Improved H 2 Evolution in Quaternary SCIGS Chalcopyrite Semiconductors
Abstract
In a search for improved photocathode materials for fuel-producing photoelectrochemical cells, quaternary AgxCu1-xGayIn1-yS2 (0 ≤ x ≤ 1.0, 0 ≤ y ≤ 1.0) p-type, chalcopyrite semiconductors (SCIGS) were prepared and tested for photochemical hydrogen evolution. The study reported here is based on the preparation of bulk phases of the quaternary system. In contrast to thin-film studies of this system, this approach enables enhanced control of the materials' chemical, structural, and electronic properties. Compared to ternary CIGS electrode materials, the quaternary SCIGS materials provide improved photoelectrochemical and electrocatalytic properties. The quaternary system allows for adjustment of the band structures and photocatalytic abilities to a finer degree than is possible in the AgxCu1-xGaS2 or AgxCu1-xInS2 ternaries, and several of the quaternary AgxCu1-xGayIn1-yS2 compositions are found to show better water-splitting capability than the ternaries, even when a platinum co-catalyst is present in the ternary systems. Our work on quaternary compounds has led to finding unexpected optoelectric properties in ternary compounds of composition AgxCu1-xGaS2. Specifically, a "V-shaped" plot of semiconductor composition versus band gap is observed, which is not easily correlated with the observed variation in semiconductor structure. Even more interesting is the observation that the silver-rich branch of this "V" produces obviously highermore »
- Authors:
-
- Princeton Univ., NJ (United States)
- Publication Date:
- Research Org.:
- Princeton Univ., NJ (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1595072
- Grant/Contract Number:
- FG02-98ER45706
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Physical Chemistry. C
- Additional Journal Information:
- Journal Volume: 122; Journal Issue: 43; Journal ID: ISSN 1932-7447
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Platinum; Semiconductors; Electrical conductivity; Lattices; Materials
Citation Formats
Ni, Danrui, Kuo, Hsin-Ya, Park, James Eujin, Lee, Tia S., Sloman, Spyder-Rider I., Cava, Robert J., and Bocarsly, Andrew B. Improved H 2 Evolution in Quaternary SCIGS Chalcopyrite Semiconductors. United States: N. p., 2018.
Web. doi:10.1021/acs.jpcc.8b05389.
Ni, Danrui, Kuo, Hsin-Ya, Park, James Eujin, Lee, Tia S., Sloman, Spyder-Rider I., Cava, Robert J., & Bocarsly, Andrew B. Improved H 2 Evolution in Quaternary SCIGS Chalcopyrite Semiconductors. United States. https://doi.org/10.1021/acs.jpcc.8b05389
Ni, Danrui, Kuo, Hsin-Ya, Park, James Eujin, Lee, Tia S., Sloman, Spyder-Rider I., Cava, Robert J., and Bocarsly, Andrew B. Wed .
"Improved H 2 Evolution in Quaternary SCIGS Chalcopyrite Semiconductors". United States. https://doi.org/10.1021/acs.jpcc.8b05389. https://www.osti.gov/servlets/purl/1595072.
