Phase of a Two-Leg Spin-1/2 Ladder with Strong Leg Interactions
journal, September 2010

Hong, Tao; Kim, Y. H.; Hotta, C.
Physical Review Letters, Vol. 105, Issue 13
DOI: 10.1103/PhysRevLett.105.137207

Observation of S =1/2 degrees of freedom in an S =1 linear-chain Heisenberg antiferromagnet
journal, December 1990

Hagiwara, M.; Katsumata, K.; Affleck, Ian
Physical Review Letters, Vol. 65, Issue 25
DOI: 10.1103/PhysRevLett.65.3181

Impurity state in the Haldane gap for an S = 1 Heisenberg antiferromagnetic chain with bond doping
journal, January 1996

Wang, Xiaoqun; Mallwitz, Steffen
Physical Review B, Vol. 53, Issue 2
DOI: 10.1103/PhysRevB.53.R492

Characterizing the Haldane phase in quasi-one-dimensional spin-1 Heisenberg antiferromagnets
journal, December 2014

Wierschem, Keola; Sengupta, Pinaki
Modern Physics Letters B, Vol. 28, Issue 32
DOI: 10.1142/S0217984914300178

Quantum magnetism in molecular spin ladders probed with muon-spin spectroscopy
journal, October 2018

Lancaster, T.; Xiao, F.; Huddart, B. M.
New Journal of Physics, Vol. 20, Issue 10
DOI: 10.1088/1367-2630/aae21a

Quenching the Haldane Gap in Spin-1 Heisenberg Antiferromagnets
journal, June 2014

Wierschem, Keola; Sengupta, Pinaki
Physical Review Letters, Vol. 112, Issue 24
DOI: 10.1103/PhysRevLett.112.247203

Dominance of long-lived excitations in the antiferromagnetic spin-1 chain NENP
journal, December 1992

Ma, Shaolong; Broholm, Collin; Reich, Daniel H.
Physical Review Letters, Vol. 69, Issue 24
DOI: 10.1103/PhysRevLett.69.3571

High-field multifrequency electron-spin-resonance study of the Haldane magnet Ni ( C 5 H 14 N 2 ) 2 N 3 ( PF 6 )
journal, January 2009

Kashiwagi, T.; Hagiwara, M.; Kimura, S.
Physical Review B, Vol. 79, Issue 2
DOI: 10.1103/PhysRevB.79.024403

Haldane gaps in a spin-1 Heisenberg chain with easy-plane single-ion anisotropy
journal, May 1992

Golinelli, O.; Jolicoeur, Th.; Lacaze, R.
Physical Review B, Vol. 45, Issue 17
DOI: 10.1103/PhysRevB.45.9798

Spin-polarized muons in condensed matter physics
journal, May 1999

Blundell, S. J.
Contemporary Physics, Vol. 40, Issue 3
DOI: 10.1080/001075199181521

Field-theory treatment of the Heisenberg spin-1 chain
journal, December 1990

Tsvelik, A. M.
Physical Review B, Vol. 42, Issue 16
DOI: 10.1103/PhysRevB.42.10499

Sample size, position, and structure effects on magnetization measurements using second-order gradiometer pickup coils
journal, January 2006

Stamenov, P.; Coey, J. M. D.
Review of Scientific Instruments, Vol. 77, Issue 1
DOI: 10.1063/1.2149190

Inelastic-neutron-scattering study of the spin dynamics in the Haldane-gap system Ni( C 2 H 8 N 2 ) 2 NO 2 ClO 4
journal, October 1994

Regnault, L. P.; Zaliznyak, I.; Renard, J. P.
Physical Review B, Vol. 50, Issue 13
DOI: 10.1103/PhysRevB.50.9174

Dirty-boson physics with magnetic insulators
journal, October 2013

Zheludev, Andrey; Roscilde, Tommaso
Comptes Rendus Physique, Vol. 14, Issue 8
DOI: 10.1016/j.crhy.2013.10.001

Possible Bose-Einstein condensate of magnons in single-crystalline ${Pb}_{2} V_{3} O_{9}$
journal, April 2010

Conner, B. S.; Zhou, H. D.; Jo, Y. J.
Physical Review B, Vol. 81, Issue 13
DOI: 10.1103/PhysRevB.81.132401

