Rational selection of co-catalysts for the deaminative hydrogenation of amides
Abstract
Theory and experiments were used to rationally design co-catalysts for the deaminative hydrogenation of amides. TBD was found to be the optimal catalyst, assisting the C–N bond cleavage while preventing the formation of adducts with the catalyst.
- Authors:
-
- Hylleraas Centre for Quantum Molecular Sciences, Department of Chemistry, University of Oslo, N-0315 Oslo, Norway
- Department of Chemistry, University of Missouri, Columbia, USA
- Department of Chemistry, Yale University, New Haven, USA
- Department of Electronics, ETSIT, University of Valladolid, 47011 Valladolid, Spain
- Publication Date:
- Research Org.:
- Univ. of Missouri, Columbia, MO (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1595161
- Alternate Identifier(s):
- OSTI ID: 1594890; OSTI ID: 1777141
- Grant/Contract Number:
- SC0018222; 250044; 262695; nn4654k; 85378
- Resource Type:
- Published Article
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Name: Chemical Science Journal Volume: 11 Journal Issue: 8; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United Kingdom
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Artús Suàrez, Lluís, Jayarathne, Upul, Balcells, David, Bernskoetter, Wesley H., Hazari, Nilay, Jaraiz, Martín, and Nova, Ainara. Rational selection of co-catalysts for the deaminative hydrogenation of amides. United Kingdom: N. p., 2020.
Web. doi:10.1039/C9SC03812D.
Artús Suàrez, Lluís, Jayarathne, Upul, Balcells, David, Bernskoetter, Wesley H., Hazari, Nilay, Jaraiz, Martín, & Nova, Ainara. Rational selection of co-catalysts for the deaminative hydrogenation of amides. United Kingdom. https://doi.org/10.1039/C9SC03812D
Artús Suàrez, Lluís, Jayarathne, Upul, Balcells, David, Bernskoetter, Wesley H., Hazari, Nilay, Jaraiz, Martín, and Nova, Ainara. Wed .
"Rational selection of co-catalysts for the deaminative hydrogenation of amides". United Kingdom. https://doi.org/10.1039/C9SC03812D.
@article{osti_1595161,
title = {Rational selection of co-catalysts for the deaminative hydrogenation of amides},
author = {Artús Suàrez, Lluís and Jayarathne, Upul and Balcells, David and Bernskoetter, Wesley H. and Hazari, Nilay and Jaraiz, Martín and Nova, Ainara},
abstractNote = {Theory and experiments were used to rationally design co-catalysts for the deaminative hydrogenation of amides. TBD was found to be the optimal catalyst, assisting the C–N bond cleavage while preventing the formation of adducts with the catalyst.},
doi = {10.1039/C9SC03812D},
journal = {Chemical Science},
number = 8,
volume = 11,
place = {United Kingdom},
year = {2020},
month = {2}
}
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https://doi.org/10.1039/C9SC03812D
https://doi.org/10.1039/C9SC03812D
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