@article{osti_1595072,
title = {Improved H 2 Evolution in Quaternary SCIGS Chalcopyrite Semiconductors},
author = {Ni, Danrui and Kuo, Hsin-Ya and Park, James Eujin and Lee, Tia S. and Sloman, Spyder-Rider I. and Cava, Robert J. and Bocarsly, Andrew B.},
abstractNote = {In a search for improved photocathode materials for fuel-producing photoelectrochemical cells, quaternary AgxCu1-xGayIn1-yS2 (0 ≤ x ≤ 1.0, 0 ≤ y ≤ 1.0) p-type, chalcopyrite semiconductors (SCIGS) were prepared and tested for photochemical hydrogen evolution. The study reported here is based on the preparation of bulk phases of the quaternary system. In contrast to thin-film studies of this system, this approach enables enhanced control of the materials' chemical, structural, and electronic properties. Compared to ternary CIGS electrode materials, the quaternary SCIGS materials provide improved photoelectrochemical and electrocatalytic properties. The quaternary system allows for adjustment of the band structures and photocatalytic abilities to a finer degree than is possible in the AgxCu1-xGaS2 or AgxCu1-xInS2 ternaries, and several of the quaternary AgxCu1-xGayIn1-yS2 compositions are found to show better water-splitting capability than the ternaries, even when a platinum co-catalyst is present in the ternary systems. Our work on quaternary compounds has led to finding unexpected optoelectric properties in ternary compounds of composition AgxCu1-xGaS2. Specifically, a "V-shaped" plot of semiconductor composition versus band gap is observed, which is not easily correlated with the observed variation in semiconductor structure. Even more interesting is the observation that the silver-rich branch of this "V" produces obviously higher H2 evolution rates than observed with the copper-rich branch.},
doi = {10.1021/acs.jpcc.8b05389},
journal = {Journal of Physical Chemistry. C},
number = 43,
volume = 122,
place = {United States},
year = {Wed Sep 26 00:00:00 EDT 2018},
month = {Wed Sep 26 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
Electrochemical Photolysis of Water at a Semiconductor Electrode
journal, July 1972
- Fujishima, Akira; Honda, Kenichi
- Nature, Vol. 238, Issue 5358, p. 37-38
Band structure-controlled solid solution of Cd1-xCd1-x ZnxSZnxS photocatalyst for hydrogen production by water splitting
journal, November 2006
- Xing, C.; Zhang, Y.; Yan, W.
- International Journal of Hydrogen Energy, Vol. 31, Issue 14
Photocatalytic Water Splitting: Recent Progress and Future Challenges
journal, September 2010
- Maeda, Kazuhiko; Domen, Kazunari
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 18, p. 2655-2661
Water Splitting on Semiconductor Catalysts under Visible-Light Irradiation
journal, June 2009
- Navarro Yerga, Rufino M.; Álvarez Galván, M. Consuelo; del Valle, F.
- ChemSusChem, Vol. 2, Issue 6
Photoelectrochemical Study of Nanostructured ZnO Thin Films for Hydrogen Generation from Water Splitting
journal, June 2009
- Wolcott, Abraham; Smith, Wilson A.; Kuykendall, Tevye R.
- Advanced Functional Materials, Vol. 19, Issue 12
Nitrogen-Doped ZnO Nanowire Arrays for Photoelectrochemical Water Splitting
journal, June 2009
- Yang, Xunyu; Wolcott, Abraham; Wang, Gongming
- Nano Letters, Vol. 9, Issue 6
Visible-light-driven photocatalytic carbon-doped porous ZnO nanoarchitectures for solar water-splitting
journal, January 2012
- Lin, Yan-Gu; Hsu, Yu-Kuei; Chen, Ying-Chu
- Nanoscale, Vol. 4, Issue 20
Photoelectrochemical Decomposition of Water into H2 and O2 on Porous BiVO4 Thin-Film Electrodes under Visible Light and Significant Effect of Ag Ion Treatment
journal, May 2006
- Sayama, Kazuhiro; Nomura, Atsushi; Arai, Takeo
- The Journal of Physical Chemistry B, Vol. 110, Issue 23
Rapid Screening of BiVO 4 -Based Photocatalysts by Scanning Electrochemical Microscopy (SECM) and Studies of Their Photoelectrochemical Properties
journal, July 2010
- Ye, Heechang; Lee, Joowook; Jang, Jum Suk
- The Journal of Physical Chemistry C, Vol. 114, Issue 31
Photoelectrochemical water splitting using visible-light-responsive BiVO4 fine particles prepared in an aqueous acetic acid solution
journal, January 2010
- Iwase, Akihide; Kudo, Akihiko
- Journal of Materials Chemistry, Vol. 20, Issue 35
Nanoporous BiVO4 Photoanodes with Dual-Layer Oxygen Evolution Catalysts for Solar Water Splitting
journal, February 2014
- Kim, Tae Woo; Choi, Kyoung-Shin
- Science, Vol. 343, Issue 6174, p. 990-994
Efficient solar water splitting by enhanced charge separation in a bismuth vanadate-silicon tandem photoelectrode
journal, July 2013
- Abdi, Fatwa F.; Han, Lihao; Smets, Arno H. M.