Low-temperature magnetic measurements of an S =1 linear-chain Heisenberg antiferromagnet
journal, October 1992

Avenel, O.; Xu, J.; Xia, J. S.
Physical Review B, Vol. 46, Issue 13
DOI: 10.1103/PhysRevB.46.8655

The magnetic field behaviour of a Haldane-gap antiferromagnet
journal, October 1993

Golinelli, O.; Jolicoeur, T.; Lacaze, R.
Journal of Physics: Condensed Matter, Vol. 5, Issue 42
DOI: 10.1088/0953-8984/5/42/007

Thermodynamic properties of the Haldane spin chain: a statistical model for the elementary excitations
journal, December 1993

Regnault, L. -P; Zaliznyak, I. A.; Meshkov, S. V.
Journal of Physics: Condensed Matter, Vol. 5, Issue 50
DOI: 10.1088/0953-8984/5/50/004

Long symmetric high-pressure cell for magnetic measurements in superconducting quantum interference device magnetometer
journal, July 2006

Kamenev, K. V.; Tancharakorn, S.; Robertson, N.
Review of Scientific Instruments, Vol. 77, Issue 7
DOI: 10.1063/1.2221537

Zeeman Levels with Exotic Field Dependence in the High Field Phase of an S = 1 Heisenberg Antiferromagnetic Chain
journal, October 2003

Hagiwara, M.; Honda, Z.; Katsumata, K.
Physical Review Letters, Vol. 91, Issue 17
DOI: 10.1103/PhysRevLett.91.177601

Magnetic excitations in coupled Haldane spin chains near the quantum critical point
journal, October 2000

Zheludev, A.; Masuda, T.; Tsukada, I.
Physical Review B, Vol. 62, Issue 13
DOI: 10.1103/PhysRevB.62.8921

WIMDA: a muon data analysis program for the Windows PC
journal, August 2000

Pratt, F. L.
Physica B: Condensed Matter, Vol. 289-290
DOI: 10.1016/S0921-4526(00)00328-8

Continuum dynamics of the 1-D Heisenberg antiferromagnet: Identification with the O(3) nonlinear sigma model
journal, February 1983

Haldane, F. D. M.
Physics Letters A, Vol. 93, Issue 9
DOI: 10.1016/0375-9601(83)90631-X

Observation of fractional spin S =1/2 on open ends of S =1 linear antiferromagnetic chains: Nonmagnetic doping
journal, September 1991

Glarum, S. H.; Geschwind, S.; Lee, K. M.
Physical Review Letters, Vol. 67, Issue 12
DOI: 10.1103/PhysRevLett.67.1614

Characterization of a quasi-one-dimensional spin-1/2 magnet which is gapless and paramagnetic for $g μ_{B} H ≲ J$ and $k_{B} T ≪ J$
journal, January 1999

Hammar, P. R.; Stone, M. B.; Reich, Daniel H.
Physical Review B, Vol. 59, Issue 2
DOI: 10.1103/PhysRevB.59.1008

Determining the anisotropy and exchange parameters of polycrystalline spin-1 magnets
journal, September 2019

Blackmore, W. J. A.; Brambleby, J.; Lancaster, T.
New Journal of Physics, Vol. 21, Issue 9
DOI: 10.1088/1367-2630/ab3dba

Y 2 BaNi O 5 : A nearly ideal realization of the S = 1 Heisenberg chain with antiferromagnetic interactions
journal, September 1996

Xu, Guangyong; DiTusa, J. F.; Ito, T.
Physical Review B, Vol. 54, Issue 10
DOI: 10.1103/PhysRevB.54.R6827

Similar Records in DOE PAGES and OSTI.GOV collections:

Similar Records

Title: Near-ideal molecule-based Haldane spin chain

Abstract

Citation Formats

Zone-boundary excitations in coupled Haldane spin chain compounds PbNi 2 V 2 O 8 and SrNi 2 V 2 O 8 journal, September 2001

Controlling Magnetic Order and Quantum Disorder in Molecule-Based Magnets journal, May 2014

Rigorous results on valence-bond ground states in antiferromagnets journal, August 1987