- Nature Communications, Vol. 4, Issue 1
Low-Temperature Reactively Sputtered Tungsten Oxide Films for Solar-Powered Water Splitting Applications
journal, January 2006
- Miller, Eric L.; Marsen, Bjorn; Cole, Brian
- Electrochemical and Solid-State Letters, Vol. 9, Issue 7
Size effects of WO3 nanocrystals for photooxidation of water in particulate suspension and photoelectrochemical film systems
journal, May 2009
- Hong, Suk Joon; Jun, Hwichan; Borse, Pramod H.
- International Journal of Hydrogen Energy, Vol. 34, Issue 8
Preparation and characterization of (Zn,Cd)S photoelectrodes for hydrogen production
journal, November 1998
- Arriaga, L. G.; Fernández, A. M.; Solorza, O.
- International Journal of Hydrogen Energy, Vol. 23, Issue 11
High-performance CdS–ZnS core–shell nanorod array photoelectrode for photoelectrochemical hydrogen generation
journal, January 2015
- Zhang, Jian; Wang, Lianhui; Liu, Xiaoheng
- Journal of Materials Chemistry A, Vol. 3, Issue 2
Facile Fabrication of an Efficient Oxynitride TaON Photoanode for Overall Water Splitting into H 2 and O 2 under Visible Light Irradiation
journal, September 2010
- Abe, Ryu; Higashi, Masanobu; Domen, Kazunari
- Journal of the American Chemical Society, Vol. 132, Issue 34
Stable Hydrogen Evolution from an AgRhO 2 Photocathode under Visible Light
journal, March 2018
- Park, James Eujin; Hu, Yuan; Krizan, Jason W.
- Chemistry of Materials, Vol. 30, Issue 8
p -Type CuRhO 2 as a Self-Healing Photoelectrode for Water Reduction under Visible Light
journal, January 2014
- Gu, Jing; Yan, Yong; Krizan, Jason W.
- Journal of the American Chemical Society, Vol. 136, Issue 3
Photocatalytic water splitting using semiconductor particles: History and recent developments
journal, December 2011
- Maeda, Kazuhiko
- Journal of Photochemistry and Photobiology C: Photochemistry Reviews, Vol. 12, Issue 4
Development of photocatalyst materials for water splitting
journal, February 2006
- Kudo, A.
- International Journal of Hydrogen Energy, Vol. 31, Issue 2, p. 197-202
Photocatalytic H 2 Evolution under Visible-Light Irradiation over Band-Structure-Controlled (CuIn) x Zn 2(1 - x ) S 2 Solid Solutions
journal, April 2005
- Tsuji, Issei; Kato, Hideki; Kobayashi, Hisayoshi
- The Journal of Physical Chemistry B, Vol. 109, Issue 15
Characterization of Primary Carrier Transport Properties of the Light-Harvesting Chalcopyrite Semiconductors CuIn(S 1– x Se x ) 2
journal, July 2017
- Frick, Jessica J.; Kushwaha, Satya K.; Cava, Robert J.
- The Journal of Physical Chemistry C, Vol. 121, Issue 32
Chalcopyrite CuIn(S 1– x Se x ) 2 for Photoelectrocatalytic H 2 Evolution: Unraveling the Energetics and Complex Kinetics of Photogenerated Charge Transfer in the Semiconductor Bulk
journal, June 2018
- Frick, Jessica J.; Cava, Robert J.; Bocarsly, Andrew B.