μSR frequency spectra using the maximum entropy method journal, December 1994

Continuum in the Spin-Excitation Spectrum of a Haldane Chain Observed by Neutron Scattering in CsNiCl 3 journal, June 2001

Numerical renormalization-group study of low-lying eigenstates of the antiferromagnetic S =1 Heisenberg chain journal, August 1993

Multiparticle States in the S = 1 Chain System CsNiCl 3 journal, June 2001

Static properties of the S =1 one-dimensional antiferromagnet AgVP 2 S 6 journal, November 1995

Impurities in s =1 Heisenberg antiferromagnets journal, June 1995

Effect of the Haldane gap on quasi-one-dimensional systems journal, September 1990

Dimensionality Selection in a Molecule-Based Magnet journal, February 2012

Dynamics of an anisotropic Haldane antiferromagnet in a strong magnetic field journal, February 2004

Quantum criticality journal, February 2011

Molecular magnets journal, September 2007

Spectral function for the S = 1 Heisenberg antiferromagetic chain journal, April 2008

Magnetic Spin Ladder ( C 5 H 12 N ) 2 Cu Br 4 : High-Field Magnetization and Scaling near Quantum Criticality journal, May 2001

The crystal and molecular structure of diiodotetrakis(pyridine)nickel(II) [Nipy4I2] journal, January 1973

Bose-Einstein Condensation of S = 1 Nickel Spin Degrees of Freedom in NiCl 2 − 4 SC ( NH 2 ) 2 journal, February 2006

Spin-Vacancy-Induced Long-Range Order in a New Haldane-Gap Antiferromagnet journal, July 1999

Quantum phase transitions driven by rhombic-type single-ion anisotropy in the S = 1 Haldane chain journal, August 2017

Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an S = 1 quantum antiferromagnet journal, April 2017

Gap of the linear spin-1 Heisenberg antiferromagnet: A Monte Carlo calculation journal, January 1986

Cluster Algorithms for General- S Quantum Spin Systems journal, July 2001

Finite-lattice extrapolations for a Haldane-gap antiferromagnet journal, August 1994

Theory of electron spin resonance in Haldane-gap antiferromagnets journal, October 1992

Spin dynamics of the anisotropic spin-1 antiferromagnetic chain at finite magnetic fields journal, February 2015

Antiferromagnetism in a Family of S = 1 Square Lattice Coordination Polymers NiX 2 (pyz) 2 (X = Cl, Br, I, NCS; pyz = Pyrazine) journal, March 2016

Superexchange interaction and symmetry properties of electron orbitals journal, July 1959

Magnetic properties of the Haldane-gap material [Ni(C 2 H 8 N 2 ) 2 NO 2 ](BF 4 ) journal, March 2008

Neutron Scattering Study of Magnetic Excitations in the Spin S = 1 One-Dimensional Heisenberg Antiferromagnet Y 2 B a N i O 5 journal, September 1996

Magnetic order in the quasi-one-dimensional spin- 1 ∕ 2 molecular chain compound copper pyrazine dinitrate journal, January 2006

Consequences of critical interchain couplings and anisotropy on a Haldane chain journal, April 2015

Dynamics of paramagnets at zero temperature journal, May 2007

Evidence of a magnetic Bose glass in ( CH 3 ) 2 CHNH 3 Cu ( Cl { 0.95 } Br { 0.05 } ) 3 from neutron diffraction journal, February 2010

Sensitive SQUID magnetometry for studying nanomagnetism journal, April 2011

NMR relaxation in the spin-1 Heisenberg chain journal, September 2019

Bose-Einstein condensation in quantum magnets journal, May 2014

Quasiparticle breakdown in a quantum spin liquid journal, March 2006

Padé approximations for the magnetic susceptibilities of Heisenberg antiferromagnetic spin chains for various spin values journal, January 2013

Critical properties of coupled anisotropic Haldane spin chains in a magnetic field journal, August 2015

Field-induced magnetic ordering and single-ion anisotropy in the quasi-one-dimensional Haldane chain compound SrNi 2 V 2 O 8 : A single-crystal investigation journal, June 2013

Triplet spin resonance of the Haldane magnet Pb Ni 2 V 2 O 8 with interchain coupling journal, March 2008

Dynamic structure factor [ S ( Q ,ω)] of the S =1 quasi-one-dimensional Heisenberg antiferromagnet: Neutron-scattering study on AgVP 2 S 6 journal, July 1991

Nonlinear Field Theory of Large-Spin Heisenberg Antiferromagnets: Semiclassically Quantized Solitons of the One-Dimensional Easy-Axis Néel State journal, April 1983

Bose glass and Mott glass of quasiparticles in a doped quantum magnet journal, September 2012

Massive triplet excitations in a magnetized anisotropic Haldane spin chain journal, October 2003

Linear Magnetic Chains with Anisotropic Coupling journal, August 1964

Field-Induced Tomonaga-Luttinger Liquid Phase of a Two-Leg Spin-1/2 Ladder with Strong Leg Interactions journal, September 2010

Observation of S =1/2 degrees of freedom in an S =1 linear-chain Heisenberg antiferromagnet journal, December 1990

Impurity state in the Haldane gap for an S = 1 Heisenberg antiferromagnetic chain with bond doping journal, January 1996

Characterizing the Haldane phase in quasi-one-dimensional spin-1 Heisenberg antiferromagnets journal, December 2014

Quantum magnetism in molecular spin ladders probed with muon-spin spectroscopy journal, October 2018

Quenching the Haldane Gap in Spin-1 Heisenberg Antiferromagnets journal, June 2014

Dominance of long-lived excitations in the antiferromagnetic spin-1 chain NENP journal, December 1992

High-field multifrequency electron-spin-resonance study of the Haldane magnet Ni ( C 5 H 14 N 2 ) 2 N 3 ( PF 6 ) journal, January 2009

Haldane gaps in a spin-1 Heisenberg chain with easy-plane single-ion anisotropy journal, May 1992

Spin-polarized muons in condensed matter physics journal, May 1999

Field-theory treatment of the Heisenberg spin-1 chain journal, December 1990

Sample size, position, and structure effects on magnetization measurements using second-order gradiometer pickup coils journal, January 2006

Inelastic-neutron-scattering study of the spin dynamics in the Haldane-gap system Ni( C 2 H 8 N 2 ) 2 NO 2 ClO 4 journal, October 1994

Dirty-boson physics with magnetic insulators journal, October 2013

Possible Bose-Einstein condensate of magnons in single-crystalline Pb 2 V 3 O 9 journal, April 2010

Low-temperature magnetic measurements of an S =1 linear-chain Heisenberg antiferromagnet journal, October 1992

The magnetic field behaviour of a Haldane-gap antiferromagnet journal, October 1993

Thermodynamic properties of the Haldane spin chain: a statistical model for the elementary excitations journal, December 1993

Long symmetric high-pressure cell for magnetic measurements in superconducting quantum interference device magnetometer journal, July 2006

Zeeman Levels with Exotic Field Dependence in the High Field Phase of an S = 1 Heisenberg Antiferromagnetic Chain journal, October 2003

Magnetic excitations in coupled Haldane spin chains near the quantum critical point journal, October 2000

WIMDA: a muon data analysis program for the Windows PC journal, August 2000

Continuum dynamics of the 1-D Heisenberg antiferromagnet: Identification with the O(3) nonlinear sigma model journal, February 1983

Observation of fractional spin S =1/2 on open ends of S =1 linear antiferromagnetic chains: Nonmagnetic doping journal, September 1991

Characterization of a quasi-one-dimensional spin-1/2 magnet which is gapless and paramagnetic for g μ B H ≲ J and k B T ≪ J journal, January 1999

Determining the anisotropy and exchange parameters of polycrystalline spin-1 magnets journal, September 2019

Y 2 BaNi O 5 : A nearly ideal realization of the S = 1 Heisenberg chain with antiferromagnetic interactions journal, September 1996

Zone-boundary excitations in coupled Haldane spin chain compounds PbNi 2 V 2 O 8 and SrNi 2 V 2 O 8
journal, September 2001

Controlling Magnetic Order and Quantum Disorder in Molecule-Based Magnets
journal, May 2014

Rigorous results on valence-bond ground states in antiferromagnets
journal, August 1987