- Chemistry of Materials, Vol. 30, Issue 13
Indium induced band gap tailoring in AgGa1−xInxS2 chalcopyrite structure for visible light photocatalysis
journal, April 2008
- Jang, Jum Suk; Borse, Pramod H.; Lee, Jae Sung
- The Journal of Chemical Physics, Vol. 128, Issue 15
Solution Transformation of Cu 2 O into CuInS 2 for Solar Water Splitting
journal, January 2015
- Luo, Jingshan; Tilley, S. David; Steier, Ludmilla
- Nano Letters, Vol. 15, Issue 2
Durable hydrogen evolution from water driven by sunlight using (Ag,Cu)GaSe 2 photocathodes modified with CdS and CuGa 3 Se 5
journal, January 2015
- Zhang, Li; Minegishi, Tsutomu; Nakabayashi, Mamiko
- Chemical Science, Vol. 6, Issue 2
Copper Indium Selenides and Related Materials for Photovoltaic Devices
journal, April 2002
- Stanbery, Billy J.
- Critical Reviews in Solid State and Materials Sciences, Vol. 27, Issue 2, p. 73-117
First-principles study on CuAlTe 2 and AgAlTe 2 for water splitting
journal, December 2014
- Huang, Dan; Ju, Zhiping; Ning, Hua
- Materials Chemistry and Physics, Vol. 148, Issue 3
Photocatalyst AgInS2 for active overall water-splitting: A first-principles study
journal, January 2014
- Huang, Dan; Persson, Clas
- Chemical Physics Letters, Vol. 591
Photoelectrochemical water reduction over wide gap (Ag,Cu)(In,Ga)S 2 thin film photocathodes
journal, January 2017
- Septina, Wilman; Sugimoto, Minori; Chao, Ding
- Physical Chemistry Chemical Physics, Vol. 19, Issue 19
Electronic structure and fundamental absorption edges of KPb2Br5, K0.5Rb0.5Pb2Br5, and RbPb2Br5 single crystals
journal, May 2012
- Tarasova, A. Yu.; Isaenko, L. I.; Kesler, V. G.
- Journal of Physics and Chemistry of Solids, Vol. 73, Issue 5
Visible Light Induced Catalytic Water Reduction without an Electron Relay
journal, October 2007
- Tinker, Leonard L.; McDaniel, Neal D.; Curtin, Peter N.
- Chemistry - A European Journal, Vol. 13, Issue 31
Heterogeneous photocatalytic preparation of supported catalysts. Photodeposition of platinum on titanium dioxide powder and other substrates
journal, June 1978
- Kraeutler, Bernhard; Bard, Allen J.
- Journal of the American Chemical Society, Vol. 100, Issue 13
Enhanced photocatalytic hydrogen production over In-rich (Ag–In–Zn)S particles
journal, July 2013
- Lin, Po-Chang; Wang, Pei-Ying; Li, Yuan-Yao
- International Journal of Hydrogen Energy, Vol. 38, Issue 20
Structural and Optical Properties of the Cu 1- x Ag x GaS 2 System
journal, August 1993
- Matsushita, Hiroaki; Endo, Saburo; Irie, Taizo
- Japanese Journal of Applied Physics, Vol. 32, Issue Part 2, No. 8A
Growth, structural and optical properties of non-stoichiometric CuIn(S1−xSex)2 thin films deposited by solution growth technique for photovoltaic application
journal, April 2006
- Chavhan, S.; Sharma, R.
- Journal of Physics and Chemistry of Solids, Vol. 67, Issue 4
Photocatalytic H 2 Evolution Reaction from Aqueous Solutions over Band Structure-Controlled (AgIn) x Zn 2(1 - x ) S 2 Solid Solution Photocatalysts with Visible-Light Response and Their Surface Nanostructures
journal, October 2004
- Tsuji, Issei; Kato, Hideki; Kobayashi, Hisayoshi
- Journal of the American Chemical Society, Vol. 126, Issue 41
Photochemical hydrogen production with cadmium sulfide suspensions
journal, July 1984
- Buehler, Niklaus; Meier, Kurt; Reber, Jean Francois
- The Journal of Physical Chemistry, Vol. 88, Issue 15
Photochemical production of hydrogen with zinc sulfide suspensions
journal, November 1984
- Reber, Jean Francois; Meier, Kurt
- The Journal of Physical Chemistry, Vol. 88, Issue 24