μSR frequency spectra using the maximum entropy method
journal, December 1994

Continuum in the Spin-Excitation Spectrum of a Haldane Chain Observed by Neutron Scattering in ${CsNiCl}_{3}$
journal, June 2001

Numerical renormalization-group study of low-lying eigenstates of the antiferromagnetic S =1 Heisenberg chain
journal, August 1993

Multiparticle States in the $S = 1$ Chain System ${CsNiCl}_{3}$
journal, June 2001

Static properties of the S =1 one-dimensional antiferromagnet ${AgVP}_{2}$ $S_{6}$
journal, November 1995

Impurities in s =1 Heisenberg antiferromagnets
journal, June 1995

Effect of the Haldane gap on quasi-one-dimensional systems
journal, September 1990

Dimensionality Selection in a Molecule-Based Magnet
journal, February 2012

Dynamics of an anisotropic Haldane antiferromagnet in a strong magnetic field
journal, February 2004

Quantum criticality
journal, February 2011

Molecular magnets
journal, September 2007

Spectral function for the $S = 1$ Heisenberg antiferromagetic chain
journal, April 2008

Magnetic Spin Ladder ( C 5 H 12 N ) 2 Cu Br 4 : High-Field Magnetization and Scaling near Quantum Criticality
journal, May 2001

The crystal and molecular structure of diiodotetrakis(pyridine)nickel(II) [Nipy4I2]
journal, January 1973

Bose-Einstein Condensation of $S = 1$ Nickel Spin Degrees of Freedom in ${NiCl}_{2} − 4 SC ({NH}_{2})_{2}$
journal, February 2006

Spin-Vacancy-Induced Long-Range Order in a New Haldane-Gap Antiferromagnet
journal, July 1999

Quantum phase transitions driven by rhombic-type single-ion anisotropy in the $S = 1$ Haldane chain
journal, August 2017

Combining microscopic and macroscopic probes to untangle the single-ion anisotropy and exchange energies in an $S = 1$ quantum antiferromagnet
journal, April 2017

Gap of the linear spin-1 Heisenberg antiferromagnet: A Monte Carlo calculation
journal, January 1986

Cluster Algorithms for General- $S$ Quantum Spin Systems
journal, July 2001

Finite-lattice extrapolations for a Haldane-gap antiferromagnet
journal, August 1994

Theory of electron spin resonance in Haldane-gap antiferromagnets
journal, October 1992

Spin dynamics of the anisotropic spin-1 antiferromagnetic chain at finite magnetic fields
journal, February 2015

Antiferromagnetism in a Family of S = 1 Square Lattice Coordination Polymers NiX ₂ (pyz) ₂ (X = Cl, Br, I, NCS; pyz = Pyrazine)
journal, March 2016

Superexchange interaction and symmetry properties of electron orbitals
journal, July 1959

Magnetic properties of the Haldane-gap material [Ni(C 2 H 8 N 2 ) 2 NO 2 ](BF 4 )
journal, March 2008

Neutron Scattering Study of Magnetic Excitations in the Spin S = 1 One-Dimensional Heisenberg Antiferromagnet Y 2 B a N i O 5
journal, September 1996

Magnetic order in the quasi-one-dimensional spin- $1 ∕ 2$ molecular chain compound copper pyrazine dinitrate
journal, January 2006

Consequences of critical interchain couplings and anisotropy on a Haldane chain
journal, April 2015

Dynamics of paramagnets at zero temperature
journal, May 2007

Evidence of a magnetic Bose glass in ${({CH}_{3})}_{2} {CHNH}_{3} Cu {({Cl}_{{0.95}} {Br}_{{0.05}})}_{3}$ from neutron diffraction
journal, February 2010

Sensitive SQUID magnetometry for studying nanomagnetism
journal, April 2011

NMR relaxation in the spin-1 Heisenberg chain
journal, September 2019

Bose-Einstein condensation in quantum magnets
journal, May 2014

Quasiparticle breakdown in a quantum spin liquid
journal, March 2006

Padé approximations for the magnetic susceptibilities of Heisenberg antiferromagnetic spin chains for various spin values
journal, January 2013

Critical properties of coupled anisotropic Haldane spin chains in a magnetic field
journal, August 2015

Field-induced magnetic ordering and single-ion anisotropy in the quasi-one-dimensional Haldane chain compound SrNi 2 V 2 O 8 : A single-crystal investigation
journal, June 2013

Triplet spin resonance of the Haldane magnet Pb Ni 2 V 2 O 8 with interchain coupling
journal, March 2008

Dynamic structure factor [ S ( Q ,ω)] of the S =1 quasi-one-dimensional Heisenberg antiferromagnet: Neutron-scattering study on ${AgVP}_{2}$ $S_{6}$
journal, July 1991

Nonlinear Field Theory of Large-Spin Heisenberg Antiferromagnets: Semiclassically Quantized Solitons of the One-Dimensional Easy-Axis Néel State
journal, April 1983

Bose glass and Mott glass of quasiparticles in a doped quantum magnet
journal, September 2012

Massive triplet excitations in a magnetized anisotropic Haldane spin chain
journal, October 2003

Linear Magnetic Chains with Anisotropic Coupling
journal, August 1964

Field-Induced Tomonaga-Luttinger Liquid Phase of a Two-Leg Spin-1/2 Ladder with Strong Leg Interactions
journal, September 2010

Observation of S =1/2 degrees of freedom in an S =1 linear-chain Heisenberg antiferromagnet
journal, December 1990

Impurity state in the Haldane gap for an S = 1 Heisenberg antiferromagnetic chain with bond doping
journal, January 1996

Characterizing the Haldane phase in quasi-one-dimensional spin-1 Heisenberg antiferromagnets
journal, December 2014

Quantum magnetism in molecular spin ladders probed with muon-spin spectroscopy
journal, October 2018

Quenching the Haldane Gap in Spin-1 Heisenberg Antiferromagnets
journal, June 2014

Dominance of long-lived excitations in the antiferromagnetic spin-1 chain NENP
journal, December 1992

High-field multifrequency electron-spin-resonance study of the Haldane magnet Ni ( C 5 H 14 N 2 ) 2 N 3 ( PF 6 )
journal, January 2009

Haldane gaps in a spin-1 Heisenberg chain with easy-plane single-ion anisotropy
journal, May 1992

Spin-polarized muons in condensed matter physics
journal, May 1999

Field-theory treatment of the Heisenberg spin-1 chain
journal, December 1990

Sample size, position, and structure effects on magnetization measurements using second-order gradiometer pickup coils
journal, January 2006

Inelastic-neutron-scattering study of the spin dynamics in the Haldane-gap system Ni( C 2 H 8 N 2 ) 2 NO 2 ClO 4
journal, October 1994

Dirty-boson physics with magnetic insulators
journal, October 2013

Possible Bose-Einstein condensate of magnons in single-crystalline ${Pb}_{2} V_{3} O_{9}$
journal, April 2010

Low-temperature magnetic measurements of an S =1 linear-chain Heisenberg antiferromagnet
journal, October 1992

The magnetic field behaviour of a Haldane-gap antiferromagnet
journal, October 1993

Thermodynamic properties of the Haldane spin chain: a statistical model for the elementary excitations
journal, December 1993

Long symmetric high-pressure cell for magnetic measurements in superconducting quantum interference device magnetometer
journal, July 2006

Zeeman Levels with Exotic Field Dependence in the High Field Phase of an S = 1 Heisenberg Antiferromagnetic Chain
journal, October 2003

Magnetic excitations in coupled Haldane spin chains near the quantum critical point
journal, October 2000

WIMDA: a muon data analysis program for the Windows PC
journal, August 2000

Continuum dynamics of the 1-D Heisenberg antiferromagnet: Identification with the O(3) nonlinear sigma model
journal, February 1983

Observation of fractional spin S =1/2 on open ends of S =1 linear antiferromagnetic chains: Nonmagnetic doping
journal, September 1991

Characterization of a quasi-one-dimensional spin-1/2 magnet which is gapless and paramagnetic for $g μ_{B} H ≲ J$ and $k_{B} T ≪ J$
journal, January 1999

Determining the anisotropy and exchange parameters of polycrystalline spin-1 magnets
journal, September 2019

Y 2 BaNi O 5 : A nearly ideal realization of the S = 1 Heisenberg chain with antiferromagnetic interactions
journal, September 1996